共查询到18条相似文献,搜索用时 62 毫秒
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在室温下测量了Znse-ZnTe应变层超晶格的光吸收谱,观测到对应于第一轻重空穴跃迁的吸收台阶.根据测量所得的超晶格带隙确定了ZnSe-ZnTe的价带不连续为1.10eV. 相似文献
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在16K至室温范围内测量了ZnSe-ZnS应变层超晶格的激子吸收谱.观测到对应于1E-1HH1E-1LH及1E-3HH跃迁的三个激子吸收峰. 相似文献
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本文给出了CaAs衬底上生长的ZnSe-ZnS应变超晶格的室温Raman分析,观测了该超晶格中ZnSe子层和ZnS子层的纵光学振动模(LO),首次发现在一些样品中ZnSe子层的纵光学声子模LOZnS出现红移,另一些样品中LOZnSe出现蓝移,而ZnS子层的LOZnS总是向低波数方向移动,并利用限制效应和应变效应给出了解释。 相似文献
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考虑到真实超晶格系统的有限宽度会造成晶格的非周期性 ,我们修正了用来决定拉曼频移峰值位置的公式中的倒格矢一项。在线性驰豫应变假设下给出了应变超晶格纵向原子间距的几何模型。在上述理论基础上计算了有限宽度的ZnSe/ZnTe应变超晶格LA声子的拉曼频移。数值计算结果同现有实验结果作了比较 ,符合很好。 相似文献
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Shang‐En Wu S. Dhara Tao‐Hung Hsueh Yi‐Feng Lai Cheng‐Yu Wang Chuan‐Pu Liu 《Journal of Raman spectroscopy : JRS》2009,40(12):2044-2049
The optical properties of focused ion beam‐engraved, perfectly aligned and spatially controlled multi‐quantum‐well (MQW) InGaN/GaN nanopillars were investigated. Crystalline MQW nanopillars with a diameter of 30–95 nm and high aspect ratios (7:1–16:1) showed a maximum of three‐fold enhancement in emission intensity per unit active area. A light‐emitting contour map of Taiwan is drawn with a nanopillar structure to demonstrate the site control of the technique adopted in the present study. Raman scattering studies were used to characterize the newly created surfaces. Unknown peaks in GaN and InGaN nanostructures are identified for surface optical (SO) phonon modes with proper assignments of wave vectors using multiple excitations, and the SO mode for the ternary phase is reported for the first time. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
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Evolution of the 128-cm-1 Raman phonon mode with temperature in Ba(Fe1-xCox)2As 2 (x = 0.065 and 0.2) 下载免费PDF全文
We report electronic Raman scattering measurements on Ba(Fei1-xCox)2As2(x = 0.065 and 0.2) single crystals with Raman shifts from 9 cm-1 up to 600 cm-1 in the symmetry of Blg with respect to 1 Fe unit cell.When the crystals are cooled down,the evident quasielastic peaks of Raman spectra occur only in the crystal with x = 0.065,which is due to the contribution of orbital ordering between xz and yz Fe 3d orbitals,as we reported in another work.Here,we analyze the Eg phonon at 128 cm-1,which has the same function form of its Raman tensors as those of xz and yz Fe 3d orbitals in these two crystals respectively.Unlike their electronic continuums,no anomalies are found in the Eg phonons of these two samples,which simply follows the expressions corresponding to the anharmonic phonon decay into acoustic phonons with the same frequencies and opposite momenta.Our results indicate that the structural and magnetic phase transition might be completely suppressed by chemical doping and there is not any indication of coupling between charge nematicity and Eg phonon mode from our experimental results,which is consistent with the results in our previous work. 相似文献
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Jingzhi Shang Chunxiao Cong Jun Zhang Qihua Xiong Gagik G. Gurzadyan Ting Yu 《Journal of Raman spectroscopy : JRS》2013,44(1):70-74
Few‐layer graphene grown by chemical vapor deposition has been studied by Raman and ultrafast laser spectroscopy. A low‐wavenumber Raman peak of ~120 cm−1 and a phonon‐induced oscillation in the kinetic curve of electron–phonon relaxation process have been observed, respectively. The Raman peak is assigned to the low‐wavenumber out‐of‐plane optical mode in the few‐layer graphene. The phonon band shows an asymmetric shape, a consequence of so‐called Breit‐Wigner‐Fano resonance, resulting from the coupling between the low‐wavenumber phonon and electron transitions. The obtained oscillation wavenumber from the kinetic curve is consistent with the detected low‐wavenumber phonon by Raman scattering. The origin of this oscillation is attributed to the generation of coherent phonons and their interactions with photoinduced electrons. Copyright © 2012 John Wiley & Sons, Ltd. 相似文献
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Qing‐Hu Zhong Rui‐Qiang Wang Liang‐Bin Hu Yu‐Zhen Yan Shou‐Liang Bu Xue‐Hua Yi 《Journal of Raman spectroscopy : JRS》2013,44(5):752-757
We have presented a theoretical calculation of the differential cross section for the electron Raman scattering process associated with the interface optical phonon modes in cylindrical GaAs quantum dots (QDs) with a AlAs matrix. We consider the Fröhlich electron–phonon interaction in the framework of the dielectric continuum approach. The selection rules for the processes are studied. Singularities are found to be sensitively size‐dependent, and, by varying the size of the QDs, it is possible to control the frequency shift in the Raman spectra. A discussion of the phonon behavior for QDs with different size is presented. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献
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S.W.H. Eijt R. Currat J.E. Lorenzo P. Saint-Grégoire B. Hennion Y.M. Vysochanskii 《The European Physical Journal B - Condensed Matter and Complex Systems》1998,5(2):169-178
The low frequency lattice dynamics and its relationship to the second order paraelectric-to-ferroelectric transition in Sn2P2S6 is studied. The dispersion branches of the acoustic and lowest lying optical phonons in the a*-c* plane have been obtained in the ferroelectric phase, for x-polarized phonons. Close to the phase transition a considerable softening is found for the lowest optical mode (Px), comparable to the behaviour observed in previous Raman investigations. As found previously in Sn2P2Se6, a strong coupling between the TO(Px) and TA(uxz) phonons is observed, although, apparently, not strong enough to lead to an incommensurate phase. The soft TO(Px) mode at the zone center is observed. The temperature dependence of its frequency and damping shows that the transition is
not entirely displacive. At low temperatures an unusual apparent negative LO-TO splitting is observed which is shown to arise
from the coupling of the x-polarized soft mode to the nearby z-polarized optical phonon. For comparison, the soft TO(Px) dispersion in the a*-b* plane is measured in both the paraelectric and ferroelectric phases. Consistent frequency changes and LO-TO splitting are
observed, revealing a significant interaction between the TA(uyx) and LA(uxx) acoustics branches and the TO and LO soft optic branches, respectively. In contrast, the nearby y-polarized optic branch shows almost no temperature dependence. Finally, the influence of piezoelectric effects on the limiting
acoustic slopes in the ferroelectric phase is discussed.
Received: 11 May 1998 / Revised and Accepted: 15 June 1998 相似文献
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Santanu Bhattacharya Anindya Datta Sandip Dhara Dipankar Chakravorty 《Journal of Raman spectroscopy : JRS》2011,42(3):429-433
Raman scattering studies were performed in GaN nanoribbons grown along [1 0 0]. These samples were prepared inside Na‐4 mica nanochannels by the ion‐exchange technique and subsequent annealing in NH3 ambient. Detailed morphological and structural studies including the crystalline orientation were performed by analyzing the vibrational properties in these GaN nanoribbons. Pressure in the embedded structure was calculated from the blue shift of the E2(high) phonon mode of GaN. Possible red shift of optical phonon modes due to the quantum confinement is also discussed. In addition to the optical phonons allowed by symmetry, two additional Raman peaks were also observed at ∼633 and 678 cm−1 for these nanoribbons. Calculations for the wavenumbers of the surface optical (SO) phonon modes in GaN in Na‐4 mica yielded values close to those of the new Raman modes. The SO phonon modes were calculated in the slab (applicable to belt‐like nanoribbon) mode, as the wavenumber and intensity of these modes depend on the size and the shape of the nanostructures. The effect of surface‐modulation‐assisted electron–SO phonon scattering is suggested to be responsible for the pronounced appearance of SO phonon modes. A scaling factor is also estimated for the interacting surface potential influencing the observed SO Raman scattering intensities. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
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AAO模板法制备CdS纳米微粒的SERS光谱研究 总被引:2,自引:1,他引:2
在自制的孔径约15nm多孔氧化铝模板上沉积银纳米粒子,然后用电化学方法在此衬底上沉积CdS纳米微粒。研究了CdS纳米阵列在457.5nm波长激光激发下的表面增强拉曼散射(SERS)性质。实验结果显示CdS的SERS信号有三个振动模式,分别对应1LO、2LO和3LO纵光学声子模,它们的强度随着作为SERS衬底的银纳米粒子高度的增加而增强,当银纳米粒子的长/径比(长度与直径的比值)达到4时,这种增强趋近饱和。最后对CdS纳米微粒光学声子模的增强机理进行了分析和讨论。 相似文献