PREPARATION OF LOW MOLECULAR WEIGHT POLY（GLYCIDYL METHACRYLATE） BY PHOTOPOLYMERIZATION

Low molecular weight poly（glycidyl methacrylate）s （PGMAs） were prepared by photopolymerization in ethyl acetate, with benzophenone （BP） as photoinitiator, and triethylamine （TEA） as hydrogen donor. The existence of semipinacol dormant end groups in PGMA was confirmed by FT-IR and ^1H-NMR, and the content of the semipinacol dormant groups was determined quantitatively by ^1H-NMR measurement. The effects of various thctors, such as reaction time, BP concentration and monomer concentration on the synthesis of the polymers were investigated systematically. The molecular weights of the polymers were also investigated with GPC. It is shown that increasing BP concentration and decreasing irradiation time and monomer concentration led to a significant decrease of the molecular weights.     

THE BIRCH REDUCTION OF（1－OXO－CYCLOHEXENYLO）－2＇－［2＇，3＇，b］－6，7－MEHYLENEDIOXYBENZOZEPINE

ＴＨＥＢＩＲＣＨＲＥＤＵＣＴＩＯＮＯＦ（１－ＯＸＯ－ＣＹＣＬＯＨＥＸＥＮＹＬＯ）－２＇－［２＇，３＇，ｂ］－６，７－ＭＥＨＹＬＥＮＥＤＩＯＸＹＢＥＮＺＯＺＥＰＩＮＥＪｉａｎｇＨｏｎｇＷＡＮＧ；ＹｕｎＺｈｅｎＪＩＡＮＧ；ＺｈｉＺｈｏｎｇＺＨＡＯ（Ｉｎｓ...     

UNUSUAL FORMATION OF ORGANO－NEODYMIUM AND －SAMARIUM CATIOHS AND X－RAY STRUCTURE OF［（MeOCH_2CH_2C_5H_4）_2Sm（thf）］［Co（CO）_4］

ＵＮＵＳＵＡＬ　ＦＯＲＭＡＴＩＯＮ　ＯＦ　ＯＲＧＡＮＯ－ＮＥＯＤＹＭＩＵＭ　ＡＮＤ　－ＳＡＭＡＲＩＵＭ　ＣＡＴＩＯＨＳ　ＡＮＤ　Ｘ－ＲＡＹ　ＳＴＲＵＣＴＵＲＥ　ＯＦ［（ＭｅＯＣＨ_２ＣＨ_２Ｃ_５Ｈ_４）_２Ｓｍ（ｔｈｆ）］［Ｃｏ（ＣＯ）_４］ＵＮＵＳＵＡ...     

［Cu_2（Gly－GlyO）_2（4，4＇－bpy）（OH）_2］·9H_2O

将Ｇｌｙ－ＧｌｙＯ、４，４＇－联吡啶与Ｃｕ（ＮＯ_３）_２·Ｈ_２Ｏ在二次水溶液中反应，合成出以４，４＇－ｂｐｙ为中继基、Ｃｌｙ－ＧｌｙＯ为螯环的新型双核铜配合物，经Ｘ射线单晶结构分析确定该配合物晶体的化学结构式为［（Ｈ_２ＮＣＨ_２ＣＯＮＨＣＨ_２ＣＯＯ）Ｃｕ（ＯＨ）（Ｃ_（１０）Ｈ_８Ｎ_２）Ｃｕ（ＯＮ）（Ｈ_２ＮＣＨ_２ＣＯＮＨＣＨ_２ＣＯＯ）］·９Ｈ_２Ｏ．晶体属Ｐ　空间群，晶胞参数ａ＝１．１４１２ｎｍ，ｂ＝１．２２９８ｎｍ，ｃ＝１．４２６９ｎｍ，α＝１１３．８２°，β＝１０１．９１°，γ＝１０３．６４°，Ｚ＝２．最终一致性因子Ｒ值为０．０６８，Ｒ_ｗ值为０．０５７，标准偏差σ＝０．１９５１。     

Synthesis and Crystal Structure of Pyridine－2－thiolato－Molybdenum Complex［Et_4N］［Mo（CO_4）（pyS）］

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＰｙｒｉｄｉｎｅ－２－ｔｈｉｏｌａｔｏ－ＭｏｌｙｂｄｅｎｕｍＣｏｍｐｌｅｘ［Ｅｔ_４Ｎ］［Ｍｏ（ＣＯ_４）（ｐｙＳ）］ＹｕＰｅｉ－Ｈｕａ；ＨｕａｎｇＬｉａｎｇ－Ｒｅｎ；ＺｈｕａｎｇＢｏ－Ｔａｏ...     

Crystal Structure of μ－［meso－1，2－Bis（n－propylsulphinyl）ethane］－（O，O＇）－［diphenyltin（Ⅳ）dichloride］

ＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆμ－［ｍｅｓｏ－１，２－Ｂｉｓ（ｎ－ｐｒｏｐｙｌｓｕｌｐｈｉｎｙｌ）ｅｔｈａｎｅ］－（Ｏ，Ｏ＇）－［ｄｉｐｈｅｎｙｌｔｉｎ（Ⅳ）ｄｉｃｈｌｏｒｉｄｅ］￥ＹｕＸｉ－Ｌｉｎ；ＢａｏＪｉａｎ－Ｃｈｕｎ；ＳｈａｏＰｉｎ－Ｘ...     

ELECTRON TRANSFER AGENT DEPENDENCY OF MONOOXYGENATION OF CYCLOHEXANE CATALYZED BY SILICA IMMOBILIZED N，N＇－BIS［2－（BENZIMIDAZOLYLMETHYL）］AMINO FERROUS ACETATE COMPLEX

ＥＬＥＣＴＲＯＮＴＲＡＮＳＦＥＲＡＧＥＮＴＤＥＰＥＮＤＥＮＣＹＯＦＭＯＮＯＯＸＹＧＥＮＡＴＩＯＮＯＦＣＹＣＬＯＨＥＸＡＮＥＣＡＴＡＬＹＺＥＤＢＹＳＩＬＩＣＡＩＭＭＯＢＩＬＩＺＥＤＮ，Ｎ＇－ＢＩＳ［２－（ＢＥＮＺＩＭＩＤＡＺＯＬＹＬＭＥＴＨＹＬ）］ＡＭ...     

Synthesis and Crystal Structure of Pyridine－2，6－dicarboxylate Vanadium Complex：［（Pyridine－2，6－dicarboxylate）VO_2］_2［4，4＇－bipyridine］·4H_2O

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆＰｙｒｉｄｉｎｅ－２，６－ｄｉｃａｒｂｏｘｙｌａｔｅＶａｎａｄｉｕｍＣｏｍｐｌｅｘ：［（Ｐｙｒｉｄｉｎｅ－２，６－ｄｉｃａｒｂｏｘｙｌａｔｅ）ＶＯ_２］_２［４，４＇－ｂｉｐｙｒｉｄｉｎｅ］·...     

THE STUDY OF STRUCTURE AND DYNAMICS OF DINUCLEAR COMPLEXES ［Mo（VI）］_2－EDTA AND ［Mo（VI）］_2－EGTABY~1HNMR

ＴＨＥＳＴＵＤＹＯＦＳＴＲＵＣＴＵＲＥＡＮＤＤＹＮＡＭＩＣＳＯＦＤＩＮＵＣＬＥＡＲＣＯＭＰＬＥＸＥＳ［Ｍｏ（ＶＩ）］_２－ＥＤＴＡＡＮＤ［Ｍｏ（ＶＩ）］_２－ＥＧＴＡＢＹ~１ＨＮＭＲＲｕｉＦａｎｇＳＯＮＧ；ＦｅｉＬＩ；ＧｕａｎｇＭｉｎＬＩＵ；ＹｏｕＧａ?..     

［Li（THF）_4］［（t－BuCp）Yb（NPh_2）_3］的合成及晶体结

合成了标题配合物［Ｌｉ（ＴＨＦ）＿４］［ｔ－ＢｕＣｐ）Ｙｂ（ＮＰｈ＿２）＿３］，经元素分析、红外光谱表征，并测定了其晶体结构。配合物属正交晶系，Ｐｂｃａ空间群，晶体学参数ａ＝１．４５１５（５），ｂ＝２．２８３３（５），ｃ＝３．３５５４（６）ｎｍ；Ｖ＝１１．１２０９（５）ｎｍ￣３；Ｄ＿ｃ＝１．３１ｇ·ｃｍ￣＿（－３）；Ｆ（０００）＝４４．２３，Ｚ＝８。最后一致性因子Ｒ＝０．０４７，Ｒ＿ｗ＝０．０４５，平均Ｙｂ－Ｎ键长是０．２２６４（９）ｎｍ。     

聚甲基丙烯酸4［（4＇－硝基－1＇硫酰基苯）－1－羟烷氧基本基］酯的合成

new series of sulfur-contalning side chain liquid crystalline polymers were described. Mesomorphic side chains with methylene spacer in different length have been synthesized and their structures were identified by NMR, IR and MS.The liquid crystalline nature of the polymers was characterlzed by microscopy.The Polymers have liquid crystalline nature.     

REACTIVE POLY（ARYLENEETHERSULPHONE） ：MALEIMIDE－TERMINATED POLY（ARYLENEETHERSULPHONE） OLIGOMERS USING N－（4－HYDROXYPHENYL） MALEIMIDE AS AN ENDBLOCKING MONOMER

ＲＥＡＣＴＩＶＥ　ＰＯＬＹ（ＡＲＹＬＥＮＥＥＴＨＥＲＳＵＬＰＨＯＮＥ）　：ＭＡＬＥＩＭＩＤＥ－ＴＥＲＭＩＮＡＴＥＤ　ＰＯＬＹ（ＡＲＹＬＥＮＥＥＴＨＥＲＳＵＬＰＨＯＮＥ）　ＯＬＩＧＯＭＥＲＳ　ＵＳＩＮＧ　Ｎ－（４－ＨＹＤＲＯＸＹＰＨＥＮＹＬ）　ＭＡＬＥ...     

聚甲基丙烯酸4［（4＇－硝基－1＇硫酰基苯）－1－羟烷氧基本基］酯的合成

聚甲基丙烯酸４［（４＇－硝基－１＇硫酰基苯）－１－羟烷氧基本基］酯的合成张维邦，蒋，许家瑞，曾汉民（中山大学材料科学研究所广州５１０２７５）关键词含硫液晶单元，侧链液晶高分子，液晶合成与表征侧链高分子液晶是高分子液晶的重要组成部分，是当前高分子科学中...     

Synthesis and Crystal Structure of［Tris（2－benzimidazylmethyl）amine］［Imidazole］Copper（Ⅱ）Perchlorate

ＳｙｎｔｈｅｓｉｓａｎｄＣｒｙｓｔａｌＳｔｒｕｃｔｕｒｅｏｆ［Ｔｒｉｓ（２－ｂｅｎｚｉｍｉｄａｚｙｌｍｅｔｈｙｌ）ａｍｉｎｅ］［Ｉｍｉｄａｚｏｌｅ］Ｃｏｐｐｅｒ（Ⅱ）ＰｅｒｃｈｌｏｒａｔｅＺｈｏｕＷｅｉ－Ｈｏｎｇ；ＬｉｕＸｉａｏ－Ｌａｎ；ＭｉａｏＦａ...     

TRANSFER HYDROGENATION OF KETONES BY PROPAN－2－OL OVER POLY（PHENYLENE OXIDE） ANCHORED RUTBENIUM CATALYST

ＴＲＡＮＳＦＥＲ　ＨＹＤＲＯＧＥＮＡＴＩＯＮ　ＯＦ　ＫＥＴＯＮＥＳ　ＢＹ　ＰＲＯＰＡＮ－２－ＯＬ　ＯＶＥＲ　ＰＯＬＹ（ＰＨＥＮＹＬＥＮＥ　ＯＸＩＤＥ）　ＡＮＣＨＯＲＥＤ　ＲＵＴＢＥＮＩＵＭ　ＣＡＴＡＬＹＳＴ￥ＨａｎＲｏｎｇＧＡＯ；ＹｕｎＸＵ；ＳｈｉＪ...     

N，N＇－二（乙酰芳香环）－穴醚［2，2］的合成

Ｎ，Ｎ＇－二（乙酰芳香环）－穴醚［２，２］的合成余江，许振华，徐光宪（北京大学化学与分子工程学院，稀土材料化学及应用国家重点实验室，北京，１００８７１）关键词大环，穴醚［２，２］，ＨＴＴＡ穴醚（Ｃｒｙｐｔａｎｄ）是含有Ｏ及Ｎ和Ｓ等杂原子的多聚大环化合...     

Synthesis and Structure of the Hexanuclear Diazenido－oxomolybdate ［（n－C_4H_9）_4N］_3［Mo_6O_（18）（N_2C_6H_4－p－NO_2）］

ＳｙｎｔｈｅｓｉｓａｎｄＳｔｒｕｃｔｕｒｅｏｆｔｈｅＨｅｘａｎｕｃｌｅａｒＤｉａｚｅｎｉｄｏ－ｏｘｏｍｏｌｙｂｄａｔｅ［（ｎ－Ｃ_４Ｈ_９）_４Ｎ］_３［Ｍｏ_６Ｏ_（１８）（Ｎ_２Ｃ_６Ｈ_４－ｐ－ＮＯ_２）］ＬｉＨａｉ－Ｌｉａｎ；ＹｏｕＸｉａｏ－Ｚｅｎｇ；...     

cis－［Pt（NH_3）_2Cl_2］和trans－［Pt（NH_3）_2Cl_2］的微型合成

ｃｉｓ－［Ｐｔ（ＮＨ_３）_２Ｃｌ_２］和ｔｒａｎｓ－［Ｐｔ（ＮＨ_３）_２Ｃｌ_２］的微型合成袁书玉，来月英（清华大学化学系，北京１０００８４）ｃｉｓ－［Ｐｔ（ＮＨ２）２Ｃｌ２］为一抗癌药物，而它的反式异构体却没有这一特性。其原因也已在进行研究［１］。由...     

AN EFFICIENT AND STEREOSPECIFIC SYNTHESIS OF 1－PALMITOYL－2－［（z，z，z）－9，12，15－LINOLENOYL］－SN 2－GLYCEROPHOSPHOCHOLINE

ＡＮＥＦＦＩＣＩＥＮＴＡＮＤＳＴＥＲＥＯＳＰＥＣＩＦＩＣＳＹＮＴＨＥＳＩＳＯＦ１－ＰＡＬＭＩＴＯＹＬ－２－［（ｚ，ｚ，ｚ）－９，１２，１５－ＬＩＮＯＬＥＮＯＹＬ］－ＳＮＧＬＹＣＥＲＯＰＨＯＳＰＨＯＣＨＯＬＩＮＥ￥ＪｉｅＸＩＡａｎｄＹｏｎｇＺｈｅｎｇＨ...     

PRACTICAL METHOD FOR SYNTHESIS OF NEW GLYCOLIPIDS N－［4（DIALKYL－L－GLUTAMATECARBONYLETHYLCARBO－NYLAMINO）BUTYL］LACTOBIONAMIDES

ＰＲＡＣＴＩＣＡＬＭＥＴＨＯＤＦＯＲＳＹＮＴＨＥＳＩＳＯＦＮＥＷＧＬＹＣＯＬＩＰＩＤＳＮ－［４（ＤＩＡＬＫＹＬ－Ｌ－ＧＬＵＴＡＭＡＴＥＣＡＲＢＯＮＹＬＥＴＨＹＬＣＡＲＢＯ－ＮＹＬＡＭＩＮＯ）ＢＵＴＹＬ］ＬＡＣＴＯＢＩＯＮＡＭＩＤＥＳ￥ＺｈｏｎｇＺｈｉ...