冲击加载下Zr51Ti5Ni10Cu25Al9金属玻璃的塑性行为

进行了10—27 GPa应力范围内Zr₅₁Ti₅Ni₁₀Cu₂₅Al₉金属玻璃的平面冲击实验以研究其高压-高应变率加载下的塑性行为.由样品自由面粒子速度剖面的分析获得了冲击加载过程的轴向应力,并通过轴向应力与静水压线的比较获得剪应力.实验结果表明,尽管存在明显的松弛效应,但Zr基金属玻璃的Hugoniot弹性极限随着冲击应力的增加而增加.然而,塑性波阵面上的剪应力则显示先硬化而后软化现象,而且软化的幅度随冲击应力的增加而增加.冲击加载下Zr基金属玻璃的上述剪应力变化特征与分子动力学模拟结果比较一致,但与压剪实验结果和一维应力冲击实验结果明显不同.     

Effect of a fullerene C60 addition on the strength properties of nanocrystalline copper and aluminum under shock-wave loading

The Hugoniot elastic limit and the spall strength of aluminum and copper samples pressed from a mixture of a metallic powder and 2–5 wt % C₆₀ fullerene powder are measured under a shock loading pressure up to 6 GPa and a strain rate of 10⁵ s^?1 by recording and analyzing full wave profiles using a VISAR laser interferometer. It is shown that a 5% C₆₀ fullerene addition to an initial aluminum sample leads to an increase in its Hugoniot elastic limit by an order of magnitude. Mixture copper samples with 2% fullerene also exhibit a multiple increase in the elastic limit as compared to commercial-grade copper. The elastic limits calculated from the wave profiles are 0.82–1.56 GPa for aluminum samples and 1.35–3.46 GPa for copper samples depending on the sample porosity. The spall strength of both aluminum and copper samples with fullerene additions decreases approximately threefold because of the effect of high-hardness fullerene particles, which serve as tensile stress concentrators in a material under dynamic fracture.     

The Influence of the Cobalt Content on the Strength Properties of Tungsten Carbide Ceramics under Dynamic Loads

Based on the registration and analysis of the full wave profiles, the Hugoniot elastic limit and spall strength of ceramics based on tungsten carbide with different cobalt content are measured. We also study the influence of the cobalt content on the mechanical characteristics of tungsten carbide such as hardness, fracture strength, Young’s modulus, shear modulus, and sound velocity. It is shown that in the process of spalling, the failure stresses grow and the dynamic elastic limit decreases almost linearly within the scatter of their values with growing cobalt content; moreover, the value of the Hugoniot elastic limit is abruptly practically halved as the cobalt content grows from 0 to 2 wt %.     

Bestimmung von Oszillatorenstärken durch Lebensdauermessungen der ersten angeregten Niveaus für die Elemente Ba,Sr, Ca,In und Na

The lifetimes of the first excited state of the elements Ca, Sr, Ba, In and Na were measured with the method ofOsberghaus ¹. Oscillator strengthes (f) of resonance lines were computed from the measured lifetimes (τ). The measurements were corrected for imprisonment of radiation in the investigated vapor. The error of the τ-values was estimated to be approximately three percent. We got following resultslifetimes for Ca 4¹ P ₁ (4·67±0·11)·10^?9sec, for Sr 5¹ p ₁ (4·56±0·21)·10^?9 sec, for Ba 6¹ p ₁ (8·36±0·25)·10^?9sec, for In 6² S _1/2 (8·531±0·085)·10^?9sec and for Na 3² P-dublett (1·59±0·039)·10^?8sec. For the Na 3² P-dublett the dependency of the lifetime on the pressure of foreign gases (N₂, C₃H₈, C₆H₅?CH₃) was studied.     

Elastische und unelastische Streuung von Elektronen an Gasen

The theoretical differential cross section for the elastic scattering and for the excitation of optical transitions in helium by electron impact has been refined in Born approximation by use of the two parameter Eckart eigenfunction for the ground state and for the excited states. The angular distributions of 25 kev electrons scattered elastically and inelastically by helium were measured in the angular range 2·3·10^?4≦?≦4·10^?2. The intensity distribution of the elastically scattered electrons is in accordance with the theoretical curve for?>7·10^?3 and is disturbed at smaller angles by the primary beam. Normalization of the experimental values to the theoretical elastic differential cross section leads to agreement between the experimental differential cross section for the excitation of the 2¹ P and 3¹ P state and the scattering formulae given in this paper. There are small systematic deviations (<20%) for the 2¹ P differential cross section in the angular range 3·10^?3<?<1·10^?2 only. The oscillator strength of these two transitions has been determined from the scattering measurements:f ₂₁=0·312±0·04 andf ₃₁=0·0898±0·006.     

Mößbauereffekt in FeCl2, FeSO4 und FeSO4 · 7 H2O

Mößbauereffect measurements were performed with FeCl₂, FeSO₄ and FeSO₄ · 7 H₂O in the temperature range between 5 and 300 ?K. The quadrupole splittings at 5 ?K were determined to be (1.300±0.027) mm/sec, (3.650±0.053) mm/sec, and (3.350±0.053) mm/sec respectively. From the temperature dependence of the quadrupole splittings it follows that in FeCl₂ the energy of the excited 3d-electron-level isδ=150 cm^?1, in FeSO₄ δ ₁=360 cm^?1 andδ ₂=1680 cm^?1 and in FeSO₄ · 7 H₂Oδ ₁=480 cm^?1 andδ ₂=1300 cm^?1. The magnitudes of the magnetic field at the iron nucleus at 5 ?K are (202±8) kOe for FeSO₄ and (0±4) kOe for FeCl₂.     

First-principles study of structural,elastic, electronic and thermodynamic properties of topological insulator Bi2Se3 under pressure

The structural, elastic, electronic and thermodynamic properties of the rhombohedral topological insulator Bi₂Se₃ are investigated by the generalized gradient approximation (GGA) with the Wu–Cohen (WC) exchange-correlation functional. The calculated lattice constants agree well with the available experimental and other theoretical data. Our GGA calculations indicate that Bi₂Se₃ is a 3D topological insulator with a band gap of 0.287 eV, which are well consistent with the experimental value of 0.3 eV. The pressure dependence of the elastic constants C_ij, bulk modulus B, shear modulus G, Young’s modulus E, and Poisson’s ratio σ of Bi₂Se₃ are also obtained successfully. The bulk modulus obtained from elastic constants is 53.5 GPa, which agrees well with the experimental value of 53 GPa. We also investigate the shear sound velocity V_S, longitudinal sound velocity V_L, and Debye temperature Θ_E from our elastic constants, as well as the thermodynamic properties from quasi-harmonic Debye model. We obtain that the heat capacity C_v and the thermal expansion coefficient α at 0 GPa and 300 K are 120.78 J mol^?1 K^?1 and 4.70 × 10^?5 K^?1, respectively.     

Dipolar studies in CaF2 with Ce3+

Dielectric relaxation in CaF₂ doped with various amounts of Ce³⁺ (0·01 to 1·0 mol%) was measured. The value of the activation energy for orientation of the dipoles {Ce³⁺-F^? interstitial} was determined to be H = (0·46 ± 0·01) eV. The frequency factor was found to have the value τ_o = (5 ± 1) × 10^?15 sec, giving for the vibrational frequency of the interstitial the value ν_o = (5 ± 1) × 10¹³ sec^?1.The number of dipoles contributing to the dielectric loss peak was determined to be between 10¹⁷ and 8 × 10¹⁷ cm^?3 for the different doping amounts of Ce³⁺. Optical absorption measurements showed the existence of large aggregate bands. We could verify that there exists a second-order reaction of aggregation, which is responsible for the non-linearity found between optical absorption at 305 nm and the nominal concentration of Ce³⁺ in the samples. On the other hand, if we assume that the centers which contribute to optical absorption at 305 nm are those also responsible for the relaxation peak, we find that the number contributing to each process is not the same. We can define an interaction radius R as the minimum separation between two dipoles allowing them to contribute to the relaxation peak. From our experimental data R ? 3·8 × 10^?7 cm.     

Messung der Lebensdauer angeregter Kernniveaus von Al28, Cs133, Pr141, W182 und Pt195

The halflife of excited states in some nuclei has been measured by the method of delayed coincidences. Two different experimental arrangements have been used: a conventional scintillation counter equipment and a fast gasfilled parallelplate avalanche-counter. The results of these measurements are: 31 keV-level in Al²⁸:T _1/2=(1.91±0.08) · 10^?9 sec, 81 keV-level in Cs¹³³:T _1/2=(6.25±0.05) · 10^?9 sec, 145 keV-level in Pr¹⁴¹:T _1/2=(1.85±0.03) · 10^?9 sec, 100keV-level in W¹⁸²:T _1/2=(1.45±0.04) · 10^?9 sec, 1290 keV-level in W¹⁸² T _1/2=(1.05±0.03) · 10^?9 sec, 99 keV-level in Pt¹⁹⁵:T _1/2≦1.6 · 10^?10 sec, 129 keV-level in Pt¹⁹⁵:T _1/2=(6.2±0.7) · 10^?10 sec. These experimental values are discussed and compared with theoretical model predictions.     

High strain rate deformation and fracture of the magnesium alloy Ma2-1 under shock wave loading

This paper presents the results of measurements of the dynamic elastic limit and spall strength under shock wave loading of specimens of the magnesium alloy Ma2-1 with a thickness ranging from 0.25 to 10 mm at normal and elevated (to 550°C) temperatures. From the results of measurements of the decay of the elastic precursor of a shock compression wave, it has been found that the plastic strain rate behind the front of the elastic precursor decreases from 2 × 10⁵ s^?1 at a distance of 0.25 mm to 10³ s^?1 at a distance of 10 mm. The plastic strain rate in a shock wave is one order of magnitude higher than that in the elastic precursor at the same value of the shear stress. The spall strength of the alloy decreases as the solidus temperature is approached.     

Elastic properties of Se and As2Se3 glasses under pressure and temperature

The sound velocities and their pressure and temperature variations of Se and As₂Se₃ glasses have been determined by means of a pulse superpositions method, and other elastic constants and their pressure and temperature derivatives were calculated from these data. The bulk modulus was found to be 94·6 kbar for Se glass and 143·7 kbar As₂Se₃ glass, both of which are higher than the values calculated from the previous compression data. No anomaly was observed in any of the pressure and temperature dependence of elastic behavior of these glassses. Furthermore, the comparison of the pressure and temperature derivatives of the bulk modulus indicates that the thermodynamic self-consistency is satisfied on these materials. The bulk moduli of these glasses and crystalline As and Se were used to obtain an empirical bulk modulus-volume relationship for compounds in the As?Se system. The acoustic Grüneisen parameter was calculated and compared with the thermal Grüneisen parameter.     

Amorphous germanium III. Optical properties

The optical properties of thick sputtered films (～30μ) of amorphous Ge, grown with different substrate temperatures (0ˇ-T _sˇ-350°C), were obtained between 0·05 and 4·5 eV by a combination of reflectance, transmittance and ellipsometric measurements. The refractive index at 0·15 eV decreases monotonically with increasing T _s, or equivalently, with increasing density, and is 4·13±0·05 eV in the highest density films. The absorption edge is approximately exponential (10²?α?10⁴ cm^?1) but shifts monotonically to higher energy and increases in slope with increasing T _s. Similarly, the peak in ε₂ grows by about 10% and shifts by about 0·15 eV to higher energies, reaching a maximum of about 23 at 2·90±0·05 eV in the high density films. The peak in the transition strength ω²ε₂ occurs at 4·2±0·2 eV in all films, but increases in magnitude with increasing T _s. The sum rules for n _eff(ω) and ε_0,eff(ω) are evaluated for ▄ω?5 eV and vary monotonically with T _s. These trends are neither compatible with Galeener's void resonance theory nor with changes in the oxygen content of the films, determined by the examination of absorption peaks at 0·053 eV and 0·09 eV. An explanation, suggested here and expanded in I, is based on the observed changes in the structure of the network and voids.     

Messung der Verweilzeit von He-Atomen an Glasoberflächen

Mean sticking times of helium on a glass surface are determined at very low pressures from nonstationary molecular flow through glass capillaries. The temperature range covered is 13.8 °K to 20.4 °K. Resulting sticking times are of the order of 10^?7 to 10^?5 sec. They show a characteristic dependence on temperature and pressure. These measurements can be interpreted by means of a simple model: He-atoms mostly are bound to the surface with an adsorption energyE of 229 cal/mol?0.01 eV (±20%). However with a probability of 10^?4 the energy is 530 cal/mol?0.023 eV (±6%). In both cases sticking times τ follow the equation τ=τ₀exp(E/RT) where τ₀ is about 10^?9 to 10^?10 sec.     

The Effect of Small Additions of Carbon Nanotubes on the Mechanical Properties of Epoxy Polymers under Static and Dynamic Loads

The results of measurements of the mechanical characteristics of cured epoxy composites containing small and ultrasmall additions of single-walled carbon nanotubes in the concentration range from 0 to 0.133 wt % under static and dynamic loads are presented. Static measurements of strength characteristics have been carried out under standard test conditions. Measurements of the Hugoniot elastic limit and spall strength were performed under a shock wave loading of the samples at a deformation rate of (0.8–1.5) ß 10⁵ s^-1 before the fracture using explosive devices by recording and subsequent analyzing the evolution of the full wave profiles. It has been shown that agglomerates of nanotubes present in the structure of the composites after curing cause a significant scatter of the measured strength parameters, both in the static and in the dynamic test modes. However, the effects of carbon nanotube additions in the studied concentration interval on the physical and mechanical characteristics of the parameters were not revealed for both types of loading.     

Interatomic force constants studies of AMF3perovskite-type crystals (A = K,Rb; M = Mg,Ni, Co,Zn, Mn)

A simple model involving only three force constants allows us to evaluate the short range interactions in perovskite fluorides from the experimental values of the elastic constants and the lattice parameters of these compounds. The results indicate that the A-F bonds are quite central in character whereas the M-F bonds are axially symmetric; thus the short range A-F interactions are assumed to have the Born-Mayer form:ZZZZZBy studying the variations of the force constants with respect to the lattice parameter r, it is determined that ρ = 0·232 , λ = 2·8 × 10^?8 ergs for K⁺-F^?; ρ = 0·232 , λ = 4·1 × 10^?8 ergs for Rb⁺-F^?; λ₂, ρ₂ and ρ₂ are respectively 6·9 × 10^?10 ergs, 0·34 , 0·98for Co²⁺-F^? and 2·9 × 10^?10 ergs, 0·46 , 1·40for Mn²⁺-F^?. Taking into account both the short range repulsive potential and the long range electrostatic potential we can study the variations of the lattice energy as a function of r near the equilibrium position and deduce a theoretical value of the lattice distance. In spite of the simplicity of the model, the discrepancy between the experimental and the theoretical values is less than 10 per cent for all the compounds.     

Phonon coupled cooperative low-spin 1A1high-spin 5T2 transition in [Fe(phen)2(NCS)2] and [Fe(phen)2(NCSe)2] crystals

Heat capacities of [Fe(phen)₂(NCS)₂] and [Fe(phen)₂(NCSe)₂] were measured between 13⁵ and 375 K. A heat capacity anomaly due to the spin-transition from low-spin ¹A₁ to high-spin π₂ electronic ground state was found at 176·29 K for the SCN-compound and at 231·26 K for the SeCN-compound, respectively. Enthalpy and entropy of transition were determined to be ΔH = 8·60 ± 0·14 kJ mol^?1 and ΔS = 48·78 ± 0·71 J K^?1 mol^?1 for the SCN-compound and ΔH = 11·60 ± 0·44 kJ mol^?1 and ΔS = 51·22 ± 2·33 J K^?1 mol^?1 for the SeCN-compound. To account for much larger value of ΔS compared with the magnetic contribution, we suggest that there is significant coupling between electronic state and phonon system. We also present a phenomenological theory based on heterophase fluctuation. Gross aspects of magnetic, spectroscopic, and thermal behaviors were satisfactorily accounted for by this model. To examine closely the transition process, infrared spectra were recorded as a function of temperature in the range 4000 ? 30 cm^?1. The spectra revealed clearly the coexistence of the ¹A₁, and the ⁵T₂ ground states around T_c.     

Microwave cyclotron resonance of hot electrons in p-type GaSb

A microwave photocreated cyclotron resonance signal is observed in p-type GaSb in the temperature range 1–30 K. Circular polarization and other measurements identify the carriers as electrons in the (000) conduction band. The problem of a surface effect on the measured peak position, reported for the first time is avoided by bulk carrier creation. An exponential loss of signal intensity at 27 K is explained by the theory of background plasma effects. The measured ωτ of 1·5–4 yields an electron collision time of τ ～ 10^?11 sec. The scattering mechanism at liquid helium temperatures is identified as being partly due to neutral defect acceptor scattering of hot electrons, with an unidentified residual scattering process. The electron polaron effective mass is measured to be (m *(polaron)/m₀) = 0·0412 ± 0·0012 for hot electrons with an average energy of ～ 14 MeV and is isotropic within 1 per cent. When corrections for conduction-band non-parabolicity and hot polaron effects are applied, the band-edge free electron mass is calculated to be (m₀*(free)/m₀) = 0·0396 ± 0·0021 (±5·2 per cent).     

The exciton absorption in deformed germanium

Absorption spectra at 77° K near the direct (κ = 0) exciton transition are reported for deformed and undeformed single-crystal films of n-type Ge oriented on (111); Elliott's theory is applied. The optical width of the forbidden band for this transition is found as E_{g 0} = (0.8821 ±±0.0002) eV, while the exciton binding energy is found as E_ex(0) = = (0.0016±0.0003) eV for undeformed Ge at 77 ° K. The mean temperature coefficient of E_g for κ = 0 in the range 77 °–297 ° K is (dE_g/ /dT)_p =?3.50 · 10^?4 eV/deg. The effects of thermoelastic deformation on the exciton spectrum give (dE_g/dT)_d = (?1.5±0.1) · 10^?4 eV/deg. The half-width σ ≈ 5 · 10^?4 eV of the exciton peak gives the exciton lifetime as gt ≥ 10^?12 sec.     

Use of smoke samples in diamond-anvil cells to measure pressure dependence of optical spectra: Application to the ZnO exciton

We present measurements of ZnO exciton peak energies, E₀, at pressures up to 107.3 kbar. Smoke samples consisting of randomly oriented single crystal particles were prepared by oxidizing metallic zinc in air and were collected on one diamond face of a Merrill-Bassett pressure cell. Pressures were measured by the ruby fluorescence technique. In the pressure range between 5 and 90 kbar, our results indicate a consistent linear dependence with dE₀/dP = 2.33 × 10^?3 eV kbar^?1 for both increasing and decreasing pressures. A mixed phase structure is suggested by the observed irregular peak shapes and measured pressure dependence for the sample that had been taken beyond ? 90 kbar where the transformation to the NaCl structure has been reported.     

Magneto-acoustic attenuation in AuSb2

Quantum oscillations in the ultrasonic attenuation in AuSb₂ were studied as a function of temperature, magnetic field and crystal orientation. The effective masses of the carriers associated with the F₅ and F₆ oscillations were measured in a (110) plane. For the F₅ oscillations, the Dingle temperature and apparent magnetic breakdown field appear to depend strongly upon orientation. For the F₆ oscillations, however, there were no signs of magnetic breakdown up to the highest magnetic fields available (70 kOe) and the Dingle temperature was roughly independent of orientation. From the acoustic velocities, the elastic constants were determined at 77 K: C₁₁ = (14·7 ± 0·9) × 10¹¹ dyne/cm², C₁₂ = (6·0 ± 0·9) × 10¹¹ dyne/cm², and C₄₄ = (2·59 ± 0·06) × 10¹¹ dyne/cm². These elastic constants give an adiabatic compressibility K_s = (1·13 ± 0·12) × 10^?12 cm²/dyne and a Debye temperature ?_D = (203 ± 15) K.