Coriolis intensity perturbations in the SO2 molecule: Experimental determination of the relative signs of (∂μ∂Qi)

The Coriolis interactions between ν₁ and ν₃, and between ν₂ and ν₃ in SO₂ have been analyzed to obtain the signs of the products $\text{ζ}{}_{3.1}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_1\text{)}$ and $\text{ζ}{}_{3.2}{}^{\mathrm{c}}\text{(}\text{?μ}{}^{\mathrm{a}}\text{?Q}{}_3\text{)(}\text{?μ}{}^{\mathrm{b}}\text{?Q}{}_2\text{)}$. It has been found that both of the signs of these products are positive. Then, relative signs of ($\text{?μ}\text{?Q}{}_1$) have been determined using the calculated values of the Coriolis zeta constants for the present definition of the normal coordinates. The obtained sign combination of ($\text{?μ}\text{?Q}{}_{\mathrm{i}}$) is ±(+?+), which agrees with the one predicted by the molecular orbital calculations. Using the sign combination (+?+), the polar tensors of S and O atoms were also calculated.     

Analysis of the Raman spectrum of SF6

The Raman active fundamentals ν₁(A1g), ν₂(Eg), ν₅(F2g), and the overtone 2ν₆ of SF₆ have been investigated with a higher resolution and the band origins were estimated to be: ν₁ = 774.53 cm^?1, ν₂ = 643.35 cm^?1, ν₅ = 523.5 cm^?1, and 2ν₆ = 693.8 cm^?1. Raman and infrared data have been combined for estimation of several anharmonicity constants. The ν₆ fundamental frequency is calculated as 347.0 cm^?1. From the analysis of the ν₂ Raman band, the following rotational constants of both the ground and upper states have been calculated:

$\text{B}{}_0\text{= 0.09111 ± 0.00005}\text{cm}{}^{\mathrm{?1}}\text{; D}{}_0\text{= (0.16±0.08)10}{}^{\mathrm{?7}}\text{cm}{}^{\mathrm{?1}}$

;

$\text{B}{}_2\text{= 0.09116 ± 0.00005}\text{cm}{}^{\mathrm{?1}}\text{; D}{}_2\text{= (0.18±0.04)10}{}^{\mathrm{?7}}\text{cm}{}^{\mathrm{?1}}$

.     

Rotation-vibration analysis of the Coriolis-coupled ν5g, ν6g, ν8g and ν9 bands of H2CCO

Medium resolution infrared grating spectra of gaseous ketene, H₂CCO were recorded between 1000 and 400 cm^?1, both at instrument temperature (40°C) and with cooling (?40°C). Interferometric Fourier spectra were also measured at ?70°C with resolution 0.22 cm^?1 between 450 and 330 cm^?1. The K structure of the fundamentals ν₅, ν₆, ν₈, and ν₉ was assigned. These fundamentals are coupled by a-axis Coriolis interactions. These couplings were analysed on the symmetric top basis for setting up the perturbation matrix and by utilizing the K-dependent Coriolis shifts of levels. A preliminary analysis of the Coriolis intensity anomalies was also undertaken.Band center values from combination differences are $\text{ν}{}_5{}^0\text{= 587.30 (27)}$ and $\text{ν}{}_6{}^0\text{= 528.36 (39)}\text{cm}{}^{\mathrm{?1}}$. Synthetic spectra indicate the band origins of ν₈ and ν₉ to be close to 977.8 and 439.0 cm^?1, respectively. Estimates of Coriolis coupling constants obtained from synthetic spectra are $\text{ζ}{}_{58}{}^{\mathrm{a}}\text{= + 0.33 (5)}$, $\text{ζ}{}_{68}{}^{\mathrm{a}}\text{= + 0.714 (20)}$, $\text{ζ}{}_{59}{}^{\mathrm{a}}\text{= ? 0.774 (20)}$, and $\text{ζ}{}_{69}{}^{\mathrm{a}}\text{= ? 0.30 (2)}$. Approximate ratios of unperturbed vibrational transition moments obtained from spectral simulations are $\text{M}{}_8{}^0\text{:±iM}{}_5{}^0\text{:±iM}{}_6{}^0\text{:M}{}_9{}^0\text{≈ +2:?9:+10:+0.5}$.     

Infrared spectrum of acetonitrile: Analysis of Coriolis resonance

The Coriolis resonance between ν₄ and ν₇ in CH₃CN and between ν₁ and ν₅, ν₃ and ν₆, and ν₄ and ν₇ in CD₃CN has been analyzed, applying the technique developed by DiLauro and Mills, to obtain the signs of [$\text{ζ}{}_{\mathrm{r,sa}}{}^{\mathrm{y}}\text{(}\text{?p}\text{?Q}{}_{\mathrm{r}}\text{)(}\text{?p}\text{?Q}{}_{\mathrm{sa}}\text{)}$] and the ratio of $\text{?μ}\text{?Q}{}_{\mathrm{r}}$ to $\text{?μ}\text{?Q}{}_{\mathrm{s}}$ for the interacting pairs in CD₃CN. For (ν₄, ν₇) in both CH₃CN and CD₃CN, the sign of [$\text{ζ}{}_{\mathrm{r,sa}}{}^{\mathrm{y}}\text{(}\text{?p}\text{?Q}{}_{\mathrm{r}}\text{)(}\text{?p}\text{?Q}{}_{\mathrm{sa}}\text{)}$] is found to be negative as it is also for (ν₁, ν₅) in CD₃CN. For (ν₃, ν₆) the sign of this interaction term is found to be positive. For a given definition of normal coordinates the signs of these interaction terms give the relative signs of $\text{?p}\text{?Q}{}_{\mathrm{r}}$ and $\text{?p}\text{?Q}{}_{\mathrm{sa}}$; our study also gives approximate values for the corresponding ratio [$\text{(}\text{?p}\text{?Q}{}_{\mathrm{r}}\text{)}\text{(}\text{?p}\text{?Q}{}_{\mathrm{sa}}\text{)}$]     

Strengths and lorentz broadening coefficients for spectral lines in the ν3 and ν2 + ν4 bands of 12CH4 and 13CH4

Line strengths and self- and nitrogen-broadened half-widths were measured for spectral lines in the ν₃ and ν₂ + ν₄ bands of ¹²CH₄ and ¹³CH₄ from 2870–2883 cm^?1 using a tunable diode laser spectrometer. From measurements made over a temperature range from 215 to 297 K, on samples of ¹²CH₄ broadened with N₂, we deduced that the average temperature coefficients n, defined as $\text{b}{}_{\mathrm{<mtext>L</mtext>}}{}^0\text{(T) = b}{}_{\mathrm{<mtext>L</mtext>}}{}^0\text{(T}{}_0\text{)(}\text{T}\text{T}{}_0\text{)}{}^{\mathrm{?n}}$, of the Lorentz broadening coefficients for the ν₃ and ν₂ + ν₄ bands of ¹²CH₄ were 0.97 ± 0.03 and 0.89 ± 0.04, respectively. A smaller increase is observed in line half-width with increasing pressure for E-species lines, for both self- and nitrogen-broadening, than for other symmetry species lines over the range of pressures measured, 70 to 100 Torr.     

An upper limit to the cross section for the reaction νμe−→νμe− at SPS energies

Candidates for the purely leptonic process $\text{ν}{}_{\mathrm{\mu }}\text{e}{}^{\mathrm{?}}\text{→}\text{ν}{}_{\mathrm{\mu }}\text{e}{}^{\mathrm{?}}$ have been searched for in the bubble chamber Gargamelle exposed to the CERN-SPS antineutrino wide-band beam. No single e^?, of energy greater than 1 GeV, was found in a total of 230 000 pictures, corresponding to 7400 charged current events. This leads to an upper limit for the observed cross section of $\text{σ}{}_{\mathrm{<mtext>obs</mtext>}}\text{< 1.6 × 10}{}^{\mathrm{?42}}\text{(}\text{E}{}_{\mathrm{\nu }}{}^{\mathrm{?}}\text{GeV}\text{)}$ cm² (90% C.L.). Interpretation of this value in terms of the standard W Weinberg-Salam model yields an upper limit to the mixing parameter sin²θ_W < 0.39 at 90% C.L.     

Vibronic coupling as a major cause of the anharmonicity of antisymmetric stretching in the ground state of NO2

Approximate experimental and theoretical information about vibronic coupling of the $\text{X}\text{?}{}^2\text{A}{}_1$ (ground) and $\text{A}\text{?}{}^2\text{B}{}_2$ electronic states of NO₂—by its antisymmetric vibration ν₃(b₂)—is tested in model calculations of the accurately known ground-state levels ν₃ = 0, 1, 2, 3. The test is positive and it is estimated that 64% of the very large observed anharmonic constant χ₃₃ has its origin in vibronic coupling. In this model, ν₃ in the à state is predicted at about 1200 cm^?1.     

Charge properties of the hadronic system in vp and νp interactions

Charge properties of the hadronic systems from νp and $\text{ν}\text{p}$ scattering in BEBC are studied in the framework of the quark-parto model (QPM). The average charges $\text{〈Q}{}_{\mathrm{<mtext>jet</mtext>}}\text{〈}{}^{\mathrm{<mtext>\nu </mtext>}}$ and $\text{〈Q}{}_{\mathrm{<mtext>jet</mtext>}}\text{〈}{}^{\mathrm{<mtext>\nu </mtext>}}$ of a quark jet and a d-qua jet, respectively, are determined according to two different methods. The difference $\text{〈Q}{}_{\mathrm{<mtext>jet</mtext>}}\text{〈}{}^{\mathrm{\nu }}\text{? 〈Q}{}_{\mathrm{<mtext>jet</mtext>}}\text{〈}{}^{\mathrm{<mtext>\nu </mtext>}}$ is in agreement with e QPM value of 1. Scaling of charge and energy flow in the angular variable λ is demonstrated. The ratios $\text{ΔQ}{}^{\mathrm{<mtext>\nu </mtext>}}\text{/ΔQ}{}^{\mathrm{\nu }}$ of charge flows in νp a $\text{ν}\text{p}$ scattering are in accord with the QPM in both hemispheres.     

Upper bounds on the fine structure constant and on nucleon magnetic moments in terms of Compton scattering cross sections

We derive and compare with experimental data the bound

$\text{α??λm}{}_{\mathrm{<mtext>p</mtext>}}\text{?m}{}_{\mathrm{<mtext>p</mtext>}}\text{ν}{}^2{}_1\text{2π}{}^2\text{∫}\text{ν}{}_0\text{∞}\text{d}\text{ν′σ}{}_{\mathrm{<mtext>tot</mtext>}}\text{(ν′)}\text{(ν′}{}^2\text{+ν}{}^2{}_1\text{)}\text{+2πm}{}_{\mathrm{<mtext>p</mtext>}}\text{∫}\text{ν}{}_0\text{∞}\text{ν′}{}^2\text{d}\text{ν′σ}{}_{\mathrm{<mtext>tot</mtext>}}\text{(ν′)}\text{(ν′}{}^2\text{+ν}{}^2{}_1\text{){ν′}{}^2\text{(}\text{d}\text{σ}\text{d}\text{t)}{}_0\text{+πλ}{}^2\text{+2ν′|λ|}\text{π}\text{(}\text{d}\text{σ}\text{d}\text{t)}{}_0\text{?}\text{σ}{}^2{}_{\mathrm{<mtext>tot</mtext>}}\text{16π}\text{}}{}^{\mathrm{?1}}$

, where α is the fine-structure constant, m_p the proton mass, ν₀ the photo-pion production threshold, σ_tot and $\text{(}\text{d}\text{σ}\text{d}\text{t}\text{)}{}_0$ are the unpolarized total hadronic photo-absorption cross section on protons and the unpolarized forward differential cross section for proton Compton scattering at photon-lab energy ν′, and λ and ν₁ are any real numbers. We derive similar bounds on proton and neutron magnetic moments.     

Neutral currents and new quarks

We propose a unified explanation of charged and neutral current neutrino scattering data, based on a minimal model with 3 quark and 3 lepton doublets. The data force a unique p and n quark doublet structure. Our inclusive neutral current predictions for $\text{sin}{}^2\text{θ}{}_{\mathrm{<mtext>W</mtext><mtext>\; =\; </mtext><mtext>3</mtext><mtext>8</mtext>}}$ are identical to the Weinberg-Salam model, but our νp→νp predictions agree better with experiment. We make predictions for $\text{ν}\text{?}\text{p→}\text{ν}\text{?}\text{p}$, predictions physics, supernova explosions, and $\text{ψ →ν}\text{ν}\text{?}$ decay.     

Limitation on scalar neutrino masses from Tau decay

The apparent absence of the decay $\text{τ →}\text{ν}{}_{\mathrm{\tau }}\text{ν}{}_{\mathrm{?}}{}^1\text{?,}\text{where}\text{? =}\text{e or}\text{μ}\text{and}\text{ν}{}_{\mathrm{i}}$ is the spin-zero supersymmetric partner of ν_i, implies that the $\text{ν}{}_{\mathrm{i}}$ masses are sufficiently large that the decay is suppressed (assuming the supersymmetric partners exist). We give the resulting limits, which depend on the mass of the W? (the supersymmetric partner of the W) which mediates the decay, and on whether one or both $\text{ν}$ is massive. These are the only experimental limits on $\text{ν}$ masses.     

Measurement of the νμ and νμ nucleon charged-current total cross sections,and the ratio of νμ neutron to νμ proton charged-current total cross sections

The total ν_μ and $\text{ν}{}_{\mathrm{\mu }}$ nucleon charged-current cross sections have been measured in BEBC filled with deuterium and exposed to the wide-band neutrino and antineutrino beams at the CERN-SPS. Assuming a linear energy dependence for the cross sections, σ = aE(?_ν, we obtained the coefficients , where the quoted error is mainly systematic. The ratio of the cross sections is $\text{σ}{}_{\mathrm{<mtext>\nu </mtext><mtext>N</mtext>}}\text{/σ}{}_{\mathrm{<mtext>\nu </mtext><mtext>N</mtext>}}\text{= 0.53 ± 0.03}$.We also determined the ratio of the charged-current cross section for neutrino interactions on neutrons and protons R = σ_νn/σ_νp = 2.10 ± 0.08 (statistical) ±0.22 (sysetmatic). The dependence of R on the variables x, y and E_ν is discussed.     

νW2 at small ω′ and resonance form factors in a quark model with broken SU(6)

The small ω′ behaviour of F₂^en/F₂^ep and the apparent difference in the q² dependences of the magnetic form factor of the proton and of the transition to Δ⁺(1236) are quantitatively correlated in a model where nucleon consistes of a quarks and a scalar or vector core. The proton and Δ transition form factors suggest that only the scalar core contributes at large q² and small ω′. As a result the ω′ dependence of $\text{F}{}_2{}^{\mathrm{<mtext>en</mtext>}}\text{F}{}_2{}^{\mathrm{<mtext>ep</mtext>}}$ is obtained for ω′ < 3 and predictions for the weak structure functions and polarisation asymmetries at smallω′ are presented. We predict $\text{F}{}^{\mathrm{<mtext>\nu </mtext><mtext>p</mtext>}}\text{F}{}^{\mathrm{<mtext>\nu </mtext><mtext>n</mtext><mtext>\omega \prime \to 1</mtext><mtext>0</mtext>}}$ asymmetries $\text{ω′→1}\text{1}$ and also expect that $\text{G}{}_{\mathrm{<mtext>m</mtext>}}{}^{\mathrm{<mtext>n</mtext>}}\text{G}{}_{\mathrm{<mtext>m</mtext>}}{}^{\mathrm{<mtext>p</mtext>}}\text{→}\text{?1}\text{2}$ as q²→∞.     

Vibrational spectra and force constants of symmetric tops: High resolution spectra of monoisotopic H3SiCl in the 2200-cm−1 region and rovibrational analysis of the ν1 and ν4 fundamentals

The gas phase infrared spectra of monoisotopic H₃Si³⁵Cl and H₃Si³⁷Cl have been studied in the $\text{ν}{}_1\text{ν}{}_4$ region near 2200 cm^?1 with a resolution of 0.012 and 0.04 cm^?1, respectively, and rotational fine structure for ΔJ = ±1 branches has been resolved. In addition, some information on ν₃ + ν₄ of H₃Si³⁵Cl near 2750 cm^?1 has been obtained. ν₁ and ν₄ are weakly coupled by Coriolis x, y resonance, $\text{B}\text{Ω}{}_{14}\text{ζ}{}_{14}\text{～ 2 × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$, only the upper states K′ = 2, l = 0 and K′ = 1, l = ?1 being substantially affected. Local perturbation due to rotational l(±1, ±1)-type resonance with ν₃ + ν₅⁺¹ + ν₆⁺¹ and ν₃ + ν₅⁺¹ + ν₆^?1 is revealed in the ΔK = +1 and ?1 branches, respectively. From a fit of the experimental line positions, standard deviations of 1.4 and 3.8 × 10^?3 cm^?1, respectively, to a model with five interacting levels conventional excited state parameters and interaction constants have been obtained. In $\text{H}{}_3\text{Si}{}^{35}\text{Cl}\text{H}{}_3\text{Si}{}^{37}\text{Cl}$ the fundamentals are ν₁, $\text{2201.94380(15)}\text{2201.9345(7)}$ and ν₄, $\text{2209.63862(8)}\text{2209.6254(2)}\text{cm}{}^{\mathrm{?1}}$, respectively. Q branches of the “hot” band (ν₃ + ν₄) ? ν₃ and of ν₄ of the ²⁹Si and ³⁰Si species have been detected.     

A study of the K = 3nA1 - A2 centrifugal splitting in the 3ν2 and 4ν2 states of PH3 using a difference-frequency laser system

A frequency tunable infrared source has been constructed by using the (Ar-laser) - (dyelaser) difference frequency method developed by Pine and applied to the observation of the overtone bands of PH₃ 3ν₂ ← 0 and 4ν₂ ← ν₂ in the 3.4 μm region and 4ν₂ ← 0 in the 1.6-μm region. A Stark modulation method was used to increase the sensitivity of detection. For transitions which were well modulated, the minimum detectable absorption coefficient was estimated to be ～3 × 10^?7 cm^?1 using a 3-m cell. Emphasis was placed on the observation of the A₁-A₂ splitting for K = 3n rotational levels. For the 3ν₂ state splittings were observed for K = 3, 6, and 9 because PH₃ is a very nearly spherical top in this state. The magnitude and the J dependence of the observed K = 3n splittings have been analyzed by using a normal symmetric rotor Hamiltonian and a centrifugal distortion term of the form $\text{τ}{}_{\mathrm{xxxz}}\text{[(J}{}_{\mathrm{+}}{}^3\text{+ J}{}_{\mathrm{?}}{}^3\text{)J}{}_{\mathrm{z}}\text{+ J}{}_{\mathrm{z}}\text{(J}{}_{\mathrm{+}}{}^3\text{+ J}{}_{\mathrm{?}}{}^3\text{)]}\text{4}$.     

A search at high energies for antineutrino-electron elastic scattering

We have searched for candidates for the weak neutral leptonic current reaction $\text{ν}{}_{\mathrm{\mu }}\text{+}\text{e}{}^{\mathrm{?}}\text{→}\text{ν}{}_{\mathrm{\mu }}\text{+}\text{e}{}^{\mathrm{?}}$ in the Fermilab 15 ft bubble chamber filled with a heavy neon-hydrogen mix. Based on zero observed events of this type we find the 90% confidence level upper limit for the rate for this reaction relative to the total antineutrino charged current rate to be 3.9 × 10^?4 and, in the Weinberg-Salam model, sin²θ_W ? 0.37.     

Experimental limits on the mass and decay lifetime of νμ

The nonobservation of photon-induced e⁺e^? pairs pointing in the neutrino beam direction in large bubble chambers would allow one to set an upper limit on the product m_νμλ^CM for muon-type neutrinos, where m_νμ is the mass and λ^CM is the intrinsic partial decay width in sec^?1 for ν_μ→γ+X. In the theory of Eliezer and Ross where , this implies an upper limit on m_νμ considerably smaller than the present upper limit, and a large lower limit on the lifetime τ_νμ.     

Acetylene fluorescence

Previously unobserved acetylene ${}^1\text{A}{}_{\mathrm{u}}\text{(}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{) →}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ fluorescence occurs following 1933-Å ArF laser excitation of C₂H₂ or C₂H₄ and their deuterated analogs in solid Ne and Ar hosts at 4.2 K. Acetylene is a photolysis product of matrix-isolated ethylene. Ground-state vibrational levels as high as ν″₃ = 30 of the degenerate ν₃ bending vibration are observed for C₂D₂. Only ν₃ is appreciably active in the fluorescence. The negative ν₃ anharmonicity, previously observed in the gas phase, also occurs in Ne host. Consideration of rotational selection rules indicates that the Ne host strongly hinders free rotation about the low-moment-of-inertia $\text{a}\text{?}$ axis in the excited state.     

The ã3A2 ← X̃1A1 absorption spectrum of thioformaldehyde: A vibrational and rotational analysis

The results of a vibrational and rotational analysis of the banded $\text{a}\text{?}{}^3\text{A}{}_2\text{←}\text{X}\text{?}{}^1\text{A}{}_1$ transition in $\text{CH}{}_2\text{S}\text{CD}{}_2\text{S}$ are presented. Only three of the six vibrational modes are active in the spectrum with $\text{ν′}{}_2\text{=}\text{1320}\text{1012}$, $\text{ν′}{}_3\text{=}\text{859}\text{798}$, and $\text{2ν′}{}_4\text{=}\text{711}\text{516}\text{cm}{}^{\mathrm{?1}}$. The spin forbidden transition gains intensity primarily by a mixing of the ${}^1\text{A}{}_1\text{(π}{}^1\text{,π)}$ and ${}^3\text{A}{}_2\text{(π}{}^1\text{,n)}$ states. This is confirmed by a rotational analysis of the 0₀⁰ band of both isotopes. The rotational analysis shows that the coupling in the $\text{a}\text{?}{}^3\text{A}{}_2$ state is near Hund's case b and that the spin constants are nearly 10 times greater than those observed for CH₂O. A $\text{CNDO}\text{2}$ calculation shows that this difference is due to the greater spin orbit coupling of S in CH₂S and to the smaller energy differences between the $\text{B}\text{?}{}^1\text{A}{}_1\text{(π}{}^1\text{,π)}$, $\text{b}\text{?}{}^3\text{A}{}_1\text{(π}{}^1\text{,π)}$, $\text{X}\text{?}{}^1\text{A}{}_1$, and the $\text{a}\text{?}{}^3\text{A}{}_2\text{(π}{}^1\text{,n)}$ states. The r₀ structure calculated from the rotational constants is $\text{r}{}_{\mathrm{<mtext>CS</mtext>}}\text{= 1.683}\text{A}\text{?}$, $\text{r}{}_{\mathrm{<mtext>CH</mtext>}}\text{= 1.082}\text{A}\text{?}$, β_HCH = 119.6°, and α (out of plane) = 16.0°. A simultaneous fit of the vibrational levels in ν′₄ of CH₂S and CD₂S to a double minimum potential function yielded a barrier to molecular inversion of 13 cm^?1 and an equilibrium out-of-plane angle of 15°.     

Intensity measurements and self-broadening coefficients in the γ band of O2 at 628 nm using intracavity laser-absorption spectroscopy (ICLAS)

Quantitative measurements of intensities and widths were made for individual rotational lines of the atmospheric oxygen $\text{b}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{(ν′ = 2) ← X}{}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}\text{(ν″ = 0)}$ γ band by using a recently developed, highly sensitive, intracavity laser-absorption spectroscopic technique (ICLAS) at 300 torr m. The total band intensity derived from the line intensities is $\text{1.26 ± 0.05}\text{cm}{}^{\mathrm{?1}}\text{km}{}^{\mathrm{?1}}\text{atm}{}^{\mathrm{?1}}$ (STP). Self-broadening collision coefficients for the ^PP and ^PQ branch lines have been determined from the absorption line width and were found to vary from 0.055 cm^?1 atm^?1 at N″ = 1 to 0.037 cm^?1 atm^?1 at N″ = 27.