共查询到19条相似文献,搜索用时 62 毫秒
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二溴对甲基偶氮羧质子化及其离解 总被引:1,自引:0,他引:1
用萃取法对二溴对甲基偶氮羧进行了纯化,并用分光光度法研究了二溴对甲基偶氮羧的质子化和五级离解作用,测定了其质子化常数和逐级离解常数,获得满意的效果。 相似文献
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对甲基偶氮氯膦(CPApM)作为不对称偶氮氯膦类光度分析显色剂,已应用于稀土氧化物与有关矿石、镍基合金中测定钇的含量,本文以分光光度法测得了CPApM的离解常数及质子化常数,运用HMO法进行半经验量子化学计算,并对其电子结构、离解作用与质子化作用及微观机理作了探讨。 相似文献
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Guo Qiang SHANGGUAN* Ning WANG Hong En WANG Arthur E. MARTELL Department of Chemistry Jining Medical College Jining Department of Chemistry Texas A&M University College Station Texas 《中国化学快报》2001,(2)
One of our current interests focuses on the design and synthesis of polyaza macrocyclic ligands, the determination of their protonation constants, and the stabilities of corresponding metal complexes. Two polyazadiphenol macrocycles, R(babp)2(dfc)21 and [24]RBPyBC2, one octaazamacrocycle, BPBD3,4, and several hexaaza macrocyclic ligands, BFBD5, BMXD6, and OBISDIEN7, have been reported recently. We have also reported the synthesis of a new dinucleating 24-membered hexaazadiphenol macr… 相似文献
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Lazaro J. Yamin Carlos A. Ponce Mario R. Estrada Francisco Tomas Vert 《Journal of Molecular Structure》1996,360(1-3):109-117
Ab initio molecular orbital calculations with 4-31G//4-31G, 6-31G*//4-31G and 6-31+G//4-31G basis sets have been used to examine the structure, relative energy, protonation and deprotonation of a series of seven hydroxamic acids in the gas phase. The results show that hydroxamic acids are predominantly in the E-TS form and that the most probable protonation site is the carbonyl oxygen atom, while deprotonation proceeds by loss of NH hydrogen. 相似文献
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本文探索了抑制电导离子色谱法测定pK_a<7的一元弱酸的离解常数,对以HCl为标准测定HF、HNO_2的离解常数和以HF为标准测定乳酸、乙酸和甲酸的离解常数及测定方法的主要误差来源进行了讨论。 相似文献
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Kamil I. Utegenov 《Journal of organometallic chemistry》2011,696(21):3408-3414
The addition of phosphines to the manganese allenylidene complexes Cp(CO)2MnCCC(Ph)R (R = H, Ph) proceeds selectively at the Cα atom to result in the α-phosphonioallenyl complexes Cp(CO)2Mn−-C(+PR31)CC(Ph)R. The protonation of the latter affords the η2-(1,2)-phosphonioallenes Cp(CO)2Mn{η2-(1,2)-HC(+PR31)CC(Ph)R}, rather than the phosphoniovinylcarbenes Cp(CO)2MnC(+PR31)-HCC(Ph)R. All complexes obtained are stereochemically rigid and do not isomerize into the η2-(2,3)-phosphonioallene isomers. 相似文献
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Jiří Dybal Emanuel Makrlík Petr Vaňura Jan Budka 《Monatshefte für Chemie / Chemical Monthly》2008,139(10):1175-1178
From extraction experiments in the two-phase water-nitrobenzene system and γ-activity measurements, the stability constant
of protonated 1,3-alternate-25,27-bis(1-octyloxy)calix[4]arene-crown-6 in nitrobenzene saturated with water was determined. By using DFT calculations,
the most probable structure of the 1,3-alternate-25,27-bis(1-octyloxy)calix[4]arene-crown-6 · H3O+ complex species was derived.
Correspondence: Emanuel Makrlík, Faculty of Applied Sciences, University of West Bohemia, Pilsen, Czech Republic. 相似文献
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Charles Fehr 《Angewandte Chemie (International ed. in English)》1996,35(22):2566-2587
Enantioselective protonation, until recently a largely overlooked reaction, has, in the last five years, developed into a field of intense research activity. The progress achieved parallels or complements that obtained in the understanding of enolate structures and reactivities. The conceptual simplicity and attractiveness of enantioselective protonation results from the fact that after reaction, the chiral proton donor is regenerated in its original protonated form by an extractive workup. Enantioselective protonation has been applied to the synthesis of amino acids, antiinflammatory agents (2-arylpropanoic acids), and fragrance compounds such as (S)-α-damascone, for which its industrial feasibility has been demonstrated. 相似文献
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Christopher S. Griffith George A. Koutsantonis Brian W. Skelton Allan H. White 《Journal of organometallic chemistry》2003,670(1-2):198-204
The acid–base chemistry of some ruthenium ethyne-1,2-diyl complexes, [{Ru(CO)2(η-C5H4R)}2(μ2-CC)] (R=H, Me) has been investigated. Initial protonation of [{Ru(CO)2{η-C5H4R}}2(μ2-CC)] gave the unexpected complex cation, crystallised as the BF4 salt, [{Ru(CO)2(η-C5H4R}}3(μ3-CC)][BF4] (R=Me structurally characterised). This synthesis proved to be unreliable but subsequent, careful protonation experiments gave excellent yields of the protonated ethyne-1,2-diyl complexes, [{Ru(CO)2{η-C5H4R)}2(μ2-η1:η2-CCH)](BF4) (R=Me structurally characterised) which could be deprotonated in high yield to return the starting ethyne-1,2-diyl complexes. 相似文献