大港常压渣油临氮与临氢热反应过程中胶体稳定性变化研究

对比了大港常压渣油临氮和临氢热反应过程中的胶体稳定性变化。结果表明,随着反应时间的延长,在热反应生焦诱导期内,渣油样品的胶体稳定性迅速下降;开始生焦后,胶体稳定性缓慢下降。从组分组成和组分性质角度,对大港常压渣油样品在热反应过程中胶体稳定性变化原因进行了分析。结果表明,随着反应时间的延长,沥青质含量先上升、后下降,在生焦诱导期结束时达到最大值,与体系胶体稳定性的变化特征相一致。随着热反应的进行,饱和分和轻芳烃组分的含量在上升,重芳烃、轻胶质、中胶质、重胶质含量下降,临氮热反应过程中轻胶质、中胶质、重胶质含量的下降更为显著。对渣油样品各组分的数均相对分子质量和平均偶极矩进行了研究。结果表明,随着热反应的进行,轻、中、重胶质组分的数均相对分子质量和平均偶极矩呈下降趋势,而沥青质的数均相对分子质量和偶极矩先增大后减小,从而使沥青质和胶质的分子性质差别先增加后减小,与体系胶体稳定性的变化趋势一致;同时沥青质的偶极矩变化表明,强极性的沥青质优先聚集生焦、临氢热反应过程中,氢与催化剂的作用有助于抑制沥青质分子量增大和极性增强,从而有助于抑制生焦。     

溶液法测定分子偶极矩的简化处理

偶极矩是与分子结构有关的物理化学常数。对于判断分子的空间构型,考察键的旋转,研究分子的电性等均有作用。基础物理化学实验中常采用溶液法测定分子的偶极矩。该法只适用于稀溶液(溶质的摩尔分数X:为10~(-1)—10~(-2)),因而准确测定溶液的密度较困难,也很费时,不易获得重现结果。本文介绍E.AGuggenheim提出的简化计算方法,该法采用近似处理     

中东常压渣油热反应样品Zeta电位的研究

长期以来,有诸多研究者认识到了渣油的胶体性质,并且利用各种实验手段对其进行了研究。渣油的胶体稳定性对其热反应性能有重要影响作用。前人的研究认为,渣油胶体体系中的分散相主要是由沥青质构成,分散介质由芳香分和饱和分共同构成,吸附层由胶质构成。胶体的一个重要性质是电性质,渣油分子中含有大量的杂原子,使渣油极性分子的存在和渣油胶粒具有一定的电性。     

极性分子键角与键偶极矩的关系

研究了基态极性分子的键角和键偶极矩之间的关系。我们采用原子偶极矩校正的Hirshfeld （ADCH）电荷来计算键偶极矩,利用电子的局域函数和键临界点处的局域函数值来分析键的电子结构。通过对IVA族（IVA = C,Si,Ge）、VA族（VA = N,P,As ）、VIA族（VIA = O,S,Se）和VIIA族（VIIA = F,Cl,Br）元素形成的系列共价型基态分子,以及环状基态分子的键角和键偶极矩数据进行分析,发现在键的电子结构类似的情况下,由于键偶极矩的排斥作用,这些分子的键角随键偶极矩的增加而增大。这一发现有助于加深我们对分子几何结构的认识。     

大庆渣油族组分非等温热反应的研究

采用动态热重分析法在升温速率为６．２Ｋ·ｍｉｎ￣（－１）及惰性气流量１００ｃｍ￣３·ｍｉｎ￣（－１）的条件下，对大庆渣油族组分的热转化行为进行了考察，获得了族组分的热转化速率峰值、速率峰值处的反应温度、转化率和剧裂分解温度区间等动力学基本数据以及各族组分的生焦性能。数据分析表明，族组分的热反应活性顺序为：饱和分＞胶质＞芳香分＞沥青质。在大庆渣油族组分热转化的两个温区内，采用分段一级动力学模型较好地拟合了实验数据，确定了各族组分在两个温区内的热反应动力学参数。     

委内瑞拉常压渣油供氢热转化研究

采用高压釜研究了委内瑞拉常压渣油的常规减黏裂化与供氢热转化过程。结果表明,相比常规减黏裂化而言,供氢热转化过程中的供氢剂能够抑制气体产物、沥青质以及焦的形成,后者的气体收率比前者低0.5%~1.2%,生焦率低0.02%~0.98%,残渣油沥青质含量低0.6%~1.3%;在反应温度425℃、反应时间5~20 min条件下,供氢热转化过程的总降黏率、净降黏率变化分别为46.1%~54.8%、10.2%~33.0%;供氢热转化过程的较佳反应条件为425℃、5 min,此条件下供氢热转化生成油斑点实验等级为一级(ASTM D4740),运动黏度(50℃)为185.5 mm²/s,净降黏率为26.4%,满足了船运的基本要求。     

单硝基甲苯和多硝基甲苯偶极矩的理论计算和实验测定

用 MINDO/3和 CNDO/2法对单硝基甲苯和多硝基甲苯的平衡几何构型进行了全优化和 SCF 计算,求得了o,m,p-MNT,2,3-,2,4-,2,5-,2,6-,3,4-,3,5-DNT 和2,3,4-,2,3,5-,2,3,6-,2,4,5-,2,4,6-以及3,4,5-TNT 的“气相”偶极矩。用折射法实测了 MNT 和 DNT 共9种化合物在 CCl_4溶液中的偶极矩。计算值和实测值之间存在良好的线性关系。以甲苯和硝基苯的计算值通过“向量加和”近似地估算了 MNT,DNT 和 TNT的偶极矩,估算值与上述实验值和量子化学计算值之间也线性相关。     

白藜芦醇分子的转动惯量和电偶极矩

通过分子轨道理论和杂化轨道理论推断出较稳定的白藜芦醇分子是平面型分子,然后根据白藜芦醇分子结构特点计算了该化合物的一种稳定异构体的转动惯量,用矢量合成法计算了其电偶极矩,为微波辅助白藜芦醇萃取理论研究提供转动惯量和电偶极矩的数据.     

中东常压渣油热反应过程中沥青质的缔合性变化规律

用表面张力法研究了中东常压渣油热反应过程中正庚烷沥青质缔合性的变化。测定沥青质的不同浓度甲苯溶液的表面张力,利用溶液的临界胶束浓度表征沥青质的缔合性。定义蒸气压渗透法(VPO法)测得的沥青质平均分子量和表面张力法计算得到的平均分子量之比为沥青质的缔合度参数。结果表明,随着热反应的进行,在生焦诱导期内,沥青质的临界胶束浓度下降、沥青质缔合度参数增大,缔合性增强；达到生焦诱导期后临界胶束浓度上升、缔合度参数下降,缔合性下降。     

臭氧分子中配位氧的成键形式与偶极矩方向

本文用CNDO/2法对O_3分子进行了计算.结果表明,中心氧带有正电,由此推断,在成键过程中配位氧也进行了杂化.     

Electro-optical investigations of the dipole moments of nanoparticles

In this paper, the electric properties of polar nanoparticles are examined. Special attention is paid to the terminology, classification and the physical bases of the different electric moments. A short history of the electro-optic studies of dipole moments of nanoparticles and the electro-optic Conferences is presented. The connection of the polar properties with the particle electric charge is considered. The potential of the colloid electro-optics for studying the properties of anisometric, anisotropic polar nanoparticles is discussed in details. Examples of such studies are presented. A comparative analysis is made of the potential of dielectric, electro-optic and dielectrophoretic measurements for studying the electric properties, size, shape and structure of polar nanoparticles.     

钌离子催化氧化法研究大港减压渣油组分化学结构

利用钌离子催化氧化方法对大港减压渣油芳香分、胶质和庚烷沥青质进行了选择性降解,通过GC、GC-MS等分析手段对降解反应产物中一元正构脂肪酸、α,ω-二元正构脂肪酸和苯二～六元羧酸的含量和分布分别进行了定量分析。结果表明,芳香分、胶质和庚烷沥青质中的芳香结构上都存在大量烷基取代基和桥接不同芳碳的聚亚甲基桥。烷基取代基碳数最大约为33,聚亚甲基桥最大碳数约为24,而且这两种结构单元的含量均随碳数的增加而减少,并呈现出了偶碳优势。庚烷沥青质C12以下侧链相对较多而C16＋较少,与芳香分的分布相反;正构烷基侧链的浓度按庚烷沥青质、胶质和芳香分的顺序递减。降解产物中都检测到了苯二甲酸到苯六甲酸等一系列的苯多酸,表明三个组分中都存在稠环芳香结构。庚烷沥青质中缩合程度较高的迫位缩合结构含量最高,芳香分渺位缩合结构最多,胶质介于两者之间。     

反应温度对加氢残渣油四组分含量和结构的影响

以沙轻减渣为原料,在高压釜内研究了不同反应温度下加氢反应前后渣油的四组分含量及其结构组成变化。结果表明,加氢残渣油中的饱和分含量明显增加,而芳香分和胶质的含量均降低,四组分含量随反应温度的升高均呈现规律性变化。加氢后四组分的H/C摩尔比和平均相对分子质量均降低,芳碳分率增加。随反应温度升高,四组分的H/C摩尔比和平均相对分子质量降低,烷基碳分率降低;芳香分、胶质和沥青质的芳碳分率增加;胶质和沥青质的总环数和芳环数均降低。渣油加氢过程中四组分都发生了明显的氢解和脱烷基反应。加氢反应中,胶质和沥青质结构单元间的各种桥键可发生明显地断裂,导致其结构单元数减少,且结构单元数随反应温度的升高而减少。     

Kerr constants and dipole moments of aminobenzoic acids in dioxane

Aminobenzoic acids in dioxane have been investigated by dipole moment and Kerr effect methods.m-Aminobenzoic acid exists in a solution mainly (60 %) in thesyn-form. Inp-aminobenzoic acid, conjugation flattens the pyramidal configuration of the nitrogen atom, which is even more flattened ino-aminobenzoic acid owing to an intramolecular hydrogen bond.Translated fromIzvestiya Akademii Nauk. Seriya Khimicheskaya, No. 5, pp. 859–861, May, 1994.     

Charge transfer associated with the physical process of hardness equalization and the chemical event of the molecule formation and the dipole moments

In this article, we have basically launched a search whether the dipole charge and dipole moment of heteronuclear diatomics can be justifiably evaluated in terms of charge transfer kernel using the hardness equalization principle as basis. We have derived a formula for computing dipole charge (q) on the basis of hardness equalization principle as q = aδ + b, where “a” and “b” are the constants and “δ” is the kernel of charge transfer from less hard atom to more hard atom during the rearrangement of charge on molecule formation. We have computed the dipole charges and dipole moments of as many as six different sets of compounds of widely diverse physicochemical behavior in terms of the algorithm derived in the present work. The computed dipole charge nicely reveals the known chemicophysical behavior of such compounds as are brought under the study. A comparative study of the nature of variation of theoretically evaluated and experimentally determined dipole moments reveals that there is an excellent agreement between the two sets of dipole data. Thus, the new algorithm derived for the calculation of the dipole charge using the hardness equalization principle as a basis is efficacious in computing the distribution and rearrangement of charge associated with the chemical event of molecule formation. © 2010 Wiley Periodicals, Inc. Int J Quantum Chem, 2011     

塔河常压渣油沥青质含硫官能团形态与其性质的关系研究

以塔河常压渣油为原料,分离正庚烷沥青质,并将正庚烷沥青质分成三个极性不同的亚组分。测定沥青质亚组分的平均偶极矩,利用¹H-NMR谱关联得到沥青质平均结构参数以分析沥青质亚组分缔合性质,采用X射线吸收近边结构谱(XANES)表征沥青质亚组分中含硫官能团形态,分析硫原子存在形态对沥青质性质的影响。结果表明,随着沥青质亚组分极性降低,H/C原子比增大;沥青质极性增加,缔合性增强;沥青质中还原态硫主要以噻吩硫形式存在,其次为硫醚;亚砜、砜和磺酸盐是主要的含氧硫化物。噻吩、砜和磺酸盐等官能团的存在对沥青质性质具有影响,但对沥青质极性及缔合性的影响不明显,杂原子硫不是影响沥青质极性和缔合性的主导因素。     

Intramolecular and intermolecular hydrogen-bonding effects on the dipole moments and photophysical properties of some anthraquinone dyes

The present work stems from our interest in the synthesis, characterization and biological evaluation of lanthanide(III) complexes of a class of coumarin based imines which have been prepared by the interaction of hydrated lanthanide(III) chloride with the sodium salts of 3-acetylcoumarin thiosemicarbazone (ACTSZH) and 3-acetylcoumarin semicarbazone (ACSZH) in 1:3 molar ratio using thermal as well as microwave method. Characterization of the ligands as well as the metal complexes have been carried out by elemental analysis, melting point determinations, molecular weight determinations, magnetic moment, molar conductance, IR, (1)H NMR, (13)C NMR, electronic, EPR, X-ray powder diffraction and mass spectral studies. Spectral studies confirm ligands to be monofunctional bidentate and octahedral environment around metal ions. The redox behavior of one of the synthesized metal complex was investigated by cyclic voltammetry. Further, free ligands and their metal complexes have been screened for their antimicrobial as well as DNA cleavage activity. The results of these findings have been presented and discussed.     

Electric dipole moments in polar solvents. II. Tetraisoamylammonium nitrate ion pairs in chlorobenzene. Effect of mutual polarization of the ions

The dielectric constant and conductivity of dilute solutions of tetraisoamylammonium nitrate in chlorobenzene are measured between –34.6° and 99.0°C to give association constants for the formation of ion pairs (K _A) and triple ions, and electric dipole moments. The quantityK _A as a function of temperature is reproduced by the Denison-Ramsey-Fuoss treatment for unolarized ion pairs [Eq. (2)] with a distance of closest approach of 4.90 Å. The dielectric data are reproduced by Onsager's equation with an inherent (gas-phase) dipole moment of the ion pairs of 14.2±0.3 D. Other methods of calculation lead to consistent dipole moments, confirming that the mutual polarization of the ions is important. The energetics of ionic association is considered on the basis that the ion pair may be treated as a polarizable dipole in a spherical cavity.