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1.
IntroductionInthepastdecade ,alotofinteresthasbeencon centratedonpreparingandcharacterizingbridgingmetalcomplexesforinvestigatingtheirpotentiallyusefulelec tronicormagneticproperties .1,2 Recently ,severalmetalcomplexesbridgedbydicarboxylatehavebeensynthes…  相似文献   

2.
Introduction  Photoinducedelectrontransfer (PET)isoneofthemostinterestingfeaturesofdonor acceptorsystemsforthedesignandtheconstructionofartificialmoleculardevicesforenergyconversionandinformationprocessingwhichhaveanumberofpotentiallyintriguingapplicat…  相似文献   

3.
IntroductionAmongtheinteractionsbetweenporphyrinsandfunctionalmoleculessuchasaminoacids ,ubiquinoneplaysimportantbiologicalfunctions .Themolecularrecognitionofaminoacidsandtheirderivativesisanimportanttopicforbothunderstandingthemechanismofaminoacyl tr…  相似文献   

4.
NTRODUCTIONItisknownthatdialkylsulfidesareefectiveextractantsfortheextractionandsepara tionofnoblemetals〔1,2〕.Paladiumcomplex...  相似文献   

5.
INTRODUCTIONThesynthesisofpolynuclearcopper lanthanoidcomplexesisofspecialinterestforsev eralreasons〔1-4〕.Thesecomplexesareim...  相似文献   

6.
Thalliumisatoxicmetal.Becauseitsconcentrationinenvironmentalandbiologicalsam plesisinthe 1ng/grangeorless[1] ,itisdifficulttodeterminethemetalbyusingconventionalelectroanalysismethods .Differentialpulseanodicstrippingvoltammetry(DPASV )isasensitivemethodfor…  相似文献   

7.
IntroductionOwingtotheformationofstableanddeeplycoloredcomplexeswithheavymetalions(suchaslead(Ⅱ)etc),theferrocenylaroylhydrazonesarenotonlypotentiallyusefulasspe-cificreagentsinanalyticalandextractivechemistry[1]butalsostronglyactivebiologically,andc…  相似文献   

8.
1INTRODUCTIONCoppercomplexeshavealargevarietyofstericstructuresandplayanimportantroleincatalysingtheenzymaticactivities,which...  相似文献   

9.
1INTRODUCTIONItiswelknownthatlanthanideelementstendtobecoordinatedwithpolycar boxy ormacrocyclic containingspeciestoformpolyn...  相似文献   

10.
Oneofthemostimportantaimsofphotochemistryisthedesignandconstructionofmoleculardevicesforener gyconversionandinformationprocessing .Thephotoactivemoleculardevicesarebasedonthephotoinducedelectrontransferbetweendonor acceptortypeorganiccompoundsandaccept…  相似文献   

11.
IntroductionCopper(Ⅱ)complexeswithorganicacidsandotherdonorligandsexistextensivelywithinhumanbodies,andplayanimportantroleinavastrangeofchemicalandbiochemicalcatalyticsystems[1].Muchattentionhasbeenpaidtowhattheymayrevealtothestructuresandtheprobable…  相似文献   

12.
0IntroductionNumerousuniqueframeworkshavebeenreportedbyassemblyofrationaldesignedorganiclig-andswithmetalionsoverthepastdecade1~3.Itisknownthatbothimidazoleandcarboxylatearefunctionalgroupsforcoordinationtotransitionmetalionstoformcomplexes4~6.Howeve…  相似文献   

13.
催化酯化新进展(英)   总被引:1,自引:0,他引:1  
酯化是一经典的有机合成反应,随着肽合成的进展,在此领域已做了大量的研究工作。介绍了一些新的酯化有机催化剂如: N , N ′ Dicycloh exylcarbodiim ide, 4dim ethylam in op yridin e, Bis[4( 2, 2dim ethyl1, 3dioxolyl)m ethy ] carbodiim ide, benzotriazolyl N oxytrisoim ethylam inophosphonium 和 2eth ox y1(eth oxycarbonyl)1,2dihydroqu inolin e。参考文献 20 篇。  相似文献   

14.
IntroductionAxiallydissymmetric 1,1′ binaphthyland 1,1′ bi phenylligandsbearingtwoidenticalgroupsinthe 2 ,2′ positionhaveprovedtoberemarkablyusefulinenantiose lectivecatalysis ,withopticalyieldscloseto 10 0 %enan tiomericexcess (ee)obtainedinseveralpreparativelyim p…  相似文献   

15.
1INTRODUCTIONMacrocyclicdioxotetramineswithvariousfunctionalpendantshavereceivedmuchat tention,theintroductionofvariousadditi...  相似文献   

16.
Introduction  Non covalentinteractionshaveabiginfluenceontheconformationalorganizationofthebiomoleculeswhichisresponsiblefortheregio andstereo specificityofvariousbiologicalprocesses .1Amongtheseinteractions ,thein tramolecularstackinginteractionbetweens…  相似文献   

17.
IntroductionAsearlyas1851,Deville[1]firstidentifiedseveraldoublecarbonatesoftheformulA2CO3·MCO3·4H2O(A=Na,KandM=Mg,Ni,Co)andreportedthepotassiumcom-poundswithanorthorhombicsystem[1].Sinceeachofthethreecarbonateoxygensisabletoparticipateincoordination…  相似文献   

18.
IntroductionTheabilityofdithiocarbamate(dtc)bindingtometalshasbeenknownformanyyears .Itformschelateswithvirtu allyalltransitionmetals.1Thebidentateanionisalsowellknownasabridgebetweentwotransitionmetalcenters.2 Wa ter solubledialkyldithiocarbamatecomplexes…  相似文献   

19.
造影剂通常为Gd3+、Mn2+或Fe3+的稳定化合物.它们能改变体内水分子氢核的弛豫速率,从而提高正常与病变组织的磁共振成像(MagneticResonanceImaging,MRI)对比度或显示体内器官的功能状态.因此,开发新优MRI造影剂具有重要...  相似文献   

20.
1 INTRODUCTIONThecondensationofaldehydeswithaminesisavaluablesyntheticmethodleadingtopolyazapolycyclics,includingcagedcompounds.Animportantapplicationofthisreactionisthesynthesisofhexabenzylhexaazaisowurtzitane(HBIW)anditsderivativeswithsubstitutedbenz…  相似文献   

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