端面抽运Tm，Ho：YLF激光器双稳特性的理论分析与实验研究

报道了波长为792nm激光二极管端面抽运Tm,Ho：YLF连续激光器的双稳输出特性.在考虑能量传递上转换和基态对2μm激光重吸收的前提下,建立了Tm,Ho：YLF双稳激光器准三能级速率方程理论模型.通过对Tm,Ho：YLF激光器速率方程的求解,理论预见了Tm,Ho：YLF激光器双稳输出的特性,并分析了其产生的机理.进行了激光二极管端面抽运Tm,Ho：YLF激光器双稳输出的实验研究,当激光晶体温度为253K时,双稳区的宽度可达1.6W,跃变点输出功率的跃变量可达82.5mW.通过对比发现理论结果与实验结果比 关键词： 端面抽运 Tm Ho：YLF晶体 连续输出 光学双稳     

激光二极管端面抽运室温Tm,Ho:YLF连续固体激光器

报道了激光二极管端面抽运Tm，Ho：YLF固体激光器的输出特性.室温下，选用不同透过率的输出耦合镜进行了实验研究，确定了最佳输出耦合镜透过率为2%. 利用小孔扫描的方法，得到了激光远场的光强分布，证明激光为基横模输出，并且给出了热焦距随抽运功率的变化关系.通过在激光谐振腔内插入两个固体Fabry-Perot标准具的方法，获得了2μm激光的单频输出，阈值功率为250mW，在抽运功率为2.8W时，单频输出功率为118mW.此单频激光器可用作激光振荡器和激光放大器的种子源. 关键词： 激光光学 激光二极管 Tm Ho:YLF固体激光器 单频     

室温下光纤耦合二极管泵浦Tm:YAP激光器

 为实现室温下小型化、高效率的1.9 mm激光输出,采用793.5 nm激光二极管泵浦Tm:YAP晶体，晶体采用热电制冷及风冷的方式控制在18 ℃，采用1∶1的聚焦耦系统，获得功率为2.2 W、中心波长为1 928 nm的激光输出，光光转换效率为31%，斜率效率达41%。对影响激光输出的耦合输出率、腔型、腔长、晶体工作温度等因素进行了实验分析，实验结果表明：输出功率的变化与温度基本成线性关系,当增加激光谐振腔长时，由于高阶模式损耗加大以及晶体热透镜效应的加重导致腔内损耗加大，输出功率和斜率效率都有所下降。     

The growth and optical properties of ZnO nanowires at the junctions of nanowalls

Highly pure ZnO nanowires at the junctions of nanowalls have been successfully prepared via a simple vapor phase route at relative low temperature in the absence of catalyst. SEM, TEM, Raman scattering and PL were employed to characterize as-grown samples. The nanowires have average diameter of 10 nm with [001] growth direction. Raman scattering shifted from higher frequency to lower frequency and the enhancement of PL intensity of the green emission to the UV may be attributed to smaller nanowires and thinner nanowalls. This nanostructure may have important applications in batteries, light-emitting and energy conversion devices and other fields demanding high surface area materials.     

798 nm半导体激光激发下Yb3+, Tm3+:ZBLAN玻璃的上转换发光

在用７９８ｎｍ半导体激光直接激发Ｔｍ＾３＋离子至＾３Ｆ４能级时,Ｔｍ＾３＋和Ｙｂ＾３＋共掺的锆系氟化物（Ｔｍ＾３＋,Ｙｂ＾３＋;ＺＢＬＡＮ）玻璃中观测到了较强的上转换蓝光。分析了发光机理：Ｔｍ＾３＋离子把能量传递给Ｙｂ＾２＋离子,被激发的Ｙｂ＾３＋离子又把能量传递给Ｔｍ＾３＋离子,从而把Ｔｍ＾３＋激发至发射蓝光的能级＾１Ｇ４和＾１Ｄ２。对这种泵浦机制的特点进行了讨论。     

Tm∶YVO4晶体中Tm3+的发光研究

测量了Tm∶YVO4 晶体的吸收光谱 ,以 34 6nm、36 3nm(1D2 )、475nm(1G4 )、6 98nm (3 F2 ,3 F3 )和 80 1nm(3 H4 )光激发时的发射光谱 ,以及位于 45 4nm (1D2 → 3 F4 )、475nm (1G4 → 3 H6)、6 46nm (1G4 → 3 F4 )、80 6nm(3 H4 →3 H6)的荧光谱线的激发光谱 ,对测量的结果进行了详细分析 ,解释了离子能级间的跃迁过程。提出了Tm∶YVO4 晶体基质与Tm3 + 之间的能量交换的概念和新的跃迁通道 ,证实了存在1D2 +3 H6→1G4 +3 F4 以及1G4 +3 H6→3 H4 +3 H5的能量传递过程 ,还可能存在交叉弛豫过程 1G4 +3 H6→3 F2 +3 F4 。这些过程使得Tm∶YVO4 晶体难以实现1D2 能级上转换发光 (4 5 4nm左右 ) ,但 475nm的上转换发光 (1G4 →3 H6)较强 ,3 F4 能级是潜在红外激光发射能级。     

Preparation of LixCa1−xTiO3 solid electrolytes by the sol-gel method

Solid electrolytes based on lithium doped CaTiO_3,Li_xCa_1−xTiO₃ (x=0-0.5) were prepared by the sol-gel method in an ethanol and water mixture medium. Phase identification and morphology observation of the products were carried out by X-ray diffraction (XRD) and transmission electron microscopy (TEM). The results show that the Li_xCa_1−xTiO₃ powders sintered above 700 ^°C are of cubic perovskite structure and the mean size of Li_xCa_1−xTiO₃ powders is about 80 nm. A study of ionic conductivity by AC impedance implies that the conductivity of Li_xCa_1−xTiO₃ increases with the increase of substituted Li⁺ ions and reaches a maximum value of 4.53×10⁻⁴ S cm⁻¹ at x=0.1, and then decreases for x>0.1.     

医用高功率CTH∶YAG脉冲激光器

为了提高Cr,Tm,Ho∶YAG激光器的输出功率对CTH∶YAG准三能级能量转移特性进行了分析,优化了谐振腔的腔长及腔镜的曲率半径,采用了高漫反射陶瓷聚光腔.结果表明,有效抽运光谱带的反射率高达95%,在冷却水温为19 ℃,抽运能量为159 J时,获得最大单脉冲输出能量5.11 J,斜率效率5.6%.     

Tm3+/Yb3+共掺杂玻璃和玻璃陶瓷中蓝色 上转换发光中的能量传递过程

利用高温固相法制备了Tm³⁺/Yb³⁺共掺杂的氟氧化物玻璃和玻璃陶瓷材料,在980 nm的激光激发下,样品发射出明亮的蓝色上转换荧光。通过对玻璃和玻璃陶瓷样品的对比,发现Tm³⁺离子和Yb³⁺离子之间存在着Tm³⁺(³H₄)→Yb³⁺(²F_5/2)的反向能量传输通道,并且与晶场有较强的依赖关系。分析了在玻璃和玻璃陶瓷中蓝色上转换发光过程,随着敏化剂Yb³⁺浓度的增加,在玻璃中正向和反向能量传递的竞争作用使得Tm³⁺离子在Yb³⁺离子的最佳浓度时上转换发光最强;而在玻璃陶瓷中, Tm³⁺离子的上转换发光始终随着Yb³⁺离子的浓度增加而增强。     

Effect of annealing temperature on luminescence of Eu ions doped nanocrystal zirconia

Effect of annealing temperature on luminescence of Eu³⁺ ions was studied in nanocrystal zirconia prepared by co-precipitation. The XRDs reveal with annealing temperature increasing the tetragonal crystal phase of the samples is stable. The emission spectra show the strong emission at 595 and 604 nm at 394 nm excitation. Under continuous UV (394 nm) irradiation the 604 nm emission intensity changes of the samples show as a function of irradiation time. In addition, the charge-transfer states of the samples are affected by the annealing temperature. These are associated with the defects at/in the surface of the nanocrystalline ZrO₂ with Eu³⁺ ions.