Temperature-driven structural phase transition for trapped ions and a proposal for its experimental detection

A Wigner crystal formed with trapped ions can undergo a structural phase transition, which is determined only by the mechanical conditions on a classical level. Instead of this classical result, we show that through consideration of quantum and thermal fluctuation, a structural phase transition can be driven solely by a change in the system's temperature. We determine a finite-temperature phase diagram for trapped ions using the renormalization group method and the path integral formalism, and propose an experimental scheme to observe the predicted temperature-driven structural phase transition, which is well within the reach of the current ion trap technology.     

Evidence for a phase transition in BEA

Differential scanning calorimetry and positron lifetime measurements show positive evidence for a phase transition in BEA at 28.5°C.     

Direct experimental evidence for a negative heat capacity in the liquid-to-gas phase transition in hydrogen cluster ions: backbending of the caloric curve

By selecting specific decay reactions in high-energy collisions (60 keV/amu) of hydrogen cluster ions with a helium target (utilizing event-by-event data of a recently developed multicoincidence experiment) and by deriving corresponding temperatures for these microcanonical cluster ensembles (analyzing respective fragment distributions), we are able to construct caloric curves for H+3(H2)(m) cluster ions (6相似文献   

Data cluster analysis: Abrupt transition

A cluster analysis optimization technique for partitioning data is applied to a class of distributions which are functions of a single variable. It is shown that under certain realizable conditions an infinitesimal change in the data distribution causes a large, abrupt change in the location of the optimal boundary separating two data clusters. This abrupt (phase) transition is illustrated with an example.     

Emission of quasi-thermal ions from a solid bombarded by cluster ions

Comparative studies of the emission of quasi-thermal atomic and cluster ions from V, Nb, Ta, Au, and In targets bombarded by cluster ions Au _m ⁻(m = 1–9), as well as from Si and Bi targets bombarded by cluster ions Au _m ⁻(m = 1–9) and Bi _m ⁻(m = 1–5), with energy E ₀ ranging from 6 to 21 keV are carried out. In the case of bombardment by heavy cluster ions, the fraction of the quasi-thermal component in the energy spectra of sputtered atomic ions reaches 50 (for V, In, and Au), 70 (Nb), or more than 90% (Ta). In addition, quasi-thermal ions play a considerable part in the emission of small cluster ions Au₂⁺, In₂⁺, In₃⁺, and Bi _n ⁺(n = 2–7). The results of the generalizing investigation favor the presence of thermal spike conditions at cluster bombardment and their appreciable contribution to the emission of atomic and small cluster ions.     

Evidence for a diffuse transition in lead chloride

The Raman spectra and the electrical conductivity of lead chloride single crystals at various temperatures, up to the melting point, have been investigated.From the results of both techniques we have found evidence of the beginnings of a diffuse transition to a state of high conductivity at temperatures close to the melting point of PbCl₂.     

Structural phase transition in a large cluster

The effect of a phase transition between structures in a large cluster with a pair interatomic interaction on the thermodynamic parameters of the cluster is analyzed. The statistical parameters of a cluster consisting of 923 atoms are determined for an icosahedron and a face-centered cubic (fcc) structure. The specific heat and entropy of this cluster are calculated in the case when the transition between the icosahedron and fcc structures has the greatest effect on these parameters, so that at zero temperature this cluster has the structure of an icosahedron, and as the temperature increases to the melting point it assumes an fcc structure. Even with this, the contribution of the excitations of the atomic configurations to the thermodynamic parameters of a cluster is small compared with the excitation of vibrations in the cluster. The contribution of a configurational excitation in the thermodynamic parameters of a cluster becomes substantial for the liquid state of clusters.     

High pressure effect on structural transition of Fe cluster during rapid quenching processes

Molecular dynamics simulations of 21,952 atoms have been performed to study local structure evolution and glass formation in iron melts rapidly cooled under high pressures.In the quenching processes,structural transition details have been analyzed by using the radial distribution function g(r) and bond pair analysis technique.It is shown that high pressure strengthens the order degree of the glass system and favors the glass formation.That means with the increase of pressures,a more compacted local structure with more ideal icosahedra can be obtained.The calculations of free volume of the system indicate that the decrease of the number of the defected ideal icosahedra under high pressure contributes to the glass formation of Fe.     

Evidence for a percolation-driven transition to coherent surface superconductivity

Above the upper critical field we have investigated the field dependences of the surface conductance, G'-iG" and the critical current J(c) of an electropolished pure niobium cylinder. The low frequency limits of G', G", and J(c) display power-law singularities, defining a transition to coherent surface superconductivity at H(c)(c3). The critical exponents as well as the dynamical scaling of G'-iG" are consistent with predictions for a two-dimensional percolation transition. Relating H(c)(c3) to the conventional onset field, we find H(c)(c3)/H(c3)=0.81, and, surprisingly, this ratio turns out to be independent of significant variations of H(c3) due to differently structured surfaces.     

Attosecond resolved charging of ions in a rare-gas cluster

A scheme to probe dissipative multielectron motion in time is introduced. In this context attosecond probing enables one to obtain information which is lost at later times and cannot be retrieved by conventional methods in the energy domain due to the incoherent nature of the dynamics. As a specific example we will trace the transient charging of ions in a rare-gas cluster during a strong femtosecond vacuum-ultraviolet pulse by means of delayed attosecond pulses.     

Molecular-dynamics simulation of methane adsorbed on MgO: Evidence for a Kosterlitz-Thouless transition

A realistic model of a monolayer molecular crystal of methane adsorbed on the (100) surface of MgO has been studied by means of molecular dynamics. The model treates the atomicity of the MgO substrate explicitly. Large corrugations in energy are found for both the translational and rotational motion of methane across the substrate. The preferred configurations of adsorption is over an Mg²⁺ ion in a tripod-down orientation. The orientationally ordered low-energy states of the monolayer have been found. Finite-size-scaling calculations on systems of different sizes indicate, however, that the ordered state exhibits only quasi-long-range order. The disclinations in the ordered phase exist in low concentrations and in bound pairs. Evidence is presented for a Kosterlitz-Thouless-type unbinding transition occurring at T _c ≈ 27 K. No evidence is found for a first-order transition. The specific heat exhibits an anomaly at T ≈ 32 K. The disclination density in the region of the transition is reported; below T _c, this density can be fitted to an Arrhenius-type law, yielding an estimate of the core enegy for a bound vortex-antivortex pair.     

Parastatistics and phase transition from a cluster as a fluctuation to a cluster as a distinguishable object

A phase transition of the first kind is a jump of a function, a phase transition of the second kind is a jump of its first derivative, a phase transition of the third kind, a jump of the second derivative. A phase transition from one statistic to another is very gradual, but finally it is as considerable as the phase transition of the first kind. However, we cannot introduce a clearly defined parameter to which this transition corresponds. This is due to the fact that the fluctuations near the critical point are huge, and this violates, in the vicinity of that point, the main law of equilibrium thermodynamics, which asserts that fluctuations are relatively small. The paper describes the transition in the supercritical fluid region of equilibrium thermodynamics from parastatistics to mixed statistics, in which the Boltzmann statistics is realized for long-living clusters. In economics this corresponds to a negative nominal credit rate. Examples of this non-standard situation are presented.     

Evidence for a spin-reorientation type phase transition in FeGeO3

Using single crystal susceptibility, Mössbauer and magnetoelectric measurements, the nature of the two low temperature phase transitions in the clinopyroxine metagermanate FeGeO₃ is studied. It is concluded that FeGeO₃ orders antiferromagnetically along the unique b axis at T_N = 47 ± 1°K and undergoes a spontaneous, second-order phase transition of the spin reorientation type at T_R = 17 ± 3°K. Only below T_R does FeGeO₃ exhibit magnetoelectricity.