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Dipl.-Ing. P. Israiloff Dr. H. Völlenkle Prof. Dr. A. Wittmann 《Monatshefte für Chemie / Chemical Monthly》1974,105(6):1387-1404
The crystal structure of the isotypic compoundsT 11Ge8 (T=V, Cr, Mn) has been determined by means of direct methods fromWeissenberg data of a Cr11Ge8 single crystal. A finalR-value of 7.7% was obtained by least squares refinement based on 684 observed reflexions. The orthorhombic unit cell (Pnam-D 2h 16 ) with the dimensionsa-13.171,b=15.775 andc=4.939 Å contains 4 formula units Cr11Ge8. Atoms are arranged mainly in primary layers atz=1/4, 3/4 with nets comprising squares, pentagons and hexagons which are all centered by atoms of secondary layers atz≈0, 1/2. Secondary layer atoms formT—T-chains as well as Ge?Ge-chains inz-direction with short bond lengths (2.47 Å). The structural relationship between Cr11Ge8, Cr5Ge3 (W5Si3-type) and V6Si5 is discussed. 相似文献
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Zusammenfassung Die Verbindungen {Sc,Y,Tb,Dy,Ho,Er,Tm,Yb,Lu}6Cu8Si8 sowie {Y,Yb}6Cu8Ge8 werden hergestellt. Diese sind isotyp mit der Gd6Cu8Ge8-Struktur. Die Gitterparameter werden ermittelt.
Mit 1 Abbildung 相似文献
Silicides and germanides with Gd6Cu8Ge8-structure type
The compounds {Sc,Y,Tb,Dy,Ho,Er,Tm,Yb,Lu}6Cu8Si8 and {Y,Yb}6Cu8Ge8 have been prepared. They were found to be analogous with the Gd6Cu8Ge8-structure type. The lattice parameters have been determined.
Mit 1 Abbildung 相似文献
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W. Rieger 《Monatshefte für Chemie / Chemical Monthly》1970,101(2):449-462
Zusammenfassung Die Verbindungen Gd(Dy, Er, Lu)6Cu8Ge8 wurden hergestellt und ihre Struktur bestimmt. Gd6Cu8Ge8 kristallisiert orthorhombisch in einem neuen Strukturtyp mita=14,000±0,008 Å,b=6,655±0,003 Å,c=4,223±0,004 Å, Raumgruppe D
2h
25
-I mmm mit 2 Gd in 2 (d), 4 Gd in 4 (e), 8 Cu in 8 (n), 4 Ge in 4 (f) und 4 Ge in 4 (h), N=1. Die Struktur ist durch Verwandtschaft zum AlB2- und CaZn5-Typ gekennzeichnet. Die anderen genannten Phasen sind dem Gd6Cu8Ge8 isotyp.
Mit 4 Abbildungen 相似文献
Crystal structure of Gd6Cu8Ge8, and of isotypic phases
The compounds Gd(Dy, Er, Lu)6Cu8Ge8 have been prepared and their structure has been determined. Gd6Cu8Ge8 crystallizes in a new structure type witha=14.000±0.008 Å,b=6.655±0.003 Å,c=4.223±0.004 Å, space group D 2h 25 -I mmm with 2 Gd in 2 (d), 4 Gd in 4 (e), 8 Cu in 8 (n), 4 Ge in 4 (f) and 4 Ge in 4 (h), N=1. The structure is characterized by close relationship to the AlB2 and CaZn5 structure types. The other phases mentioned above are isotypic to Gd6Cu8Ge8.
Mit 4 Abbildungen 相似文献
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A tetramer of nine-atom deltahedral germanium clusters and charge 8-, [Ge9=Ge9=Ge9=Ge9]8- , has been characterized as a (Rb-18C6)(+) salt (18C6 = 18-crown-6 polyether). The clusters are connected by pairs of parallel bonds, and the electrons are delocalized over the whole anion. The size of the tetramer is of nanorod dimensions, ca. 2 nm. 相似文献
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Imai M Sato A Udono H Imai Y Tajima H 《Dalton transactions (Cambridge, England : 2003)》2011,40(16):4045-4047
A ternary type-I Si clathrate K(8)Ga(8)Si(38) has been revealed to be an indirect band gap semiconducting material with an energy gap (E(g)) of approximately 0.10 eV, which is much smaller than the calculated E(g) value that is 0.15 eV wider than E(g) of elemental Si with the diamond-type structure. 相似文献
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The new intermetallic type-I clathrate Na8Zn4Ge42 was obtained by direct reaction of the elements, and its crystal structure was determined by means of single-crystal X-ray diffraction methods. The structure is described in space group Pm3 n (no. 223) with a = 10.6982(1) Å. A mixed Zn/Ge occupancy is found for one of the network sites (6c). Na8Zn4Ge42 represents an air-stable electron-precise Zintl phase with exclusively Na cations located in the cavities of a polyanionic host network of four-connected Zn and Ge atoms. 相似文献
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Chemical Vapor Transport of Intermetallic Systems. Chemical Transport of Cr(Ge) (Mixed Crystal) Cr3Ge, Cr5Ge3, Cr11Ge8, CrGe, Cr11Ge19 and Ge(Cr) (Mixed Crystal) All intermetallics in the Cr/Ge-system can be prepared by CVT-methods. The composition of the deposited crystals is influenced first and foremost by the composition of the starting material. Thermodynamic calculations allow to understand the process qualitatively. 相似文献
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The compound [K(18‐crown‐6)]8[Ge9=Ge9=Ge9=Ge9] ˙ 8en ( 1 ) featuring a [Ge9=Ge9=Ge9=Ge9]8‐cluster anion was synthesized from K4Ge9 for the first time. The X‐ray single crystal analysis shows that, in many respects such as bond connection and packing style, compound 1 is quite different from the previously reported compounds [Rb(18‐crown‐6)]8[Ge9=Ge9=Ge9=Ge9] ˙ 2en ( 2 ) and [Rb(18‐crown‐6)]8[Ge9=Ge9=Ge9=Ge9] ˙ 6en ( 3 ). Crystal packing of 1 gives strong indications that the highly charged nano‐rods self assembly in a hexagonal rod packing. 相似文献
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Pustková P. Shánělová J. Čičmanec P. Málek J. 《Journal of Thermal Analysis and Calorimetry》2003,72(1):355-362
The structural relaxation of Ge38S62 glass has been studied by length dilatometry and calorimetry. The Tool-Narayanaswamy-Moynihan model was applied on obtained
data of structural relaxation and parameters of this model were determined: Δh*= 483±2 kJ mol-1, ln(A/s)= -81±1, β= 0.7±0.1 and x=0.6±0.1. Both dilatometric and calorimetric relaxation data were compared on the basis of the fictive relaxation rate. It
was found that the relaxation rates are very similar and well correspond to the prediction of phenomenological model.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
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《Chemistry (Weinheim an der Bergstrasse, Germany)》2009,15(37):9611-9611
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《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(37):11495-11495
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《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(37):10479-10479
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《Chemistry (Weinheim an der Bergstrasse, Germany)》2014,20(38):11962-11973
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《Chemistry (Weinheim an der Bergstrasse, Germany)》2011,17(38):10485-10494