有效声子谱对超导体临界温度的影响

本文由超导体强耦合能隙方程出发,对64种有效声子谱求得了近3500个临界温度的数值解。它们说明,在谱面积A不变时,T_c具有条件极值(T_c/A)_max。T_c主要取决于α²F(ω)上峰的位置及其面积,与峰的宽度关系不大。控制<ω>及<ω²>两个参量时,用双δ谱来代替L谱所产生的误差为3.2％。本文分析并澄清了文献中关于“λ=2极限”的争论。 关键词：     

Removal of inelastic scattering part from Ti2p XPS spectrum of TiO2 by deconvolution method using O1s as response function

Ti2p and O1s XPS spectra of a clean surface of single crystal TiO₂ fractured in situ were taken to study the removal of the inelastic scattering part from the Ti2p spectrum. The features of inelastic scattering peaks in EELS were more influenced by surface than O1s XPS. It indicates that O1s XPS is proper as the response function to deconvolute a Ti2p spectrum. FWHM of the non-energy loss peak of Ti2p_3/2 is smaller than that of O1s. When the raw O1s spectrum is used as the response function, the deconvoluted spectrum has negative intensity values in some regions and beat waves. The replacement of the non-energy loss peak of O1s with narrower Gaussian peak takes off the beat waves. Peak separation of the deconvoluted spectrum reveals that it has six peaks. Two of them are main peaks of Ti2p_3/2 and 2p_1/2. The others are classified into two kinds of satellite peaks, whose energy separation from the main peaks are 3 and 13 eV. Although the latter satellites have been discussed by many authors, the former satellites are first reported here.     

New interpretation of the electronic structure of SiO2

The SiO₂ electronic density of states has been calculated within the Bethe lattice approximation using a simplified tight-binding hamiltonian. All of the experimentally found features, except a peak in the Si L_{2, 3} spectrum, are reproduced in our calculation when only unlike-atom bonds are present in the structure of the oxide. We have found that a possible origin of the peak in the Si L_{2, 3} spectrum is the presence of clusters of elemental Si in the oxide.     

Identification of the phosphor vacancy defect in electron irradiated p-type Inp

A new EPR spectrum has been observed in electron irradiated p-type InP. The spectrum is isotropic, has an effective g-factor of 2.05 + 0.04 and a peak to peak linewidth of 1800 G. Its introduction rate R = 1 cm⁻¹ . We attribute this spectrum to the neutral phosphor vacancy V⁰_P.     

铁磁-d波超导结中的粗糙界面散射和自旋反转效应对隧道谱的影响

考虑到铁磁层中的自旋极化效应、以及界面的粗糙散射和自旋反转效应,利用推广了的Blonder Tinkham Klapwijk理论模型,计算铁磁d波超导结中的自旋极化隧道谱.研究表明1)自旋反转效应能使零偏压电导峰变得尖锐;2)粗糙的界面散射除了能压低零偏压电导峰的高度,还能使零偏压凹陷处感应出一中心峰.结果能定性地解释最近的两篇关于La_2/3Ba_1/3 MnO₃/DyBa₂Cu₃O_{7关键词： 自旋极化效应 自旋反转效应 粗糙界面散射效应 隧道谱}     

CF3CDCl2分子红外多光子光热吸收谱

本文报道用铂丝光热吸收池作为探测器得到了CF₃CDCI₂的红外多光子吸收谱。并发现在线性吸收谱中944cm^-1处的吸收峰在多光子吸收谱中分裂为947cm^-1和927cm^-1两个吸收峰。这一现象与科里奥利力和非谐性引起的简正振动的耦合作用有关。这样,在用CF₃CDCI₂/CF₃CHCI₂体系分离氘同位素时,可以根据这一新结果选择更合适的激发波长。实验还发现在线性吸收谱中986cm^-1处的吸收峰在多光子吸收谱中出现约6cm^-2的红移。这种红移现象起源于分子振动能级的非谐性。 关键词：     

Raman scattering in amorphous boron

Raman scattering measurements have been performed at room temperature in thin film evaporated amorphous B and B_0.91C_0.09. The amorphous B spectrum indicates density of states features similar to those observed in infrared absorption as well as lower frequency scattering attributed to acoustic plus optic-like modes. The addition of C to amorphous B broadens the spectrum and shifts the lowest frequency peak to higher frequencies. A comparison of the amorphous B and broadened crystalline β-B Raman spectra indicates a number of similarities in peak frequencies that are consistent with similar short range order in both materials.     

Chemical effects on Al and Cu Auger electron spectra for the intermetallic compound CuAl2

This paper describes an experimental study of the intermetallic compound CuAl₂ using Auger electron spectroscopy (AES). Chemical effects in the CuAl₂ spectrum are observed corresponding to energy shifts of the Cu and Al peaks and the appearance of a new peak for the compound. These results are found to be in good agreement with those obtained using the technique of soft X-ray emission spectroscopy (SXES). The origin of the new peak appears to be a transition from a hybridised s-d band localized at the Cu site in the compound to an Al core state. This gives a band-like contribution to the CuAl₂ AES spectrum.     

Preparation and characterization of SnO2 nanoparticles using high power pulsed laser

Tin dioxide (SnO₂) nanoparticles having 3 nm size were synthesized by irradiating pure tin metal using high power Nd:YAG laser in deionized water. Formation of nano-SnO₂ crystallites was confirmed by X-ray diffraction (XRD) and AFM study. UV-vis absorption spectral studies showed a peak at 240 nm. FTIR spectrum showed a band in the range of 400-700 cm⁻¹ which was assigned to Sn-O antisymmetric vibrations. Photoluminescence spectrum of synthesized SnO₂ nanoparticles showed peak corresponding to 3.175, 2.901 and 2.613 eV respectively.     

金属玻璃(Fe0.8Ni0.15Cr0.05)78Si8B14的起始磁导率减落现象

在77—553K范围内的不同温度下测量了金属玻璃(Fe_0.8Ni_0.15,Cr_0.05)₇₈Si₈B₁₄的起始磁导率减落。测量结果表明,减落的温度关系表现为一个具有单一弛豫峰的不对称谱。在273K下考察了减落的动力学行为。用Hesse-Rubartsch方法拟合动力学曲线得到一个左右不对称的单峰激活能谱,最可几激活能大约为1.40eV。考察了减落的退火效应及退火动力学行为,结果表明,在宽的温度范围内,减落呈现明显的退火效应,而且退火动力学行为近似服从lnt动力学。 关键词：     

Optical and scintillation properties of Sr3BGa3Si2O14 (B = Nb,Ta) single crystals

Optical and scintillation properties of Sr₃NbGa₃Si₂O₁₄ [SNGS] and Sr₃TaGa₃Si₂O₁₄ [STGS] single crystals with the langasite-type crystal structure were investigated as a novel scintillator materials. In the transmittance spectra of the SNGS and STGS polished specimens, absorption peaks around 380 and 505 nm were observed and the absorptions are considered to be attributable to the excess oxygen in the crystals. An emission peak around 420 nm was observed in the X-ray radioluminescence spectrum of the SNGS crystal. On the other hand, there was an emission peak around 335 nm in the X-ray radioluminescence spectrum of the STGS crystal.     

Valence electronic structure of uranyl nitrate UO2(NO3)2·2H2O

Experimental and theoretical studies on the electronic structure of a uranyl nitrate hydrate, UO₂(NO₃)₂·2H₂O, have been performed by X-ray photoelectron spectroscopy (XPS) and with relativistic DV-Xα molecular orbital methods. The XPS spectra are measured within five minutes of X-ray irradiation, which causes negligible damage to the sample. Taking into consideration the calculated results, each peak of the experimental spectrum is assigned. The theoretical spectrum of the uranyl nitrate is in good agreement with the present experimental spectrum.     

Radioluminescent mechanism of Li2B4O7:Cu crystal

The structure of the radioluminescent (RL) spectrum of Li₂B₄O₇:Cu crystal is complex, having no normal Gauss peaks. The RL spectrum recorded showed one sharp and strong peak near 365 nm. For the purpose of explaining this phenomenon, we used the self-trapped exciton (STE) model to analyze experimental data of absorption spectrum, emission spectrum, radioluminescence spectrum and decay-time curves. We found a short lifetime component (of the order of ns) from phosphorous signals of Li₂B₄O₇:Cu. We realized that the short lifetime component related to inherent signal of host lattice and the d-p transitions of Cu⁺. This result is applicable in the detector system with high time resolution.     

Impurities and the static central peak in lead germanate

The static central peak in the Raman spectrum of lead germanate (Pb₅Ge₃O₁₁) has been studied as a function of barium-doping and oxygen concentration. It is found that the substitution of barium for lead dramatically increases the intensity and temperature spread of the central peak while also shifting it and the Curie point to much lower temperatures. On the other hand, variations in the observed central peak intensity in nominally pure samples cannot be correlated with variation in oxygen content and must be attributed to some as yet unidentified impurities or defects.     

Two peaks observed in the electroluminescence spectra of Alq3-based OLEDs

Tris(8-hydroxyquinolato) aluminum (Alq₃)-based organic light-emitting diodes were fabricated with or without using a hole transport layer (HTL). As a conventional device, the ITO/Alq₃/Mg-Ag device yielded a green-light emission with a single peak at 525 nm in the electroluminescence (EL) spectrum. In contrast, two sub-peaks were observed in the EL spectrum of some ITO/HTL/Alq₃/Mg-Ag devices. This difference was tentatively explained by comparing EL with the photoluminescence (PL) spectrum reported in the literature.     

Temperature peak-shift correction methods for NaI(Tl) and LaBr3(Ce) gamma-ray spectrum stabilisation

NaI(Tl) and LaBr₃(Ce) detectors are frequently operated under unstable temperature conditions when used in an open environment. These temperature changes result in a peak shift and spectral distortion during measurement. Two methods are proposed to stabilise the measured spectra; they are applied using a software algorithm, without the necessity of adjusting the gain. Both methods are based on the experimental observation that the relative channel displacement due to temperature changes is approximately the same for all channels. The first method corrects the spectrum using experimental data obtained under controlled conditions in the laboratory, and thus it only depends on the detector temperature. The second method uses one known peak in the spectrum to correct all of the channels: the NORM ⁴⁰K peak for the NaI(Tl) detector, the internal contaminant peak of ¹³⁸La for the LaBr₃(Ce), or an external source when these two cannot be easily identified.     

Phase transitions in La0.5Sr0.5FeO3−δ investigated by mechanical spectrum

The mechanical spectrum measurement was performed in ceramic La_0.5Sr_0.5FeO_3?δ from liquid nitrogen temperature to room temperature at kilohertz frequencies. From temperature dependent reduced modulus, a kink (corresponding temperature labeled as T_M) was observed which evidenced a phase transition by the mechanical spectrum at two flexural resonance frequencies. This elastic manifested phase transition is a charge disproportionation transition. Around 170 K, an internal friction peak (labeled as P1) was observed accompanied with a large modulus hardening with the decrease in temperature. Two mechanisms are proposed for P1 peak, one is elastic manifestation of magnetic freezing, and the other is the ordering or freezing of oxygen vacancies.     

The energy spectra of secondary ions emitted during ion bombardment

Secondary ion energy spectra have been measured for singly charged ions emitted from targets irradiated with 43 keV A⁺ ions. Targets studied include the 3d transition metals (Sc, Ti, V, Cr, Fe, Ni) Cu and Zn, Zr, Al and Si and the compounds SiO₂, Al₂O₃, NaCl, KCl. Energy spectra were measured in the energy range 1–600 eV. In several cases a peak in the energy spectrum in the region around 200 eV has been found. This is in addition to the usual low energy peaks in the region of 5–10 eV. In many cases the low energy peak was observed to decay steadily with irradiation time or to increase with oxygen pressure. In the case of the cleanest Zn spectrum, only the high energy peak can be detected. The data are discussed in relation to current models of secondary ion emission. We conclude that, in general, elemental metal targets which are clean are characterised by the high energy peak in the secondary ion energy spectrum. The slower ions emitted have been neutralised by electron exchange processes. The low energy peaks in unclean, partially clean, oxide coated or compound targets (NaCl, KCl) arise because the neutralisation of the slower ions is either not as efficient or is not possible. The secondary ion emission model of Blaise and Slodzian could account for the emission of ions from most targets.     

Light scattering from moving cluster walls in a model of displacive phase transitions

We calculated the spectrum of light scattered from moving cluster walls which were recently found to be important excitations for strongly anharmonic one-dimensional models exhibiting displacive phase transitions at T_c = 0. It is found that the scattering spectrum consists of a Gaussian central peak.     

Phonon-assisted stimulated emission in 2H type PbI2

The stimulated emission in 2H type PbI₂ crystals has been observed under N₂ laser beam excitation at 4.2 K. The analysis of its gain spectrum shows that the emission is induced by the recombination of free exciton assisted by the emission of one longitudinal optical phonon. At a higher level of excitation, the gain spectrum peak shifts to lower energy side. Possible mechanisms of this spectral change are discussed.