Determination of the spectroscopic quadrupole moments of 131Cs, 132Cs and 136Cs

Nuclear spectroscopic quadrupole moments of the radioactive isotopes ¹³¹Cs, ¹³²Cs, and ¹³⁶Cs have been determined from the hyperfine structure of the $\text{6}{}^2\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ state by the level crossing method. The results including a Sternheimer correction are: $\text{Q}{}_{\mathrm{<mtext>s</mtext>}}\text{(}{}^{131}\text{Cs}\text{) = ?0.625(6)}\text{b}$, $\text{Q}{}_{\mathrm{<mtext>s</mtext>}}\text{(}{}^{132}\text{Cs}\text{) = +0.508(7)}\text{b}$, $\text{Q}{}_{\mathrm{<mtext>s</mtext>}}\text{(}{}^{136}\text{Cs}\text{) = +0.225(10)}\text{b}$. The quadrupole moments of all the Cs isotopes from A = 131 to A = 137 are recalculated. It is shown, that nuclear quadrupole moments of a specific isotope obtained from different atomic P-states only agree within the limits of error after application of the Sternheimer correction. The increase of Q_s with decreasing neutron number conforms with other observations and theoretical calculations stating that for elements around Z = 55 nuclear deformation develops below N = 82. The staggering of the sign of Q_s may be interpreted as consequence of an oblate-prolate degeneracy of the nuclear energy surface. Some magnetic moments have been slightly improved: $\text{μ}{}_{\mathrm{<mtext>I</mtext>}}\text{(}{}^{132}\text{Cs}\text{) = 2.219(7) μ}{}_{\mathrm{<mtext>N</mtext>}}$, $\text{μ}{}_{\mathrm{<mtext>I</mtext>}}\text{(}{}^{136}\text{Cs}\text{) = 3.705(15)μ}{}_{\mathrm{<mtext>N</mtext>}}$ (corrected for diamagnetism).     

Beta-delayed alpha-particle emission from 118, 120 Cs

The isotopes ${}^{118}\text{Cs}\text{(T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 16}\text{s}\text{)}$ and ¹²⁰ Cs (58 s) were found to have unresolved, bell-shaped α-particle spectra extending from 7 to 10 MeV and from 6 to 9 MeV, respectively. The branching ratios are (2.4 ± 0.4) × 10^?5 and (2.0 ± 0.4) × 10^?7. The experiment confirms ¹²⁰Cs to be a delayed-proton emitter with a proton branch of (7±3) × 10^?8.     

Perhaps scalar neutrinos are the lightest supersymmetric partners

We consider the possibility that the scalar partners of the neutrinos $\text{(}\text{v}\text{)}$ are the least massive supersymmetric partners, and show that this alternative is compatible with cosmological constraints, which put a significant lower bound on photino masses but not on $\text{v}$ masses. Various consequences are examined: the photon counting rate for $\text{e}{}^{\mathrm{+}}\text{e}{}^{\mathrm{-}}\text{→γ}\text{v}$$\text{v}\text{?}\text{?}$ may be large; the rate for $\text{e}{}^{\mathrm{+}}\text{e}{}^{\mathrm{-}}\text{→}\text{W}{}^{\mathrm{+}}\text{a}\text{W}{}^{\mathrm{-}}$ by $\text{v}$ exchange is enhaced; Z⁰→ increases Γ(Z⁰) by about 0.25 GeV; $\text{W}{}^{\mathrm{\pm }}\text{→}\text{?}{}^{\mathrm{+-}}\text{v}$ may be enhanced; the decay $\text{τ→}\text{v}{}_{\mathrm{\tau }}\text{?}{}_{\mathrm{?}}$$\text{v}\text{?}\text{?}$ may be detectable; there can be additional contributions to the rare decay $\text{K}{}^{\mathrm{+}}\text{→π}{}^{\mathrm{+}}\text{v}$$\text{v}\text{?}\text{?}$; restrictions on gluino masses, which depend on photinos interacting before they decay, have to be re-examined; scalar neutrinos have suitable characteristics as candidates for dark matter in the universe. We discuss one currently fashionable class of models that can predicr a light $\text{v}$.     

Analysis of the 2770-Å emission system in I2

A weak emission spectrum of I₂ near 2770 Å is reanalyzed and found to to minate on the A(1u³Π) state. The assigned bands span v″ levels 5–19 and v′ levels 0–8. The new assignment is corroborated by isotope shifts, band profile simulations, and Franck-Condon calculations. The excited state is an ion-pair state, probably the 1g state which tends toward $\text{I}{}^{\mathrm{?}}\text{(}{}^1\text{S) +}\text{I}{}^{\mathrm{+}}\text{(}{}^3\text{P}{}_1\text{)}$. In combination with other results for the A state, the analysis yields the following spectroscopic constants: T″_e = 10 907 cm^?1, $\text{D}$″_e = 1640 cm^?1, ω″_e = 95 cm^?1, $\text{R″}{}_{\mathrm{e}}\text{= 3.06}\text{A}\text{?}$; T′_e = 47 559.1 cm^?1, ω′_e = 106.60 cm^?1, $\text{R′}{}_{\mathrm{e}}\text{= 3.53}\text{A}\text{?}$.     

Observed and calculated interactions between valence states of the NO molecule

No perturbation between two valence states of NO has ever been identified, although many valence-Rydberg and several Rydberg-Rydberg perturbations have been extensively studied. The first valence-valence crossing to be experimentally documented for NO is reported here and occurs between the ¹⁵N¹⁸O B²Π (v = 18) and B′²Δ (v = 1) levels. No level shifts larger than the detection limit of 0.1 cm^?1 are observed at the crossings near $\text{J = 6.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_2\text{)]}$ and $\text{J = 12.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_1\text{)]}$; two crossings involving higher rotational levels could not be examined. Semi-empirical calculations of spin-orbit and Coriolis perturbation matrix elements indicate that although the electronic part of the $\text{B}{}^2\text{Π}\text{～ B′}{}^2\text{Δ}$ interaction is large, a small vibrational factor renders the ¹⁵N¹⁸O B (v = 18) ? B′ (v = 1) perturbation unobservable. Semi-empirical estimates are given for all perturbation matrix elements of the operators $\text{Σ}{}_{\mathrm{i}}\text{a}\text{?}{}_{\mathrm{i}}\text{l}{}_{\mathrm{i}}\text{·s}{}_{\mathrm{i}}$ and $\text{B(L}{}_{\mathrm{\pm }}\text{S}{}_{\mathrm{?}}\text{? J}{}_{\mathrm{\pm }}\text{L}{}_{\mathrm{?}}\text{)}$ which connect states belonging to the configurations $\text{(σ2p)}{}^2\text{(π2p)}{}^4\text{(π}{}^1\text{2p)}$, $\text{(σ2p)(π2p)}{}^4\text{(π}{}^1\text{2p)}{}^2$, and $\text{(σ2p)}{}^2\text{(π2p)}{}^3\text{(π}{}^1\text{2p)}{}^2$.     

Hyperfine structure determination of the 72D52state of 133Cs

The magnitude and sign of the hyperfine structure of $\text{7}{}^2\text{D}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$state of ¹³³Cs have been measured. We find the magnetic dipole coupling constant to be A = -1.7 (2) MHz.     

Nuclear moments and optical isotope shift of radioactive 133Ba

Mass separated radioactive ¹³³Ba has been investigated by means of optical spectroscopy. From hyperfine structure and isotope shift we obtain the nuclear magnetic moment μ_I = ?0.769(3) μ_n and the change of the nuclear mean square charge radius $\text{δ〈r}{}^2\text{〉 (}{}^{133}\text{Ba}\text{?}{}^{132}\text{Ba}\text{) = ?0.017(3)}\text{fm}{}^2$.     

Polarization spectroscopy of the E0g+-B0u+ band system of Br2

The E-B (0_g⁺-0_u⁺) band system of Br₂ has been investigated at Doppler-limited resolution using polarization labeling spectroscopy. Merged E state data for the three naturally occurring isotopes in the range v_E = 0–16, expressed in terms of the constants for ⁷⁹Br₂, are (in cm^?1) Y_0,0 = 49 777.962(54), Y_1,0 = 150.834(22), Y_2,0 = ?0.4182(28), Y_3,0 = 6.6(11) × 10^?4, Y_0,1 = 4.1876(28) × 10^?2, Y_1,1 = ?1.607(16) × 10^?4, and Y_0,2 = 1.39(39) × 10^?8. The bond distance is $\text{r}{}_{\mathrm{<mtext>e</mtext>}}\text{= 3.194}\text{A}\text{?}$, and the diabatic dissociation energy to $\text{Br}{}^{\mathrm{+}}\text{(}{}^3\text{P}{}_2\text{) +}\text{Br}{}^{\mathrm{?}}\text{(}{}^1\text{S}{}_0\text{)}\text{is 34 700 cm}{}^{\mathrm{?1}}$.     

Nuclear orientation study of the excited states of 129I populated in the decay of 129gTe and 129mTe

From the angular distributions of γ-rays emitted by oriented ^129gTe and ^129mTe nuclei implanted in iron by isotope separator, unique spin assignments could be made for the excited states of ¹²⁹I at 487.4 keV $\text{(}\text{5}\text{2}{}^{\mathrm{+}}\text{)}$, 696.0 keV $\text{(}\text{11}\text{2}{}^{\mathrm{+}}\text{)}$, 729.6 keV $\text{(}\text{9}\text{2}{}^{\mathrm{+}}\text{)}$, 768.9 keV $\text{(}\text{7}\text{2}{}^{\mathrm{+}}\text{)}$, 1050.4 keV $\text{(}\text{7}\text{2}{}^{\mathrm{+}}\text{)}$ and 1111.8 keV $\text{(}\text{5}\text{2}{}^{\mathrm{+}}\text{)}$. In addition, E2/M1 amplitude ratios for the following ¹²⁹I γ-rays (energies are in keV) are derived: δ(459.6) = ?(0.076^+0.037_?0.148); δ(487.4) = 0.50^+0.17_?0.10 or δ^? = 0.35^+0.15_?0.09; δ(556.7) = 0.06±0.02 or δ^? = ?(0.10±0.02); δ(624.4) = 0.10±0.26 or δ^? > 0.4; the 696.0 keV γ-ray is pure E2; δ(729.6) = ?(0.34±0.06) or δ^?1 = 0.55±0.05; δ(741.1) = ?(0.27±0.10) or δ^?1 = ?(0.43±0.12); δ(817.2) = 0.46±0.04 or δ^?1 =0.20±0.03 if $\text{I}{}^{\mathrm{\pi }}\text{(845}\text{keV}\text{) =}\text{7}\text{2}{}^{\mathrm{+}}$; δ(1022.6) = ?(0.02 ±0.02) or δ^?1 = ?(0.23±0.02); $\text{δ(1084) = 0.56}{}^{\mathrm{+0.04}}{}_{\mathrm{?0.14}}$; δ(1111.8) = 0.06±0.05 or δ^?1 = ?(0.08±0.05). The anisotropy of the 531.8 keV γ-ray excludes $\text{1}\text{2}{}^{\mathrm{+}}$ as a possible spin assignment for the 559.6 keV level, so that no $\text{1}\text{2}{}^{\mathrm{+}}$ level is fed in the decay from ¹²⁹Te. Anisotropies for the 209, 250.7, 278.4 and 281.1 keV γ-rays are also measured. Comparison of the level scheme is made with theoretical predictions from both the pairing-plus-quadrupole model and the intermediate coupling unified model.     

Rotational analyses and vibrational assignments of the 463- and 474-nm bands of NO2

The excitation spectrum of NO₂ was investigated in the blue region by using a Nd:YAG laser-pumped dye laser. The 463- and 474-nm bands of the ²B₂-²A₁ system were identified and analyzed using the simplification that occurs if the excitation spectrum is monitored at particular wavelengths. Band origins and rotational constants were obtained. Vibrational assignments have been given to these bands by comparing the Franck-Condon Factors calculated for the ²B₂-²A₁ system with the fluorescence intensities of bands going to different vibrational levels of the ground state. The vibrational assignments and molecular constants obtained in this work are (v′₁, v′₂, v′₃) = (3, 11, 0)ν₀(K′ = 0) = 21584.1, $\text{B}\text{= 0.405}$, and $\text{∥}\text{?}\text{′∥ = 0.05}\text{cm}{}^{\mathrm{?1}}$ for the 463-nm band; and (v′₁, v′₂, v′₃) = (2, 12, 0), ν₀(K′ = 1) = 21104.9, $\text{B}\text{= 0.408}$, and $\text{∥}\text{?}\text{′∥ = 0.03}\text{cm}{}^{\mathrm{?1}}$ for the 474-nm band.     

Finding out about B mesons and B-B0 mixing on the ϒ‴ resonance

We point out that existing data on the resonance shape of ?? provide useful bounds on the B meson mass: M(??)? 2 M(B) = 9_?6⁺¹² MeV if one uses the quark pair creation model. From the upper limits on $\text{B}{}^1\text{B}\text{+}\text{B}\text{B}{}^1$ production one gets M(??) ? 2M(B) < 37 MeV. We show how measurements of inclusive semileptonic B decays allow us to determine the electromagnetic mass splitting M(B⁰) ? M(B^?) without having to identify exclusive B decays. As byproducts one obtains information on the B⁰-B^? lifetime ratio and on $\text{B}{}^0\text{-}\text{B}{}^0$ mixing.     

Thermochemistry of azide salts and the azide ion using direct minimisation equations to obtain the lattice energy of the univalent azide salts

The opportunity to test a new equation for the computation of the lattice energy and at the same time examine a disparity in the literature data for the enthalpy of formation of the azide ion, $\text{ΔH}{}^{\mathrm{\theta }}{}_{\mathrm{?}}\text{(}\text{N}{}_3{}^{\mathrm{?}}\text{) (}\text{g}\text{)}$ was the motivation for this study. The results confirm our earlier calculation and show the new equation to be reliable. Thermodynamic data produced in the study take values: $\text{ΔH}{}^{\mathrm{\theta }}{}_{\mathrm{?}}\text{(}\text{N}{}_3{}^{\mathrm{?}}\text{)(}\text{g}\text{) = 144}\text{kJ mor}{}^{\mathrm{?1}}$ΔH^θ_hyd(N₃^?) = ?315 KJ mol^?1 or ΔH^θ_hyd(N₃^?) = ?295 KJ mol^?1U_POT(NaN₃) = 732 kJ mol^?1U_POT(KN₃) = 659 kJ mol^?1U_POT(RbN₃) = 637 kJ mol^?1U_POT(CsN₃) = 612 kJ mol^?1U_POT(TIN₃) = 689 kJ mol^?1. The lattice energies of azides whose enthalpies of formation are documented have been calculated as well as the enthalpy of formation of the azide radical.     

Nuclear magnetic moment of the 9.7 h 12− isomer 196mAu

The magnetic hyperfine splitting v_M=|gμ_NB_HF/h| of ^196mAu (j^π=12^?; configuration ¦(π$\text{11}\text{2}$($\text{v}\text{13}\text{2}{}^{\mathrm{+}}\text{)〉}{}_{12}{}^{\mathrm{?}}$; $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 9.7}\text{h}\text{)}$ as dilute impurity in Ni has been determined with nuclear magnetic resonance on oriented nuclei as 96.0(2) MHz. With the known hyperfine field B_HF = ?264.4(3.9) kG corrected for hyperfine anomalies the g-factor and magnetic moment of ^196mAu are deduced to be |g| = 0.476(7) and |μ| = 5.72(8) μ_N. Taking into account the known magnetic properties of $\text{π}\text{1}\text{2}{}^{\mathrm{?}}$ and $\text{v}\text{13}\text{2}{}^{\mathrm{+}}$ isomeric states in the neighbouring odd Pt, Au and Hg nuclei the structure of the 12^? state is discussed.     

The rotational spectrum of the X 2Σ+ state of the SrF radical using laser microwave optical double resonance

The pure rotational spectrum of the $\text{X}{}^2\text{Σ}{}^{\mathrm{+}}$ state of the gaseous SrF radical has been measured using microwave optical double resonance (MODR) techniques. The analysis fully confirms the recent dye laser excitation spectrum and rotational assignment of the $\text{B}{}^2\text{Σ}{}^{\mathrm{+}}\text{-X}{}^2\text{Σ}{}^{\mathrm{+}}$ system. Transitions were measured in both the v″ = 0 and v″ = 1 states to give values of B_e″ = 0.250533 cm^?1, α_e″ = 1.546 × 10^?3 cm^?1 and γ″ (spin-rotation) = 2.49 × 10^?3 cm^?1. General qualitative features of MODR in ²Σ⁺ states are treated and suggested improvements for obtaining experimental hyperfine constants are discussed. The more precise ground state constants are merged with the B-X optical analysis to obtain a more accurate set of constants for both states.     

The emission spectra of H35Cl+, H37Cl+, D35Cl+, and D37Cl+ in the region 2700–4100 Å

The $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}\text{-X}{}^2\text{Π}$ emission spectrum of HCl⁺ has been measured and analyzed for four isotopic combinations. These analyses extend previous work and provide rotational constants for the v = 0–2 levels of the ground state and for the v = 0–9 levels of the excited state. RKR potentials have been determined for both states, although the upper state could not be fitted precisely to such a model. Calculated relative intensities based on these potentials demonstrated that the electronic transition moment must change rapidly with lower state vibrational quantum number. Although considerable caution should be exercised in applying the concept of equilibrium constants to the $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}$ state, the following are the best estimates of these constants (in cm^?1) for the $\text{X}{}^2\text{Π}$ state of H³⁵Cl⁺: B_e = 9.9406, ω_e = 2673.7, A_e = ? 643.7, and $\text{r}{}_{\mathrm{e}}\text{= 1.315}\text{A}\text{?}$. For the $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}$ state of H³⁵Cl: T_e = 28 628.08, B_e ～ 7.505, ω_e ～ 1606.5, and $\text{r}{}_{\mathrm{e}}\text{= 1.514}\text{A}\text{?}$.     

The fine structure of the spectrum of the electronic NO laser

The spectrum of the electronic NO laser has been photographed with high resolution in the region 10 100–10 500 Å. It shows the band system F²Δ-C²Π whose upper and lower states are both Rydberg states configurationally mixed with valence states. Only predissociated rotational levels of the lower state appear in the spectrum. For v = 0 of C²Π a single mixed level $\text{T}{}_{\mathrm{y}}\text{(J = 5}\text{1}\text{2}\text{) = 52431}\text{cm}{}^{\mathrm{?1}}$, very close to the dissociation limit, gives rise to laser lines.     

Vibration-rotation spectrum of HCF (X̃1A′) by laser-induced fluorescence

The vibration-rotation spectrum of the HCF molecule was observed by laser-induced fluorescence with an Ar⁺ laser. The laser line of 514.5 nm coincided with two rovibronic transitions, ^rR₁(9) and ^pQ₅(9) for $\text{A}\text{?}{}^1\text{A″(020)-}\text{X}\text{?}{}^1\text{A′(000)}$. The spectrum consisted of the progression of bending vibrational mode ν₂. The rotational lines were fully resolved for each of the vibronic bands. The analysis yielded the vibrational and rotational parameters for both the ground and the excited vibronic states. The rotational parameters of the $\text{X}\text{?}{}^1\text{A′}$ state were obtained for four vibrational levels [(0v₂0), v₂ = 0 – 3].     

Charm production by weak neutral currents

We discuss quantitatively the production of charm in $\text{v}\text{N and}\text{v}\text{N}$ neutral current interactions, and the anomalous lepton events that follow from semi-leptonic charm decay. Diagonal neutral currents, in the Weinberg-Salam model and similar models, predict associated charm production with small cross sections: e.g. $\text{σ(v}\text{N}\text{→ vcc}{}^{\mathrm{?}}\text{X}\text{)/σ(v}\text{N}\text{→ μ}{}^{\mathrm{?}}\text{X}\text{) ? 10}{}^{\mathrm{?2}}$ at high energy. The meagre data on vN → ve⁺X are consistent with a rate of this order. Non-diagonal neutral currents, if present, could give larger cross sections via valence p → c transitions. It should be possible to distinguish diagonal from non-diagonal contributions by their x- or u-dependences, where u = x(1 ? y). We calculate the expected energy distributions of the leptons in characteristic vN → v?⁺X and vN → v?⁺?^?X charm decay events using simple models, and discuss some practical problems in neutral current measurements.     

Resonances in the reaction 56Fe(p, γ)57Co

Resonances in the reaction ⁵⁶Fe(p, γ)⁵⁷Co have been surveyed over the energy range 1.2 ? E_p ? 1.5 MeV wherein the analogues of the ground state $\text{(J}{}^{\mathrm{\pi }}\text{=}\text{1}\text{2}{}^{\mathrm{?}}\text{, 0.014}\text{MeV}$ state $\text{(J}{}^{\mathrm{\pi }}\text{=}\text{3}\text{2}{}^{\mathrm{?}}\text{)}$ and 0.136 MeV state $\text{(J}{}^{\mathrm{\pi }}\text{=}\text{5}\text{2}{}^{\mathrm{?}}\text{)}$ of ⁵⁷Fe are expected to occur. Gamma-ray angular distributions have been used to establish resonance and bound-state spins, and decay schemes have been determined. The analogue resonances appear to be severely fragmented, however the density of resonances of a given spin correlates quite well with (³He, d) results and with the expected analogue-state positions.     

Band contour analysis of compounds with pure isotopes: The E fundamentals of HC35Cl3

The vibration-rotation transitions for v = 1 ← 0 of NO (${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$) have been studied by using the technique of laser magnetic resonance spectroscopy. Five magnetic resonance lines are observed with three CO laser lines in the range from 1859 to 1886 cm^?1. From these, three zero-field transition frequencies, v = 1 ← 0; $\text{R(}\text{3}\text{2}\text{)}$, $\text{P(}\text{7}\text{2}\text{)}$, and $\text{P(}\text{9}\text{2}\text{)}$ are obtained with an accuracy of ±0.0007 cm^?1. The molecular constants which have been determined by borrowing centrifugal constants from a previous infrared work are $\text{B}{}_{02}{}^1\text{= 1.72004 ± 0.00006}\text{cm}{}^{\mathrm{?1}}$, $\text{B}{}_{12}{}^1\text{= 1.70212 ± 0.00010}\text{cm}{}^{\mathrm{?1}}$, and $\text{G(v = 1) ? G(v = 0) (}\text{for}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{) = 1875.8470 ± 0.0007}\text{cm}{}^{\mathrm{?1}}$.