共查询到20条相似文献,搜索用时 93 毫秒
1.
The magnetic fields at which Zeeman sublevels cross in the excited 53P1 state of the 43-day isomer 115Cdm have been determined for three pairs of levels. The crossing fields are used to determine the magnetic dipole hyperfine structure constant and the quadrupole constant . 相似文献
2.
Peter Zimmermann Theodore W. Ducas Michael G. Littman Daniel Kleppner 《Optics Communications》1974,12(2):198-201
We present a new technique for selectively populating excited states which are inaccessible by dipole excitation from the ground state. The method uses a static electric field to introduce a component of a dipole-allowed state into the state of interest. We have applied the method to cesium to measure lifetimes and a Stark mixing coefficient. The results are , , and <62D|;ez |72P>/(E7P?E6D)=0.7(3)×10?3 where is in kV/cm. 141 相似文献
3.
4.
A weak emission spectrum of I2 near 2770 Å is reanalyzed and found to to minate on the A(1u3Π) state. The assigned bands span v″ levels 5–19 and v′ levels 0–8. The new assignment is corroborated by isotope shifts, band profile simulations, and Franck-Condon calculations. The excited state is an ion-pair state, probably the 1g state which tends toward . In combination with other results for the A state, the analysis yields the following spectroscopic constants: T″e = 10 907 cm?1, ″e = 1640 cm?1, ω″e = 95 cm?1, ; T′e = 47 559.1 cm?1, ω′e = 106.60 cm?1, . 相似文献
5.
Radiative lifetimes of the 4d5 (a6S)5pz 7Po levels and the 4d5 (a6S)5pz5Po levels in MoI are reported as follows: , , , , , and (±5%). The lifetimes are measured using time resolved laser induced fluorescence and a novel atomic beam source. This novel hollow cathode effusive beam source produces an intense beam of ground state Mo atoms and metastable Mo atoms. Our measurements on the z 7PO levels are in agreement with earlier lifetime measurements. Our measurements on the z 5PO levels are the first direct radiative lifetime measurements of these levels; the z 5PO measurements are of particular interest because the a5S → z5PO multiplet is used to determine the solar abundance of Mo. 相似文献
6.
L.E. Erickson 《Optics Communications》1977,21(1):147-149
The nuclear quadrupole hyperfine splittings of Pr3+ in LaF3 have been measured for the ground electronic state using a RF optical resonance technique. A hamiltonian 2-)] was fitted to the data with zP=4.185 ± 0.003 MHzandη = 0.105 ± 0.010. Linewidths of 180 kHz were observed. 相似文献
7.
Line positions and molecular constants for the 0-0, 1-0, 2-0, 0-1, 2-1, 3-1, 0-2, 1-2, and 4-2 bands of the C2 Phillips system () are reported. Among them, five bands have not been reported previously. Rotational perturbations have been observed in the previously unobserved v = 1 level of the state. This state is perturbed by the state which was discovered by Ballik and Ramsay. These observations provide new information regarding the perturbing state. In particular, the minimum of the potential energy for the state has been found to be at 9227.4 cm?1 instead of 13 310 cm?1, which was the previous Te value for this electronic state. 相似文献
8.
We describe the optical absorption spectrum of a single crystal of Gadolinium Molybdata (GMO) at the temperature of liquid helium. We observe a set of sharp lines in the near ultra violet region; we clasify the lines into three groups A, B, and C. We study the positions of the lines as functions of the orientation of the crystal relative to the polarization of the incident light and we investigate the Zeeman effect on the lines of the groups A and B. We suggest that the observed lines of all three groups are due to transitions between the ground state and the excited , and states of the Gd3+ ion in the crystal. 相似文献
9.
Clive E. Barnes John M. Brown Alan D. Fackerell Trevor J. Sears 《Journal of Molecular Spectroscopy》1982,92(2):485-496
Lines in the ν3 (“antisymmetric” stretch) fundamental of the NCO radical in the state were studied by CO laser magnetic resonance. The observations were assigned to P and R lines in the vibration-rotation band and lead to a precise determination of the vibrational interval and the anharmonic correction to the rotational constant: ν3 = 1920.60645(19) cm?1, α3 = 0.003338(21) cm?1. A single transition in the hot band (011)-(010), was detected. This observation is used to determine the origin of the hot band as 1907.11892(20) cm?1, i.e., the anharmonicity parameter x23 = ?13.48753(28) cm?1. 相似文献
10.
Robert S. Mulliken 《Journal of Molecular Spectroscopy》1976,61(1):92-99
Predissociations in the y1Πg and Rydberg states of N2 (configurations and , respectively) and their likely causes, are discussed. Peaking of rotational intensity at unusually low J values, without sharp breaking off, is interpreted as due to case c? or case ci predissociation. Λ doubling in the y state, attributed to interactions with the state and with another, 1Σ+, state of the same electron configuration as x, is analyzed. From this analysis the location of the (unobserved) state, here labeled x′, is obtained. It is concluded that the predissociation in the Π+ levels of the y state is an indirect one mediated by the interaction with x′ coupled with predissociation of x′ by a state dissociating to atoms: combined, however, with perturbation of the y state by the k1Πg Rydberg state (configuration ), whose Π+ levels are completely predissociated. 相似文献
11.
John W. Birks Steven D. Gabelnick Harold S. Johnston 《Journal of Molecular Spectroscopy》1975,57(1):23-46
Emission from both the state and the previously unreported state of IF has been observed in the gas phase reaction of I2 with F2 at low pressures. For the state the transition moment and vibrational populations were extracted from the spectra by a least-squares method whereby theoretical band shapes were fit to the experimental data. The effect of flow rates of reactants and Ar on the relative emission from the two electronic states, the effect of pressure on the state, and extinction of emission near 470 nm all favor the population of excited electronic states through a four-center reaction complex, rather than association of F and I atoms.It is argued that there is an avoided curve crossing between the lowest two 3Π0+ states of IF, and that the ground state dissociation energy is 23 229 ± 100 cm?1. The radiative lifetime of the state is estimated to be 10?3 sec and to be much shorter than that of the state. 相似文献
12.
From a study of (p,t) reactions on 31P and 30Si it is suggested that in 29P the states with and , the pair , , and the pair , are related by weak coupling of a s proton with the states 01+, 02+, 21+ and 41+ respectively of 28Si. Completely atypical L = 2 angular distributions have been obtained for the and states in 29P and it is suggested that this is due to contribution by two-step processes. 相似文献
13.
Keiji Matsumura Kentarou Kawaguchi Keiichi Nagai Chikashi Yamada Eizi Hirota 《Journal of Molecular Spectroscopy》1980,84(1):68-73
The v = 1 ← 0 vibration-rotation bands of the NS radical in the and electronic states were observed by using a tunable diode laser. From the least-squares analysis the band origins were determined to be 1204.2755(12) and 1204.0892(19) cm?1, respectively, for and . The rotational and centrifugal distortion constants and the internuclear distance in the X2Π electronic state were obtained as follows: Be = 0.775549(10) cm?1, De = 0.00000129(33) cm?1, and , with three standard deviations indicated in parentheses. 相似文献
14.
Kentarou Kawaguchi Chikashi Yamada Yoshiaki Hamada Eizi Hirota 《Journal of Molecular Spectroscopy》1981,86(1):136-142
The fundamental bands of the CF radical in the and electronic states were observed by using an infrared tunable diode laser as a source. Zeeman modulation could be used in detecting lines not only in the state, but also in , because the CF radical deviates considerably from Hund's case (a). From the least-squares analysis of the observed spectra, the following molecular constants were obtained: Be = 1.416 704 (37) cm?1, αe = 0.018 419 (50) cm?1, , De = 6.68 (15) × 10?6cm?1, p0 = 0.008 580 (21) cm?1, p1 = 0.008 52 (11) cm?1, and , with three standard errors in parentheses. 相似文献
15.
Discharges through mixtures of helium and neon show two band groups near 4250 and 4100 Å as first observed by Druyvesteyn. These bands, assigned to the HeNe+ ion by Tanaka, Yoshino, and Freeman, have been studied under high resolution and have been fairly completely analyzed. The upper state of the transition is a very weakly bound state resulting from . There are two lower states resulting from the two components of . The upper of these two () is also very weakly bound while the lower of the two, the 2Σ+ ground state, has a dissociation energy of 0.69 eV and an re value of 1.30 Å. All bands in both band groups show four branches designated Rff, Qef, Qfe, and Pee. From their analysis the rotational constants in the various vibrational levels of the three electronic states have been determined. While no spin splitting in the B2Σ+ state has been found the ground state X2Σ shows a very large spin splitting and the state a very large doubling. The vibrational numberings in all these states were established by the study of the spectrum of 3HeNe+. At the same time the hyperfine structure observed in all lines of 3HeNe+ confirmed the nature of the upper state B2Σ+ as resulting from He+ + Ne, i.e., by charge exchange from the ground state. The component of the 2Π state has not been observed, presumably because of low intensity. 相似文献
16.
D. Ziemińska 《Nuclear Physics A》1975,242(3):461-466
The branching ratios are calculated for 11ΛB decay to the 11C ground and excited states below 8 MeV for two possible spin values of 11ΛB. It is found that the decay rate to the 11C★ state at E★ = 6.48 MeV is comparable in magnitude to that leading to the 11C ground state if is assumed. This result, unlike the branching ratios calculated for the case, is in accord with experiment and lends support to the assumption that holds for 11ΛB. The necessity of the reinterpretation of some of the so-called 13ΛC events in terms of is indicated. 相似文献
17.
Nuclear spectroscopic quadrupole moments of the radioactive isotopes 131Cs, 132Cs, and 136Cs have been determined from the hyperfine structure of the state by the level crossing method. The results including a Sternheimer correction are: , , . The quadrupole moments of all the Cs isotopes from A = 131 to A = 137 are recalculated. It is shown, that nuclear quadrupole moments of a specific isotope obtained from different atomic P-states only agree within the limits of error after application of the Sternheimer correction. The increase of Qs with decreasing neutron number conforms with other observations and theoretical calculations stating that for elements around Z = 55 nuclear deformation develops below N = 82. The staggering of the sign of Qs may be interpreted as consequence of an oblate-prolate degeneracy of the nuclear energy surface. Some magnetic moments have been slightly improved: , (corrected for diamagnetism). 相似文献
18.
Cross sections for fine-structure mixing in potassium, induced in collisions with N2, H2, CO, and CH4, were determined by methods of atomic fluorescence spectroscopy. The experiments were carried out at a temperature of 342 K, a K density of 6 × 109 cm?3 and mtorr buffer gas pressures, and yielded the following cross sections ) and (in units of 10?6 cm2): for N2, 79 and 54; for H2, 57 and 39; for CO, 98 and 64; for CH4, 86 and 58. The values for N2 and H2 supersede those reported previously by McGillis and Krause (1968). 相似文献
19.
Accurate SCF computations are reported on the Rydberg states of N2 of electron configurations , , and ---3σg2πg, also on the valence states of the configuration . The Rydberg state calculations supplement those of Lefebvre-Brion and Moser. A comparison is made between the states and the parallel set of states of the configuration. This comparison shows a sharp difference in the 1Σ+ states of the two configurations, the 1Σ+ state being very high in the latter but relatively low in the former configuration. Recknagel coefficients are given for the several states of the two configurations; as expected, these are much smaller for the configuration. Also, the 1Δ state is relatively lower for the latter configuration. 相似文献
20.
Takehiko Tanaka Robert W. Field David O. Harris 《Journal of Molecular Spectroscopy》1975,56(2):188-199
A rotational assignment of approximately 80 lines with Ka′ = 0, 1, 2, 3, and 4 has been made of the 593 nm band of NO2 using cw dye laser excitation and microwave optical double-resonance spectroscopy. Rotational constants for the 2B2 state were obtained as A = 8.52 cm?1, B = 0.458 cm?1, and C = 0.388 cm?1. Spin splittings for the Ka′ = 0 excited state levels fit a simple symmetric top formula and give . Spin splittings for Ka′ = 1 (N′ even) are irregular and are shown to change sign between N′ = 6 and 8. Assuming that the large inertial defect of 4.66 amu Å2 arises solely from A, a structure for the 2B2 state is obtained which gives and an ONO angle of 105°. Alternatively, weighting the three rotational constants equally gives and θ = 118°. 相似文献