共查询到19条相似文献,搜索用时 62 毫秒
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在(TPA)2O—Na2O—SiO2—H2O体系中MFI型硅沸石的结晶行为(Ⅱ) 总被引:1,自引:0,他引:1
以白炭黑和硅溶胶为硅源,在(TPA)2O-Na2O-SiO2-H2O体系60℃下合成了高结晶度纯相硅沸石,由SEM没得其晶粒尺寸为0.2μm和0.45μm用XRD线宽法是的为0.02μm,一180℃时合成的硅沸石样品相比,低温合成的细晶粒硅沸石已上备内米级的若干特性,其正己烷吸附量反常增大;XRD、FTIR、^29SiMAS NMR和TG/DTG/DTA的研究证明,其结构破坏温度和单斜/正交对称性 相似文献
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产次在吸附态模板剂作用下的Na2O-SiO2-EDA干粉体系中合成了硅沸石-1,利用XRD,SEM,IR等分析方法对沸石的结构,形貌,骨架振动,稳定性及催化性能进行了表征。 相似文献
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采用不同的脱铝方法得到Si/Al比为15~112的丝光沸石,用IR方法测定了样品的脱铝空穴含量,并考察样品的热稳定性和疏水性,实验结果表明,脱铝后形成的大量末端硅羟基仍有亲水性,因而单纯酸脱铝疏水化效果有限,用水蒸汽处理或(NH4)2SiF6补硅的方法使沸石表面硅羟基转变成≡Si-O-Si≡键,能显著地提高沸石疏水性。 相似文献
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1985年Bibby首次在非水体系中合成了纯硅方钠石,由此开创了一条合成分子筛的新途径。徐文旸等首次在Na_2O-SiO_2-Al_2O_3一有机胺非水体系中合成了丝光沸石(简称非水丝光沸石,用NAM表示)。晶化过程中液相无硅铝酸根离子,固相硅铝比始终保持不变,是典型的固相转化过程。利用非水体系这一特点,可以定向地合成出催化反应所需硅铝比的沸石。与水热体系相比,非水体系合成的丝光沸石在邻二甲苯异构化催化性能上要优于前者。 相似文献
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ZSM-35沸石的合成与应用 总被引:1,自引:0,他引:1
对ZSM-35沸石的结构、合成方法、模板剂、合成种类、催化方面的应用及合成原料进行了综合,并着重介绍了新颖的干法合成技术、纯硅ZSM-35的合成以及ZSM-35沸石在CO加氢直接合成低碳烯烃反应中的催化应用等内容。 相似文献
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讨论了用两种不同硅源合成钛硅沸石TS-1的方法和合成过程中应注意的问题,并通过XRD、IR、TEM和SSA等手段对沸石的结构及热稳定性进行了表征和研究,确认了钛已进入沸石骨架,初步探讨了TS-1沸石合成时TPA离子的模板作用机理,此外,通过在温和条件下用H2O2选择性氧化正己烷的反应,考察了TS-1沸石的催化活性,得到了比较满意的结果。 相似文献
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氟离子对无胺法合成高硅丝光沸石的结构导向作用 总被引:4,自引:0,他引:4
在含氟无胺体系中合成了高硅丝光沸石,研究了合成条件对丝光沸石产物的影响.结果表明,投料n(SiO2)/n(Al2O3)=20~200时,控制晶化条件可得到高硅丝光沸石纯相.由含氟无胺体系中丝光沸石的热力学稳定相区可见,氟离子的引入对方沸石的生成的相区无影响,ZSM-5和镁碱沸石生成的相区消失,丝光沸石生成的相区扩大,石英生成的相区缩小,且基本上变为两相共存区.合成产物丝光沸石的硅铝比随着氟硅比的升高同步增大,证明氟离子在无胺合成高硅丝光沸石时具有结构导向作用. 相似文献
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采用蒸气相法合成了Ni/丝光沸石覆盖物,用XRD,SEM,电子能谱证明了合成的材料为丝光沸石包覆于金属镍粉表面成的复合物。用二甲本异构化探针反应和NH3-TPD考察了该包覆物的催化活性及酸性。结果表明,Ni/丝光沸石覆盖物具有良好的表面酸性,二甲苯异构化的活性均高于采用同样方法合成的Cr/丝光沸石覆盖物,间二甲苯异构化活性可以达到97%。 相似文献
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杂原子B—ZSM—35沸石的干法合成,表征及CO+H2反应性能的研究 总被引:4,自引:2,他引:4
首次利用吸附态模板剂在Na2O-SiO2-B2O3-DEA干粉体系中合成了杂原子B-SZM-35沸石,XRD,SEM,IR,及CO加氢反应研究了其物理化学特性。结果表明,B原子同晶取代Al原子进入ZSM-35沸石骨加。 相似文献
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Xiaohui Su Gang Li Ruisen Lin Eiichi Kikuchi Masahiko Matsukata 《Frontiers of Chemistry in China》2006,1(2):179-182
Mordenite composite membranes were prepared by means of coating a porous α-alumina support with nanosized mordenite seeds
followed by hydrothermal crystallization. A systematic investigation was performed on the influence of several factors such
as ageing of the reaction mixture, alkalinity, salt addition and temperature on the formation of a mordenite membrane on the
seeded support. The ageing of the reaction mixture reduces the growth rate of mordenite crystal along a-axis and b-axis but hardly influences the growth rate along c-axis. As a result, the boundaries between the surface crystals become a little larger with prolonging the period of ageing
time. The growth rate of the mordenite crystal along individual axes increases first and then decreases with increasing concentration
of sodium hydroxide. A higher alkalinity is unfavorable for the formation of a continuous mordenite membrane. The addition
of salt in the reaction mixture has different effect on the growth rate of the mordenite crystal along each axis. With increasing
the amount of salt, there was hardly influence on the growth rate along c-axis, whereas an obvious decline was observed in the growth rate along either a-axis or b-axis, which enlarges the boundaries between the surface crystals. The growth rate of the mordenite crystal increases more
along c-axis than that along a-axis or b-axis with increasing temperature for hydrothermal crystallization. The use of a temperature as high as 473 K produces a membrane
composed of bar-like crystals with larger boundaries.
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Translated from Journal of Zhejiang University (Science Edition), 2005, 32(4) (in Chinese) 相似文献
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Isopropylation of naphthalene over modified-mordenite zeolites 总被引:2,自引:0,他引:2
Isopropylation of naphthalene with propylene was carried out over Ce-, Si-, La-, and Mg-modified mordenite zeolites. The reaction
was performed in a 500 mL batch reactor at 300°C, 8 kg/cm2, and naphthalene to catalyst weight ratio of 10:1, with excess propylene. It was attempted to eliminate the external acid
sites of zeolites by these modifications. The results indicate that the CVD silanation and magnesium or cerium modification
with Mg/Al or Ce/Al atomic ratios less than 0.5 can improve the 2,6-DIPN selectivity of mordenites. The improvement of catalyst
performance is ascribed to the selective deactivation of acid sites on the external surface of HM zeolites. 相似文献
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无胺体系高硅铝比丝光沸石的合成 总被引:1,自引:0,他引:1
Mordenite has two kinds of pore channels. The main straight channels of 0.67 nm ×0.70 nm (12-membered ring) parallel to the caxis are interconnected with small side-channels of 0.29 nm×0.57 nm (8-membered ring) parallel to the baxis. 相似文献
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采用XRD、SEM、FT-IR、MAS NMR等表征手段, 对以氟离子为结构导向剂无胺法合成的高硅丝光沸石进行了表征. 结果表明: 高硅丝光沸石结构属立方晶系, 晶胞参数小于传统低硅丝光沸石, 但b、c值要比相近硅铝比非氟体系合成的丝光沸石样品的大; 样品形貌及粒径与其硅铝比有关, 表明晶化条件对产物形貌及粒径均有影响; 随硅铝比的增大, FT-IR光谱中450、544、1053 cm-1谱带向高频移动, 720 cm-1谱带强度减弱, 表明骨架中铝减少而硅增多; 采用含氟无胺体系合成高硅丝光沸石时基本上不会产生非骨架铝. 相似文献
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Zeinab Mcheik Ludovic Pinard Joumana Toufaily Tayssir Hamieh T. Jean Daou 《Molecules (Basel, Switzerland)》2021,26(15)
Hierarchical MOR-type zeolites were synthesized in the presence of hexadecyltrimethylammonium bromide (CTAB) as a porogen agent. XRD proved that the concentration of CTAB in the synthesis medium plays an essential role in forming pure hierarchical MOR-type material. Above a CTAB concentration of 0.04 mol·L−1, amorphous materials are observed. These hierarchical mordenite possess a higher porous volume compared to its counterpart conventional micrometer crystals. Nitrogen sorption showed the presence of mesoporosity for all mordenite samples synthesized in the presence of CTAB. The creation of mesopores due to the presence of CTAB in the synthesis medium does not occur at the expense of zeolite micropores. In addition, mesoporous volume and BET surface seem to increase upon the increase of CTAB concentration in the synthesis medium. The Si/Al ratio of the zeolite framework can be increased from 5.5 to 9.1 by halving the aluminum content present in the synthesis gel. These synthesized hierarchical MOR-type zeolites possess an improved catalytic activity for n-hexane cracking compared to large zeolite crystals obtained in the absence of CTAB. 相似文献