双轴性向列相液晶的相变理论

假设一双轴性向列相液晶分子简单相互作用模型，利用平均场理论，得到从各向同性相至单轴向列相、单轴向列相至双轴向列相的相变. 结果表明，在一定温度范围内，分子形状的非轴对称性可导致系统双轴向列相的产生. 在核磁共振实验中，导出双轴向列相序参数与谱线分裂频率间的一般关系，并讨论序参数测量性的可能性. 关键词： 向列相液晶 相变     

A biaxial nematic liquid crystal

We report a biaxial nematic liquid crystal in a simple thermotropic system.     

Anchoring transitions of nematic liquid crystals

A crystalline substrate such as mica or gypsum can orient a thin layer of nematic liquid crystal spread on top. By adsorbing one or more other kinds of molecules onto the surface, we have observed transitions in the orientation of the molecules on the surface. These “anchoring transitions” are analyzed via Landau-Ginzburg theory and may be first or second-order. The second-order anchoring transition is the first two-dimensional system where critical fluctuations may be observed optically.     

扭曲向列相液晶电光效应的研究

分析了扭曲向列相液晶的电光效应.采用溴钨灯作为光源,运用光栅单色仪选择380~1 100 nm波段的光进行照射,测量在0~8 V电压条件下扭曲向列相液晶对于不同波长入射光的透射率.     

Nuclear magnetic resonance study of the smectic-cholesteric phase transition in a dimesogenic liquid crystal

Nuclear magnetic resonance (NMR) spectroscopy has provided a unique opportunity to study the characteristic smectic-A to chiral nematic phase transition in a dimesogenic liquid crystal (“KI-5S”). The order parameters in the liquid crystalline phases were obtained from the ²H NMR quadrupole splitting and ¹³C NMR chemical shift measurements, manifesting a first-order smectic-nematic phase transition.     

Theory of nine elastic constants of biaxial nematics

In this paper, a rotational invariant of interaction energy between two biaxial-shaped molecules is assumed and in the mean field approximation, nine elastic constants for simple distortion patterns in biaxial nematics are derived in terms of the thermal average （Dmn^（l）） （Dm＇n＇^（l＇））, where Dmn^（l） is the Wigner rotation matrix. In the lowest order terms, the elastic constants depend on coefficients Γ,Γ＇, λ, order parameters Q0 = Q0（D00^（2）） ＋Q2（D02^（2）＋D0-2^（2）） and Q2 = Q0（D20^（2）） ＋ Q2（D22^（2）＋D2-2^（2））. Here Γ and Γ＇ depend on the function form of molecular interaction energy vj′j″j （τ12） and probability function fk′k″k （τ12）, where r12 is the distance between two molecules, and λ is proportional to temperature. Q0 and Q2 are parameters related to multiple moments of molecules. Comparing these results with those obtained from Landau-de Gennes theory, we have obtained relationships between coefficients, order parameters used in both theories. In the special case of uniaxial nematics, both results are reduced to a degenerate case where K11=K33.     

Nonclassical equations of state for critical and tricritical points

We develop a method by which certain classical equations of state may be modified to produce nonclassical critical scaling behavior. We then apply this method to the classical free energy describing a tricritical point that was originally introduced by Griffiths. The phase behavior of the resulting nonclassical free energy is characterized by the competition between critical scaling and tricritical scaling already envisioned by previous authors.Work supported by the National Science Foundation and the Cornell University Materials Science Center.Footnotes 3–10 of Ref. 1 provide a comprehensive list of experimental investigations of tricritical points in fluid mixtures.     

向列相液晶中光学相位共轭技术的研究进展

对向列相液晶中光学相位共轭技术的研究进展进行了介绍,分析总结了向列相液晶中光学相位共轭过程的机理与实验方法,并对向列相液晶中的光学相位共轭技术的应用前景进行了展望。     

Surface controlled nematic bistability

One discusses phenomenologically the statics and dynamics of surface anchoring of nematic liquid crystals. In statics, for symmetrical situations, one can induce, under the action of an external field, a surface breaking with a bifurcation between two opposite orientations of the director. In dynamics, one shows that the surface director relaxation is intrinsically fast, and accompanied by a transient surface shear flow. In thin cells with planar anchorings, filled by cyanobiphenyl materials which orient normal to the plates under a strong electric field, there are now two effects which couple the relaxation of the surface director: a static one, which favors parallel orientation and a uniform cell texture, and a transient dynamical coupling from the surface flow, which forces π-twisted texture. With suitable electric signals, one can control the surface bifurcations to give at will one of these two bistable textures. Results are presented which show that these mechanisms could lead to a new class of surface controlled, fast nematic bistable displays. Reproduced from ‘Liquid Crystals Today’ (Vol. 8, p. 1–7, 1998) by permission from Taylor and Francis.     

Thermomechanical reorientation in nematic liquid crystals

Thermomechanical mechanism of the director reorientation in twisted nematic liquid crystals caused by the one-dimensional longitudinal temperature gradient is predicted and studied theoretically. The calculated director reorientations are in the range that can be measured experimentally very easily.     

Asymmetric dynamic phase holographic grating in nematic liquid crystal

A new scheme for recording a dynamic phase grating with an asymmetric profile in C60-doped homeotropically aligned nematic liquid crystal(NLC) was presented.An oblique incidence beam was used to record the thin asymmetric dynamic phase holographic grating.The diffraction efficiency we achieved is more than 40%,exceeding the theoretical limit for symmetric profile gratings.Both facts can be explained by assuming that a grating with an asymmetric saw-tooth profile is formed in the NLC.Finally,physical mechanism and mathematical model for characterizing the asymmetric phase holographic grating were presented,based on the photo-refractive-like(PR-like) effect.     

Molecularengineering of discotic nematic liquid crystals

Connecting two columnar phase forming discotic mesogens via a short rigid spacer leads to the formation of a π-conjugated discotic dimer snowing discotic nematic (N _D) phase. Attaching branched-alkyl chains directly to the core in hexaalkynylbenzene resulted in the stabilisation of N_D phase at ambient temperature. Pentalkynylbenzene derivatives possessing a combination of normal- and branched-alkoxy chains display a very broad N_D, phase which is stable well below and above the room temperature.     

混合排列向列液晶盒的电光响应

本文考察了一组混合排列向列液晶盒的电光响应特性,重点研究了透射光强随外电压的变化及响应时间与外电场的关系,计算了作为外电压及开启时间函数的双折射。应用液晶的线性响应理论分析了实验结果,理论与实验基本相符。结论指出:适当改变液晶器件的结构,有可能使响应时间加快。     

Kinetics of the isotropic–nematic phase transition in melted multi-component liquid crystal mixtures upon cooling

The kinetics of the phase separation and the nematic phase growth in two melted commercial multi-component liquid crystal mixtures upon cooling was studied using polarising optical microscopy and IR spectrometry. The droplets of the nematic phase revealed in the optical images across the phase transition were segmented and treated statistically. In the resulting size histograms of mixture B, two overlapping statistical ensembles related to two co-existing nematic phases were recognised; these phases were shown to be different in their chemical structures. In mixture A, any separation within the nematic phase was not found. The statistical ensembles of the nematic droplets were successfully described using the principles of irreversible thermodynamics. Analysis of the mean droplet diameter as a function of time allowed recognition of two regimes of the nematic phase evolution: (1) nucleation and rapid nucleus growth and (2) nucleus coalescence. Both the regimes were quantitatively described with the universal law for the cluster growth.     

三维动态Ising模型中的非平衡相变:三临界点的存在

用Monte Carlo方法模拟了三维动态Ising模型中的非平衡相变,用统计的观点研究了序参量的大小和分布以描述该相变过程.保持温度和外场频率不变,改变外场大小使之由小到大变化,序参量由非零值变成零值.在低温阶段,序参量呈非连续变化,为典型的非连续相变,在高温阶段,序参量呈连续变化,为典型的连续相变.本文确定了界定非平衡转变的相界,并进一步确定了相界上区分非连续连续相变的三临界点.外场频率ω减小时,三临界点温度T_TCP向高温部分移动,并满足T_TCP=1.33× 关键词： 动态相变 Ising模型 三临界点     

Effects of fields and anchoring on biaxial nematic ordering

Symmetry of a nematic liquid crystal phase is broken by an anchoring wall and also by an external field. Nematic system sandwiched between biaxial anchoring walls is introduced as a correspondent to a bulk nematic system exposed to a couple of fields, an electric field and a magnetic one in directions perpendicular to each other, and thermal behaviours of the system are studied. The crossover between a homeotropic structure and homogeneous one occurs, similarly to the bulk system in the fields, in which the anchoring condition of coexistence is shown to have the same expression as the one at the bulk. As to a characteristic phenomenon at the sandwiched system, it is proved that an appearance of a biaxial nematic order suppresses a uniaxial nematic order. A surface transition, i.e., a wetting phenomenon is shown to occur also in the biaxial nematics, even though the uniaxial order is suppressed therein.     

向列相液晶染料可调谐激光器的研究

对向列相液晶染料的可调谐激光器进行了光学特性研究. 以650 nm为中 心波长设计了SiO₂和TiO₂多层膜的一维光子晶体, 以激光染料与向列相液晶的混合物作为增益介质层, 制备了波长可调谐激光器.用Nd: YAG倍频脉冲激光器输出的532 nm激光抽运所制备的激光器样品得出如下光学特性: 激光发射波长随温度调谐范围为605.5---639.8 nm, 达到34.3 nm, 随电压调谐范围为634.5---619.5 nm, 达到15 nm. 发射激光每脉冲的阈值能量为12.3 μJ, 激光线宽小于1 nm.     

热致型胆甾酯液晶的相变研究

使用偏光显微镜观察胆甾烯壬酸酯液晶的相变，发现在不同的温度变化条件下液晶相变过程是不同的．本文讨论了其变化规律．