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1.
在实验室的热补偿恒温控制条件下, 理论预测的等温恒电流(电压)电化学振荡实际上将发生变异. 用慢流型上准定态的线性化稳定性分析法全面分析了此类恒温控制条件下铂电极BZ反应系在以温度为慢变参数的慢流型上的准稳定性及绕温度轴慢变轨迹的动力学行为. 发现在温度围绕控制值上下往复波动的每一个周期内, 准定态点将穿梭跨越于振荡区与非振荡区之间, 表现为间隙性的沿温度轴的环面型电化学振荡. 计算机模拟结果证实了上述理论分析. 相似文献
2.
Degeneration of Limit Cycle Oscillation in BZ Electrode Reaction System Controlled Externally 下载免费PDF全文
A dynamical model of electrode BZ reaction system was establisheed on the basis of three variables Oregonator model and kinetics of electrode process. Under weak periodical constraint approximation, dynamical stability of quasi steady state on the slow manifold of the system is analyzed by means of linearized stability analysis of three variable system. Meanwhile, the corresponding regime favorable for the appearance of limit cycle oscillation is calculated. Computer simulation shows that limit cycle oscillatory regime has degenerated because of the external periodical potential constraint in the electrode phase. In this regime the system behaves as a temporary self-organization. Whereas, outside this regime a kind of response oscillation appear, with same period as the constraint. 相似文献