手性分子反-2,3-环氧丁烷的旋光拉曼光谱研究

本文从拉曼峰强出发,求得了反-2,3-环氧丁烷分子的拉曼键极化率,明确了拉曼激发下电荷的分布的信息.还从旋光拉曼(Raman optical activity,ROA)谱的峰强,求取了该分子的旋光拉曼键极化率.由分子手性中心的C-H产生的偶极矩与拉曼激发过程中,电荷流动产生的跃迁磁偶极矩的耦合,来理解旋光拉曼活性产生的机理.分析表明,旋光拉曼活性分子手性中心的C-H键两侧的旋光拉曼极化率符号相反,显示着手性分子局域的不对称性.还得到了对称和反对称坐标的键极化率和旋光拉曼极化率,并且从对称性的角度,即C2群的不可约表示,讨论了这些极化率的内涵.     

基于单层反射超表面的宽带圆极化高增益天线设计

基于Pancharatnam-Berry相位原理, 设计了一种宽带圆极化反射聚焦超表面并将其应用到提高天线增益中. 首先提出了一种变形十字超表面单元, 在11-16 GHz频带范围内能够实现高效同极化转换, 并基于该单元构建了宽带反射聚焦超表面. 仿真结果表明, 垂直入射的右旋圆极化平面波宽带聚焦效果明显. 然后利用单向阿基米德螺旋天线对超表面进行照射, 其辐射的球面波经超表面反射后得到了近平面波, 有效地提高了天线的增益. 最终对所设计的天线系统进行加工并测试, 结果表明系统的-1 dB增益带宽达到25% (12.5-16 GHz), 在该频带范围内峰值增益均高于19 dBc且轴比小于3 dB. 此外, 在12-15.5 GHz范围内天线口径效率均超过50%.     

采用圆偏振啁啾飞秒激光脉冲操控CS2分子的相干拉曼散射过程

采用两束圆偏振啁啾飞秒激光脉冲,非共线相干激发三原子分子CS₂液体. 在相位匹配的方向上,探测到由CS₂频率为397 cm^-1的振动模式产生的强度对称分布的相干反斯托克斯拉曼散射(CARS)信号和相干斯托克斯拉曼散射(CSRS)信号. 当调整两束激发光的圆偏振状态时,CARS,CSRS信号的强度、偏振、波长均发生规律性的改变:CARS,CSRS信号的强度分布反映了CS₂ 在不同极化状态下的受激拉曼散射截面大小;信号光的 关键词： 啁啾脉冲 相干反斯托克斯拉曼散射(CARS) 相干斯托克斯拉曼散射(CSRS) 2')" href="#">CS₂     

Intramolecular enantiomerism as revealed from Raman optical activity spectrum

An algorithm is employed to retrieve the differential bond polarizabilities (DBP) of the C‐C bonds from the Raman optical activity spectrum of (‐)β‐pinene. (‐)β‐pinene possesses two stereo centers (chiral centers) and a local mirror reflection that interchanges the S type part and R type part in one molecular. It is demonstrated that this local mirror reflection could induce an approximate (or symmetry breaking) mirror reflection that reverses the signs of the DBP of the pair bond coordinates that are related to each other by the mirror reflection.This can be called intramolecular enantiomerism (IE). More cases of IE are discussed by the analysis of (‐)α‐pinene, (R)‐(+)‐4‐isopropyl‐1‐methylcyclohexene and (R)‐(+)‐3‐methylcyclohexanone together with previously studied limonene case. Copyright © 2015 John Wiley & Sons, Ltd.     

High gain and circularly polarized substrate integrated waveguide cavity antenna array based on metasurface

Two substrate integrated waveguide (SIW) cavity antenna arrays based on metasurface are proposed in this paper. By rotating the metasurface element, circularly polarized and high gain antennas are achieved respectively. Firstly, multi-mode resonance theory is employed to broaden the bandwidth of the slot antenna. And then, an SIW cavity composed of 4×4 cornercut elements is added on the top of the slot antenna to achieve the circular polarization and improve the front-to-back ratio. Thirdly, the metasurface elements are sequentially rotated and a high gain antenna with 2-dBi enhancement on average in the operation band is obtained. Based on the two antenna units, two 2×2 antenna arrays are designed. The circularly polarized and high gain antenna arrays are both fabricated to verify the correctness. Furthermore, the novel wideband phase shifter is employed in the circularly polarized antenna to obtain an operating bandwidth of 38% (4.05 GHz-5.95 GHz) and AR bandwidth of 24.9% (4.4 GHz-5.65 GHz). The bandwidth of the high gain antenna can reach 42.7% (3.95 GHz-6.1 GHz) and with the gain enhancement of 2 dBi compared with that of the circularly polarized antenna. The gain remains steady in most of operating band within a variation of 1 dBi. It is remarkable that the rotating of the metasurface element has a great influence on the antenna performance, which provides a new explication for the multi-function antenna design.     

Simultaneous acquisition of all four forms of circular polarization Raman optical activity: results for α‐pinene and lysozyme

A new circularly polarized (CP) Raman spectrometer is described that demonstrates simultaneous acquisition of all four forms of circular polarization Raman optical activity (ROA). The instrument is a design extension of a commercially available back scattering circular polarization (SCP) ROA spectrometer. Circular polarization of the incident beam is introduced with a quarter‐wave plate, and a half‐wave plate alternately positioned in and out of the beam controls the modulation between right circular polarization (RCP) or left circular polarization (LCP) states. Combining this modulation with the simultaneous detection of RCP and LCP scattered Raman radiation allows the measurement of incident circular polarization (ICP), SCP, in‐phase dual circular polarization(DCP_I) and out‐of‐phase DCP_II‐ROA. In addition, three different forms of backscattered Raman spectra, namely unpolarized, highly polarized, and depolarized Raman spectra, as well as a degree of circularity spectrum are obtained. The performance of the new all‐CP ROA spectrometer is evaluated with neat α‐pinene and aqueous hen lysozyme solution. Copyright © 2011 John Wiley & Sons, Ltd.     

A novel Raman optical activity instrument operating in the deep ultraviolet spectral region

Raman optical activity (ROA) has been exclusively observed in the visible (VIS) and near‐infrared (NIR) spectral regions to date. During the last few years, we have designed, constructed and tested the first ROA instrument, operating in the deep‐ultraviolet (DUV) spectral region employing 244‐nm excitation. This novel DUV ROA instrument is based on a backscattering geometry and incident circular polarization modulation (ICP); it makes use of a fast DUV imaging lens‐based spectrograph and specially designed DUV grade polarization optics. The performance of this instrument has been evaluated by analysing measured non‐resonant DUV ROA spectra of non‐absorbing enantiomeric liquid samples and by comparing these with corresponding ROA spectra recorded in the visible spectral region. Copyright © 2015 John Wiley & Sons, Ltd.     

手性物质拉曼光活性(Raman Optical Activity)研究综述

通过对大量文献的调研，本文分四个部分对手性物质的旋光现象及振动光活性进行了较为全面的介绍，重点介绍了拉曼光活性ＲＯＡ（ＲａｍａｎＯｐｔｉｃａｌＡｃｔｉｖｉｔｙ）产生机理、研究状况及对其研究的意义。     

A multi-frequency circularly polarized metasurface antenna array based on quarter-mode substrate integrated waveguide for sub-6 applications

A miniaturized multi-frequency circularly polarized array is designed in this paper. The antenna array is composed of three independent sub-arrays employing modified quarter-mode substrate ntegrated aveguide (QMSIW) to achieve three circularly polarized frequency bands. By introducing strip-slot, the impedance bandwidth of the antenna array is broadened while the dimension is decreased by 75% to realize miniaturization. Meanwhile, metasurface causes the impedance bandwidth of the sub-array to be further enhanced. Moreover, the metal vias are employed in the antenna array design to further achieve miniaturization. The antenna array is manufactured and measured to verify the design. Both the measured and simulated results display that the array achieves the impedance bandwidths of 10%, 11.7%, and 14.8% and axial ratio bandwidths of 8.8%, 8.0%, and 8.5% at 2.5, 3.5, and 4.8 GHz, respectively. The gain is stable in the operating band within an uncertainty of 0.7 dBi. The whole dimension is 0.92λ×0.63λ×0.04λ, where λ₀ is the wavelength at the lowest resonant frequency. Furthermore, the simple structure and miniaturization provides great convenience in sub-6 applications.     

Observation of resonance electronic and non‐resonance‐enhanced vibrational natural Raman optical activity

Natural resonance electronic Raman optical activity (ROA) is observed for the first time. Coincidently, the first example of vibrational ROA enhanced by low‐lying electronic transition is reported. These new phenomena were measured using the rare‐earth complex Eu(tfc)₃ (+)‐tris[3‐trifluoroacetyl‐D ‐camphorato]europium(III), where electronic resonance occurs between the 532‐nm laser excitation and the ⁷F₁ → ⁵D₁ transition of the Eu³⁺ metal center. Electronic Raman spectra involve the Raman transitions terminating on the low‐lying electronic states of Eu(tfc)₃. The observed vibrational ROA spectra are enhanced relative to typical ROA spectra by the proximity of vibrational states of Eu(tfc)₃ to its low‐lying electronic states with significant magnetic‐dipole character, whereas the parent vibrational Raman spectra do not appear to be resonance‐enhanced since the 532‐nm vibrational Raman spectrum has similar relative intensities to the corresponding Raman spectrum measured with 1064‐nm laser excitation. Copyright © 2010 John Wiley & Sons, Ltd.     

基于偏振光法油雾浓度检测的研究

针对油雾具有旋光性,提出了基于偏振光法的油雾浓度检测方法.介绍了油雾浓度检测系统的基本原理,设计了检测系统的结构,建立了检测系统的数学模型,对检测系统进行了实验研究,并对两种实验方案的结果进行了对比分析.检测系统采用双光路检测法,用法拉第旋光器进行补偿,并用称重分析法对系统进行标定.实验结果表明该方法的两种实验方案在低...     

Theoretical analysis on double Rayleigh backscattering noise in optical fibreRaman amplifiers and its suppression

In this paper, amplified double Rayleigh backscattering noise (DRB) in the optical fibre Raman amplifier is analysed. Expressions are presented for both forward pumping and backward pumping schemes. Calculation is performed to show the effective suppression of DRB noise by employing an optical isolator. The optimal position for the isolator is determined and is found to be insensitive to the power levels of the signals and pumps. The results show that a reduction of the DRB noise by almost 2 to 3 orders can be reached.     

基于光纤中SRS效应的全光波长转换

提出利用光纤中非线性效应受激喇曼散射（stimulated Raman scattering, SRS）实现波长转换的原理方案和相应的理论分析模型,并进行实验验证,将经过放大后的信号光和连续探测光同时注入光纤,在光纤中进行SRS放大,实现信号之间的转换。结果表明:利用SRS可实现波长转换,可实现跨几个THz的波长之间的转换。得到最大转换效率和消光比分别为-17.3 dB和15.7 dB。通过改变探测光的波长,可实现相隔几个THz光信号的全光波长转换和可调谐波长转换。     

Multiple optical trapping based on high-order axially symmetric polarized beams

Multiple optical trapping with high-order axially symmetric polarized beams(ASPBs) is studied theoretically,and a scheme based on far-field optical trapping with ASPBs is first proposed.The focused fields and the corresponding gradient forces on Rayleigh dielectric particles are calculated for the scheme.The calculated results indicate that multiple ultra-small focused spots can be achieved,and multiple nanometer-sized particles with refractive index higher than the ambient can be trapped simultaneously near these focused spots,which are expected to enhance the capabilities of traditional optical trapping systems and provide a solution for massive multiple optical trapping of nanometer-sized particles.     

Quantitative analysis of sugar composition in honey using 532‐nm excitation Raman and Raman optical activity spectra

Raman spectroscopy based on the 1064‐nm laser excitation was suggested as a handy non‐invasive technique allowing to quickly determine sugar content in honey and similar food products. In the present study, the green 532‐nm laser radiation is explored instead as it provides higher‐quality spectra in a shorter time. The sample fluorescence was quenched by purification with activated carbon. For control mixture decomposition of Raman spectra to standard subspectra led to a typical error of the sugar content of 3%. Raman optical activity (ROA) spectra that could be measured at the shorter excitation wavelength as well provided a lower accuracy (~8%) than the Raman spectra because of instrumental sensitivity and noise limitations. The results show that Raman spectroscopy provides elegant and reliable means for fast analyses of sugar‐based food products. Copyright © 2016 John Wiley & Sons, Ltd.     

Hydrogen bonding in homochiral dimers of hydroxyesters studied by Raman optical activity spectroscopy

Spectroscopic analysis of homochiral dimerization is important for the understanding of the homochirality of life and enantioselective catalysis. In this paper, (S)‐methyl lactate and related molecules were studied to provide detailed structural information on hydrogen bonding in homochiral dimers of chiral α‐hydroxyesters through the experimental and theoretical study of Raman optical activity. Different homochiral dimers can be distinguished by comparing their simulated Raman optical activity spectra with the experimental results. Hydrogen bonding motions are decoded with the aid of vibrational motion analysis, which are apparently involved in vibrational motions below 800 cm^–1. A common feature related to the chain‐bending mode also indicates the absolute configuration of methyl lactate and related molecules. The differing behavior of electric dipole–electric quadrupole invariants (β(A)²) compared with the electric dipole–magnetic dipole invariant (β(G′)²), suggests that the intermolecular hydrogen bonding motion behaves differently from the intramolecular one in the asymmetric molecular electric and magnetic fields. These results may help understand hydrogen‐bonded self‐recognition and other dynamical features in chiral recognition. Copyright © 2011 John Wiley & Sons, Ltd.     

A planar chiral nanostructure with asymmetric transmission of linearly polarized wave and huge optical activity in near-infrared band

Just like an electronic diode that allows the electrical current to flow in one direction only, a kind of chiral metamaterial structure with a similar functionality for the electromagnetic wave is proposed. The designed nanostructure that consists of twisted metallic split-ring resonators on both sides of a dielectric substrate achieves asymmetric transmission for a forward and backward propagating linearly polarized wave by numerical simulation in near-infrared band. Difference in transmission efficiency of the optimized structure between the same polarized waves incident from opposite directions can reach a maximum at the communication wavelength （1.55 μm）. Moreover, the simulation results of this structure also exhibit strong optical activity and circular dichroism.     

Raman optical activity of an achiral element in a chiral environment

Raman optical activity (ROA) is a relatively new technique used to determine the structure of chiral molecules and is proving useful in the study of biological molecules such as proteins and DNA/RNA. Here, for the first time, we demonstrate the applicability of ROA as a technique to study achiral groups in chiral environments, detecting the induced chirality of N‐(fluorenyl‐9‐methoxycarbonyl) (Fmoc) in a chiral self‐assembled structure of Fmoc‐dipeptides. This technique is therefore of interest to those studying self‐assembled systems that adopt a chiral structure. Copyright © 2009 John Wiley & Sons, Ltd.     

基于拉曼组合放大的长距离光纤传输系统

本文改进了一种实现长距离自适应补偿光纤传输的方法.在利用光纤光栅形成的谐振腔产生激光对信号光进行拉曼放大的基础上,再利用双抽运光对信号光进行拉曼放大,从而获得更高的拉曼增益以实现更长距离的自适应补偿光纤传输.使实验自适应补偿传输距离达125km(为目前国际上已报道的最长自适应补偿光纤传输距离).实验测量并理论分析了该长距离光纤传输系统的开关增益、放大的自发辐射噪声、噪声指数和光功率分布的特性,实验结果与理论模型符合很好.     

Raman excitation of (+)‐(R)‐methyloxirane and its origin of optical activity via bond polarizabilities

We studied the bond polarizabilities of chiral (+)‐(R)‐methyloxirane from its Raman intensities. The bond polarizabilities provide much information concerning the electronic structure of its nonresonant Raman‐excited virtual state. At the initial moment of Raman excitation by the 514.5 nm laser, the tendency of the excited charges (mapped out by the bond polarizabilities) is to spread to the methine bond near the stereogenic center and its triangular oxirane skeleton. Thereby, the coupling of the electric dipole induced by the excited charges in the methine bond and the magnetic moment vibrationally induced by the electric current in the triangular oxirane skeleton as the molecule vibrates is shown to be the key factor leading to its significant Raman chirality. When the final stage of Raman relaxation is approached, the relative magnitudes of the bond polarizabilities are congruent to the bond electronic densities of the ground state, which are otherwise by the theoretical quantities via the quantum chemical calculation. During Raman relaxation, we found that the polarizabilities of the peripheral C H bonds relax faster than the rest, as indicated by their relaxation characteristic times. Copyright © 2010 John Wiley & Sons, Ltd.