Synthesis, Crystal Structure and Electrochemical Properties of Complex [Ni(2,2’-bipy)_2(ClC_6H_4COO)(H_2O)](ClO_4)

1 INTRODUCTION Nickel is vital for organism as a trace element and it often acts as component or secondary factor of enzyme. In the latest two decades, biological inor- ganic chemistry of nickel has become one of the hottest fields and the coordination chemistry of nic- kel has made a great progress[1]. Complexes built upon organic aromatic carboxylic acid and metallic ion have attracted chemists’ interest for years due to their potential applications in material, medicine, molecular ele…     

Synthesis,Crystal Structure and Electrochemical Properties of a One-dimensional Chain Coordination Polymer [Mn （NAA ）2（ 4,4′-bipy ） （H2O）4]n

A novel one-dimensional chain coordination polymer [Mn（NAAh（4,4′-bipy）（H2O）4], has been synthesized with a-naphthaleneacetic acid, 4,4′-bipy and manganese（Ⅱ） sulfate as raw materials. Crystal data for this complex： monoclinic, space group P21/c, a = 1.1421（2）, b = 1.6337（3）, c = 0.94177（19） nm, β = 112.15（3）°, V = 1.6275（6） nm^3, De = 1.407 g/cm^3, Z = 2, μ（MoKa） = 0.467 mm^-1, F（000） = 722, S = 1.007, R= 0.0412 and wR = 0.1022. The crystal structure shows that two neighboring manganese（Ⅱ） ions are linked together by one 4,4′-bipy molecule, and the whole complex molecule forms a one-dimensional chain structure. Each manganese（Ⅱ） ion is coordinated with two oxygen atoms of two a-naphthaleneacetic acid molecules, two nitrogen atoms of two 4,4′-bipy molecules and two oxygen atoms from two water molecules, giving a distorted octahedral coordination geometry. The electrochemical properties were also analyzed.     

Synthesis,Crystal Structure and Fluorescence Property of a New Trinuclear Nickel(Ⅱ) Complex Bridged by 2,6-Pyridine Dicarboxylic Acid

A new trinuclear nickel complex,[Ni3(pdc)3(2,2'-bipy)3(H2O)2]·2H2O(H2pdc = pyridine 2,6-dicarboxylic acid,2,2'-bipy = 2,2'-bipyridine) has been hydrothermally synthesized and characterized by IR,elemental analysis and X-ray diffraction methods.Crystal data for this complex:monoclinic,space group P21/n,a = 21.206(4),b = 10.002(2),c = 28.066(6),β = 108.18(3)°,C51H41N9Ni3O16,Mr = 1212.06,V = 5.656(2) nm3,Dc = 1.423 g·cm-3,μ(MoKα) = 1.062 mm-1,Z = 4,F(000) = 2488,GOOF = 1.034,the final R = 0.0543 and wR = 0.1237 for 6149 observed reflections with Ⅰ 2σ(Ⅰ).In the complex,three nickel(Ⅱ) ions are bridged by the pyridine 2,6-dicarboxylic acid groups,and all nickel(Ⅱ) ions are seven-coordinated by nitrogen atoms of 2,2'-bipyridine and pyridine 2,6-dicarboxylic acid and oxygen atoms from pyridine 2,6-dicarboxylic and water to adopt a severely distorted pentagonal bipyramidal geometry.The emission and excitation peaks of the complex in ethanol solutions are located at 336 and 316 nm,respectively.     

N-苯基亚氨基二乙酸镍二维网状配合物的合成及结构表征(英)

A new nickel(Ⅱ) coordination compound [Ni(L^2-)(2,2′-bipy)(H₂O)]·2H₂O (H₂L=phenyliminodiacetic acid) was obtained by self-assembly of phenyliminodiacetic acid, 2,2′-bipy, and NiCl₂·6H₂O in the mixed solvent of water and ethanol (V∶V=1∶1). The complex was characterized by elemental analysis, IR spectra, and X-ray crystallography analysis. The crystal is monoclinic, space group P2₁ /c with a=0.867 4(2) nm, b=0.907 3(1) nm, c=2.643 5(5) nm, β=91.01(1)°, V=2.080 2(4) nm³, Z=4, F(000)=992, D_c=1.520 Mg·m^-3, R₁=0.027 0 and wR₂=0.067 5. In the complex, nickel (Ⅱ) atom is coordinated with a distorted octahedral geometry and extensive hydrogen bonds link the complexes into a 2D network structure. CCDC: 244926.     

Synthesis, Crystal Structure and Electrochemical Properties of One-dimensional Chain Coordination Polymer [Co(Ⅱ)(C6H5CH=CHCOOH)2(4,4''-bipy)(H2O)5]n

A one-dimensional chain coordination polymer [Co(Ⅱ)(C6H5CH=CHCOOH)2(4,4'-bipy)(H2O)5]n has been synthesized with cinnamylic acid, 4,4'-bipy and cobaltous chloride as raw materials. Crystal data for this complex: monoclinic, space group P21/c, a - 1.1481(3), b =1.1230(2), c = 1.1759(3) nm, β = 97.054(4)°, V = 1.5046(6) nm3, Mr= 617.50, Dc = 1.363 g/cm3, Z= 2, μ(MoKα) = 0.627 mm-1, F(000) = 646, S = 1.062, R 0.0443 and wR = 0.1178. The crystal structure shows that two neighboring cobalt(Ⅱ) ions are linked together by one 4,4'-bipy, and the whole complex molecule adopts a one-dimensional chain structure. Each cobalt(Ⅱ) ion is coordinated with two nitrogen atoms from two 4,4'-bipy molecules and four oxygen atoms from four water molecules, giving a distorted octahedral coordination geometry. The electrochemical properties were analyzed by combining with the crystal structure.     

N,N''''-(2-苯并咪唑基甲基)亚氨基甲基膦酸的双核镍化合物Ni2(bbimp)2(4,4''''-bipy)(H2O)2·2H2O和Ni2(bbimp)2(H2O)2][Ni(bbimp)(H2O)2]2·4H2O的晶体结构和磁学性质

该文报道了N,N′-(2-苯并咪唑基甲基)亚氨基甲基膦酸{bbimpH_2,[(C7H5N2)CH2]2NCH2PO3H2}的2个镍化合物Ni2(bbimp)2(4,4′-bipy)(H2O)2·2H2O(1)和[Ni2(bbimp)2(H2O)2][Ni(bbimp)(H2O)2]2·4H2O(2)。化合物1是4,4′-联吡啶作为桥连配体的中性双核结构。化合物2含有1个中性的[Ni2(bbimp)2(H2O)2]双核分子与2个中性的[Ni(bbimp)(H2O)2]单核分子。双核分子单元中的2个Ni!离子被2个膦酸氧桥连。在化合物2中,膦酸氧桥连的2个Ni!离子之间存在铁磁性相互作用。     

一维链状配位聚合物{[Ni(4-abaH)(2,2′-bipy)(NO_3)(H_2O)](NO_3)}_n的合成与晶体结构(英文)

<正>0 Introduction The design and synthesis of coordination polymershas been a subject of intense research due to their novel structures such as diamond,square network,brick wall network,octahedral network and so on     

配合物[Mn(2,2''-bipy)(H2O)4]·(m-phth)的水热合成和晶体结构

A mononuclear manganese complex [Mn(2,2'-bipy)(H2O)4]·(m-phth) (2,2'-bipy=2,2'-bipyridine, m-phth=isophthalate) has been synthesized by hydrothermal methods. The crystal structure was determined by singlecrystal X-ray diffraction. The crystal is of orthorhombic, space group Pnna with a=0.766 8(8) nm, b =2.050 2(2)0.027 0, R=0.028 0 and wR=0.075 5. In the crystal the manganese atom is six-coordinated by two nitrogen atoms from 2,2'-bipyradine and four oxygen atoms from water molecules, completing an octahedral coordination geometry. The isophthalate molecules are included in the lattice and connected to Mn(2,2'-bipy)(H2O)4 by hydrogen bonding interactions to form a three-dimensional supramolecular structure. CCDC:286965.     

Solvothermal Synthesis, Crystal Structure and Electrochemical Property of Complex [Co(p-MBA)2(2,2''-bipy)(H2O)]·(H2O)

One novel complex [Co(p-MBA)2(2,2'-bipy)(H2O)]·(H2O) has been synthesized by the reaction of p-methylbenzoic acid with 2,2'-bipyridine in the solvent mixture of water and methanol. It crystallizes in triclinic, space group P-1 with a=0.70479(14), b=1.1211(2), c=1.6718(3) nm, α=103.806(3), β=90.795(3), γ=104.207(3)°, V=1.2399(4) nm3, Mr=512.41, Dc=1.373 g/cm3, Z=2, F(000)=532, μ=0.733 mm-1, R=0.0432 and wR=0.0957. The crystal structural analysis shows that the cobalt atom is coordinated with three oxygen atoms from two p-methylbenzoic acids and one water molecule and two nitrogen atoms from one 2,2'-bipyridine,forming a distorted square-pyramidal coordination geometry. The cyclic voltammetry behavior of the complex is also reported.     

Synthesis, Crystal Structure and Electrochemical Properties of [Ni(phen)3]·(m-nitrobenzoic acid)2·(H2O)

A new nickel(Ⅱ) coordination complex [Ni(phen)3]·(m-nitrobenzoic acid)2·(H2O) was synthesized by self-assembly of m-nitrobenzoic acid, 1,10-phenanthroline and nickelous perchlorate. It crystallizes in the monoclinic system, space group C2/c, with a = 2.4596(6), b = 1.2124(3), c = 1.9824(5) nm, β = 97.088(5)°, V = 5.866(3) nm3, Dc = 1.474 g/cm3, Z = 4, Mr = 1301.82, μ(MoKα) = 0.417 mm-1 F(000) = 2688, R = 0.0493 and wR = 0.1025. Structural determination indicates that the nickel(Ⅱ) ion is coordinated with six nitrogen atoms from three phens, giving a distorted octahedral coordination geometry. The cyclic voltametric analysis shows that the electron transfer in the electrode reaction is irreversible.     

二苯乙醇酸铜配合物的合成、晶体结构、电化学和荧光性质

以二苯乙醇酸为配体合成了1个新的化合物[Cu(2,2′-bipy)(BAA)][Cu(2,2′-bipy)(BAA)(H2O)]2.(H2O)3(BAA=二苯乙醇酸阴离子,2,2′-bipy=2,2′-联吡啶)。该化合物晶体属三斜晶系,空间群P1,晶胞参数:a=1.121 7(5)nm,b=1.360 2(6)nm,c=2.335 2(10)nm,α=99.260(6)°,β=101.223(8)°,γ=94.805(8)°,V=3.425(3)nm3,Dc=1.385 g.cm-3,Z=6,μ(Mo Kα)=0.992 mm-1,F(000)=1 474,最终偏离因子R1=0.0561,wR2=0.1128。在标题化合物的不对称单元中有3个单核铜(Ⅱ)配合物,且3个中心铜(Ⅱ)离子的配位数不完全相同,如Cu(1)离子的配位数是4,而Cu(2)和Cu(3)离子的配位数都是5。本文还测定了标题化合物的电化学性能和荧光性能,结果表明:在电化学过程中配合物的电子转移是准可逆的,电子转移数为2个;配合物在478 nm的光激发下可发射荧光。     

单核镍(Ⅱ)配合物[Ni(IDB)_2][C_6H_4(OH)COO].ClO_4.CH_3CH_2OH.H_2O的合成和晶体结构

标题配合物是由三齿配体N, N-二(2-苯并咪唑亚甲基)胺(IDB)、Ni(ClO4)2·6H2O与水杨酸钠在乙醇溶液中反应得到的紫色晶体。用X-射线衍射测定了其单晶结构。结果表明,该晶体属三斜晶系,P 空间群,化学式:C41H43ClN10NiO9,Mr = 914.01,a = 11.010(2),b = 13.800(3),c = 15.550(3) 牛 = 100.75(3),?= 102.97(3), = 107.56(3)? V = 2111.3(7) ?,Z = 2,F(000) = 952,Dc = 1.438 g/cm3,(MoK) = 0.591 mm-1,8215个独立可观测点(I>2(I))。最终偏离因子R(I>2(I)):R = 0.0591, wR = 0.1325;R(全部数据): R = 0.1302,wR = 0.1572。结构分析表明,镍(Ⅱ)分别与2个IDB配体中的苯并咪唑的4个氮和胺基的2个氮配位形成畸变的八面体构型。     

Hydrothermal Synthesis, Crystal Structure and Electrochemical Properties of Complex Zn（phen）（m-CBA）2（H2O）

A novel complex Zn(phen)(m-CBA)2(H2O) with m-chlorobenzoic acid (m-CBA), 1,10-phenanthroline (phen) and zinc chloride has been hydrothermally synthesized and characterized. Crystal data for this complex: triclinic, space group P1, a = 0.8361(5), b = 1.2455(7), c = 1.3107(7) nm, α = 115.637(8), β = 91.014(9), γ = 104.857(8)o, V = 1.1763(11) nm3, Dc = 1.623 g/cm3, Z = 2, F(000) = 584, GOOF = 1.078, the final R = 0.0453 and wR = 0.1192. Structure analysis shows that the zinc ion coordinates with two nitrogen atoms of one 1,10-phenanthroline molecule, three oxygen atoms from two m-chlorobenzoic acid molecules and one water molecule, giving a distorted square-pyramidal coordination geometry. The cyclic voltametric behavior of the complex was also investigated.     

对位取代苯甲酸与2,2'-联吡啶配体构筑的两种二价铅配合物的合成、晶体结构及性质

水热条件下,合成了2个含对位取代苯甲酸和2,2'-联吡啶配体的二价铅配合物[Pb(4-HOBA)2(2,2'-bipy)]·H2O(4-HOBAH=4-hydroxybenzoic acid,2,2'-bipy=2,2'-bipyridine)(1)及[Pb(4-MBA)2(2,2'-bipy)](4-MBAH=4-methylbenzoic acid)(2),并通过X-射线单晶结构分析、元素分析、红外光谱、紫外光谱、荧光光谱以及热重分析等手段对配合物进行了表征与研究.X-射线单晶结构测定表明,2种晶体的不对称单元中,六配位的二价铅离子分刖与来自1个2.2'-联吡啶的2个N原子和2个对位取代苯甲酸的4个O原子螫合.配合物1属单斜晶系,P21/c空间群,a=1.09483(4)nm,b=1.751 94(6)nm,c=1.20479(4)nm,β=100.334(2)°,V=2.27339(14)nm3,Z=4,final R1=0.0254,wR2=0.0674.广泛存在的分子间氢键和弱π…π堆积作用将配合物1组装成稳定的三维超分子结构.配合物2属三斜晶系,P-1空间群,a=0.955 10(11)nm,b=1.00805(12)am,c=1.324 83(15)nm,a=109.865(1)°,β=97.322(1)°,γ=90.643(1)°,V=1.1878(2)nm3,Z=2,final R1=0.0284,wR2=0.0508.配合物2经由一对Pb…O(0.3185(2)nm)弱相互作用被组装成二聚体结构.弱的Ph…O相互作用及与配合物1中类似的π…π堆积作用共同构筑了配合物2的三维结构.在配合物1和2中,铅的6s孤电子均显示了立体化学活性,使配位键分布于半球型区域.同时,两种配合物固体均具有光致发光特性,并在蓝光区有较强发射.     

配合物[Cd(C_9H_8O_3N)_2(2,2′-bipy)(H_2O)]_2·(H_2O)_3的合成、结构及荧光和电化学性质(英文)

以对乙酰氨基苯甲酸和2,2′-联吡啶为配体合成了一个新配合物[Cd(C9H8O3N)2(2,2′-bipy)(H2O)]2·(H2O)3。该配合物晶体属三斜晶系,空间群P1,晶胞参数:a=1.2559(3)nm,b=1.5068(3)nm,c=1.6507(3)nm,α=112.14(3)°,β=101.83(3)°,γ=93.84(3)°,V=2.7959(10)nm3,Dc=1.592g·cm-3,Z=4,μ(MoKα)=0.840mm-1,F(000)=1364,最终偏离因子R1=0.0276,wR2=0.0683。标题配合物的不对称单元由2个独立的单核结构Cd(C9H8O3N)2(2,2′-bipy)(H2O)和3个晶格水分子组成。中心镉髤离子处于六配位的变形八面体环境中。本工作测定了配合物的荧光和电化学性能。     

[Ni(C_5H_5N)_2(C_7·H_6O_2N)_2]H_2O三元配合物的合成及晶体结构

合成了标题化合物。该化合物的分子式[Ni(C5H5N)2(C7H6O2N)2]H2O(C24H24N4NiO3),分子量475.18,采用单色的MoKα (λ = 0.71073 )射线测定,共收集7408个数据,其中独立衍射点2567个(Rint = 0.0272),I > 2s(I)可观测点数1926个,结果表明该化合物属单斜晶系, 空间群C2/c其晶胞参数为: a = 14.466(2),b = 12.193(2),c = 14.072(2) ;β = 116.229(2)°,V = 2226.6(5) 3,Z = 4,Dc = 1.418 g/cm3 ,μ = 0.905 mm-1,F(000) = 992. 2个水杨醛亚胺各提供2个配位原子参与配位,2个吡啶各提供1个配位原子参与配位,该配合物是六配位的八面体构型,同时讨论了该体系中不同配位原子的配位能力的差异。     

Synthesis and Crystal Structure of[Ni(C5H2N2O4)(2, 2'-bipy)(H2O)2]·2H2O

The crystal structure of [Ni(C5H2N2O4)(2, 2?-bipy)(H2O)2]·2H2O 1 has been determined by X-ray diffraction. Crystal data: triclinic system, space group P ī with a = 7.9424(3), b = 9.9417(3), c = 12.1867(3) (A。）, α = 84.771(1), β = 77.375(2), γ = 68.993(2)°, C15H18N4O8Ni, Mr = 440.7, V = 876.16(5) (A。）3, Z = 2, Dc = 1.672 g/cm3, F(000) = 456, ((MoK() = 1.162 mm-1, the final R = 0.0464 and wR = 0.1055 for 3026 observed reflections with I > 2((I). In the title compound, the nickel ion is coordinated by a nitrogen atom and an oxygen atom from the orotate ligand, two nitrogen atoms from 2, 2'-bipy and two oxygen atoms from the coordinated water molecules in a distorted octahedral geometry. The presence of intermolecular hydrogen bonding and (-( stacking interaction of aromatic rings from 2, 2'-bipy results in a 3D structure.     

配位聚合物[Ni(cpna)(bpy)(H2O)]n的合成、晶体结构及磁性质

通过水热方法,采用H₂cpna(H₂cpna=5-(2′-carboxylphenyl))和bpy(bpy=2,2′-bipyridine)与Ni(OAc)₂·4H₂O反应,合成了一个具有二维结构的配位聚合物[Ni(cpna)(bpy)(H₂O)]_n (1),并对其结构和磁性质进行了研究。结构分析结果表明该聚合物的晶体属于单斜晶系,P2₁/c空间群。3个镍(Ⅱ)离子、3个cpna配体、3个2,2′-bpy配体和3个配位水分子形成了一个[Ni₃(cpna)₃(bpy)₃(H₂O)₃]环,这些环通过镍(Ⅱ)离子与cpna配体的配位作用形成了一个二维层状结构。层与层之间又通过π-π堆积作用形成了一个三维的配位框架。研究表明,该聚合物中相邻镍(Ⅱ)离子之间存在很弱的反铁磁相互作用。     

Hydrothermal Synthesis and Electrochemical Properties of Complex Cu(CH3C6H4COOH)2(2,2''-bipy)·(H2O)

The title complex has been synthesized by 4-methylbenzoic acid and 2,2'-bipyridine (bipy) in the mixed solvent of water and methanol. It crystallizes in the triclinic system, space group (P1-) with a = 0.7047(3), b = 1.1217(5), c = 1.6718(7) nm, α = 103.826(7), β = 90.772(6), γ = 104.195(6)°, C26H25CuN2O5.50, Mr = 517.02, V = 1.2404(9) nm3, Dc = 1.384 g/cm3, Z = 2, F(000) = 536, μ(MoKα= 0.921 mm-1, R = 0.0782 and wR = 0.2172. Structural analysis shows that the copper atom is coordinated with three oxygen atoms from two 4-methylbenzoic acids and one water molecule together with two nitrogen atoms from 2,2'-bipyridine, giving a distorted square-pyramid coordination geometry. The cyclic voltametric behavior of the complex has also been described.     

一维螺旋链状配位聚合物[Cu(p-BDOA)(2，2′-bipy)·H2O]n的合成与表征(英)

A new copper(Ⅱ) coordination polymer, [Cu(p-BDOA)(2，2′-bipy)·H₂O]_n ( p-BDOA^2-=benzene-1,4-dioxyacetate dianion; 2,2′-bipy=2,2′-bipyridine) has been synthesized and characterized by elemental analysis, IR, TG and single crystal X-ray diffraction. The Crystal crystallizes in orthorhombic system, the space group is P2₁2₁2₁, with the unit cell parameters a=0.698 4(1) nm, b=1.559 7(3) nm, c=1.750 6(4) nm and V=1.906 8(7) nm³, M_r=461.91, Z=4, R=0.057 5, wR=0.078 3. Each copper(Ⅱ) atom is six-coordinated and displays a distorted square pyramidal geometry with a one-capped base by one very long semicoordinate Cu-O(carboxylate) bond. Adjacent Cu(Ⅱ) ions are bridged by carboxylate groups, resulting in a one-dimensional helical chain. The adjacent Cu…Cu distance within the polymeric chain is 1.348 4 nm. Furthermore, such chains are linked through hydrogen bonds and π-π stacking interactions to form supramolecular network. CCDC: 219234.