近红外离散波长光谱基线漂移校正方法研究

微分是(近)红外光谱多元分析校正中最常使用也是最有效的光谱基线漂移校正方法。由于数据数目较少及相邻数据在光谱意义或数学意义上缺乏连续性,微分不能直接用于离散波长光谱消除基线漂移。为此,提出了一种结合插值拟合和微分校正离散光谱基线漂移的新方法。思路是采用三次样条插值法对离散波长光谱进行拟合,然后对拟合光谱进行Savitaky-Golay卷积求导,再从微分光谱中取出对应于原离散波长光谱数值的数值,构成离散波长光谱的微分光谱,从而实现离散波长光谱的基线漂移校正。通过分别由模拟离散波长光谱数据和实际的离散波长光谱数据建立多元校正模型检验新方法效果。采用ABC干粉灭火剂和土壤的近红外光谱数据及性质建立了PLS和MLR模型。结果表明,新方法能有效消除离散波长光谱的基线漂移对多元分析校正产生的不利影响,明显地提高了多元分析校正模型的准确性,对改善离散波长光谱仪器分析准确度具有重要的理论意义和实际应用价值。     

金属丝的杨氏模量测定实验的改进

对金属丝杨氏模量测定仪重新设计.将金属丝水平放置,在中点处悬挂重物,通过测量金属丝伸长后的转角,进而测量金属丝的杨氏模量.     

Eligibility of spherical-well approximation for calculations of nucleon-transfer matrix elements

Single-particle matrix elements of nucleon transfer were calculated by the Woods-Saxon potential wave functions. The results are compared with the ones calculated by the spherical-well approximation. The eligibility of the approximation of the mean field of nuclei by the spherical well to study the initial stage of nuclear reactions at heavy-ion collisions is demonstrated. The text was submitted by the authors in English.     

核磁共振技术在SIPM开发生产中的应用

本文利用核磁共振氢谱技术，建立了生产间苯二甲酸二甲酯磺酸钠（SIPM）工序中磺化率、酯化率的快速测定方法，为工艺的进一步优化及常规的中控分析方法的建立提供了依据。并尝试利用核磁共振技术测定SIPM在水中及8％硫酸钠水溶液中不同温度下的溶解情况。对生产所用的原料、产品的纯度以及废水处理中的副产物进行了测定，结果令人满意。     

Structure characterization of foams and filled polymers by means of MRI

The structure of foams and filled polymers can be analyzed by means of MRI. It is also possible to observe the deformation behavior of the structure of foams and filled polymers in situ. A displacement experiment (rigid body) was performed in the magnet and observed by MRI. The NMR images are analyzed by image processing. Average distances between particles are estimated by the use of the autocorrelation function and the spectrum of the autocorrelation function. The spectrum shows the spatial frequency of the distances. The displacement field was calculated by the cross-correlation function. Information about particle distances and micromechanical deformation can be obtained by NMR imaging methods by combining autocorrelation and cross-correlation.     

制膜工艺对聚合物太阳电池性能影响的研究

用渡越时间法（TOF）分别测试了采用旋涂和滴涂方法制备的poly［2-methoxy-5-（2′-ethylhexyloxy）-1,4- phenylenevinylene］（MEH-PPV）薄膜的空穴迁移率,用原子力显微镜对这两种方法制备的薄膜表面形貌进行了研究.结果表明使用滴涂法有利于聚合物形成有序薄膜结构,能有效提高空穴迁移率.用滴涂法制备的基于MEH-PPV：phenyl C61- butyric acid methyl ester（PCBM）共混薄膜的太阳电池,对比用旋涂法制备的太阳电池,其能量 关键词： 太阳电池 聚合物 迁移率     

The use of the regularities of nuclear backscattering of protons for analysis of hydrogen in the surface layers of materials

The regularities of backscattering of 7.7-MeV protons from nuclei are used to quantitatively determine the hydrogen concentration in materials by the example of hydrated titanium and zirconium samples. The results obtained by the nondestructive method are in good agreement with the data of chemical analysis by a destructive method.     

Kinetics of ultrasonic degradation of phenol in the presence of TiO2 particles

The degradation of phenol by ultrasonic irradiation in the presence of TiO2 was investigated in complete darkness. The effects of amount of TiO2 and the combination of TiO2 addition with gas (air or oxygen) supply on the degradation kinetics of phenol and the formation of the reaction products were examined. The degradation rate of phenol increased with the amount of TiO2. As the dissolved oxygen concentration increased by supplying oxygen, the degradation rate of phenol also increased. A kinetic model for the disappearance of phenol was proposed. The model takes into account the OH radical formation by direct water degradation, indirect degradation by oxygen atom and indirect degradation by TiO2 catalysis. The calculated results explained well the fact that a higher amount of TiO2 and dissolved oxygen concentration gave faster disappearance rate.     

模拟合成孔径雷达数据片波差的测量和胶片、波差的容限

本文介绍一种用马赫-陈德干涉系统测量模拟合成孔径雷达数据片波差的方法.该法能把两种原因产生的波差区分开来,即把通过胶片变形的波面与平面参考波面比较,求出胶片厚度不平产生的波差;把合成孔径雷达数据片的一级衍射波面与两个半径不等的参考球面波比较,分别求出由模拟装置产生的方位维和斜距维波差.本文给出一些实验结果和分析.这种方法还可以用于测量真实合成孔径雷达数据片的波差.由胶片厚度变化产生的波差可以用液体门补偿.但是,在实际中使用液体门是很繁复的,有时也没有必要.因此,我们认瑞利准则出发导出合成孔径雷达数据片胶片厚度变化产生的波差的容限,以此作为判断是否要用液体门的依据.     

Increasing of registering capacity of nuclear emulsion for autoradiography

The ways of increasing detecting power of the type M nuclear emulsion gel have been investigated in these studies. There have been found conditions under which type M emulsion sensitivity increased by 15–20% without increasing fog grain background. The stability of photographic sensitivity during emulsion gel storage increased by two times. The prevention of latent image fading (by means of layer moisture content) decreased to 1.2% and increasing the detecting power of the emulsion (by means of exposure temperature) by up to 37°C). The exposure time of tritium labelled autographs has been decreased to about 20%.     

超声波强化提取对茯苓水溶性多糖结构影响的研究

以茯苓菌核为原料,采用正交实验法确定超声波辅助热水浸提茯苓水溶性多糖的最佳提取条件,并对超声波辅助提取中药多糖的机理进行初步研究。用苯酚硫酸法测定糖含量,傅立叶变换红外光谱仪(FTIR)分析糖类官能团,气相色谱法测定单糖组成,原子力显微镜观察多糖结构,并将测定结果与传统热水法浸提所得茯苓多糖进行对比。实验结果表明:采用超声波辅助热水浸提可以使水溶性茯苓多糖的提取率达到2.71%(传统热水浸提法提取率为1.49%),传统热水浸提得茯苓多糖(PPTH)与超声波辅助热水浸提得茯苓多糖(PPUH)具有相同的单糖组成,都包含核糖、木糖、甘露糖、果糖、半乳糖和葡萄糖,二者的红外吸收谱也基本相同,原子力显微镜扫描分析显示,PPTH整体呈现网状结构,而PPUH主要以长短不一的近棒状结构存在。     

Separate reconstruction of the speed of sound,density of the medium,and coefficient of absorption in tomographic problems

A procedure is proposed for separating contributions to the scatterer function by inhomogeneities of the speed of sound, density of a medium, and coefficient of absorption. The scatterer function is reconstructed by solving the inverse problem. The power index of the absorption coefficient’s frequency dependence is determined simultaneously. The resistance to interference of this procedure is investigated by simulations in the multifrequency mode.     

Hydrodynamics of resonance oscillations of columns of inelastic particles

We study oscillations of a one-dimensional (1D) column of N slightly inelastic particles, produced by a piston vibrating at one end of a closed tube. It is found that for large enough vibrational amplitudes of the piston, the column oscillates periodically with the period equal to the vibrational period. The oscillation patterns are governed by the shock waves propagating across the column. The averaged kinetic energy per particle is shown to be proportional to the square of the vibrational frequency, omega. This energy also strongly depends on the vibrational amplitude. The maximal value of this kinetic energy achievable by these external vibrations is found to be of order omega(2)L(2), where L is the total volume (length) of the tube free of particles. The above results on the column resonance oscillations are also predicted by a 3D hydrodynamic model of an inelastic granular gas.     

Possibility of propagation of dissipative solitons in ac-driven superlattice

The renormalization equation for nonlinear electromagnetic wave propagating in ac-driven superlattice with dissipation has been derived by averaging method. The expression for dissipative soliton potential is obtained. The values of high-frequency field amplitudes allowing for two types of dissipative soliton are found. The shape and type of such solitons are shown to be regulated by changing the high-frequency field amplitude. The chaotic behavior of electrons in superlattice is investigated by the Melnikov method.     

Pyrolysis of amines: Infrared spectrum of propargylimine

Propargylimine was detected in the gas phase for the first time. The molecule was produced by the pyrolysis of dipropargylamine, and examined by a Fourier transform infrared spectrometer. The production of this molecule was also confirmed by microwave spectroscopy. Identification of the molecule is supported by an ab initio MO calculation for its vibrational frequencies and rotational constants.     

Three regimes of dynamic fragmentation of shells

The effect of the diameter of shells of structural steel 45Cr on the parameters of the cumulative numerical distribution of fragments by mass and the cumulative mass distribution of fragments by length has been studied. It is found that the statistical fragment distributions by mass for shells of different diameters are described well by exponential relation, whereas the cumulative mass distributions of fragments by length are described by power functions. The exponents in these relations depend on the shell diameter. Plotting the cumulative mass distribution of fragments by length allows one to relate the mechanisms of dynamic fracture with fragmentation regimes, which differ in the parameters of the power relation characterizing the formation of fragments of the basic spectrum.     

Surface modification of polypropylene and compatibilization of interfaces in incompatible blends of polypropylene with polystyrene by plasma of CO2

The effect of surface modification of polypropylene (PP) film is induced by CO₂ plasma in this study. The change in chemical structures on the surface of PP film is characterized by X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared (FT-IR). The polarity of modified surface of PP film is investigated by contact angle method. The compatibilization of interfaces between polypropylene and polystyrene phases in incompatible blends is studied by the treatment of plasma of CO₂. Transition layer thickness is measured by small angle light scattering (SALS).     

Measurement of the lifetime of b-baryons

The average lifetime of weakly decaying b-baryons was studied using 3.6 million hadronic decays collected by the DELPHI detector at LEP. The measurement of the proper decay time distribution of secondary vertices was used on three complementary samples. The first sample consisted of events with a fully reconstructed and an opposite charge lepton, or an oppositely charged lepton pair accompanied by a . The other two samples were more inclusive, where b-baryon semileptonic decays were recognized by the presence of either a proton identified by the RICH detector or a and a lepton of charge opposite to that of the proton. The combined result was: Received: 19 February 1999 / Revised version: 6 April 1999 / Published online: 3 August 1999     

Dynamics of money

We present a dynamical many-body theory of money in which the value of money is a time dependent "strategic variable" that is chosen by the individual agents. The value of money in equilibrium is not fixed by the equations, and thus represents a continuous symmetry. The dynamics breaks this continuous symmetry by fixating the value of money at a level which depends on initial conditions. The fluctuations around the equilibrium, for instance in the presence of noise, are governed by the "Goldstone modes" associated with the broken symmetry. The idea is illustrated by a simple network model of monopolistic vendors and buyers.     

Evidence of glass transition in thin films of maleic anhydride derivatives: Effect of the surfactant coadsorption

The glass transition temperature of poly (maleic anhydride-alt-1-octadecen) and poly (styreneco-maleic anhydride) cumene-terminated thin films has been measured by mechanical relaxation of Langmuir films of these polymers. The dynamical properties show glass-like features (non-Arrhenius relaxation times and non-Debye mechanical response) interpreted by the coupling model. The glass transition temperature values determined by a mechanical relaxation experiment (step-compression) agree very well with those obtained by surface potential measurements. It is found that the glass transition temperature values in thin films decrease by about 100K as compared with those corresponding to the bulk polymers. The coadsorption of the water-insoluble surfactant DODAB decreases the glass transition temperature.