Stimulated Raman scattering-active isotopically pure <Superscript>12</Superscript>С and <Superscript>13</Superscript>С diamond crystals: A milestone in the development of diamond photonics

Isotopically pure ¹²С and ^13С diamonds are synthesized by chemical vapor deposition and impulsive stimulated Raman scattering in these crystals is investigated. The thermal conductivity of ¹²С isotopically pure damond and ^natC diamond with natural isotopic composition is measured. Phonon-nondegenerate Stokes lasing based on the χ⁽³⁾ nonlinearity in the ¹²С, ¹³С, and ^natC diamond “triad” is attained, which opens a new stage in the development of diamond photonics.     

Effect of pressure on the Raman spectra of synthetic diamonds with boron impurity

The raman scattering technique is used for studying diamonds with a 0.04–0.1 at % boron impurity under a pressure up to 3 GPa in a chamber with sapphire anvils. The Raman frequency increases linearly with pressure for all samples with pressure coefficients of 2.947 cm^?1/GPa for pure diamond and 3.01 cm^?1/GPa for boron-doped samples. The Raman linewidths remain unchanged for pure diamond and for diamond with a boron concentration of about 0.04 at % and decrease linearly upon an increase in pressure for samples with a boron concentration of about 0.1 at %. The Raman spectra with a line profile corresponding to the Fano resonance do not change qualitatively up to a pressure of 3 GPa. In diamond samples with a boron impurity exceeding 0.1 at %, the boron concentration in the surface layer can be substantially higher than at the center of the sample.     

Evolution of Airy structure in <Superscript>12</Superscript>C(<Superscript>12</Superscript>C, <Superscript>12</Superscript>C)<Superscript>12</Superscript>C between 5 and 10 MeV/A

We investigate the properties of a global optical potential, which describes the ¹²C + ¹²C elastic-scattering data between 70 and 130 MeV, within the nearside/farside and barrier-wave/internal-wave decomposition techniques. Particular emphasis is laid on the discussion of the incomplete absorption features of this system, and especially on the properties of the Airy minima which are observed in the experimental excitation function. The complicated angular and energy evolution of the data is explained in terms of the interference of a small set of scattering subamplitudes with a much simpler behavior.Received: 2 September 2003, Revised: 25 September 2003, Published online: 5 February 2004PACS: 24.10.-i Nuclear reaction models and methods - 24.10.Ht Optical and diffraction models - 25.70.Bc Elastic and quasielastic scattering     

Asymptotic Similarity of Time Correlation Functions and Shape of the <Superscript>13</Superscript>C and <Superscript>29</Superscript>Si NMR Spectra in Diamond and Silicon

Based on the proposed theory, we have investigated the shape of the NMR absorption spectra for ¹³C and ²⁹Si nuclei in diamond and silicon crystals attributable to the internuclear dipole–dipole interaction. In accordance with the available experimental data, we have considered both crystals with a 100% content of magnetoactive isotopes and crystals with a comparatively low dilution by nonmagnetic nuclei. The time correlation functions (the first of which is the Fourier transform of the NMR spectrum) arising in an infinite chain of coupled differential equations are shown to be mutually similar with a slight time delay. The proposed theory allows the spectrum to be calculated analytically. The results obtained agree satisfactorily with the experimental ones. It is noted that the mutual similarity of the time correlation functions is probably a corollary of the development of dynamical chaos in the system     

Diffractive scattering of <Superscript>7</Superscript>Be and <Superscript>8</Superscript>B nuclei by <Superscript>12</Superscript>C nuclei

A theory of the diffractive scattering of loosely bound three-cluster nuclei by nuclei was developed with allowance for Coulomb interaction. The differential cross sections for the scattering of projectile exotic nuclei ⁷Be and ⁸B by ¹²C nuclei at an energy of 40 MeV per nucleon were calculated within the proposed formalism. The results describe satisfactorily relevant experimental data.     

Coupled-channels analysis of K<Superscript>+</Superscript> scattering from <Superscript>6</Superscript>Li and <Superscript>12</Superscript>C using the Watanabe superposition model

Coupled-channels calculations for the elastic and inelastic scattering of K⁺ at 715 MeV/c by ⁶Li and ¹²C at 635, 715 and 800 kaon Lab momenta have been analysed. The optical potentials of ¹²C and ⁶Li are calculated in terms of the alpha-particle and deuteron optical potentials. Good fits to the experimental data and phenomenological calculations are obtained for ⁶Li and ¹²C nuclei.     

Semiclassical description of the <Superscript>6</Superscript>He+<Superscript>12</Superscript>C elastic scattering

The results of the elastic scattering of ⁶He+¹²C systemat E _Lab = 18 MeV by using the barrier and internal wave decomposition of the S-matrix element within the framework of the WKB method are presented. This is the first detailed study for the interaction of the exotic ⁶He nucleus on different stable nuclei by using a semiclassicalmethod. In this paper, we show that in order to obtain the elastic scattering cross section of the ⁶He+¹²C systemat energies close to the Coulomb barrier, it is vitally important to take into account the inner complex turning points in the calculations and the tunneling effects play a crucial role to explain the experimental data. The semiclassical results are compared with the experimental data as well as the quantum-mechanical one.     

Interface <Emphasis Type="Italic">D</Emphasis><Superscript>−</Superscript> complexes in a two-dimensional electron system

The excitation spectrum of a two-dimensional electron system in high-quality AlGaAs/GaAs quantum wells has been studied by Raman scattering. New Raman lines due to the excitation of interface D ⁻ complexes in which two electrons localized in a quantum well are coupled to a charged impurity at the quantum well interface have been identified. The ground state of the interface D ⁻ complexes has been found to change in the transverse magnetic field from spin-singlet to spin-triplet, similar to a change in the ground state of the system of two electrons localized in a harmonic potential.     

Effect of the codoping of N—H—O on the growth characteristics and defects of diamonds under high temperature and high pressure

Diamond crystals were synthesized with different doping proportions of N—H—O at 5.5 GPa—7.1 GPa and 1370 °C—1450 °C. With the increase in the N—H—O doping ratio, the crystal growth rate decreased, the temperature and pressure conditions required for diamond nucleation became increasingly stringent, and the diamond crystallization process was affected. [111] became the dominant plane of diamonds; surface morphology became block-like; and growth texture, stacking faults, and etch pits increased. The diamond crystals had a two-dimensional growth habit. Increasing the doping concentration also increased the amount of N that entered the diamond crystals as confirmed via Fourier transform infrared spectroscopy. However, crystal quality gradually deteriorated as verified by the red-shifting of Raman peak positions and the widening of the Raman full width at half maximum. With the increase in the doping ratio, the photoluminescence property of the diamond crystals also drastically changed. The intensity of the N vacancy center of the diamond crystals changed, and several Ni-related defect centers, such as the NE1 and NE3 centers, appeared. Diamond synthesis in N—H—O-bearing fluid provides important information for deepening our understanding of the growth characteristics of diamonds in complex systems and the formation mechanism of natural diamonds, which are almost always N-rich and full of various defect centers. Meanwhile, this study proved that the type of defect centers in diamond crystals could be regulated by controlling the N—H—O impurity contents of the synthesis system.     

Quantum registers based on single NV + <Emphasis Type="Italic">n</Emphasis><Superscript>13</Superscript>C centers in diamond: I. The spin Hamiltonian method

Details of the application of the spin Hamiltonian method for studying spin characteristics of a quantum register that includes an electron spin S = 1 of a single NV center in the ground electronic state and nuclear spins I = 1/2 of several isotopic atoms ¹³C located at different lattice sites near the vacancy of the NV center. Two methods of finding the hyperfine interaction tensors for these NV + n ¹³C spin systems are considered, one of which is based on the conventional electron spin resonance (ESR) method, while the other involves methods of quantum chemistry. The results of the latter method are compared with ESR data and with spectra of optically detected magnetic resonance (ODMR) and with the character of the modulation of the ODMR echo decay observed in single NV + n ¹³C systems. This comparison shows that the ab initio modeling of the spin characteristics of diamond nanoclusters containing NV centers makes it possible to obtain quantitative spin characteristics of the quantum registers under study.     

Elastic scattering of light alpha-cluster nuclei by <Superscript>12</Superscript>C nuclei

The differential cross sections for the elastic scattering of ¹²C and ¹⁶O nuclei by ¹²C nuclei are calculated on the basis of the theory of multiple diffractive scattering and the dispersive alpha-cluster model. The calculations were performed by using either an effective or a free αα amplitude. It is shown that the results obtained in these two cases are noticeably different.     

Elastic Deuteron Scattering on the <Superscript>12</Superscript>C Nucleus within a Three-Body Model

The formalism developed earlier for elastic pd scattering on the basis of Glauber theory with allowance for a total spin dependence is modified by replacing pN amplitudes by amplitudes for N¹²C scattering and is applied to elastic deuteron scattering on the ¹²C nucleus. The amplitudes for elastic N¹²C scattering are obtained within the optical model. Respective numerical calculations performed at the kinetic deuteron-beam energy of 270 MeV lead to results that agree well with data on the differential cross section for d¹²C scattering into the forward hemisphere, but the calculated spin observable A _y ^d agrees with experimental data only qualitatively.     

Description of the torsional motion in the isotopically asymmetric ionic complexes ArH<Subscript>2</Subscript>D<Superscript>+</Superscript> and ArD<Subscript>2</Subscript>H<Superscript>+</Superscript>

The internal dynamics of the isotopically asymmetric ionic complexes ArH₂D⁺ and ArD₂H⁺ is considered to be a distorted dynamics of the isotopically symmetric ArH₃⁺ complex. By using the group chain methods, a rigorous algebraic model is constructed to describe the spectrum of the asymmetric complexes with an allowance for the torsional motion of the structure of hydrogen nuclei. The model is based on the geometrical group of symmetry of internal dynamics of the isotopically symmetric ionic complex, which is used here as a noninvariant group.     

Study of synthetic diamonds by dynamic nuclear polarization-enhanced13C nuclear magnetic resonance spectroscopy

Four I_b-type synthetic diamond crystals were studied by dynamic nuclear polarization (DNP)-enhanced high resolution solid state¹³C nuclear magnetic resonance (NMR) spectroscopy. The home built DNP magic-angle-spinning (MAS) NMR spectrometer operates at a field strength of 1.9 T and the highest DNP enhancement factor of synthetic diamonds came near to 10³. Comparing with I_b-type natural diamonds, the¹³C NMR linewidths of synthetic diamonds in static spectra are broader. The¹³C spin-lattice relaxation time and DNP polarization time of synthetic diamond are shorter than those of I_b-type natural diamond. From the hyperfine structure of the DNP enhancement curve, four kinds of nitrogen-centred free radicals could be identified in synthetic diamond.     

Analysis of <Superscript>8</Superscript>B Proton Halo Nucleus Scattered from <Superscript>12</Superscript>C and <Superscript>58</Superscript>Ni at Different Energies

Angular distributions in the elastic scattering of ⁸B from ¹²C and ⁵⁸Ni targets at different energies have been analyzed in the framework of the double-folding (DF) optical model. The real central part of the nuclear optical potential is obtained by folding the M3Y effective interaction with the cluster density distribution of the ⁸B nucleus. The experimental angular distributions have been successfully reproduced. This confirms the validity of the cluster structure of the ⁸B nucleus.     

Unexpected transparency in the scattering of fragile <Superscript>6</Superscript>Li and <Superscript>6</Superscript>He Nuclei

It is found that the scattering of the fragile nucleus ⁶Li from ¹²C and ¹⁶O is unexpectedly transparent. It is shown that the internal-wave contribution is significantly large in the scattering, which suggests that some transparency could persist in the scattering involving the fragile nucleus ⁶He.     

Polarization phenomena in the intermediate energy elastic deuteron scattering from <Superscript>16</Superscript>C and <Superscript>16</Superscript>O nuclei

A model based on the multiple diffraction scattering theory and the α-cluster model with dispersion of target nuclei is proposed for describing the behavior of observables for the elastic deuteron scattering from ¹²C and ¹⁶O nuclei at intermediate energies. Differential cross-sections and analyzing powers calculated within this approach for incident-deuteron energies of 400 and 700 MeV are in a reasonable agreement with experimental data.     

Spectroscopy of <Superscript>17</Superscript>C and (sd )<Superscript>3</Superscript> structures in heavy carbon isotopes

The structure of ¹⁷C has been investigated using the three-neutron transfer reaction (¹²C,⁹C) on a ¹⁴C target at 231MeV incident energy, the reaction Q-value is Q ₀ = - 46.930MeV. Eleven new states up to 16.3MeV excitation energy were identified. The same reaction has also been used on a ¹²C target ( Q ₀ = - 38.787MeV), and excited states in ¹⁵C up to 19MeV were observed. In ¹⁷C the three transferred neutrons populate (sd )³ configurations on the ¹⁴C core. The comparison of levels populated by the (¹²C,⁹C) reaction in ¹⁷C, ¹⁶C and ¹⁵C reveals a strong similarity of their properties. This concerns especially nine states in each of the three carbon isotopes, which show practically the same excitation energies except a constant mean shift of +5.82MeV for ¹⁶C and +6.65MeV for ¹⁵C with respect to ¹⁷C. The triples of states from the three isotopes, which correspond to each other, have also similar widths and cross-section ratios. It is concluded that the same (sd )³ structures are populated in the three carbon isotopes. The observed levels of ¹⁷C are also compared to the levels of ¹⁹O with known assignments and to shell model calculations, and their decay properties are discussed.     

Nonlinear-laser effects in χ(<Superscript>3</Superscript>)-and χ(<Superscript>2</Superscript>)-active organic single crystals

The process of stimulated Raman scattering (SRS) allows one to convert laser emission wavelength of crystals, providing suitable molecular or lattice modes which contribute to third-order nonlinear optical susceptibility. Renewed interest in this field emerged because of the discovery of SRS in crystals that contain molecular units exhibiting Raman active modes. Particularly, organic nonlinear optical crystals used so far for frequency doubling and third harmonic generation seem to have a great potential for SRS application. This review paper reported same results on efficient SRS lasing effects that were discovered recently in organic crystals.