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1.
Steven P. Tanis 《Tetrahedron letters》1982,23(31):3115-3118
The Grignard reagent , derived from 3-chloromethyl furan, reacts with various alkyl- and allylic halides, in the presence of Li2CuCl4, to provide high yields of 3-substituted furans. 相似文献
2.
Three different types of butanolide complexes with EtnAlCl3?n in the molar ratios and have been investigated by IR with 1M NMR spectroscopy. The butanolides form and complexes with ethylaluminium halides, but with triethylaluminium only complexes are formed. The complexes are intermediates in the cleavage of butanolides. 相似文献
3.
Alessandro Dondoni Guido Galliani Annarosa Mastellari Alessandro Medici 《Tetrahedron letters》1985,26(24):2917-2920
-alkylthiazolium halides are transformed by KO2 into the corresponding thiazolin-2-ones and thiazolin-2-thiones; the same reactions occur with thiamine, whose thiazolin-2-one pyrophosphate has been reported to be a strong inhibitor of pyruvic dehydrogenase. 相似文献
4.
Crystals of strontium tetraiododiargentate octahydrate, SrAg2I4 · 8H2O belong to the tetragonal space group I422(D94), with a = 12.86 ± 0.03, c = 5.56 ± 0.02Å, and Z = 2. The structure may be described as having, in one-to-one ratio, columns formed by [Sr(H2O)8]2+ entities centered at (0, 0) and () and chains of edge-sharing AgI4 tetrahedra centered at (, 0) and (0, ), the chains being linked to each other through water molecules by hydrogen bonding and through van der Waals forces between iodide ions. The crystals are obtained from a saturated aqueous solution of SrI2 which is then saturated with AgI; dilution of this solution or addition of water to the crystals precipitates β-AgI. This demonstrates the ease with which the three-dimensional corner-sharing tetrahedra of the β-AgI transform to the edge-sharing chain arrangement of tetrahedra and vice versa. It is probable that the saturated solution itself contains [Sr(H2O)8]2+ and AgI4-chain entities.Anhydrous compounds of strontium and barium halides with silver and copper halides appear to be unattainable at atmospheric pressure. It is speculated that this is associated with the particular coordination requirements of the alkaline earth ions. 相似文献
5.
Brian J. Brisdon Dennis A. Edwards James W. White 《Journal of organometallic chemistry》1978,156(2):427-437
A series of carbonylmetallate anions -[MX(CO)3L2]?, where M = Mo or W, X = Cl, Br or I and L2 = 1,10-phenanthroline(phen) or 2,2′-bipyridine(bipy) have been prepared from the corresponding -M(CO)4L2 complexes. No evidence of -to -isomerisation was evident on dissolution, although in MeCN solvolysis occurred with the formation of -M(CO)3L2(MeCN). Reaction of the anions with various allyl halides resulted in high yields of η3-allyl complexes [MX(CO)2(η3-RC3H4)L2]. The significance of these observations for the mechanism of the allyl oxidative-addition reaction are discussed. 相似文献
6.
G.R. Clark C.M. Cochrane W.R. Roper L.J. Wright 《Journal of organometallic chemistry》1980,199(2):C35-C38
The osmium carbyne complex, Os(CR)Cl(CO)(PPh3)2, (R p-tolyl) reacts with Group I halides to form the mixed dimetallocyclopropene species, R)Cl(CO)(PPh3)2, R)Cl(CO)(PPh3)2, R)Cl(CO)(PPh3)2, and [R)Cl(CO)(MeCN)(PPh3)2] ClO4 X-ray crystal structure determination of R)Cl(CO)(PPh3)2 confirms the presence of a three-membered ring and the structure can be viewed as the “acetylene-like” interaction of an osmium—carbon triple bond with AgCl. In acid solution AgCl is precipitated and an alkylidene complex results from proton addition to the carbyne ligand. 相似文献
7.
Dihydroisoquinolines are formed in high yield the cyclization of α-ketoimidoyl halides prepared by the reaction of phenethyl isocyanides with acyl halides. 相似文献
8.
Reaction of dimetalated succinamides with benzyl halides and aromatic aldehydes provides short routes to diverse lignan natural products , , and , including the human urinary metabolites () and (). 相似文献
9.
R.J. Bertino B.A.W. Coller G.B. Deacon I.K. Johnson 《Journal of fluorine chemistry》1975,5(4):335-357
The lithium polyfluorobenzenesulphinates, Li O2SR (R = C6F5, -HC6F4, -HC6F4, or -HC6F4), and the dilithium tetrafluorobenzenedisulphinates, - and -(LiO2S)2C6F4, have been prepared by reaction of the appropriate polyfluoroaryllithium compounds with sulphur dioxide. All compounds were isolated as hydrates and gave the corresponding -benzylthiouronium salts on treatment with -benzylthiouronium chloride. From reactions of the lithium sulphinates with suitable mercuric salts in water, generally at room temperature, the derivatives RHgX (R = C6F5, X = Cl, Br, CH3CO2, or PhSO2; R = -HC6F4, X = Cl, Br, or CH3CO2; R = -HC6F4, X = Cl or Br; R = -HC6F4, X = Cl), -(XHg)2C6F4 (X = Cl, Br, or CH3CO2), and -(XHg)2C6X4 (X = Cl or Br) have been prepared. Similarly, the bispolyfluorophenylmercurials R2Hg (R = C6F5, -HC6F4, or -HC6F4) have been prepared from the corresponding lithium sulphinates and either mercuric salts or polyfluorophenylmercuric halides in aqueous -butanol. A possible mechanism for the sulphur dioxide elimination reactions is discussed. 相似文献
10.
A study of the photochemistry of vinylidine dihalides and and vinylhalides and revealed some interesting differences in their photobehaviour. This study led to uncover an important constraint in the generation of vinyl cations from certain α-unsubstituted vinyl halides such as . 相似文献
11.
Several π-excessive heteropolyaromatic compounds, which contain furan and thiophen ring and are possible antifungal agents, have been synthesized in good yields according to two general methods. The first method has been used to prepare compounds possessing thiophens linked by their 2- and 5-positions, such as the ter-aryls , and . Two precursors of these compounds have been obtained either by the Glaser reaction, or using a novel Pd-mediated reaction. The second method,which consists of the Ni-or Pd-catalyzed heteroarylation of heteroarene halides via cross-coupling with heteroaryl Grignard reagents or zinc halides,has been used to prepare the bi-aryls , which contain two heteroaromatic units, and the ter-aryl . Compound has been also prepared starting from 2-(2-thienyl) furan () by selective lithiation, followed by bromination.The 13C NMR signals of and have been assigned on the basis of the literature data and by relaxation measurements. Relaxation data have been also used to obtain qualitative informations on the conformational equilibria of the bi-aryls , and the ter-aryls . 相似文献
12.
Palladium catalysed alkoxycarbonylation of heterocyclic halides affords a simple and versatile synthesis of both and heterocyclic esters where a range of catalysts have been studied and a method to employ inexpensive inorganic bases has been found. 相似文献
13.
1-Ehtoxycarbonyl-1, 2-dihydroquinoline-2-phosphonates () were treated with n-butyllithium followed by alkyl halides to afford the corresponding 4-alkylated phosphonates () with complete regioselectivity in 67–97% yields. The phosphonates () were converted to 4-alkylquinolines () in ca. 50% yields by treatment with sodium iodide in HMPA or by alkaline hydrolysis in aqueous ethanol. 相似文献
14.
Stannylethynyl ethers react with acyl halides or some elemental halides under substitution of the stannyl group; the carbonyl group of ketenes insert into the single bond between the acetylenic carbon atom and the stannyl group. 相似文献
15.
Lithio reagents derived from 1-triisopropylsilylpropyne () and 1,3--[triisopropylsilyl]propane () are effective for the synthesis of or terminal enyne units (CHCHCCH) and for carboncarbon bond formation with halides, aldehydes, ketones, epoxides, and α,β-enones. 相似文献
16.
Allenyl cations, generated from allenyl or alkynyl halides and Ag+, attack styrene at the side chain or at the aromatic nucleus. The allenyl/alkynyl product ratio is dependent on the structure of the precursor halide except for highly substituted systems. 相似文献
17.
Herbert Muffler Guenter Siegemund Werner Schwertfeger 《Journal of fluorine chemistry》1982,21(2):107-132
4.5-Perfluoro-1.3-dioxolanes are available by reaction of 2(α-chloroalkoxy)perfluoro-carbonyl halides or -ketone with fluoride ions. A mechanism for the intramolecular ring- closure-reaction is proposed. Hydrogen atoms at C-2 in can be exchanged photochemically by chlorine. Starting from the 2-monochloro-derivatives the 2-monofluoro-4.5-perfluoro- 1.3-dioxolanes are formed by reaction with triethylamine- hydrofluoride. 相似文献
18.
Tri(-butyl)germanium hydride is a superior reagent for the reductive addition of alkyl halides to active olefins. 相似文献
19.
2-[(Dimethylamino)methyl]phenylcopper tetramer (R4Cu4) forms a red complex (RCu - CuBr)n with cuprous bromide. The interaction of 2-[(dimethylamino)methyl]phenylcopper with cupric halides results in the formation of the dimer RR, the 2-halo-substituted benzylamine R—Halide and minor amounts of N,N-dimethylbenzylamine RH. The formation of these products can be explained on the basis of an intramolecular electron-transfer redox reaction taking place in innersphere activated complexes of the type R4Cu3Cu - - - X - - - CuIIX(CuIIX2)n-1. The course of the metathesis reaction of 2-[(dimethylamino)methyl]phenyllithium with cuprous bromide depends on the order of addition of the reactants. Reversed addition (RLi to CuBr) results in the formation of an inseparable mixture of complexes of the type (RCu)x- (CuBr)y. Upon addition of CuBr to RLi the uncomplexed organocopper compound R4Cu4 is formed. 相似文献
20.
Masahito Ochiai Kenzo Sumi Yoshimitsu Nagao Eiichi Fujita 《Tetrahedron letters》1985,26(19):2351-2354
Vinyliodonium salts were synthesized from vinylsilanes by the reaction with iodosylbenzene and triethyloxonium tetrafluoroborate. The reaction occurs stereospecifically with retention of configuration. Vinyliodonium salts are highly effective as the activated species of vinyl iodides. Thus, a variety of substituted olefins including α-cyano and α-nitro olefins, vinyl sulfides, vinyl halides, and α,β-unsaturated esters, were prepared from under mild reaction conditions. 相似文献