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1.
Sword-like (diameter ranging from 40 nm to 300 nm) and needle-like zinc oxide (ZnO) nanostructures (average tip diameter ∼40 nm)
were synthesized on annealed silver template over silicon substrate and directly on silicon wafer, respectively via thermal
evaporation of metallic zinc followed by a thermal annealing in air. The surface morphology, microstructure, chemical analysis
and optical properties of the grown samples were investigated by field emission scanning electron microscopy, X-ray diffraction,
energy dispersive X-ray analysis, room temperature photoluminescence and Raman spectroscopy. The sword-like ZnO nanostructures
grown on annealed silver template are of high optical quality compared to needle-like ZnO nanorods for UV emission and show
enhanced Raman scattering. 相似文献
2.
Xianliang Sheng Jin Zhai Lei Jiang Daoben Zhu 《Applied Physics A: Materials Science & Processing》2009,96(2):473-479
Abstract ZnO nanoparticles with average diameter of 12 nm were used to fabricate ZnO photoanodes by electrohydrodynamic (EHD)
technique for dye-sensitized solar cells (DSSCs). To enhance the light scattering and conversion efficiency, the ZnO film
with scattering hollow cavities (HCs) was realized by calcining polystyrene spheres (PSs) in the film. The films had strong
light scattering ability and the overall light to electricity conversion efficiency (η) was improved and reached 5.5% under illumination of simulated solar light (AM-1.5, 100 mW/cm2). 相似文献
3.
Christian Fauteux My Ali El Khakani Joseph Pegna Daniel Therriault 《Applied Physics A: Materials Science & Processing》2009,94(4):819-829
ZnO nanorods, nanoneedles, nanoparticles, and nanoballs were synthesized on fused quartz substrates upon irradiation of a
droplet of methanolic zinc acetate dihydrate solution by an infrared (IR) continuous wave CO2 laser for a few seconds. The addition of monoethanolamine and water to the solution improved the alignment of the nanorods
and had a significant effect on the volume and morphology of the deposits. An increase of the zinc acetate concentration was
found to lead to an increase of the thickness and area covered by the initial ZnO seed layer on which the nanostructures grew.
By investigating the crystal structure of the deposits using X-ray and electron diffraction, we were able to show that the
nanorods grow along the c axis with a high crystalline quality. Raman and photoluminescence spectroscopy confirmed the high quality of the grown ZnO
nanostructures. As a matter of fact, their photoluminescence spectra are dominated by an intense UV emission around 390 nm. 相似文献
4.
Shoubin Xue Xing Zhang Ru Huang Huizhao Zhuang 《Applied Physics A: Materials Science & Processing》2009,94(2):287-291
ZnO thin films were first prepared on Si(111) substrates using a radio frequency magnetron sputtering system. Then the as-grown
ZnO films were annealed in oxygen ambient at temperatures of 700, 800, 900, and 1000°C , respectively. The morphologies of
ZnO films were studied by an atom force microscope (AFM). Subsequently, GaN epilayers about 500 nm thick were deposited on
the ZnO buffer layers. The GaN/ZnO films were annealed in NH3 ambient at 900°C. The microstructure, morphology and optical properties of GaN films were studied by x-ray diffraction (XRD),
AFM, scanning electron microscopy (SEM) and photoluminescence (PL). The results are shown, their properties having been investigated
particularly as a function of the ZnO layers. For better growth of the GaN films, the optimal annealing temperature of the
ZnO buffer layers was 900°C. 相似文献
5.
J. Cifre J. Bertomeu J. Puigdollers M. C. Polo J. Andreu A. Lloret 《Applied Physics A: Materials Science & Processing》1994,59(6):645-651
Silicon films were deposited at moderate substrate temperatures (280–500° C) from pure silane and a silane-hydrogen mixture (10% SiH4, 90% H2) in a hotwire CVD reactor. The morphology, structure and composition of the samples were studied with scanning electron microscopy, transmission electron microscopy, transmission electron diffraction, X-ray diffraction, Raman spectroscopy and secondary ion mass spectrometry. The sample deposited at 500° C with pure silane has an amorphous structure, whereas the samples obtained from silane diluted in hydrogen have a polycrystalline structure, even that grown at the lowest temperature (280° C). Polycrystalline samples have a columnar structure with 0.3–1 m crystallite sizes with preferential orientation in [220] direction. Deposition rates depend on the filament-substrate distance and range from 9.5 to 37 Å/s for the polycrystalline samples. The high quality of the polycrystalline samples obtained makes the hot-wire technique very promising. Moreover, it is expected to be easily scaled up for applications to large-area optoelectronic devices and to photovoltaic solar cells. 相似文献
6.
Xu Fei Ying Wan Haiming Zhang Zhanchen Cui Daming Zhang 《Applied Physics A: Materials Science & Processing》2009,96(2):467-472
A linear fluorinated bis-phenol-A novolac resin (LFAR) for optical waveguide was synthesized based on 4,4′-(hexafluoro-isopropylidene)diphenol,
epoxy chloropropane and formaldehyde. Negative fluorinated photoresist (FP) was made by composing the LFAR, diphenyl iodonium
salt and solvent. The film, which was made by spin-coating FP, had good UV light lithograph sensitivity, large hardness and
high glass transition temperature (T
g
>170°C, after crosslinking). Low-loss optical waveguides with very smooth top surface were fabricated from the resulting FP
by direct UV exposure and chemical development. For waveguides without upper cladding, the propagation loss of the channel
waveguides was measured to be 0.21 dB/cm at 1550 nm. 相似文献
7.
A. V. Kabashin W. Marine M. Meunier 《Applied Physics A: Materials Science & Processing》2008,93(4):1011-1014
ZnO is known as one of the best materials for the implementation of the random lasing effect, associated with mirror-less
laser emission in a simultaneously amplifying and highly scattering medium. Normally, the fabrication of this medium requires
a rather complicated procedure of deposition and thermal treatment of ZnO-based films on some specific substrates, yielding
wurtzite-orientation ZnO nanocrystals. We demonstrate a rapid synthesis of highly efficient ZnO-based random lasing spots
on a piece of Zn by employing the phenomenon of laser-induced air breakdown. Being ignited near the surface of a Zn target,
plasma of the air breakdown serves as a local reactor to locally transform its properties and thus form a film of well-packed
20–40 nm ZnO nanospheres. Exhibiting extremely high amplification and scattering, this medium is capable of generating the
random lasing effect within the exciton-based photoluminescent band. 相似文献
8.
Tatsunori Sakano Hiroki Fukuoka Yoshihiro Yata Toshiharu Saiki Minoru Obara 《Applied Physics A: Materials Science & Processing》2008,93(3):697-703
We employed epi-GaN substrates for ZnO film growth, and studied the deposition and post-annealing effects. ZnO films were
grown by pulsed laser deposition (PLD) method. The as-grown films were annealed for one hour under atmospheric pressure air.
ZnO morphologies after annealing were investigated and the post-annealed ZnO films grown at T
g
=700oC have very smooth surfaces and the rms with roughness is about 0.5 nm. Finally, ZnO post-annealed buffer layer was inserted
between ZnO epilayer and GaN/sapphire substrates. It is confirmed by AFM that growth temperature of 700oC helps the films grow in step-flow growth mode. It is observed by cathode luminescence spectrum that the ZnO film grown at
700oC has very low visible luminescence, indicating the decrease of the deep level defects. It is also revealed by Hall measurements
that carrier concentration is decreased by increasing the growth temperatures. It is suggested that low temperature buffer
layer growth and post-annealing technique can be used to fabricate ZnO hetero-epitaxy. 相似文献
9.
Enhanced field emission from pulsed laser deposited nanocrystalline ZnO thin films on Re and W 总被引:1,自引:0,他引:1
Dattatray J. Late Pankaj Misra B. N. Singh Lalit M. Kukreja Dilip S. Joag Mahendra A. More 《Applied Physics A: Materials Science & Processing》2009,95(2):613-620
Nanocrystalline ZnO thin films have been deposited on rhenium and tungsten pointed and flat substrates by pulsed laser deposition
method. An emission current of 1 nA with an onset voltage of 120 V was observed repeatedly and maximum current density ∼1.3 A/cm2 and 9.3 mA/cm2 has been drawn from ZnO/Re and ZnO/W pointed emitters at an applied voltage of 12.8 and 14 kV, respectively. In case of planar
emitters (ZnO deposited on flat substrates), the onset field required to draw 1 nA emission current is observed to be 0.87
and 1.2 V/μm for ZnO/Re and ZnO/W planar emitters, respectively. The Fowler–Nordheim plots of both the emitters show nonlinear
behaviour, typical for a semiconducting field emitter. The field enhancement factor β is estimated to be ∼2.15×105 cm−1 and 2.16×105 cm−1 for pointed and 3.2×104 and 1.74×104 for planar ZnO/Re and ZnO/W emitters, respectively. The high value of β factor suggests that the emission is from the nanometric features of the emitter surface. The emission current–time plots
exhibit good stability of emission current over a period of more than three hours. The post field emission surface morphology
studies show no significant deterioration of the emitter surface indicating that the ZnO thin film has a very strong adherence
to both the substrates and exhibits a remarkable structural stability against high-field-induced mechanical stresses and ion
bombardment. The results reveal that PLD offers unprecedented advantages in fabricating the ZnO field emitters for practical
applications in field-emission-based electron sources. 相似文献
10.
Chien-Chon Chen Jin-Shyong Lin Eric Wei-Guang Diau Tzeng-Feng Liu 《Applied Physics A: Materials Science & Processing》2008,92(3):615-620
Self-cleaning of a surface of nanotube arrays of anodic titanium oxide (ATO) is demonstrated. The ATO was prepared in fluoride
ion containing sulfate electrolytes with a structure of 0.4 μm length, 100 nm pores diameter, 120 nm interpore distance, 25 nm
pore wall thickness, a 8×109 pores cm−2 pore density, and 68.2% porosity. Prepared as thin films either directly from a Ti foil or on a glass substrate, these arrays
have the property that water drops spread quickly over the surface of the films without irradiation. In contrast, a flat anatase
TiO2 film requires irradiation with UV light for several minutes before the contact angle decreases to zero. The observed self-cleaning
behavior of the ATO thin films is due to the capillary effect of the nanochannel structure and the superhydrophilic property
of the anatase TiO2 surface inside the tube. 相似文献
11.
R. Guo J. Nishimura M. Matsumoto M. Higashihata D. Nakamura T. Okada 《Applied physics. B, Lasers and optics》2009,94(1):33-38
Vertically aligned ZnO nanowires were successfully grown on the sapphire substrate by nanoparticle-assisted pulsed laser deposition
(NAPLD), which were employed in fabricating the ZnO nanowire-based heterojunction structures. p-GaN/n-ZnO heterojunction light-emitting diodes (LEDs) with embedded ZnO nanowires were obtained by fabricating p-GaN:Mg film/ZnO nanowire/n-ZnO film structures. The current–voltage measurements showed a typical diode characteristic with a threshold voltage of about
2.5 V. Electroluminescence (EL) emission having the wavelength of about 380 nm was observed under forward bias in the heterojunction
diodes and was intensified by increasing the applied voltage up to 30 V. 相似文献
12.
Nanosecond pulsed laser ablation of silicon in liquids 总被引:2,自引:0,他引:2
R. Karimzadeh J. Zamir Anvari N. Mansour 《Applied Physics A: Materials Science & Processing》2009,94(4):949-955
Laser fluence and laser shot number are important parameters for pulse laser based micromachining of silicon in liquids. This
paper presents laser-induced ablation of silicon in liquids of the dimethyl sulfoxide (DMSO) and the water at different applied
laser fluence levels and laser shot numbers. The experimental results are conducted using 15 ns pulsed laser irradiation at
532 nm. The silicon surface morphology of the irradiated spots has an appearance as one can see in porous formation. The surface
morphology exhibits a large number of cavities which indicates as bubble nucleation sites. The observed surface morphology
shows that the explosive melt expulsion could be a dominant process for the laser ablation of silicon in liquids using nanosecond
pulsed laser irradiation at 532 nm. Silicon surface’s ablated diameter growth was measured at different applied laser fluences
and shot numbers in both liquid interfaces. A theoretical analysis suggested investigating silicon surface etching in liquid
by intense multiple nanosecond laser pulses. It has been assumed that the nanosecond pulsed laser-induced silicon surface
modification is due to the process of explosive melt expulsion under the action of the confined plasma-induced pressure or
shock wave trapped between the silicon target and the overlying liquid. This analysis allows us to determine the effective
lateral interaction zone of ablated solid target related to nanosecond pulsed laser illumination. The theoretical analysis
is found in excellent agreement with the experimental measurements of silicon ablated diameter growth in the DMSO and the
water interfaces. Multiple-shot laser ablation threshold of silicon is determined. Pulsed energy accumulation model is used
to obtain the single-shot ablation threshold of silicon. The smaller ablation threshold value is found in the DMSO, and the
incubation effect is also found to be absent. 相似文献
13.
Yanming Sun Yunqi Liu Ying Wang Chongan Di Weiping Wu Gui Yu 《Applied Physics A: Materials Science & Processing》2009,95(3):777-780
Organic thin-film transistors based on polycrystalline copper phthalocyanine (CuPc) were fabricated by using poly(vinyl alcohol)
as gate dielectric. After treatment of the gate dielectric using an octadecyltrichlorosilane self-assembled monolayer, a mobility
of up to 0.11 cm2/V s was achieved, which is comparable to that of single-crystal CuPc devices (0.1–1 cm2/V s). The surface morphology was analyzed and the possible reasons for the enhanced mobility are discussed. 相似文献
14.
Wang Bin Zhao Yue Min Jiahua Sang Wenbin 《Applied Physics A: Materials Science & Processing》2009,94(4):715-718
P-type ZnO was realized by dual-doping with nitrogen and silver via electrostatic-enhanced ultrasonic spray pyrolysis. The
structural, electrical, and optical properties were explored by XRD, Hall-effect, and optical transmission spectra. The resistivity
of ZnO:(N,Ag) film was found to be 56 Ω cm−1 with the high mobility of 76.1 cm2/V s. Compared with ZnO:Ag film, ZnO:(N,Ag) film exhibited a higher and more stable optical transmittance. 相似文献
15.
Self-assembled monolayers represent well-defined systems that is a good model surface to study the effect of primary ion beams used in secondary ion mass spectrometry. The effect of polyatomic primary beams on both aliphatic and aromatic self-assembled monolayers has been studied. In particular, we analysed the variation of the relative secondary ion yield of both substrate metal-cluster (Aun−) in comparison with the molecular ions (M−) and clusters (MxAuy−) by using Bi+, Bi3+, Bi5+ beams. Moreover, the differences in the secondary ion generation efficiency are discussed. The main effect of the cluster beams is related to an increased formation of low-mass fragments and to the enhancement of the substrate related gold-clusters. The results show that, at variance of many other cases, the static SIMS of self-assembled monolayers does not benefit of the use of polyatomic primary ions. 相似文献
16.
d-limonene in water nanoemulsion was prepared by ultrasonic emulsification using mixed surfactants of sorbitane trioleate and polyoxyethylene (20) oleyl ether. Investigation using response surface methodology revealed that 10% d-limonene nanoemulsions formed at S0 ratio (d-limonene concentration to mixed surfactant concentration) 0.6-0.7 and applied power 18 W for 120 s had droplet size below 100 nm. The zeta potential of the nanoemulsion was approximately −20 mV at original pH 6.4, closed to zero around pH 4.0, and around −30 mV at pH 12.0. The main destabilization mechanism of the systems is Ostwald ripening. The ripening rate at 25 °C (0.39 m3 s−1 × 1029) was lower than that at 4 °C (1.44 m3 s−1 × 1029), which was in agreement with the Lifshitz-Slezov-Wagner (LSW) theory. Despite of Ostwald ripening, the droplet size of d-limonene nanoemulsion remained stable after 8 weeks of storage. 相似文献
17.
The binding energy of excitonium negative ion for the ground1,3S-states in bulk semiconductors GaAs and ZnO in the hyperspherical coordinate method was found. Angular and radial correlations
between electrons in gerade and ungerade states were taken into account by channel functions, that are the eigenfunctions
of Hamiltonian on the surface of the sphere in the three-dimensional configuration space. Energy values were calculated using
the adiabatic and Born-Oppenheimer approximations. The obtained energy values are in agreement with those obtained using variational
method. 相似文献
18.
We have developed a novel method to modifying the surface of ZnO nanorods (ZnO NRs) using p-hexoxyterphenylol (HTph-OH) as liquid crystal ligands. The structure and morphology of the modified ZnO NRs were characterized using Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD) and atomic force microscopy (AFM). AFM measurement showed that the dispersion of ZnO NRs could be dramatically improved by the surface modification of HTph-OH and further annealing treatment at its liquid crystal state temperature (150 °C). The remarkable decrease of the annealed composite film roughness is because the HTph-OH chains self-organize into more ordered structure induced by mesogens after annealing treatment, which may push the ZnO NRs to form oriented nano-dispersing structure. The optical properties of the modified ZnO NRs were investigated by UV-vis absorption spectroscopy and photoluminescence spectroscopy (PL). Markedly enhanced band-edge ultraviolet photoluminescence and significantly reduced defect-related emission were observed. We attribute this observation to the nearly perfect surface passivation of the ZnO NRs by the HTph-OH molecules. Meanwhile, UV emission of modified ZnO NRs could be further enhanced by increasing the concentration of HTph-OH and annealing treatment at its liquid crystal state temperature. 相似文献
19.
H. Kim A. Cepler C. Cetina D. Knies M. S. Osofsky R. C. Y. Auyeung A. Piqué 《Applied Physics A: Materials Science & Processing》2008,93(3):593-598
Present p-type ZnO films tend to exhibit high resistivity and low carrier concentration, and they revert to their natural n-type state
within days after deposition. One approach to grow higher quality p-type ZnO is by codoping the ZnO during growth. This article describes recent results from the growth and characterization
of Zr–N codoped p-type ZnO thin films by pulsed laser deposition (PLD) on (0001) sapphire substrates. For this work, both N-doped and Zr–N
codoped p-type ZnO films were grown for comparison purposes at substrate temperatures ranging between 400 to 700 °C and N2O background pressures between 10−5 to 10−2 Torr. The carrier type and conduction were found to be very sensitive to substrate temperature and N2O deposition pressure. P-type conduction was observed for films grown at pressures between 10−3 to 10−2 Torr. The Zr–N codoped ZnO films grown at 550 °C in 1×10−3 Torr of N2O show p-type conduction behavior with a very low resistivity of 0.89 Ω-cm, a carrier concentration of 5.0×1018 cm−3, and a Hall mobility of 1.4 cm2 V−1 s−1. The structure, morphology and optical properties were also evaluated for both N-doped and Zr–N codoped ZnO films. 相似文献
20.
L. S. Azhgirey M. A. Ignatenko N. P. Yudin 《Zeitschrift für Physik A Hadrons and Nuclei》1992,343(1):35-38
The momentum spectra of protons, produced at 0° as a result of fragmentation of relativistic deuterons on nuclei, are analyzed. Possible causes of the existing discrepancy of the data on the 0° proton spectrum from the1
H(d,p)X reaction at 9.1 GeV/c with results of the impulse approximation calculations are considered. It is shown that taking into account the finite angular resolution of the experimental setup and the corresponding renormalization of the experimental data, on the one hand, and also the inclusion of the additional (to stripping) contribution of protons from the scattering of deuteron nucleons by target protons, on the other, make it possible to match these data with the results of calculations within the framework of the relativistic impulse approximation using the deuteron wave function for the Paris potential. 相似文献