共查询到20条相似文献,搜索用时 31 毫秒
1.
Jacob G. Reynolds 《Silicon Chemistry》2007,3(5):267-269
The Partial Charge Model was developed to predict the hydroxylation, polymerization, and precipitation of ions. The purpose
of this study is to evaluate the Partial Charge Model for describing the polymerization of silica in aqueous solutions. The
Partial Charge Model predicts the stability of ions and complexes based on the assumption that the stable species will have
the same electronegativity as the mean electronegativity of the solution. The silica system was chosen for model validation
because of the rare availability of self-consistent thermodynamic data on many dissolved but polymerized silicate anions,
including both linear and cyclical species. The electronegativity of each species was calculated using the Partial Charge
Model and the results were plotted against the stability constants for the ions. The silicate anions segregated into groups
on the plot based on the number of charges per silicon atom in the polymer. Plots of the log of the stability constant versus
the change in electronegativity produced a linear relationship for the silica polymers containing one negative charge per
silicon atom, which resulted in an r
2 of 0.9978. Thus, the Partial Charge Model successfully describes the thermodynamics of silica polymerization in aqueous solution
for species that are sufficiently alike, but was not accurate for all silica species. 相似文献
2.
Kang Yeol Lee Minjung Kim Young Wook Lee Jae-Joon Lee Sang Woo Han 《Chemical physics letters》2007,440(4-6):249-252
A new solution-phase method for synthesis of metal nanoparticles–carbon nanotubes (CNTs) assemblies is described. By injection of CNTs solution into the diethyl ether/aqueous solution of metal salt biphasic mixture, metal (Ag, Au, Pd, and Pt) nanoparticles–decorated CNTs composite materials can be prepared. Metal nanoparticles have spontaneously and selectively formed on the sidewalls of CNTs through redox reaction between CNTs and metal ions. This phenomenon has been probed by transmission electron microscopy, scanning electron microscopy, energy dispersive X-ray analysis, and Raman spectroscopy. 相似文献
3.
Ligand-protonation constants and complexation kinetics of differently protonated forms of 10-methyl-1,4,8,12-tetraazacyclopentadecan-10-amine, 1,4,8,12-tetraazacyclopentadecane, and 1,4,8,12-tetraazacyclopentadecan-10-carboxylic acid with Cu(II) and Ni(II) in aqueous solution have been determined. These results are combined with a wide range of published complexation rate constants of partially protonated macrocyclic ligands with the same metal ions. Insight is gained into the electrostatic effects and the outer-sphere interaction of partially protonated ligands with aquated metal ions. An outer-sphere chelate effect has been ascertained. 相似文献
4.
Hu M Ishizuka Y Igarashi Y Oki T Nakanishi H 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2000,56(6):1233-1243
This study focused on further analysis of the aggregation behavior of pradimicin derivatives and their interaction with cations in aqueous solution. BMY was compared with two other pradimicin antibiotics (T2 and FB) with the same aglycone moiety but consisting of different substitute groups. The surface tension measurement showed a clear critical micelle concentration at 1-2 mM of the BMY aqueous solution. The role of Zn2+ in replacing the Ca2+ was examined using 1H nuclear magnetic resonance (NMR) method. From changes in the NMR spectrum and precipitability, it was concluded that zinc ion has lower affinity and higher precipitating ability to BMY than the divalent cations of alkaline earth metal. The aggregation behavior of T2 and FB in aqueous solution was also studied using NMR method. The results suggest that the supramolecular behavior of T2 is similar to BMY whether or not Ca2+ ions are present in solution and that there are two binding sites for calcium ions in a T2 molecule. Unlike BMY and T2, the NMR spectrum of FB does not show distinct change upon Ca2+ addition. The interaction of pradimicin antibiotics with divalent metal ions was thought to be related to ionic electronegativity and to the amphoteric property of the antibiotics. 相似文献
5.
Jeon B Sankaranarayanan SK van Duin AC Ramanathan S 《The Journal of chemical physics》2011,134(23):234706
Corrosion is a fundamental problem in electrochemistry and represents a mode of failure of technologically important materials. Understanding the basic mechanism of aqueous corrosion of metals such as Cu in presence of halide ions is hence essential. Using molecular dynamics simulations incorporating reactive force-field (ReaxFF), the interaction of copper substrates and chlorine under aqueous conditions has been investigated. These simulations incorporate effects of proton transfer in the aqueous media and are suitable for modeling the bond formation and bond breakage phenomenon that is associated with complex aqueous corrosion phenomena. Systematic investigation of the corrosion process has been carried out by simulating different chlorine concentration and solution states. The structural and morphological differences associated with metal dissolution in the presence of chloride ions are evaluated using dynamical correlation functions. The simulated atomic trajectories are used to analyze the charged states, molecular structure and ion density distribution which are utilized to understand the atomic scale mechanism of corrosion of copper substrates under aqueous conditions. Increased concentration of chlorine and higher ambient temperature were found to expedite the corrosion of copper. In order to study the effect of solution states on the corrosion resistance of Cu, partial fractions of proton or hydroxide in water were configured, and higher corrosion rate at partial fraction hydroxide environment was observed. When the Cl(-) concentration is low, oxygen or hydroxide ion adsorption onto Cu surface has been confirmed in partial fraction hydroxide environment. Our study provides new atomic scale insights into the early stages of aqueous corrosion of metals such as copper. 相似文献
6.
Prof. Kasper P. Kepp 《Chemphyschem》2020,21(5):360-369
Humans have appreciated the “noble” metals for millennia, yet modern chemistry still struggles with different definitions. Herein, metal nobleness is analyzed using thermochemical cycles including the different bulk, gas, and solution states implied by these definitions. The analysis suggests that metal nobleness mainly reflects inability to fulfil the electron demands of electronegative oxygen. Accordingly, gold is the most noble metal in existence, not because of d-band properties of the solid state, but because gold's electronegativity is closest to that of oxygen, producing weaker polar covalent bonding. The high electronegativity arises from the effective nuclear charge due to diffuse d-states, enforced by relativistic effects. This explanation accounts for the activity series, corrosion tendency, and trends in oxygen chemisorption, which other models do not. While gold is the most noble metal, the ranking of Ag, Pt, and Pd depends on the thermochemistry as discussed in detail. 相似文献
7.
The electronegativities of 82 elements in different valence states and with the most common coordination numbers have been quantitatively calculated on the basis of an effective ionic potential defined by the ionization energy and ionic radius. It is found that for a given cation, the electronegativity increases with increasing oxidation state and decreases with increasing coordination number. For the transition-metal cations, the electronegativity of the low-spin state is higher than that of the high-spin state. The ligand field stabilization, the first filling of p orbitals, the transition-metal contraction, and especially the lanthanide contraction are well-reflected by the relative values of our proposed electronegativity. This new scale is useful for us to estimate some quantities (e.g., the Lewis acid strength for the main group elements and the hydration free energy for the first transition series) and predict the structure and property of materials. 相似文献
8.
Carbon nanotube (CNT) and metal nanoparticle (NP) assemblies are conjugated nanosystems with potential applications in catalysis, sensing, and light harvesting. Due to poor solubility of CNTs, previously reported synthetic approaches are limited to large multi-walled CNTs, bundles of single-walled CNTs (SWNTs), or surface-bound CNTs. Here we report a solution-phase synthesis of SWNT-metal NP assemblies that is generally applicable to common metal elements. Key to the process is the poly(styrene-alt-maleic acid) surfactant which disperses SWNTs in aqueous solutions and acts as templates for the binding of metal ions and metal NPs. 相似文献
9.
Robinson EW Leib RD Williams ER 《Journal of the American Society for Mass Spectrometry》2006,17(10):1469-1479
Effects of protein conformation on electron capture dissociation (ECD) were investigated using high-field asymmetric waveform ion mobility spectrometry (FAIMS) and Fourier-transform ion cyclotron resonance mass spectrometry. Under the conditions of these experiments, the electron capture efficiency of ubiquitin 6+ formed from three different solution compositions differs significantly, ranging from 51 +/- 7% for ions formed from an acidified water/methanol solution to 88 +/- 2% for ions formed from a buffered aqueous solution. This result clearly indicates that these protein ions retain a memory of their solution-phase structure and that conformational differences can be probed in an ECD experiment. Multiple conformers for the 7+ and 8+ charge states of ubiquitin were separated using FAIMS. ECD spectra of conformer selected ions of the same charge states differ both in electron capture efficiency and in the fragment ion intensities. Conformers of a given charge state that have smaller collisional cross sections can have either a larger or smaller electron capture efficiency. A greater electron capture efficiency was observed for ubiquitin 6+ that has the same collisional cross section as one ubiquitin 7+ conformer, despite the lower charge state. These results indicate that the shape of the molecule can have a greater effect on electron capture efficiency than either collisional cross section or charge state alone. The cleavage locations of different conformers of a given charge state were the same indicating that the presence of different conformers in the gas phase is not due to difference in where charges are located, but rather reflect conformational differences most likely originating from solution. Small neutral losses observed from the singly- and doubly-reduced ubiquitin 6+ do not show a temperature dependence to their formation, consistent with these ions being formed by nonergodic processes. 相似文献
10.
Density functional theory calculation of gas-phase Delta G of replacement of a water molecule by NH(3) on [M(H(2)O)(6)](n+)(g) for 19 different metal ions correlates well with Delta G of formation of mono NH(3) complexes of these ions in water, suggesting this approach will permit prediction of formation constants in aqueous solution, and produce insights into theories of metal complex formation reactions. 相似文献
11.
查尔酮修饰β环糊精与过渡金属离子间相互作用 总被引:2,自引:0,他引:2
利用稳态荧光光谱和时间分辨荧光技术研究了新型环表衍生物(DMAC-CD)与过渡金属离子之间的相互作用。结果表明,由于该环糊精衍生物在水溶液是"自包结"构象存在,使其所连的二甲氢基查尔酮的羰基及氮杂烷氧链与过渡金属离子发生强烈配位作用,从而观察到主体分子DMAC-CD与金属离子间的诱导电子转移猝灭极大地偏离了Stern--volmer直线关系,符合典型的静态猝灭机制。测定了该主体分子与过渡金属离子间形成配合物的 稳定常数和荧光猝灭速率常。结果显示该查尔酮修饰的环糊精对过渡金属离子,特别是Cu^2+的很高的敏感性和选择性。 相似文献
12.
13.
Hiroto Watanabe Tohru Saitoh Tamio Kamidate Kensaku Haraguchi 《Mikrochimica acta》1992,106(1-2):83-90
A dilute micellar solution of poly(oxyethylene) 4-nonylphenyl ether with oxyethylene units 7.5 (PONPE-7.5) was separated into two phases (aqueous and surfactant phases) at room temperature. The partition constants of several chelating reagents and their metal chelates between the two phases were determined at 293 K and ionic strength 0.1 (NaClO4). The partition constants of the neutral metal chelates depend on the kind of metal ions and were considerably smaller than those expected from the regular solution theory. These facts suggested that the chelates were incorporated into a hydrocarbon environment in the surfactant phase, whereas the chelating reagents were distributed in the poly(oxyethylene) part of PONPE-7.5. A brief review was also presented on the analytical applications to the extraction of metal ions and organic compounds. 相似文献
14.
Hydrated trivalent rare earth metal ions containing yttrium and all naturally abundant lanthanide metals are formed using electrospray ionization, and the structures and reactivities of these ions containing 17-21 water molecules are probed using blackbody infrared radiative dissociation (BIRD) and infrared action spectroscopy. With the low-energy activation conditions of BIRD, there is an abrupt transition in the dissociation pathway from the exclusive loss of a single neutral water molecule to the exclusive loss of a small protonated water cluster via a charge-separation process. This transition occurs over a narrow range of cluster sizes that differs by only a few water molecules for each metal ion. The effective turnover size at which these two dissociation rates become equal depends on metal ion identity and is poorly correlated with the third ionization energies of the isolated metals but is well correlated with the hydrolysis constants of the trivalent metal ions in bulk aqueous solution. Infrared action spectra of these ions at cluster sizes near the turnover size are largely independent of the specific identity of the trivalent metal ion, suggesting that any differences in the structures of the ions present in our experiment are subtle. 相似文献
15.
《Arabian Journal of Chemistry》2020,13(5):5229-5240
As one of the most toxic heavy metal ions, lead pollution has become an urgent problem. Here, a cubic crystal nanoparticle (Prussian blue analogue, PBA), referred to as potassium manganese ferrocyanide (KMFC) was synthesized and used as a highly-effective sorbent for removing Pb(II) from aqueous solution. KMFC is a mesoporous material that has excellent ion exchange properties, which was confirmed by a series of characterizations. This paper investigated the adsorptive attributes of KMFC for lead ions in aqueous solution. The influences of temperature, contact time and pH on adsorption were studied in batch experiments. The KMFC possessed a robust adsorption capacity for resident lead ions in aqueous solution, which attained 1075.27 mg g−1 at room temperature (25 °C), based on the Langmuir model, which was far higher than any previously reported values. The adsorption process was well fitted to a pseudo-second-order kinetic model, as well as Langmuir and Temkin isotherm models, and was endothermic and spontaneous on the basis of thermodynamic analysis. The adsorption of Pb(II) on the surface of KMFC started with electrostatic attraction, due to the electronegativity of KMFC. Further, ion exchange was the dominant mechanism in this adsorption process, which was confirmed by FTIR, XPS, and other supplementary experiments. The good chemisorption (K+ exchange) properties of KMFC suggested that it likely has excellent prospects in applications for heavy metal ions adsorption. This study not only provided a new perspective for the design and development of heavy metal sorbents but provided a deep insight into the mechanism of adsorption of heavy metal ions by PBA. 相似文献
16.
亲和毛细管电泳间接紫外检测法测定金属络合物的亲和常数 总被引:6,自引:2,他引:6
采用亲和毛细管电泳间接紫外检测方法 ,根据“峰漂移”模型 ,通过迁移时间的测定 ,可以获得在水体系中有极低亲和常数的金属络合物的亲和常数。将该方法分别应用于镁离子 柠檬酸体系和锰离子 酒石酸体系 ,在 pH为 5 .0 1,运行电压为 2 0kV ,缓冲溶液组成为咪唑和醋酸的条件下 ,测定了缓冲溶液中加入不同浓度配体后金属离子迁移时间的变化 ,经过数据处理后得出它们的亲和常数对数值分别是 3.2 7和 2 .2 8,与文献值较为一致。该方法适用于结合比为 1∶1的金属络合物的亲和常数的测定。 相似文献
17.
Composite electrodes made of graphite, paraffin and metal hexacyanoferrates exhibit a voltammetric response of the hexacyanoferrate ions, the potential of which depends linearly on the logarithm of concentration of alkali and alkaline-earth metal ions. This behaviour has been observed on account of the fact that the electrochemical reaction is accompanied by an exchange of these ions between the solution and the zeolitic lattice of the hexacyanoferrates for charge compensation. The voltammetric determination of the formal potential of these electrodes in a solution allows the quantitative analysis of the ions which are exchanged between the metal hexacyanoferrates and the aqueous solutions. Iron(III), copper(II), silver(I), nickel(II) and cadmium(II) hexacyanoferrates have been studied for the determination of H(+), Li(+), Na(+), K(+), Rb(+), Cs(+), NH(+)(4), Mg(2+), Ca(2+) and Ba(2+). In some cases, the selectivity constants are as low as 3.10(-4), or even so small that their exact value is inaccessible. Electrodes made of iron (III), copper (II), silver (I), nickel (II) and cadmium (II) hexacyanoferrates are most suitable for the determination of potassium ions. Electrodes with nickel (II) and cadmium (II) hexacyanoferrates are also suitable for the determination of caesium ions. The working range of the electrodes also depends on the conductivity of the solutions and can range from 10(-5) to 1 mol l(-1). Typical standard deviations of the potential measurements are 3 mV. 相似文献
18.
镧系金属离子Ln3+定量构效关系的神经网络研究 总被引:8,自引:0,他引:8
以Ln3+离子的半径、电负性、4f电子排布周期因子q(本文自定义)以及基态L值等为参数,使用函数连接型神经网络(FLN)对Ln3+离子的EDTA等络合常数lgK、水化能ΔH、水解常数pK1及氢氧化物溶解度pKm分别进行非线性关联和预测,获得了非常好的结果.与对应的线性模型比较表明,神经网络关联效果是较理想的. 相似文献
19.
Sanyal A Rautaray D Bansal V Ahmad A Sastry M 《Langmuir : the ACS journal of surfaces and colloids》2005,21(16):7220-7224
We show here that reaction of the fungus, Fusarium oxysporum, with the aqueous heavy-metal ions Pb2+ and Cd2+ results in the one-step formation of the corresponding metal carbonates. The metal carbonates are formed by reaction of the heavy-metal ions with CO2 produced by the fungus during metabolism and thus provide a completely biological method for production of crystals of metal carbonates. The PbCO3 and CdCO3 crystals thus produced have interesting morphologies that are shown to arise because of interaction of the growing crystals with specific proteins secreted by the fungus during reaction. An additional advantage of this approach is that the reaction leads to detoxification of the aqueous solution and could have immense potential for bioremediation of heavy metals. Under conditions of this study, the metal ions are not toxic to the fungus, which readily grows after exposure to the metal ions. 相似文献
20.
Iuchi S 《The Journal of chemical physics》2012,136(6):064519
A simple model electronic Hamiltonian to describe the potential energy surfaces of several low-lying d-d states of the [Fe(bpy)(3)](2+) complex is developed for use in molecular dynamics (MD) simulation studies. On the basis of a method proposed previously for first-row transition metal ions in aqueous solution, the model Hamiltonian is constructed using density functional theory calculations for the lowest singlet and quintet states. MD simulations are then carried out for the two spin states in aqueous solution in order to examine the performance of the model Hamiltonian. The simulation results indicate that the present model electronic Hamiltonian reasonably describes the potential energy surfaces of the two spin states of the aqueous [Fe(bpy)(3)](2+) system, while retaining sufficient simplicity for application in simulation studies on excited state dynamics. 相似文献