Theory of percolation in fluids of long molecules

We use the reference interaction site model (RISM) integral equation theory to study the percolation behavior of fluids composed of long molecules. We examine the roles of hard core size and of length-to-width ratio on the percolation threshold. The critical density _c is a nonmonotonic function of these parameters exhibiting competition of different effects. Comparisons with Monte Carlo calculations of others are reasonably good. For critical exponents, the theory yields =2=2 for molecules of any noninfinite lengthL. WhenL is very large, the theory yields _cL ^–2. These predictions compare favorably with observations of the conductivity for random assemblies of conductive fibers. The threshold region where asymptotic scaling holds requires the correlation length (/ _c ) ^–v to be much larger thanL. Evidently, the range of densities in this region diminishes asL increases, requiring that density deviations from _c be no larger thanL ^–2. Otherwise, crossover behavior will be observed.     

Growth of correlation in the Hopfield model

Introducing a finite correlation ₀ between any two learned patterns (others remaining uncorrelated), we observe in a numerical simulation that the Hopfield model stores these two patterns with correlation _f such that _f0 for any loading capacity. The patterns are memorized perfectly (with _f= ₀) up to -0.05 for finite correlations ₀ not exceeding a value _c(), where _c() decreases continuously to zero at -0.05.     

On the relative entropy

ForA any subset of () (the bounded operators on a Hilbert space) containing the unit, and and restrictions of states on () toA, ent _A (|)—the entropy of relative to given the information inA—is defined and given an axiomatic characterisation. It is compared with ent _A ^A (|)—the relative entropy introduced by Umegaki and generalised by various authors—which is defined only forA an algebra. It is proved that ent and ent ^S agree on pairs of normal states on an injective von Neumann algebra. It is also proved that ent always has all the most important properties known for ent ^S : monotonicity, concavity,w* upper semicontinuity, etc.     

A method for calculating the space-time metric inside a collapsing or expanding sphere

A class of solutions of Einstein's field equations is found in which the quantities can be expressed as power series in r. Using null coordinates it is shown that the spacetime metric inside a spherically symmetric distribution of matter can be calculated to any degree of accuracy by evaluating the terms in the power series step by step, provided we know the central density, _O,as a function of time, and the equation of state in the form p=f(), f() being a function analytic at _O.The method is found to be applicable to all cases met with in nature.Presented at the International Conference on Gravitation and Relativity, Copenhagen, July 1971.     

Determination of the electron density at the Cu nucleus in Cu-Au alloys

The half-life of⁶⁴Cu in Cu–Au solid solutions has been measured as a function of the Cu concentration. Relative changes of electron densities (0)/(0) at the Cu nucleus are deduced. The observed nonlinear concentration dependence of (0)/(0) is discussed in terms of volume and charge transfer effects.     

Non-classical conductivity in a bulk semiconductor up to 35 K

We observed non-classical contributions to the conductivity in three-dimensional samples at temperatures up to 35 K. The experiments were carried out inn-type Hg_0.8Cd_0.2Te samples having dimensions as large as 8 ×28×25 m³. The two resistivity contributions, i.e. the normal metallic behaviour ₀ and a part provided by electron interference, are separated using a method disturbing the additional contribution by heating the electrons in electrical fields. The observed temperature and electric field dependence are compared with existing theories.     

Spatial structure in diffusion-limited two-particle reactions

We analyze the limiting behavior of the densities _A(t) and _B(t), and the random spatial structure(r) = ( _A(t)., _B(t)), for the diffusion-controlled chemical reaction A+Binert. For equal initial densities _B(0) = _b(0) there is a change in behavior fromd 4, where _A(t) = _B(t) C/t^d/4, tod 4, where _A(t) = _b(t) C/t ast ; the termC depends on the initial densities and changes withd. There is a corresponding change in the spatial structure. Ind < 4, the particle types separate with only one type present locally, and , after suitable rescaling, tends to a random Gaussian process. Ind >4, both particle types are, after large times, present locally in concentrations not depending on type or location. Ind=4, both particle types are present locally, but with random concentrations, and the process tends to a limit.     

High-temperature resistivity of Ti1-X Al X alloys

We have measured the high-temperature resistivities of dilute Ti_1-x Al _x alloys withx0.135 up to 1100 K (2.6 _D , where _D is the Debye temperature). We observe that possesses a strong downward deviation from a linear temperature-dependence at high temperatures (several hundred degrees Kelvin). Eventually, saturates to a constant. This non-Bloch-Grüneisen-like behavior is compared with the predictions of current theories.     

Anisotropy of the low temperature resistivity of hexagonal single crystalline spin glass systems

The impurity contribution to the resistivity in zero field (T) of dilute hexagonal single crystals of ZnMn, CdMn and MgMn has been studied in the mK range on samples cut parallel () and perpendicular () to thec-axis, using a SQUID technique for the measurements. Typical spin glass behavior is found in (T) as well as (T) for all alloys, with Kondo like logarithmic increases at higher temperatures and maxima atT _m at lower temperatures, indicating the influence of impurity interactions. The differences in the corresponding isotropic resistivity _poly(T) between the three systems can qualitatively be understood within the framework of a theoretical model by Larsen, describing (T) as a function of universal quantitiesT/T _K and _RKKY/T _K , where _RKKY is the RKKY-interaction strength andT _K the Kondo temperature. With respect to the two lattice directions studied, the behavior of (T and (T is anisotropic in the Kondo regime as well as in the range where ordering becomes important. While the anisotropy in the Kondo slope can be understood by an anisotropic unitarity limit, the understanding of the anisotropy in region where impurity interactions are important remains problematic.Dedicated to Prof. Dr. S. Methfessel on the occasion of his 60th birthday     

Electrogravitational induction and rotation

The Faradayan hypothesis of inductive coupling of the electromagnetic and gravitational fields is briefly discussed. An experiment designed to test the hypothesis wherein samples are spun to see if any electrogravitational charge is induced is described. Results of the experiment are reported. They imply the induction of a charge density * for spinning samples that behaves as *=_ma, where _m is the mass density of an element of matter experiencing an acceleration a, and is the coupling coefficient for the hypothetical electrogravitational induction effect. In this experiment, is found to have the value(9.6±3.3)×10 ^–13 statcoulombs/dyne. Tests that seem to rule out explanations of the observed charges in terms of conventional charging mechanisms are considered.     

On Strong Superadditivity of the Entanglement of Formation

We employ a basic formalism from convex analysis to show a simple relation between the entanglement of formation E_F and the conjugate function E^* of the entanglement function E()=S(Tr_A). We then consider the conjectured strong superadditivity of the entanglement of formation E_F()E_F(_I)+E_F(_II), where _I and _II are the reductions of to the different Hilbert space copies, and prove that it is equivalent with subadditivity of E^*. Furthermore, we show that strong superadditivity would follow from multiplicativity of the maximal channel output purity for quantum filtering operations, when purity is measured by Schatten p-norms for p tending to 1.     

Self-diffusion in simple models: Systems with long-range jumps

We review some exact results for the motion of a tagged particle in simple models. Then, we study the density dependence of the self-diffusion coefficientD _N() in lattice systems with simple symmetric exclusion in which the particles can jump, with equal rates, to a set ofN neighboring sites. We obtain positive upper and lower bounds onF _N()=N{(1–)–[D_N()/D_N(0)]}/[(1–)]x for [0, 1]. Computer simulations for the square, triangular, and one-dimensional lattices suggest thatF _N becomes effectively independent ofN forN20.     

The role of the distribution of nucleons in finite nuclei

The total energy of many-nucleon system is expressed as a functional E[ _p(r), _n(r)] of the proton and neutron densities _p(r) and _n(r), respectively. The distribution(r) of nucleons in the nucleus, which is essential to determine the energy functional, is chosen. The energy density formalism is applied to finite nuclei, and then the binding energies per nucleon together with the mean square radii, for some medium and heavy nuclei, are obtained. Finally the achieved results are compared with the corresponding experimental values.     

The crystal structure of kettnerite,CaBi[OF¦CO3]

Macroscopic, microscopic, goniometric, qualitative spectrographic and quantitative chemical data of kettnerite [2] with some new observations are given. The unit cell dimensions determined from the powder and rotating crystal photographs area ₀=b ₀=5.36±0.02 Å,c ₀=13.59±0.03 Å. There are four molecules in the unit cell. The crystal structure of kettnerite was studied from the ordinary and generalized projections of the Patterson function along the [010] axis. Direct evidence of tetragonal layers (Ca. 2 F, Ca) and (Bi, 2 O, Bi) parallel to the basal face was found. The spatial arrangement of these layers corresponds to the symmetry of the space groupP 4/nmm. These layers alternate in the [001] direction being interleaved by single CO₃ layers. Both the biaxial character of the mineral and the uncertainty concerning the rotation of the CO₃ groups indicate a lower, most probably an orthorhombic symmetry. The highest possible symetry is that ofCmma. The structure is related to that of the typeX ₁ found by Sillén et al. for several bismuth oxyhalides and especially to that of bismutite.

---

CaBi[OF¦ CO₃]

, , , [2] . , :a ₀=b ₀=5,36±0,02 Å, ₀=13,59±0,03 Å;Z=4. [010]. (Ca, 2 F, ) (Bi, 2 O, Bi), (010). 4/. , ₃. ₃ . C. , , ₁, .

---

---

We wish to express gratitude to our colleagues Dr. A. Línek and Ing. C. Novák (Institute of Technical Physics, Czech. Acad. Sci.) for the use of the M1 equipment [11]. We are also very grateful to Mr. Z. iký for carrying out most of the numerical calculations.     

Analysis of the dc-resistivity of YBa2Cu3Ox: Deduction of the intragrain resistivity

The resistivity (100 K) scatters very much for YBa₂Cu₃O_x prepared as single crystals, epitaxial films or bulk samples which consist of grains of 1 to 10 m diameter. An analysis of (T) for granular bulk samples is presented indicating the existence of a low intrinsic resistivity ⁱ (T)= _0L ⁱ + ⁱ T with _0L ⁱ 0 and ⁱ 0.5µcm/K. The large grain boundary resistivity _b between the grains (>1 m) yield a macroscopic percolative conduction path lengtheningL/L ₀>1 with a reduced effective cross sectionC<C ₀ and thus, (T)= _b +(LC ₀/L ₀ C)· ⁱ (T). Evidence is presented for weak links inside single crystals and grains.     

What determinates the chemical changes of the internal conversion coefficients for inner atomic shells?

Calculations of internal conversion coefficients (ICC) of the E1–E4 and M1–M4 transitions for nuclei in ions show that the relative changes _i / _i of the ICC _i for deep inner subshells can differ significantly from the relative changes _i/_i of the electron densities _i at the nucleus. For the K conversion _i/ _i are many times greater than _i/_i. Especially large deviations of _i/ _i are characteristic of transitions of high multipolarity; however, for the M1 transitions they can also be significant. Illustrations of various dependencies of _i/ _iare presented for the conversion in the regionZ-50.     

Self-Dual Solutions for SU(2) and SU(3) Gauge Fields on Euclidean Space

Self-dual solutions for SU(2) gauge fields on Euclidean space that satisfy Yang's ansatz are generalized by considering as a function of for a special case when is a complex analytic function and for SU(3) when _i, i = 1, 2, 3, are complex analytic functions.     

Influence of the Flux Density,the Flux,and the Energy of Electrons on the Change in the Optical Properties of ZnO + K2SiO3 Coatings

The change in the diffusion reflection spectra and the total solar radiation absorption coefficient as by a reflecting heat-regulating coating (HRC) fabricated from ZnO pigment and K₂SiO₃ liquid potash glass in the People's Republic of China is investigated as a function of the flux density , the flux , and the energy E of electrons. The established regularities in the changes of a _s and under irradiation provide additional information on the formation of color centers (CC) in these systems and correlate with the results obtained previously for coatings fabricated in Russia.     

Metastable states in the van der Waals-Maxwell theory

A slight modification of the recent Penrose and Lebowitz treatment of thermodynamic metastable states is presented. For the case of periodic boundary conditions, this modification allows the condition of metastability to be extended to all the metastable states in the van der Waals-Maxwell theory of the liquid-vapor phase transition, that is, for all states satisfyingf ₀()+1/2 ²>f(, 0+) andf₀()+x>0 wheref(, 0+) is the (stable) Helmholtz free energy density of the generalized van der Waals-Maxwell theory andf ₀() is the Helmholtz free energy density of a reference system with no long-range interaction, is a mean field-type term arising from a long-range Kac interaction, is the overall mean particle density, andx is any positive number. For the case of rigid-wall boundary conditions, a more restrictive condition is placed onx.     

On the equivalence of boundary conditions

We show that ifb andb are two boundary conditions (b.c.) for general spin systems on ^d such that the difference in the energies of a spin configuration in ^d is uniformly bounded, |H _,b ()–H _,b()|C < , then any infinite-volume Gibbs states and obtained with these b.c. have the same measure-zero sets. This implies that the decompositions of and into extremal Gibbs states are equivalent (mutually absolutely continuous). In particular, if is extremal,=. Application of this observation yields in an easy way (among other things) (a) the uniqueness of the Gibbs states for one-dimensional systems with forces that are not too long-range; (b) the fact that various b.c. that are natural candidates for producing non-translation-invariant Gibbs states cannot lead to such an extremal Gibbs state in two dimensions.Supported in part by NSF Grant PHY 78–15920 and by the Swiss National Foundation For Scientific Research.