Unification of the kinetic and hydrodynamic approaches in the theory of dense gases and liquids

The paper discusses one of the approaches to the kinetics and hydrodynamics of dense gases and liquids based on modification of Bogolyubov's conditions of correlation weakening for the Liouville equation for the nonequilibrium distribution function. An entropy of a nonequilibrium state that depends on both the kinetic and the hydrodynamic parameters is defined. Generalized transport equations are obtained for the hydrodynamic variables, and these equations are consistent with the kinetic equation for the single-particle distribution function.deceasedV. A. Steklov Mathematics Institute; Moscow Institute of Radio Technology, Electronics, and Automation; Institute of the Physics of Condensed Systems, Ukrainian Academy of Sciences. Translated from Teoreticheskaya i Matematicheskaya Fizika, Vol. 96, No. 3, pp. 325–350, September, 1993.     

Nonequilibrium Statistical Operator Method and Generalized Kinetic Equations

We consider some principal problems of nonequilibrium statistical thermodynamics in the framework of the Zubarev nonequilibrium statistical operator approach. We present a brief comparative analysis of some approaches to describing irreversible processes based on the concept of nonequilibrium Gibbs ensembles and their applicability to describing nonequilibrium processes. We discuss the derivation of generalized kinetic equations for a system in a heat bath. We obtain and analyze a damped Schrödinger-type equation for a dynamical system in a heat bath. We study the dynamical behavior of a particle in a medium taking the dissipation effects into account. We consider the scattering problem for neutrons in a nonequilibrium medium and derive a generalized Van Hove formula. We show that the nonequilibrium statistical operator method is an effective, convenient tool for describing irreversible processes in condensed matter.     

Models of a linearized Boltzmann collision integral

For rarefied gas flows at moderate and low Knudsen numbers, model equations are derived that approximate the Boltzmann equation with a linearized collision integral. The new kinetic models generalize and refine the S-model kinetic equation.     

Two-Time Temperature Green's Functions in Kinetic Theory and Molecular Hydrodynamics: III. Taking the Interaction of Hydrodynamic Fluctuations into Account

We describe a systematic method for constructing equations for Green's functions in molecular hydrodynamics and kinetics problems. The method allows consecutively accounting for the contribution to the generalized kinetic coefficients due to the interaction of two, three, and more hydrodynamic modes. In contrast to the standard perturbation theory in the coupling constant, the consecutive approximations are taken with respect to the degree of higher correlations described by irreducible functions.     

Application of a direct method for solving the Boltzmann equation in supersonic flow computation

The Boltzmann kinetic equation is used to numerically study the evolution of separated flows over a backward-facing step at low Knudsen numbers. The Boltzmann equation is solved by applying an explicit–implicit scheme. To improve the efficiency of the solution algorithm, it is parallelized with the help of MPI. The solution obtained with the kinetic equation is compared with those based on continuous medium equations. It is shown that the kinetic approach makes it possible to reproduce the distributions of surface pressure, friction coefficient, and heat transfer, as well as to obtain a flow structure close to experimental data.     

Numerical study of Couette flow based on a nonlinear nonequilibrium kinetic model of the Boltzmann equation for monatomic gases

The two-dimensional Couette flow with heat transfer was studied numerically using a non-linear nonequilibrium kinetic model of the Boltzmann equation. The effects of a maximum normal stress and a minimum streamwise energy flux were found depending on the Knudsen number.     

Microscopic solutions of kinetic equations and the irreversibility problem

As established by N.N. Bogolyubov, the Boltzmann-Enskog kinetic equation admits the so-called microscopic solutions. These solutions are generalized functions (have the form of sums of delta functions); they correspond to the trajectories of a system of a finite number of balls. However, the existence of these solutions has been established at the “physical” level of rigor. In the present paper, these solutions are assigned a rigorous meaning. It is shown that some other kinetic equations (the Enskog and Vlasov-Enskog equations) also have microscopic solutions. In this sense, one can speak of consistency of these solutions with microscopic dynamics. In addition, new kinetic equations for a gas of elastic balls are obtained through the analysis of a special limit case of the Vlasov equation.     

Hydrodynamic limits with shock waves of the Boltzmann equation

We show that piecewise smooth solutions with shocks of the Euler equations in gas dynamics can be obtained as the zero Knudsen number limit of solutions of the Boltzmann equation for hard sphere collision model. The construction of the Boltzmann solutions is done in two steps. First we introduce a generalized Hilbert expansion with shock layer correction to construct approximations to the solutions of the Boltzmann equations with small Knudsen numbers. We then apply the recently developed macro‐micro decomposition and energy method for Boltzmann shock layers to construct the exact Boltzmann solutions through the stability analysis. © 2004 Wiley Periodicals, Inc.     

A Relaxation Scheme for Solving the Boltzmann Equation Based on the Chapman-Enskog Expansion

Abstract In [16] a visco-elastic relaxation system, called the relaxed Burnett system, was proposed by Jinand Slemrod as a moment approximation to the Boltzmann equation. The relaxed Burnett system is weaklyparabolic, has a linearly hyperbolic convection part, and is endowed with a generalized eotropy inequality. Itagrees with the solution of the Boltzmann equation up to the Burnett order via the Chapman-Enskog expansion. We develop a one-dimensional non-oscillatory numerical scheme based on the relaxed Burnett system forthe Boltzmann equation. We compare numerical results for stationary shocks based on this relaxation scheme,and those obtained by the DSMC (Direct Simulation Monte Carlo), by the Navier-Stokes equations and bythe extended thermodynamics with thirteen moments (the Grad equations). Our numerical experiments showthat the relaxed Burnett gives more accurate approximations to the shock profiles of the Boltzmann equationobtained by the DSMC, for a range of Mach numbers for hypersonic flows, th     

Ordinary differential equation system for population of individuals and the corresponding probabilistic model

The key model for particle populations in statistical mechanics is the Bogolyubov–Born–Green–Kirkwood–Yvon (BBGKY) equation chain. It is derived mainly from the Hamilton ordinary differential equation (ODE) system for the particle states in the position-momentum phase space. Many problems beyond physics or chemistry, for instance, in the living-matter sciences (biology, medicine, ecology, and sociology) make it necessary to extend the notion of a particle to an individual, or active particle. This challenge is met by the generalized kinetic theory. The corresponding dynamics of the state vector can also be regarded to be described by an ODE system. The latter, however, need not be the Hamilton one. The question is how one can derive the analogue of the BBGKY paradigm for the new settings. The present work proposes an answer to this question. It applies a very limited number of carefully selected tools of probability theory and common statistical mechanics. It also uses the well-known feature that the maximum number of the individuals which can mutually interact directly is bounded by a fixed value of a few units. The proposed approach results in the finite system of equations for the reduced many-individual distribution functions thereby eliminating the so-called closure problem inevitable in the BBGKY theory. The thermodynamic-limit assumption is not needed either. The system includes consistently derived terms of all of the basic types known in kinetic theory, in particular, both the “mean-field” and scattering-integral terms, and admits the kinetic equation of the form allowing a direct chemical-reaction reading. The approach can deal with Hamilton’s model which is nonmonogenic. The results may serve as the basis of the generalized kinetic theory and contribute to stochastic mechanics of populations of individuals.     

Radiative processes and non-equilibrium thermodynamics

With the assumption of an elementary physical concept meteorologically effective radiative processes (absorption-emission, scattering) can be included consistently in nonequilibrium thermodynamics of irreversible phenomena. Analogously to the usual Gibbs relations a fundamental equation was formulated for monochromatic light rays as the nucleus of the theory.Using the methods of classical irreversible theory, a complete entropy balance equation is derived in which the entropy variations of the mass as well as of the radiation field are explicitly represented. The resulting entropy source strength function through its analytical structure reveals the dynamical character of the irreversible variation terms. The-expression being positive according to the second law of thermodynamics is found to have a bilinear form as a function of the irreversible fluxes representing the entropy generating radiative processes and their conjugated thermodynamic forces. The mathematical structure and the positive sign of, following the usual line of reasoning, motivate the assumption of constitutive relations for the irreversible radiative processes. These equations developed from purely thermodynamical reasoning turn out to be equivalent to the usual radiative transfer equation which is founded on a very different theoretical concept. A very fundamental relationship can be deduced in this context from the entropy production function. It provides a direct thermodynamical proof that in nonscattering media the definition of a local temperature is necessarily accompanied by the validity of the Kirchhoff law.     

Construction and Study of Exact Solutions to A Nonlinear Heat Equation

We construct and study exact solutions to a nonlinear second order parabolic equation which is usually called the “nonlinear heat equation” or “nonlinear filtration equation” in the Russian literature and the “porous medium equation” in other countries. Under examination is the special class of solutions having the form of a heat wave that propagates through cold (zero) background with finite velocity. The equation degenerates on the boundary of a heat wave (called the heat front) and its order decreases. The construction of these solutions by passing to an overdetermined system and analyzing its solvability reduces to integration of nonlinear ordinary differential equations of the second order with an initial condition such that the equations are not solvable with respect to the higher derivative. Some admissible families of heat fronts and the corresponding exact solutions to the problems in question are obtained. A detailed study of the global properties of solutions is carried out by the methods of the qualitative theory of differential equations and power geometry which are adapted for degenerate equations. The results are interpreted from the point of view of the behavior and properties of heat waves with a logarithmic front.     

Diffusive semiconductor moment equations using Fermi�CDirac statistics

Diffusive moment equations with an arbitrary number of moments are formally derived from the semiconductor Boltzmann equation employing a moment method and a Chapman?CEnskog expansion. The moment equations are closed by employing a generalized Fermi?CDirac distribution function obtained from entropy maximization. The current densities allow for a drift-diffusion-type formulation or a ??symmetrized?? formulation, using dual-entropy variables from nonequilibrium thermodynamics. Furthermore, drift-diffusion and new energy-transport equations based on Fermi?CDirac statistics are obtained and their degeneracy limit is studied.