Regulation of the mechanical properties of thermoplastic carbon fiber-reinforced plastics by changing their production conditions and surface treatment of the fibers

The effect of technological parameters of processing and surface treatment of carbon fibers on the mechanical properties of carbon fiber-reinforced plastics (CFRPs) was investigated. The copolymer of 1,3,5-trioxane with 1,3-dioxolane was used as the polymer matrix, and medium-modulus hydrated cellulose Ural LO-24 carbon fibers served as the reinforcing filler. The polymer matrix was mixed with the carbon fibers by the method of combined extrusion. The dependence of the mechanical properties of CFRPs on the technological parameters of screw-disk extrusion was studied. It was found that the properties of the composites were greatly affected by the size of the working disk gap, the disk rotation rate, and the temperature in the zone of normal stresses. The surface of the carbon fibers was activated with atmospheric oxygen in the temperature range of 450–600°C, with mass loss of the fibers no greater than 3–4%. A 30–40% increase in the mechanical properties of the CFRPs was achieved. A decrease in the melt index of the 1,3,5-trioxane copolymer with 1,3-dioxolane reinforced with oxidized carbon fibers was observed, which should be taken into account in processing the composites into products. Introduction of carbon fibers in the 1,3,5-trioxane copolymer with 1,3-dioxolane allows us to increase the wear resistance and decrease the friction coefficient, which makes it possibile to use these materials in the friction units of machines and mechanisms, such as plain bearings, gears, and flange packings.Presented at the 10th International Conference on the Mechanics of Composite Materials (Riga, April 20–23, 1998).Ukrainian State University of Chemical Technology, Dnepropetrovsk, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, Vol. 34, No. 5, pp. 673–682, September–October, 1998.     

Effect of temperature on the mechanical properties of boron fibers

The effect of exposure to temperatures on the interval 20–600°C for up to 1000 h on the physicomechanical properties of boron fibers at room temperature has been investigated. Prolonged exposure to temperatures up to 200°C does not have much effect on the mechanical characteristics of the fibers, whereas heating for one hour at 300–350°C increases the strength of the fibers by 10–12%.All-Union Scientific Research Institute of Aviation Materials, Moscow. Translated from Mekhanika Polimerov, No. 2, pp. 329–332, March–April, 1971.     

Strength of boron fibers

The tensile and flexural strength and elastic properties of continuous boron fibers 95–105 µ in diameter obtained by depositing boron on a tungsten filament 10–12 µ in diameter have been investigated. The strength properties are primarily determined by the defects present at the boron sheath-core interface and for the fibers investigated have a limit of approximately 400 kgf/mm². Coarse surface or internal defects are capable of reducing the strength of the fibers to 200–250 kfg/mm².All-Union Scientific-Research Institute of Aviation Materials, Moscow. Translated from Mekhanika Polimerov, No. 6, pp. 1126–1127, November–December, 1970.     

Interaction of a polymer matrix and short reinforcing fibers

A model of a glass-reinforced plastic with short unidirectional fibers is proposed. The distribution of tensile stresses in the polymer matrix and the fibers and the shear stress distribution at the interface in uniaxial tension are investigated in the elastic formulation.Riga Polytechnic Institute. Translated from Mekhanika Polimerov, No. 6, pp. 1030–1035, November–December, 1971.     

Choice of optimal structure of glass laminates with random reinforcement. I

The effect of structural parameters — length, diameter, and distribution of the reinforcing elements — on the mechanical characteristics of glass-reinforced plastics is investigated with reference to the case of glass laminates with randomly distributed, straight, uncut glass fibers in parallel planes. It is shown that the reduced strength of these laminates as compared with unidirectional material is associated with the redistribution of the load between the fibers and the resin and the relative reduction in the number of fibers in the cross section. A formula is proposed for estimating the strength of glass-reinforced plastics with a random distribution of the fibers in parallel planes.All-Union Scientific-Research Institute of Glass-Reinforced Plastics and Glass Fiber, Moscow Region. Moscow Bauman Higher Technical College. Translated from Mekhanika Polimerov, Vol. 4, No. 6, pp. 1043–1050, November–December, 1968.     

Effect of residual stresses on the strength of oriented glass-reinforced plastics

The effect of structural residual stresses on the strength of a glass-reinforced plastic loaded along and across the fibers is investigated. It is established that the residual stresses lead to an increase in the strength of the glass-reinforced plastic across the fibers and to cracking of the polymer matrix in tension along the fibers, but have practically no effect on the combined deformation of the matrix and the fibers in compression.Moscow Ordzhonikidze Aviation Institute. Translated from Mekhanika Polimerov, No. 3, pp. 475–480, May–June, 1969.     

Thermal deformation of unidirectionally reinforced hybrid composites. Report no. 1

Conclusion We conducted a dilatometric study of three types of hybrid unidirectionally reinforced composites (organic-glass-, organic-carbon-, and carbon-glass-fiber plastics), each of which was represented by several batches differing in the relative content of the two types of fibers. The tests were performed on a specially-designed laboratory prototype. It was shown that, for the materials studied, the coefficient of linear expansion can be controlled by means of hybridization — by combining several types of fibers with positive and negative values of the coefficient of linear expansion in one composite. Analytic expressions for the coefficient that were obtained by generalizing a three-phase model of a two-component composite with isotropic fibers to the case of a hybrid composite with anisotropic fibers satisfactorily describe the experimental data.Translated from Mekhanika Kompozitnykh Materialov, No. 2, pp. 229–236, March–April, 1989.     

Influence of acetone-soluble fraction content on physicomechanical properties of cellulose triacetate

The influence of a change in the acetone-soluble fraction content on the physicomechanical properties of irradiated triacetate (CTA) fibers has been investigated. The results obtained showed that irradiation of CTA sharply alters the acetone-soluble content of CTA fibers, which correlates well with the changes in physicomechanical propertiesKaunas Polytechnic Institute. Translated from Mekhanika Polimerov, No. 3, pp. 537–539, May–June, 1970.     

Structure and properties of ceramic composites based on ZrO2

Monodisperse fine powders of high purity obtained by sol-gel method are used for production of high technical data ceramics. The fiber reinforcement is used for hardening of composite materials. It was of interest to study production possibility of reinforced composite material based on ZrO₂ obtained by sol-gel method with filler from fibers of partially stabilized zirconia. ZrO₂ powders were obtained by precipitation of its hydrated gel from aqueous zirconium oxychloride solution by ammonium hydroxide followed by thermal treatment. For composite reinforcement ceramic partially stabilized (8 mole Y₂O₃) ZrO₂ fibers 0.16–0.67 mm in length and 5–7 m in diameter were used. Content of the fibers in composite was 20 wt.%. From powders and their mixtures with fibers, the samples were pressed as disks, beams and cylinders, and anneal in air at 1100–1600°C temperature range. The investigation has shown that the fibers of partially stabilized zirconia change the composite structure, increase the content of tetragonal modification that promotes its hardening. Treatment temperature of precursor determines physical chemical properties of compositions with fibers. Their high specific surface and reaction ability provides a workability of forming and sintering processes into strong composite material. The ceramics was increased by 2.5–3 times as strength after fibrous filler introduction into ZrO₂ hydrogel matrix.Presented at the Ninth International Conference on the Mechanics of Composite Materials (Riga, October 1995).Presented at the Ninth International conference on the Mechanics of Composite Materials (Riga, October 1995). Institute of General and Inorganic Chemistry of the Academy Sciences of the Belarus. Minsk. Translated from Mekhanika Kompozitnykh Materialov, Vol. 32, No. 3, pp. 418–427, May–June. 1996.     

Theoretical and maximum attainable strength of various uniaxially oriented polymers (film,fibers)

The theoretical strength of various ideally oriented synthetic fibers was calculated. The calculation was based on an assumption that the rupture of polymers involves simultaneous breaking of molecular chains and pulling asunder the chain ends. The temperature-time dependence of the strength of fibers was analyzed and the maximum attainable strength of fibers of various kinds was calculated to show that it is 2–5 times higher than that recorded in practice. The main causes of the difference between the attainable and attained levels of strength are associated with imperfections of the supermolecular structure and an insufficient degree of orientation of materials of this kind. The principal means of obtaining high strength levels of synthetic fibers were discussed.Mekhanika Polimerov, Vol. 2, no. 6, pp. 845–856, 1966     

Changes in the strength of gamma-irradiated cellulose during storage

A comparison of the physicochemical properties of irradiated specimens of cotton and viscose fibers, stored for long periods at various temperatures, with the properties of the starting specimens has revealed reversible effects consisting in the recovery of the strength and heat of wetting of the starting fibers.Tashkent Lenin State University. Translated from Mkhanika Polimerov, No. 5, pp. 941–944, September–October, 1970.     

Quantitative evaluation of the brittleness of carbon fibers

A simple method is proposed for the rapid determination of the brittleness of fibers. Measurement data are given for glass and carbon fibers. It is shown that the conditions of heat processing for carbon fibers may fundamentally alter their brittleness.A. F. Ioffe Physical-Engineering Institute, Academy of Sciences of the USSR, Leningrad. Translated from Mekhanika Polimerov, No. 5, pp. 950–952, September–October, 1973.     

Strength and deformability of reinforced polymers in tension normal to the fibers

The strength and deformability of reinforced polymers in tension across the fibers is investigated. It is assumed that the polymer deforms as an ideal elastoplastic body. Relations are obtained for the nature of the deformation of the polymer between the fibers and the strength and deformability of the composite with allowance for the structural distribution of the components. Theoretical stress-strain diagrams are presented for composites with different reinforcement densities and resin elasticities. The theoretical values of the strength and deformation of reinforced polymers with the load applied across the fibers are compared with the results of experiments on model specimens of epoxy-Thiokol polymers.Leningrad Mechanical Institute. Translated from Mekhanika Polimerov, No. 4, pp. 682–687, July–August, 1970.     

Realization of the mechanical properties of fibers in high-modulus polymer composites

The effect of scatter in the strength and deformation properties of the high-modulus fibers, the degree of twist, and the presence of pores in the polymeric matrix on the degree of realization of the potential possibilities of these fibers in composite materials is briefly considered.All-Union Scientific-Research Institute of Aviation Materials, Moscow. Translated from Mekhanika Polimerov, No. 6, pp. 1123–1125, November–December, 1972.     

Polypropylene reinforced with aramid and glass fibers

The effect of the chemical nature of the aramid fibers Phenylone, Terlon, Armos, and SVM on the mechanical, thermophysical, and antifriction properties of reinforced polypropylene was investigated. It was found that the composite filled with SVM fibers based on a stiff-chain polymer has high tensile strength and bending modulus. Reinforcement of polypropylene with Phenylone stiff-chain fibers produces a composite with a high impact viscosity. Organoplastics based on polypropylene and aramid fibers have a low density and friction coefficient and high durability. Reinforcement of polypropylene with aramid (SVM) and glass fibers increases the technological properties of the composites. The glass-filled organoplastics developed can be used in instrument making, radio engineering, and machine building as antifriction and construction materials.Ukrainian State Chemical Technological University, Dnepropetrovsk, Ukraine. Translated from Mekhanika Kompozitnykh Materialov, No. 1, pp. 106–110, January–February, 1996.     

Transverse compression of PPTA fibers

Results of single transverse compression testing of PPTA and PIPD fibers, using a novel test device, are presented and discussed. In the tests, short lengths of single fibers are compressed between two parallel, stiff platens. The fiber elastic deformation is analyzed as a Hertzian contact problem. The inelastic deformation is analyzed by elastic-plastic FE simulation and by laser-scanning confocal microscopy of the compressed fibers ex post facto. The results obtained are compared to those in the literature and to the theoretical predictions of PPTA fiber transverse elasticity based on PPTA crystal elasticity.Presented at the 11th International Conference on Mechanics of Composite Materials (Riga, June 11–15, 2000).3TEX, Inc. 109, MacKenan Drive, Cary, North Carolina 27511, USA. Published in Mekhanika Kompozitnykh Materialov, Vol. 36, No. 4, pp. 533–544, March–April, 2000.     

A study of the physicomechanical properties of carbon fibers at high temperatures

Conclusions 1. Carbon fibers, similar to graphite materials, are heat-resistant and do not Iose their short-term tensile strength in the temperature range studied — 20 to 2000°C.2. Young's modulus of carbon fibers hardly changes in the temperature range 20 to 1200°C, but a significant decrease is observed upon a further increase in temperature.Translated from Mekhanika Polimerov, No. 4, pp. 626–630, July–August, 1977.     

Three-dimensional reinforced fabric materials

Three-dimensional materials whose principle of construction is based on marked curvature of the fibers of multilayered three-dimensionally woven fabric are discussed. The effect of the law and degree of curvature of fibers on the deformative properties of the composite material is investigated on the basis of the model proposed.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 2, pp. 311–318, March–April, 1970.     

Structural theory of the tensile and compressive strengths of reinforced plastics

The strength conditions of unidirectionally and orthogonally reinforced plastics subjected to uniaxial tension and compression in the direction of, and at an angle to, the reinforcement are developed, with consideration given to possible failure of the fibers, binder, or the bond between the fibers and binder. Proposed strength conditions take into account the structure of the material, the properties of its components, and stress concentration.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 6, pp. 988–995, November–December, 1975.     

Effect of curvature of the reinforcement on the mechanical and thermophysical properties of a composite

The elastic constants and thermal expansion coefficients of a composite consisting of a matrix with low elastic properties and exceptionally stiff fibers have been experimentally determined. The curvature of the reinforcement in the specimens has been investigated. The results of the experiments are compared with the corresponding theoretical characteristics. The calculations are based on a model with an ideal arrangement of the fibers [4] and a model that takes the curvature of the reinforcement into account [5, 6].Moscow Power Engineering Institute. Translated from Mekhanika Polimerov, No. 6, pp. 1036–1039. November–December, 1971.