紫外波段有机染料DMT掺杂SiO2薄膜的光谱特性

本文采用溶胶 凝胶法合成了紫外波段有机染料DMT掺杂SiO2 薄膜和块体材料 薄膜中掺杂浓度高达 1 2 4× 1 0 - 2 mol/L ,块体材料浓度掺至 1 5× 1 0 - 3mol/L 由于SiO2“笼”的束缚作用 ,在荧光光谱中未观察到荧光猝灭现象 ;由于SiO2 “笼”的极化作用 ,370nm的发射峰较其在环己烷中发生了 34～ 44nm左右的红移 ;580～ 590nm的发射峰的量子效率比 370nm的发射峰略高     

有机染料TMQ掺杂的SiO2薄膜的光谱特性

采用溶胶 -凝胶法合成了紫外波段有机染料 TMQ掺杂的 Si O2 薄膜和块体材料。薄膜中掺杂的染料浓度高达 1.2 4× 10 -2 mol/ L,块体材料中染料浓度可掺至 1.5× 10 -3 mol/ L。由于Si O2 “笼”的束缚作用 ,在吸收光谱中未观察到二聚体的特征谱带 ,在荧光光谱中未观察到荧光猝灭现象 ;同时由于 Si O2 “笼”的极化作用 ,其吸收峰和发射峰的位置相对于其在环己烷溶液中的吸收峰和发射峰位置发生了 10 nm左右的红移。     

用Z-扫描技术研究卟啉铜偶合TiO2/SiO2有机-无机材料的非线性吸收特性

应用溶胶-凝胶技术, 成功地把5,10,15,20-四(4-磺酸苯基)卟啉铜掺杂到SiO₂/TiO₂无机凝胶中, 制备成有机-无机复合材料. 采用开孔Z-扫描技术, 使用波长532 nm、脉宽7ns的YAG脉冲激光为光源, 测定了不同浓度卟啉铜掺杂的SiO₂/TiO₂凝胶Z-扫描曲线. 应用Z扫描理论对获得的曲线进行分析与理论拟合, 得到复合材料的非线性吸收系数. 这些非线性吸收是由材料中卟啉铜的单聚体与二聚体的反饱和吸收所引起. 研究表明, 随着掺杂浓度的增大, 复合材料的非线性吸收明显增强. 掺杂浓度为1.11×10^-4 (A2), 1.48×10^-4 (A3)与3.01×10^-4 mol/L (A4)凝胶的非线性吸收系数分别为1.705×10^-11, 1.892×10^-11和4.854×10^-11 m/W. 讨论了单聚体与二聚体的浓度变化对非线性吸收的影响. 随着掺杂浓度的增加, 凝胶中二聚体与多聚体含量的增加, 导致非线性吸收系数的增大. 同时测定了无机材料对该光源的抗激光损伤阈值为～5 J/cm².     

Er3+单掺及Er3+/Yb3+共掺SiO2-Al2O3-La2O3玻璃光谱性质研究

研究了单掺Er³⁺及Er³⁺/Yb³⁺共掺SiO₂-Al₂O₃-La₂O₃玻璃的光谱性质随稀土离子浓度变化规律,应用McCumber理论计算了玻璃在1.53 μm的发射截面及积分吸收截面.结果表明:在Er³⁺离子掺杂浓度相同时,玻璃在980 nm吸收截面与Yb³⁺掺杂浓度成反比;当样品中Yb³⁺离子掺杂浓度为3.94×10²⁰ cm^-3时,玻璃在1.53 μm的吸收截面和发射截面最大,在1.40～1.60 μm积分吸收截面也最大;Er³⁺/Yb³⁺共掺SiO₂-Al₂O₃-La₂O₃玻璃在1.53 μm的荧光半高宽随Er³⁺掺杂浓度升高而增加,当Er³⁺离子掺杂浓度为2.41×10²⁰ cm^-3时,玻璃的荧光半高宽(FWHM)达到52.5 nm.     

CdxHg1－xTe/SiO2固溶体微晶掺杂玻璃三阶非线性光学性质的

本文首次报道了对采用溶胶凝胶和原位生长工艺制备的Cd_xHg_1-xTe/SiO₂固溶体微品掺杂玻璃进行的三阶非线性光学性质实验研究及其结果。利用回返式简并四波混频技术,测得该固溶体掺杂玻璃的三阶非线性极化率的值为10^-12esu量级。此结果比纯SiO₂基体提高了2个数量级。表明该固溶体掺杂玻璃三阶非线性明显增强,在同样条件下,测得CS₂的三阶非线性极化率x⁽³⁾为(1.7±0.2)×10^-12esu,与国际上报道完全一致。     

Yb:FAP晶体的光谱特性

研究了Yb:FAP晶体的光谱特性.用980nm的InGaAs激光二极管激发测量了Yb:FAP晶体的偏振发射光谱和荧光寿命,结合晶体的偏振吸收光谱,采用对易法计算了晶体的吸收截面和发射截面.讨论了Yb³⁺掺杂浓度对Yb:FAP的光谱参数的影响.在较低掺杂浓度下,Yb:FAP晶体π偏振方向在903nm处的吸收截面为10×10^-20cm²,在1.043μm处的发射截面为5.8×10^-20cm²,激光上能级的荧光寿命为1.1ms.比较了Yb:FAP晶体和Yb:YAG晶体的光谱性能参数.     

表面层对1 064 nm高反射镜损伤阈值影响

 采用电子束蒸发的方法制备了３种具有不同表面层材料及结构的中心波长为1 064 nm的零度高反镜,３种膜系表面层分别为1/4波长光学厚度的HfO₂,1/2波长光学厚度的SiO₂,以及1/4波长光学厚度的SiO₂。光谱测试表明：三者在1 064 nm处均有较高的反射率（高于99.8%）,利用热透镜的方法测量得到３个膜系辐照激光正入射情况下,薄膜对光的吸收比例分别为3.0×10^-6,5.0×10^-6和6.5×10^-6,其损伤阈值分别为32.5,45.2和28.4 J/cm²。并在膜层内部电场分布和膜层材料物理特性的基础上分析了３种不同表面层膜系吸收和损伤阈值差别的原因。     

金原子团簇的分频散射光谱研究

液相金原子团簇是一种非线性光学介质.它在580nm处产生一个最强共振散射峰.当激发波长为290nm(1.03×10¹⁵Hz)时,液相金原子团簇在580nm(1/2×1.03×10¹⁵Hz)和870nm(1/3×1.03×10¹⁵Hz)分别产生一个1/2分频和1/3分频散射峰;当激发波长为580nm(5.02×10¹⁴Hz)时在290nm(2×5.02×10^-14Hz)和870nm(2/3×5.02×10¹⁴Hz)分别产生一个2倍频和2/3分频散射峰;当激发波长为870nm(3.34×10¹⁴Hz)时在580nm(3/2×3.34×10¹⁴Hz)和290nm(3×3.34×10¹⁴Hz)分别产生一个3/2分频和3倍频散射峰.分频散射和倍频散射峰与共振散射峰具有相似的散射行为.从激励光与液相金原子团簇相互作用的运动方程出发,根据傅氏变换理论,较好地解释了液相金原子团簇产生的一些非线性散射光谱.     

掺铍GaAs量子阱的光致荧光

测量了掺铍的,阱宽约为10nm的GaAs量子阱在4.2K的光致荧光。掺杂浓度分别为1×10¹⁷和5×10¹⁸cm^-3。测量结果表明:对于无规掺杂,局域在阱中心的铍的状态密度与导带电子从n=1量子能级到阱中心中性铍的跃迁概率的乘积大于对应于介面铍的乘积。另外,实验结果也表明:当掺杂浓度升高时,由于带隙收缩的影响,阱中心铍的电离能减小。     

用于白光LED的单一基质白光荧光粉Ca2SiO3Cl2:Eu2+，Mn2+的发光性质

用高温固相法合成了Eu²⁺，Mn²⁺共激活的Ca₂SiO₃Cl₂高亮度白色发光材料，并对其发光性质进行了研究. 该荧光粉在近紫外光激发下发出强的白色荧光，Eu^{2+中心形成峰值为419 nm和498 nm的特征宽带，通过Eu2+中心向Mn2+中心的能量传递导致了峰值为578 nm的发射，三个谱带叠加从而在单一基质中得到了白光. 激发光谱均分布在250—415 nm的波长范围，红绿蓝三个发射带的激发谱峰值分别位于385 nm，412 nm，370 nm和396 nm处，可以被InGaN管芯产生的紫外辐射有效激发. Ca₂SiO₃Cl₂:Eu2+，Mn2+是一种很有前途的单一基质白光LED荧光粉.}     

Fluorescent Sensing of both Fe(III) and pH Based on 4-Phenyl-2-(2-Pyridyl)Thiazole and Construction of OR Logic Function

In the presented paper we investigated a 2-pyridylthiazole derivative, 4-phenyl-2-(2-pyridyl)thiazole (2-PTP), as the molecular fluorescent switches. It was firstly found that 2-PTP could perform a “turn-on” fluorescent sensing for Fe(III) with selectivity and reversibility. A 2:1 stoichiometry between 2-PTP and Fe(III) was determined according to the molar ratio method. The binding constant was evaluated as (1.90 ± 0.05) × 10⁵ (L/mol)². The detection limit was found as 2.2 × 10^?7 M (S/N = 3). Secondly, 2-PTP also exhibited a pH-dependent dual-emission. The pK _a(2-PTP-H⁺/2-PTP) value was then estimated as 2.0. To explain the identical emission at 479 nm of both the Fe(III) coordinated form and the protonated form of the ligand, we proposed a “locked” conformation. Finally, combining the two external stimuli as inputs, an OR logic gate was constructed using the fluorescent emission at 479 nm as the output channel.     

The influence of the activator concentration on electroluminescence properties of thin layers in a system ZnS: Cu,Mn, Cl

The influence of activators, especially copper, on the electric properties of vacuum-evaporated electroluminescent layers excited by dc voltage is investigated. In the course of the “one step” method of preparation, non-uniform incorporation of the activators occurs. The layers are divided into three groups according to the copper concentration. 1 — “low” (1×10^?3 g Cu/g ZnS) with the emission stimulated at Al^? electrode, 2 — “medium” (5–8×10^?3 g Cu/g ZnS) with the emission at both polarities, 3 — “high” (9×10^?3?5×10^?2 g Cu/g ZnS) with the emission at Al⁺ electrode. Layers in these groups differ not only in their electrical properties and in the existence of the forming process but they have also various distribution of the light-emitting regions. The light emission has been found in the intermediate regions between the microcrystalline grains as well as on the interface between the microcrystalline grain and ZnS phosphor phase. According to structural properties the light emission originates from microcrystalline grains too.     

消逝波激励的双波段光纤回音壁模式激光辐射

将石英光纤浸入低折射率的染料溶液中后构成圆柱形微腔.采用轴向光抽运消逝波激励激光增益的方式,使增益区域局限在圆柱形微腔回音壁模式的模场区域内,由此显著地提高了抽运效率,增加了沿光纤轴向的增益长度.在一根石英光纤的轴向分段填入浓度同为2×10^-3mol/L的罗丹明6G和罗丹明B乙醇溶液,在567—576nm 和592—600nm的两个波长范围内同时获得回音壁模式的激光辐射;分段填入浓度为8×10^-4和8×10^-3mol/L的罗丹明B乙醇溶液, 关键词： 消逝波激励 圆柱形微腔 回音壁模式 双波段激光辐射     

Hemoglobin-catalyzed fluorometric method for the determination of glutathione

A new spectrofluorometric method for the determination of glutathione based on the reaction catalyzed by hemoglobin was reported. The reaction product gave a highly fluorescent intensity with the excitation and emission wavelengths of 320.0 nm and 413.0 nm, respectively. The optimum experimental conditions were investigated. Results showed that low concentration glutathione enhanced the fluorescence intensity significantly. The line ranges were 1.0 × 10^–6–1.0 × 10^–5 mol L^–1 of glutathione and 6.0 × 10^-10 mol L^-1–1.0 × 10^-8 mol L^-1, respectively. The detection limit was calculated to be 1.1 × 10^-11 mol L^-1. The recovery test by the standard addition method gave values in the range of 90.78%-102.20%. This method was used for the determination of glutathione in synthetic and real samples with satisfactory results.     

Preparation and optical properties of UV dye DMT-doped silica films

UV dye DMT-doped silica films were prepared by sol-gel process with dioxane as the cosolvent. Luminescence quenching was not observed even if the DMT concentration in the visibly transparent silica film is as high as 1.26×10⁻² M. The emission peaks centered at ∼375 nm for the films show red-shift of 35-45 nm, comparing with that of the cyclohexane solution of DMT. The fluorescence quantum efficiency of the films centered at ∼590 nm are larger than those at ∼375 nm.     

Measurement of Ar(I) and Ar(II) transition probabilities in LTE ARC plasmas

The transition probabilities of two Ar(I) lines and one Ar(II) line have been measured in emission on wall-stabilized argon arc plasmas (0·5×10⁵?p, Nm^-2?3×10⁵; 10,000?T, K?20,000; 10²²?N_e, m^-3?5×10²³) using the “method of best fit (MBF)”. The results (without line-wing correction) are for Ar(I) at 714·7 nm, A_nm=5·66×10⁵ s^-1±5%; for Ar(I) at 430·0 nm, A_nm=3·40×10⁵ s^-1±5%; for Ar(II) at 480·6 nm, A_nm=8·82×10⁷ s^-1±7%. These values were not influenced by deviations from LTE, which have been observed at electron number densities n_e?10²³ m^-3. The small uncertainties were achieved after careful corrections of different sources of error.     

一种新型有机染料的宽带双光子吸收和光限幅特性的研究

研究了一种新型双共轭链有机染料分子的双光子吸收（TPA）及其光功率限幅特性，实验研究了该有机染料的双光子吸收谱和光功率限幅曲线. 结果证实在浓度为1×10^-2 mol/L的四氢呋喃（THF）溶液中，该有机染料在近红外区有宽达400nm的宽带非线性双光子吸收及光功率限幅特性. 它的双光子吸收谱存在三个峰，分别位于730，850和980nm，并且在850nm处有最大的TPA截面，为σ′₂＝25.9×10^-47　cm^{4·s 关键词： 宽带 双光子吸收 光限幅 双共轭链有机分子}     

Amplified spontaneous emission enhanced forward stimulated Raman scattering in dye solutions

We study forward stimulated Raman emission from the weakly fluorescent dye 4^′-diethylamino-N-methyl-4-stilbazolium tosylate (DEST) in 1,2 dichloroethane solution excited by a 28-ps, 532-nm Nd:YAG laser. Neat 1,2 dichloroethane emits the first Stokes line at 631 nm with a spectral width of 1.6 nm, corresponding to a Raman shift of 2956 cm^-1. We observe a reduction of spectral width with the addition of DEST in 1,2 dichloroethane solution. The single-pass conversion efficiency for forward Raman emission is as high as 10% in a 1-cm-path-length sample. The pulse duration of forward stimulated Raman emission, measured by a third-order autocorrelation technique, is 10 ps in neat 1,2 dichloroethane, whereas it is ～3 ps for 4×10^-5 mol/l of DEST solution.     

青蒿素光化学合成中二氢青蒿酸与单线态氧反应的动力学研究

青蒿素是一种优异的抗疟药,广泛用于临床医学. 但由于青蒿素天然来源的限制,青蒿素的化学合成一直受到高度关注. 二氢青蒿酸是合成青蒿素的关键前体. 二氢青蒿酸与单线态氧反应形成过氧化物是青蒿素光化学制备中的关键步骤,制约着青蒿素化学合成的产率. 然而关于二氢青蒿酸与单线态氧反应的重要动力学信息并未有报道. 本文通过光敏化法产生单线态氧,研究二氢青蒿酸与单线态氧之间的反应速率常数. 通过直接检测单线态氧在1270 nm处的发光衰减动力学,得出单线态氧与二氢青蒿酸在不同溶剂中的反应速率常数分别为：在CCl₄中为1.81×10⁵ (mol/L)^-1·s^-1,在CH₃CN中为5.69×10⁵ (mol/L)^-1·s^-1,DMSO中为3.27×10⁶ (mol/L)^-1·s^-1. 发现在三种溶剂中二氢青蒿酸与单线态氧的反应速率常数随着溶剂极性的增加而增加. 这些结果为优化青蒿素光化学合成的实验条件提供了基础知识,有助于提高青蒿素的合成效率.