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Eva Tudela Jairo Gonzlez Rubn Vicente Javier Santamaría Miguel A. Rodríguez Alfredo Ballesteros 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2014,126(45):12293-12296
An allylic gold(I) cation, proposed as key intermediate in the gold‐promoted rearrangement of 1,5‐enynes bearing a fixed conformation, has been detected and characterized by NMR spectroscopy. Moreover, its participation in the overall transformation was confirmed. Computational studies indicate that the gold‐catalyzed transformation occurs through an uncommon rearrangement. Additionally, this study led us to isolate and characterize a stable homoantiaromatic carbocation. 相似文献
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Divergente Koordinationschemie: Parallele Synthese von [2×2]‐Eisen(II)‐Gitterkomplextautokonformeren
Bernhard Schfer Jean‐Franois Greisch Isabelle Faus Tilmann Bodenstein Ivan alitro Olaf Fuhr Karin Fink Volker Schünemann Manfred M. Kappes Mario Ruben 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2016,128(36):11040-11044