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1.
We consider a family of linearly viscoelastic shells with thickness \(2\varepsilon\), clamped along their entire lateral face, all having the same middle surface \(S=\boldsymbol{\theta}(\bar{\omega})\subset \mathbb{R}^{3}\), where \(\omega\subset\mathbb{R}^{2}\) is a bounded and connected open set with a Lipschitz-continuous boundary \(\gamma\). We make an essential geometrical assumption on the middle surface \(S\), which is satisfied if \(\gamma\) and \(\boldsymbol{\theta}\) are smooth enough and \(S\) is uniformly elliptic. We show that, if the applied body force density is \(O(1)\) with respect to \(\varepsilon\) and surface tractions density is \(O(\varepsilon)\), the solution of the scaled variational problem in curvilinear coordinates, \(\boldsymbol{u}( \varepsilon)\), defined over the fixed domain \(\varOmega=\omega\times (-1,1)\) for each \(t\in[0,T]\), converges to a limit \(\boldsymbol{u}\) with \(u_{\alpha}(\varepsilon)\rightarrow u_{\alpha}\) in \(W^{1,2}(0,T,H ^{1}(\varOmega))\) and \(u_{3}(\varepsilon)\rightarrow u_{3}\) in \(W^{1,2}(0,T,L^{2}(\varOmega))\) as \(\varepsilon\to0\). Moreover, we prove that this limit is independent of the transverse variable. Furthermore, the average \(\bar{\boldsymbol{u}}= \frac{1}{2}\int_{-1}^{1} \boldsymbol{u}dx_{3}\), which belongs to the space \(W^{1,2}(0,T, V_{M}( \omega))\), where
$$V_{M}(\omega)=H^{1}_{0}(\omega)\times H^{1}_{0}(\omega)\times L ^{2}(\omega), $$
satisfies what we have identified as (scaled) two-dimensional equations of a viscoelastic membrane elliptic shell, which includes a long-term memory that takes into account previous deformations. We finally provide convergence results which justify those equations.
  相似文献   

2.
Particle image velocimetry (PIV) has been used to investigate transitional and turbulent flow in a randomly packed bed of mono-sized transparent spheres at particle Reynolds number, \(20<{{ Re}}_{\mathrm{p}}< 3220\). The refractive index of the liquid is matched with the spheres to provide optical access to the flow within the bed without distortions. Integrated pressure drop data yield that Darcy law is valid at \({{ Re}}_{\mathrm{p}} \approx 80\). The PIV measurements show that the velocity fluctuations increase and that the time-averaged velocity distribution start to change at lower \({{ Re}}_{\mathrm{p}}\). The probability for relatively low and high velocities decreases with \({{ Re}}_{\mathrm{p}}\) and recirculation zones that appear in inertia dominated flows are suppressed by the turbulent flow at higher \({{ Re}}_{\mathrm{p}}\). Hence there is a maximum of recirculation at about \({{ Re}}_{\mathrm{p}} \approx 400\). Finally, statistical analysis of the spatial distribution of time-averaged velocities shows that the velocity distribution is clearly and weakly self-similar with respect to \({{ Re}}_{\mathrm{p}}\) for turbulent and laminar flow, respectively.  相似文献   

3.
We formulated a paradox in the theory of turbulent premixed flame in the flamelet regime: discrepancy between the Damköhler (1940) and Shelkin (1943) estimate of the turbulence flame speed \(U_{t} \sim {u}^{\prime }\) in the case of strong turbulence (\({u}^{\prime }>>S_{L} \)) and numerous experiments that show a strong dependence of Ut on the speed of the instantaneous flame SL. We name this discrepancy the Damköhler-Shelkin paradox. The first aim of the research is to validate and clarify this estimate, which is based on intuitive considerations, as the paradox must be a statement that seems contradictory to observations but is actually true. We analysed the turbulent flame in the context of the original hyperbolic combustion equation that directly describes the leading edge of the flame, which is a locus of the Zel’dovich “leading points” controlling the speed of the turbulent flame. Analysis of the corresponding characteristic equations results in the expression for speed on the steady-state turbulent flame \(U_{t} ={u}^{\prime }\sqrt {1+(S_{L} /{u}^{\prime })^{2}} \), which is the case when \({u}^{\prime }>>S_{L} \) becomes \(U_{t} \cong {u}^{\prime }\). This result confirms and improves the Damköhler-Shelkin estimate \(U_{t} \sim {u}^{\prime }\). The second aim is to resolve the Damköhler-Shelkin paradox. We explain the discrepancy with observations by the fact that turbulent flames are transient due to insufficient residence time in the real burners to reach statistical equilibrium of wrinkle structures of the random flame surface. We consider the transient flame in the intermediate asymptotic stage when the small-scales wrinkles are in statistical equilibrium, while at the same time the large-scale wrinkles are far from equilibrium. The expressions for the flame speed and width, which we deduce using the dimensional analysis and general properties of the ransom surface, \(U_{t} \sim ({u}^{\prime }S_{L})^{1/2}\) and \(\delta _{t} \sim ({u}^{\prime }Lt)^{1/2}\), show that this transient flame is in fact a turbulent mixing layer travelling with constant speed Ut depending on SL, the intermediate steady propagation (ISP) flame. Qualitative estimations of the times required for the small-scale and large-scale wrinkles to reach statistical equilibrium show that the turbulent Bunsen- and V-flames correspond to the intermediated asymptotic stage, and the turbulent flames with a complete equilibrium structure of the wrinkled flamelet surface are not attainable under laboratory conditions. We present the results of numerical simulations of the impingent flames, which count in favour of the belief that these flames are also transient.  相似文献   

4.
This study considers the quasilinear elliptic equation with a damping term,
$$\begin{aligned} \text {div}(D(u)\nabla u) + \frac{k(|{\mathbf {x}}|)}{|{\mathbf {x}}|}\,{\mathbf {x}}\cdot (D(u)\nabla u) + \omega ^2\big (|u|^{p-2}u + |u|^{q-2}u\big ) = 0, \end{aligned}$$
where \({\mathbf {x}}\) is an N-dimensional vector in \(\big \{{\mathbf {x}} \in \mathbb {R}^N: |{\mathbf {x}}| \ge \alpha \big \}\) for some \(\alpha > 0\) and \(N \in {\mathbb {N}}\setminus \{1\}\); \(D(u) = |\nabla u|^{p-2} + |\nabla u|^{q-2}\) with \(1 < q \le p\); k is a nonnegative and locally integrable function on \([\alpha ,\infty )\); and \(\omega \) is a positive constant. A necessary and sufficient condition is given for all radially symmetric solutions to converge to zero as \(|{\mathbf {x}}|\rightarrow \infty \). Our necessary and sufficient condition is expressed by an improper integral related to the damping coefficient k. The case that k is a power function is explained in detail.
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5.
Statistically planar turbulent premixed and partially premixed flames for different initial turbulence intensities are simulated for global equivalence ratios ??>?=?0.7 and ??>?=?1.0 using three-dimensional Direct Numerical Simulations (DNS) with simplified chemistry. For the simulations of partially premixed flames, a random distribution of equivalence ratio following a bimodal distribution of equivalence ratio is introduced in the unburned reactants ahead of the flame. The simulation parameters in all of the cases were chosen such that the combustion situation belongs to the thin reaction zones regime. The DNS data has been used to analyse the behaviour of the dissipation rate transports of both active and passive scalars (i.e. the fuel mass fraction Y F and the mixture fraction ξ) in the context of Reynolds Averaged Navier–Stokes (RANS) simulations. The behaviours of the unclosed terms of the Favre averaged scalar dissipation rates of fuel mass fraction and mixture fraction (i.e. \(\widetilde {\varepsilon }_Y =\overline {\rho D\nabla Y_F^{\prime \prime } \cdot \nabla Y_F^{\prime \prime } } /\overline{\rho }\) and \(\widetilde {\varepsilon }_\xi =\overline {\rho D\nabla \xi ^{\prime \prime }\cdot \nabla \xi ^{\prime \prime }} /\overline {\rho })\) transport equations have been analysed in detail. In the case of the \(\widetilde {\varepsilon }_Y \) transport, it has been observed that the turbulent transport term of scalar dissipation rate remains small throughout the flame brush whereas the terms due to density variation, scalar–turbulence interaction, reaction rate and molecular dissipation remain the leading order contributors. The term arising due to density variation remains positive throughout the flame brush and the combined contribution of the reaction and molecular dissipation to the \(\widetilde {\varepsilon }_Y \) transport remains negative throughout the flame brush in all cases. However, the behaviour of scalar–turbulence interaction term of the \(\widetilde {\varepsilon }_Y \) transport equation is significantly affected by the relative strengths of turbulent straining and the straining due to chemical heat release. In the case of the \(\widetilde {\varepsilon }_\xi \) transport, the turbulent transport term remains small throughout the flame brush and the density variation term is found to be negligible in all cases, whilst the reaction rate term is exactly zero. The scalar–turbulence interaction term and molecular dissipation term remain the leading order contributors to the \(\widetilde {\varepsilon }_\xi \) transport throughout the flame brush in all cases that have been analysed in the present study. Performances of existing models for the unclosed terms of the transport equations of \(\widetilde {\varepsilon }_Y \) and \(\widetilde {\varepsilon }_\xi \) are assessed with respect to the corresponding quantities obtained from DNS data. Based on this exercise either suitable models have been identified or new models have been proposed for the accurate closure of the unclosed terms of both \(\widetilde {\varepsilon }_Y \) and \(\widetilde {\varepsilon }_\xi \) transport equations in the context of Reynolds Averaged Navier–Stokes (RANS) simulations.  相似文献   

6.
We present fully resolved computations of flow over periodic hills at the hill-Reynolds numbers \(\text {Re}_{H}=?5{,}600\) and \(\text {Re}_{H}=?10{,}595\) with the highest fidelity to date. The calculations are performed using spectral incompressible discontinuous Galerkin schemes of \(8^{\text {th}}\) and \(7^{\text {th}}\) order spatial accuracy, \(3^{\text {rd}}\) order temporal accuracy, as well as 34 and 180 million grid points, respectively. We show that the remaining discretization error is small by comparing the results to h- and p-coarsened simulations. We quantify the statistical averaging error of the reattachment length, as this quantity is widely used as an ‘error norm’ in comparing numerical schemes. The results exhibit good agreement with the experimental and numerical reference data, but the reattachment length at \(\text {Re}_{H}=?10{,}595\) is predicted slightly shorter than in the most widely used LES references. In the second part of this paper, we show the broad range of capabilities of the numerical method by assessing the scheme for underresolved simulations (implicit large-eddy simulation) of the higher Reynolds number in a detailed h/p convergence study.  相似文献   

7.
In this paper we study the limit as \(\varepsilon \rightarrow 0\) of the singularly perturbed second order equation \(\varepsilon ^2 \ddot{u}_\varepsilon + \nabla _{\!x} V(t,u_\varepsilon (t))=0\), where V(tx) is a potential. We assume that \(u_0(t)\) is one of its equilibrium points such that \(\nabla _{\!x}V(t,u_0(t))=0\) and \(\nabla _{\!x}^2V(t,u_0(t))>0\). We find that, under suitable initial data, the solutions \(u_\varepsilon \) converge uniformly to \(u_0\), by imposing mild hypotheses on V. A counterexample shows that they cannot be weakened.  相似文献   

8.
9.
Consider a weakly nonlinear CGL equation on the torus \(\mathbb {T}^d\):
$$\begin{aligned} u_t+i\Delta u=\epsilon [\mu (-1)^{m-1}\Delta ^{m} u+b|u|^{2p}u+ ic|u|^{2q}u]. \end{aligned}$$
(*)
Here \(u=u(t,x)\), \(x\in \mathbb {T}^d\), \(0<\epsilon <<1\), \(\mu \geqslant 0\), \(b,c\in \mathbb {R}\) and \(m,p,q\in \mathbb {N}\). Define \(I(u)=(I_{\mathbf {k}},\mathbf {k}\in \mathbb {Z}^d)\), where \(I_{\mathbf {k}}=v_{\mathbf {k}}\bar{v}_{\mathbf {k}}/2\) and \(v_{\mathbf {k}}\), \(\mathbf {k}\in \mathbb {Z}^d\), are the Fourier coefficients of the function \(u\) we give. Assume that the equation \((*)\) is well posed on time intervals of order \(\epsilon ^{-1}\) and its solutions have there a-priori bounds, independent of the small parameter. Let \(u(t,x)\) solve the equation \((*)\). If \(\epsilon \) is small enough, then for \(t\lesssim {\epsilon ^{-1}}\), the quantity \(I(u(t,x))\) can be well described by solutions of an effective equation:
$$\begin{aligned} u_t=\epsilon [\mu (-1)^{m-1}\Delta ^m u+ F(u)], \end{aligned}$$
where the term \(F(u)\) can be constructed through a kind of resonant averaging of the nonlinearity \(b|u|^{2p}+ ic|u|^{2q}u\).
  相似文献   

10.
The influence of transverse concentration gradients on detonation propagation in \(\hbox {H}_2\)–air mixtures is investigated experimentally in a wide parameter range. Detonation fronts are characterized by means of high-speed shadowgraphy, OH* imaging, pressure measurements, and soot foils. Steep concentration gradients at low average \(\hbox {H}_2\) concentrations lead to single-headed detonations. A maximum velocity deficit compared to the Chapman–Jouguet velocity of 9 % is observed. Significant amounts of mixture seem to be consumed by turbulent deflagration behind the leading detonation. Wall pressure measurements show high local pressure peaks due to strong transverse waves caused by the concentration gradients. Higher average \(\hbox {H}_2\) concentrations or weaker gradients allow for multi-headed detonation propagation.  相似文献   

11.
We deal with one dimensional p-Laplace equation of the form
$$\begin{aligned} u_t = (|u_x|^{p-2} u_x )_x + f(x,u), \ x\in (0,l), \ t>0, \end{aligned}$$
under Dirichlet boundary condition, where \(p>2\) and \(f:[0,l]\times {\mathbb {R}}\rightarrow {\mathbb {R}}\) is a continuous function with \(f(x,0)=0\). We will prove that if there is at least one eigenvalue of the p-Laplace operator between \(\lim _{u\rightarrow 0} f(x,u)/|u|^{p-2}u\) and \(\lim _{|u|\rightarrow +\infty } f(x,u)/|u|^{p-2}u\), then there exists a nontrivial stationary solution. Moreover we show the existence of a connecting orbit between stationary solutions. The results are based on Conley index and detect stationary states even when those based on fixed point theory do not apply. In order to compute the Conley index for nonlinear semiflows deformation along p is used.
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12.
A spatially two-dimensional sixth order PDE describing the evolution of a growing crystalline surface h(xyt) that undergoes faceting is considered with periodic boundary conditions, as well as its reduced one-dimensional version. These equations are expressed in terms of the slopes \(u_1=h_{x}\) and \(u_2=h_y\) to establish the existence of global, connected attractors for both equations. Since unique solutions are guaranteed for initial conditions in \(\dot{H}^2_{per}\), we consider the solution operator \(S(t): \dot{H}^2_{per} \rightarrow \dot{H}^2_{per}\), to gain our results. We prove the necessary continuity, dissipation and compactness properties.  相似文献   

13.
Let \({S\subset\mathbb{R}^2}\) be a bounded Lipschitz domain and denote by \({W^{2,2}_{\text{iso}}(S; \mathbb{R}^3)}\) the set of mappings \({u\in W^{2,2}(S;\mathbb{R}^3)}\) which satisfy \({(\nabla u)^T(\nabla u) = Id}\) almost everywhere. Under an additional regularity condition on the boundary \({\partial S}\) (which is satisfied if \({\partial S}\) is piecewise continuously differentiable), we prove that the strong W 2,2 closure of \({W^{2,2}_{\text{iso}}(S; \mathbb{R}^3)\cap C^{\infty}(\overline{S};\mathbb{R}^3)}\) agrees with \({W^{2,2}_{\text{iso}}(S; \mathbb{R}^3)}\).  相似文献   

14.
Hong  Qinghui  Xie  Qingguo  Xiao  Peng 《Nonlinear dynamics》2017,90(2):1015-1033
Attention is focused in this work on quasiperiodic motion of nonlinear systems whose spectrum contains uniformly spaced sideband frequencies with a distance \(\omega _{d}\) apart, around a frequency \(\omega \) with \(\omega \gg \omega _{d}\) and its integer multiples, which are referred to as carrier frequencies. The ratio of the two frequencies \(\omega \) and \(\omega _{d}\) is an irrational number. A new method based on the traditional incremental harmonic balance (IHB) method with multiple timescales, referred to as Lau method, where two timescales, \(\tau _{1}=\omega t\) (a fast timescale) and \(\tau _{2}=\omega _{d}t\) (a slow timescale), are introduced, is presented to analyze quasiperiodic motion of nonlinear systems. An amplitude increment algorithm is adapted to deal with cases where the two frequencies \(\omega \) and \(\omega _{d}\) are    unknown a priori, in order to automatically trace frequency response of quasiperiodic motion of nonlinear systems and accurately calculate all frequency components and their corresponding amplitudes. Results of application of the present IHB method to quasiperiodic free vibration of a hinged–clamped beam with internal resonance between two transverse modes are shown and compared with previously published results with Lau method and those from numerical integration. While differences are noted between results predicted by the present IHB method and Lau method, excellent agreement is achieved between results from the present IHB method and numerical integration even in cases of strongly nonlinear vibration. The present IHB method is also used to analyze quasiperiodic free vibration of high-dimensional models of the hinged–clamped beam.  相似文献   

15.
This study investigated the dynamic displacement and dissolution of \(\hbox {CO}_{2}\) in porous media at 313 K and 6/8 MPa. Gaseous (\(\hbox {gCO}_{2}\)) at 6 MPa and supercritical \(\hbox {CO}_{2 }(\hbox {scCO}_{2}) \) at 8 MPa were injected downward into a glass bead pack at different flow rates, following upwards brine injection. The processes occurring during \(\hbox {CO}_{2}\) drainage and brine imbibition were visualized using magnetic resonance imaging. The drainage flow fronts were strongly influenced by the flow rates, resulting in different gas distributions. However, brine imbibition proceeded as a vertical compacted front due to the strong effect of gravity. Additionally, the effects of flow rate on distribution and saturation were analyzed. Then, the front movement of \(\hbox {CO}_{2}\) dissolution was visualized along different paths after imbibition. The determined \(\hbox {CO}_{2}\) concentrations implied that little \(\hbox {scCO}_{2}\) dissolved in brine after imbibition. The dissolution rate was from \(10^{-8}\) to \(10^{-9}\, \hbox {kg}\, \hbox {m}^{-3} \, \hbox {s}^{-1}\) and from \(10^{-6}\) to \(10^{-8}\, \hbox {kg}\, \hbox {m}^{-3} \, \hbox {s}^{-1}\) for \(\hbox {gCO}_{2}\) at 6 MPa and \(\hbox {scCO}_{2 }\) at 8 MPa, respectively. The total time for the \(\hbox {scCO}_{2}\) dissolution was short, indicating fast mass transfer between the \(\hbox {CO}_{2}\) and brine. Injection of \(\hbox {CO}_{2}\) under supercritical conditions resulted in a quick establishment of a steady state with high storage safety.  相似文献   

16.
In this paper, we consider the perturbed KdV equation with Fourier multiplier
$$\begin{aligned} u_{t} =- u_{xxx} + \big (M_{\xi }u+u^3 \big )_{x},\quad u(t,x+2\pi )=u(t,x),\quad \int _0^{2\pi }u(t,x)dx=0, \end{aligned}$$
with analytic data of size \(\varepsilon \). We prove that the equation admits a Whitney smooth family of small amplitude, real analytic quasi-periodic solutions with \(\tilde{J}\) Diophantine frequencies, where the order of \(\tilde{J}\) is \(O(\frac{1}{\varepsilon })\). The proof is based on a conserved quantity \(\int _0^{2\pi } u^2 dx\), Töplitz–Lipschitz property and an abstract infinite dimensional KAM theorem. By taking advantage of the conserved quantity \(\int _0^{2\pi } u^2 dx\) and Töplitz–Lipschitz property, our normal form part is independent of angle variables in spite of the unbounded perturbation.
  相似文献   

17.
Conditions guaranteeing asymptotic stability for the differential equation
$$\begin{aligned} x''+h(t)x'+\omega ^2x=0 \qquad (x\in \mathbb {R}) \end{aligned}$$
are studied, where the damping coefficient \(h:[0,\infty )\rightarrow [0,\infty )\) is a locally integrable function, and the frequency \(\omega >0\) is constant. Our conditions need neither the requirement \(h(t)\le \overline{h}<\infty \) (\(t\in [0,\infty )\); \(\overline{h}\) is constant) (“small damping”), nor \(0< \underline{h}\le h(t)\) (\(t\in [0,\infty )\); \(\underline{h}\) is constant) (“large damping”); in other words, they can be applied to the general case \(0\le h(t)<\infty \) (\(t\in [0,\infty \))). We establish a condition which combines weak integral positivity with Smith’s growth condition
$$\begin{aligned} \int ^\infty _0 \exp [-H(t)]\int _0^t \exp [H(s)]\,\mathrm{{d}}s\,\mathrm{{d}}t=\infty \qquad \left( H(t):=\int _0^t h(\tau )\,\mathrm{{d}}\tau \right) , \end{aligned}$$
so it is able to control both the small and the large values of the damping coefficient simultaneously.
  相似文献   

18.
In this paper we focused our study on derived from Anosov diffeomorphisms (DA diffeomorphisms ) of the torus \(\mathbb {T}^3,\) it is, an absolute partially hyperbolic diffeomorphism on \(\mathbb {T}^3\) homotopic to a linear Anosov automorphism of the \(\mathbb {T}^3.\) We can prove that if \(f: \mathbb {T}^3 \rightarrow \mathbb {T}^3 \) is a volume preserving DA diffeomorphism homotopic to a linear Anosov A,  such that the center Lyapunov exponent satisfies \(\lambda ^c_f(x) > \lambda ^c_A > 0,\) with x belongs to a positive volume set, then the center foliation of f is non absolutely continuous. We construct a new open class U of non Anosov and volume preserving DA diffeomorphisms, satisfying the property \(\lambda ^c_f(x) > \lambda ^c_A > 0\) for \(m-\)almost everywhere \(x \in \mathbb {T}^3.\) Particularly for every \(f \in U,\) the center foliation of f is non absolutely continuous.  相似文献   

19.
The dynamic stall problem for blades is related to the general performance of wind turbines, where a varying flow field is introduced with a rapid change of the effective angle of attack (AOA). The objective of this work is to study the aerodynamic performance of a sinusoidally oscillating NACA0012 airfoil. The coupled \(k{-}\omega \) Menter’s shear stress transport (SST) turbulence model and \(\gamma {-}Re_{\uptheta }\) transition model were used for turbulence closure. Lagrangian coherent structures (LCS) were utilized to analyze the dynamic behavior of the flow structures. The computational results were supported by the experiments. The results indicated that this numerical method can well describe the dynamic stall process. For the case with reduced frequency \(K = 0.1\), the lift and drag coefficients increase constantly with increasing angle prior to dynamic stall. When the AOA reaches the stall angle, the lift and drag coefficients decline suddenly due to the interplay between the first leading- and trailing-edge vortex. With further increase of the AOA, both the lift and drag coefficients experience a secondary rise and fall process because of formation and shedding of the secondary vortex. The results also reveal that the dynamic behavior of the flow structures can be effectively identified using the finite-time Lyapunov exponent (FTLE) field. The influence of the reduced frequency on the flow structures and energy extraction efficiency in the dynamic stall process is further discussed. When the reduced frequency increases, the dynamic stall is delayed and the total energy extraction efficiency is enhanced. With \(K = 0.05\), the amplitude of the dynamic coefficients fluctuates more significantly in the poststall process than in the case of \(K = 0.1\).  相似文献   

20.
A large number (1253) of high-quality streaming potential coefficient (\(C_\mathrm{sp})\) measurements have been carried out on Berea, Boise, Fontainebleau, and Lochaline sandstones (the latter two including both detrital and authigenic overgrowth forms), as a function of pore fluid salinity (\(C_\mathrm{f})\) and rock microstructure. All samples were saturated with fully equilibrated aqueous solutions of NaCl (10\(^{-5}\) and 4.5 mol/dm\(^{3})\) upon which accurate measurements of their electrical conductivity and pH were taken. These \(C_\mathrm{sp}\) measurements represent about a fivefold increase in streaming potential data available in the literature, are consistent with the pre-existing 266 measurements, and have lower experimental uncertainties. The \(C_\mathrm{sp}\) measurements follow a pH-sensitive power law behaviour with respect to \(C_\mathrm{f}\) at medium salinities (\(C_\mathrm{sp} =-\,1.44\times 10^{-9} C_\mathrm{f}^{-\,1.127} \), units: V/Pa and mol/dm\(^{3})\) and show the effect of rock microstructure on the low salinity \(C_\mathrm{sp}\) clearly, producing a smaller decrease in \(C_\mathrm{sp}\) per decade reduction in \(C_\mathrm{f}\) for samples with (i) lower porosity, (ii) larger cementation exponents, (iii) smaller grain sizes (and hence pore and pore throat sizes), and (iv) larger surface conduction. The \(C_\mathrm{sp}\) measurements include 313 made at \(C_\mathrm{f} > 1\) mol/dm\(^{3}\), which confirm the limiting high salinity \(C_\mathrm{sp}\) behaviour noted by Vinogradov et al., which has been ascribed to the attainment of maximum charge density in the electrical double layer occurring when the Debye length approximates to the size of the hydrated metal ion. The zeta potential (\(\zeta \)) was calculated from each \(C_\mathrm{sp}\) measurement. It was found that \(\zeta \) is highly sensitive to pH but not sensitive to rock microstructure. It exhibits a pH-dependent logarithmic behaviour with respect to \(C_\mathrm{f}\) at low to medium salinities (\(\zeta =0.01133 \log _{10} \left( {C_\mathrm{f} } \right) +0.003505\), units: V and mol/dm\(^{3})\) and a limiting zeta potential (zeta potential offset) at high salinities of \({\zeta }_\mathrm{o} = -\,17.36\pm 5.11\) mV in the pH range 6–8, which is also pH dependent. The sensitivity of both \(C_\mathrm{sp}\) and \(\zeta \) to pH and of \(C_\mathrm{sp}\) to rock microstructure indicates that \(C_\mathrm{sp}\) and \(\zeta \) measurements can only be interpreted together with accurate and equilibrated measurements of pore fluid conductivity and pH and supporting microstructural and surface conduction measurements for each sample.  相似文献   

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