HGZ－Ⅱ型自动辉光放电光源的研制

在仔细研辉光放电光源工作过程的基础上，在国内首先设计、制成了ＨＧＺ－Ⅱ型自动辉光放电光源。该光源除换样品外，实现了抽空、进气、对光、预燃、曝光、充气、复位等摄谱全过程的自动控制。有水压、真空度、短路保护措施和醒铃线路。设计合理，性能良好，操作简便，工作安全，可靠。程控部分的编排包括顺序控制。时序控制和条件控制。由于使用了通用执行元、器件，降低了成本，提高了耐用性。为满足表层，逐层分析的需要，还专门设计了计数电路。供电源实现了高压直流供电和脉冲供电。该光源可应用于合金中主成分和少量杂质分析及金属、合金表层，逐层成分分析。     

基于OBE和EHS理念的制药过程安全与环保课程体系建设

“制药过程安全与环保”为制药工程专业本科生必修核心课程，但其课程体系不完善，基于OBE和EHS理念，从课程目标、课程内容、课程思政、教材、教学方法、课程考核与评价方法等方面对该课程进行了建设和完善，取得了一些创新性成果与经验，制定了教学目标，创新性地设置了课程内容，开展了课程思政，主编了教材，提出了适宜的教学方法，建立了课程考核与评价方法，可以为全国其他高等院校类似课程的教学与建设提供有益的借鉴。     

HGZ—Ⅱ型自动辉光放电光源的研制

在仔细研辉光放电光源工作过程的基础上，在国内首先设计，制成了ＨＧＺ－Ⅱ型自动辉光放电光源。该光源除换样品外，实现抽空、进气、对光、预燃、曝光、充气、复位等摄谱全过程的自动控制。有水压、真空度、短路保护措施施和醒铃线路。设计合理，性能良好，操作简便，工作安全，可靠。程控部分的编排包括顺序控制。时序控制和条件控制。由于使用通用执行元、器件，降低了成本，提高了耐用性。为满足表层，逐层分析的需要，还专门设     

植物样品中单宁的微波溶出快速测定法研究

研究了利用微波代替一般的沸水浴处理试样的方法。对不同植物样品中单宁的浸提测定，与常规方法做了对照，并讨论了微波功率、时间、酸度等因素对测定结果的影响。研究表明，此法可大大地缩短测定时间，提高测定效率，节省人力、物力，不污染环境，便于大批量样品的测定，相对标准偏差≤１．４％，测定结果较为满意。为植物样品中单宁的测定，提供了一个快速、简便、准确的分析方法，并可借鉴于其它样品的测定。     

银基微电极方波伏安法测定矿样中痕量铅镉

研究了银基质微电极的伏安特性，经与玻碳电极比较，具有灵敏度高、重现性好、分辨率强、线性范围宽、使用寿命长等优点。并克服了宏观电极的某些缺点，消除了充电电流的影响，基线平稳，峰形清晰。     

19世纪化学界一颗闪闪发光的明星——纪念著名化学家本生逝世100周年

１９世纪以来，一直处于封建割据状态的德国，经过一系列政治、经济、教育体制的改革，提高了国民科学文化素质，加速了国家工业化进程。一批批学者纷纷到英、法等先进国家留学或进行学术访问，积极学习外国先进的科学技术，逐步实现了大学、实验室和工厂企业一体化的循环加速发展机制，使德国很快在钢铁、煤炭、机械、纺织、合成染料和药物等方面成为世界头号强国。先进的教学科研体制，优越的科研条件以及一系列奖励措施，大大调动了各行各业科学研究人员的积极性和创造精神，培养了一大批世界一流的科学家、高素质的企业家和工程师，为德…     

3—巯基—2—丁醇合成方法的改进及其异构体组成的分析鉴定

以丁酮、氨、硫为原料，通过综合反应合成２，４，５－三甲基－２－乙基噻唑淋－△＾３，再经水解、还原共三步反应合成了３－巯基－２－丁醇。考察反应温度、催化剂、时间等因素对反应的影响，确定了优化条件：在３５℃进行缩合反应，以磷酸作为催化剂在３５℃下水解４ｈ，以ＫＢＨ４作为还原剂在２５℃下还原。简化了操作，缩短了反应时间，降低了成本，收率达５４％。通过ＧＣ，ＧＣ－ＭＳ，＾１ＨＮＭＲ等手段确定了产品的组成及     

杂多酸催化合成淀粉聚醚多元醇及其反应中间体稳定性

采用可溶性固体杂多酸做均相反应催化剂，两步反应使用一种催化剂，在中温、常压条件下，合成了产率较高的符合工业技术指标的淀粉聚醚多元醇，而且催化剂能得到95％以上的回收，简化了工艺过程，提高了产品质量，降低了成本，用元素分析、IR、^1HNMR和羟值的测定确定了产物的组成和相对分子质量，对中试实验进行了初步探索，得出最佳合成条件。     

环境监测现状

目前，全国已形成了国家、省、市、县四级环境监测网络，共有专业、行业监测站4800多个，其中环保系统监测站2200多个，行业监测站2600多个，国控的空气质量监测网站103个，酸雨监测网站113个，水质监测网站135个。同时，还建有噪声监测网、辐射监测网和区域监测网等。到2005年，国控环境监测网络调整为：环境空气监测网站226个，测点数793个；酸雨监测网站239个，测点数472个；水质监测网站197个；监测断面1074个；生态监测网站15个。目前，我国已制定各类国家环境标准410项，覆盖了大气、水质、土壤、噪声、辐射、农药等领域。开展了环境质量监测，     

无机微孔材料磷酸镍的合成与表征

在水热条件下，合成了三种新型磷酸镍无机微孔材料，通过ICP、CHN元素分析、EDX确定了成分，对其进行了红外光谱、XRD粉末衍射结构表征，用SEM观察了它们的形貌，通过TG-DTA和TG-DSC分析了它们的热稳定性。     

N-去甲万古霉素的亲和吸附

通过交联聚丙烯酸甲酯与乙醇胺反应,形成聚(N-羟乙基丙烯酰胺)树脂,在酸催化作用下与环氧氯丙烷反应,形成含有α-羟基氯乙基的树脂.含α-羟基氯乙基的树脂与D-丙氨酸、L-丙氨酸或甘氨酸反应,分别得到含有这3种氨基酸的吸附剂.这3种吸附剂吸附N-去甲万古霉素的结果表明,含D-丙氨酸的吸附剂的吸附量最大,含甘氨酸的吸附剂的吸附量次之,而含L-丙氨酸的吸附剂不吸附N-去万古霉素.说明前两种吸附剂对N-去甲万古霉素存在亲和吸附作用.含D-丙氨酸吸附剂的最佳吸附pH值为5.8,当吸附液中的盐(NaCl)浓度增加时,吸附量降低.用0.4mol/LNa₂CO₃/CH₃CN(摩尔比7∶3,pH=9.5)作为洗脱剂可完全脱附被吸附的N-去甲万古霉素.     

合成聚芳酯树状分子的新方法

以３，５－二羟基 苯甲酸为起始原料，经甲醇酯化保护羧基，与苯甲酰氯反应，得到３，５－二苯甲酰氧基苯甲酸甲酯用ＡｌＣｌ３．ＮａＩ去掉保护基甲基，以高收率得到３，５－二苯甲酰氧基苯甲酸。其结构均是由ＩＲ，＾１ＨＮＭＲ，ＥＡ等方法证实。     

Partitioning and adsorption in gas-liquid-solid chromatography: Models of temporal moments for retention and variance

Summary The resolution of gaseous chemical species in gasliquid-solid chromatography is influenced by absorption (partitioning) in the liquid and adsorption at the liquid-solid interface. We consider fundamental mass transfer models with adsorption and partitioning effects for solid chromatographic supports covered with thin films of stationary liquid. The dynamic models, based on mass-balance partial-differential equations, include the significant phenomena: convection, axial dispersion, gas-liquid mass transfer, intraparticle diffusion, and liquid-solid adsorption. Expressions for retention time and band variance (first and second temporal moments) are presented and evaluated for four distinct models: (1) capillary tube with inner surface covered with a uniform-thickness liquid film, (2) column of nonporous spheres covered with a uniform-thickness liquid film, (3) porous spherical particles with intraparticle pores covered with a uniform-thickness liquid film, (4) porous spherical particles with intraparticle pores completely filled with liquid.     

表面等离子体子共振传感器用于研究不同材质包裹的磁性纳米粒子性质

利用自行设计组装的以白色发光二极管为光源的表面等离子体子共振传感器实验装置, 检测了不同材质包裹的磁性纳米粒子连接靶向DNA与生物素化DNA探针的结合程度. 结果表明, 与聚苯乙烯磁性微球连接的靶向DNA相比, Fe3O4@SiO2核壳式纳米微球连接的靶向DNA与生物素化的DNA探针结合速率较快, 且其相对标准偏差较小.     

Synthesis and copolymerization of new phosphorus‐containing acrylates

Two phosphorus‐containing acrylate monomers were synthesized from the reaction of ethyl α‐chloromethyl acrylate and t‐butyl α‐bromomethyl acrylate with triethyl phosphite. The selective hydrolysis of the ethyl ester monomer with trimethylsilyl bromide (TMSBr) gave a phosphonic acid monomer. The attempted bulk polymerizations of the monomers at 57–60 °C with 2,2′‐azobisisobutyronitrile (AIBN) were unsuccessful; however, the monomers were copolymerized with methyl methacrylate (MMA) in bulk at 60 °C with AIBN. The resulting copolymers produced chars on burning, showing potential as flame‐retardant materials. Additionally, α‐(chloromethyl)acryloyl chloride (CMAC) was reacted with diethyl (hydroxymethyl)phosphonate to obtain a new monomer with identical ester and ether moieties. This monomer was hydrolyzed with TMSBr, homopolymerized, and copolymerized with MMA. The thermal stabilities of the copolymers increased with increasing amounts of the phosphonate monomer in the copolymers. A new route to highly reactive phosphorus‐containing acrylate monomers was developed. A new derivative of CMAC with mixed ester and ether groups was synthesized by substitution, first with diethyl (hydroxymethyl)phosphonate and then with sodium acetate. This monomer showed the highest reactivity and gave a crosslinked polymer. The incorporation of an ester group increased the rate of polymerization. The relative reactivities of the synthesized monomers in photopolymerizations were determined and compared with those of the other phosphorous‐containing acrylate monomers. Changing the monomer structure allowed control of the polymerization reactivity so that new phosphorus‐containing polymers with desirable properties could be obtained. © 2003 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 41: 2207–2217, 2003     

稀土奥贝蠕铁制取工艺及其性能的研究

稀土奥贝蠕铁可用含稀土的蠕化剂及等温淬火工艺稳定地制取,藉助高温扫描电子显微镜,观察并研究了稀土蠕铁奥氏体化过程及稀土奥贝蠕铁随温度升高时组织的变化。用带有加热装置的万能材料试验等土奥贝蠕铁的各种性能进行了系统测定了如抗拉强度、延伸率、冲吉韧性、热膨胀系数及伸长百分率,结果表明,稀土奥贝蠕铁在室温和高温下均有良好的性能。     

Selection of anion exchangers for detoxification of dilute-acid hydrolysates from spruce

Six anion-exchange resins with different properties were compared with respect to detoxification of a dilute-acid hydrolysate of spruce prior to ethanolic fermentation with Saccharomyces cerevisiae. The six resins encompassed strong and weak functional groups as well as styrene-, phenol-, and acrylic-based matrices. In an analytical experimental series, fractions from columns packed with the different resins were analyzed regarding pH, glucose, furfural, hydroxymethylfurfural, phenolic compounds, levulinic acid, acetic acid, formic acid, and sulfate. An initial adsorption of glucose occurred in the strong alkaline environment and led to glucose accumulation at a later stage. Acetic and levulinic acid passed through the column before formic acid, whereas sulfate had the strongest affinity. In a preparative experimental series, one fraction from each of six columns packed with the different resins was collected for assay of the fermentability and analysis of glucose, mannose, and fermentation inhibitors. The fractions collected from strong anion-exchange resins with styrene-based matrices displayed the best fermentability: a sevenfold enhancement of ethanol productivity compared with untreated hydrolysate. Fractions from a strong anion exchanger with acrylic-based matrix and a weak exchanger with phenol-based resin displayed an intermediate improvement in fermentability, a four- to fivefold increase in ethanol productivity. The fractions from two weak exchangers with styrene- and acrylic-based matrices displayed a twofold increase in ethanol productivity. Phenolic compounds were more efficiently removed by resins with styrene-and phenol-based matrices than by resins with acrylic-based matrices.     

芳香硝基化合物还原制备芳胺的研究进展

综述了芳香硝基化合物还原制备芳胺的方法及近年的研究进展.其方法主要包括催化氢化法、CO/H2O还原法、金属还原法、硫化碱还原法、金属氢化物还原法、电化学还原法和光化学还原法.其中催化氢化法中的氢气还原法和水合肼还原法符合绿色化学的理念,并且反应收率高,选择性好,具有很高的应用价值.     

Synthesis of branched copolysilanes from trichlorosilanes

Soluble polymers and copolymers have been prepared from monosubstituted trichlorosilanes via thermal reductive coupling with sodium in toluene. Phenyltrichlorosilane has been copolymerized with methylphenyl dichlorosilane, with n-hexyltrichlorosilane, with tetrachlorosilane and with tetrakis(chlorodimethylsilyl)silane. n-Hexyltrichlorosilane has been copolymerized with methylphenyldichlorosilane, with phenyltrichlorosilane and with silicon tetrachloride. Soluble polymers and copolymers with molecular weight in the range ≈ 2,000 to ≈ 10⁶ have been obtained. The absorption and emission spectra of the resulting polymers are strongly affected by the presence of trisilyl- and tetrasilylsubstituted silicon atoms. © 1995 John Wiley & Sons, Inc.     

微量元素变化对反复呼吸道感染的影响

检测了240例反复呼吸道感染患儿血微量元素含量。结果表明,反复呼吸道感染患儿血锌、铁、钙低于正常对照组(P<0.01);血铅高于正常对照组(P<0.01);血铜、镁两组相当,差异不显著(P<0.05)。提示反复呼吸道感染患儿体内存在锌、铁、钙元素缺乏及铅含量升高。