两原子与双模腔场喇曼相互作用(g1≠g2)的辐射谱

研究了两个有效双能级原子与双模腔场具有不同耦合常数(g₁≠g₂)时通过喇曼相互作用的辐射谱,详细讨论了双模腔场分别处于不同数态时的情形,发现其辐射谱具有如下新特点:当模1腔场处于真空态,模2腔场处于弱场中时,随着R=g₂/g₁的增加,辐射谱交替出现对称的10峰、6峰结构,与单模双原子情形相比较,更为灵敏地反映出两原子与腔场间不同的喇曼相互作用强度;当模1腔场处于真空态、模2腔场处于强场中时,0相似文献   

非简并拉曼过程中交流斯塔克位移对腔场谱的影响

研究了原子与双模光场非简并拉曼耦合过程中交流斯塔克位移对腔场谱的影响.给出了原子处于基态且双模初始场为光子数态、相干态和压缩真空态时光谱结构的数值结果.发现数态光场在弱场条件下每模腔场谱都是三峰结构，在强场条件下则为双峰或单峰结构，相干态和压缩真空态光场的腔场谱在弱场或强场条件下都是双峰结构.随着斯塔克位移参数的变化,双峰的高度此长彼消. 关键词： 交流斯塔克位移 非简并拉曼过程 腔场谱     

119Sn Mössbauer study of the CePtSn Kondo compound

We have measured¹¹⁹Sn Mössbauer spectra of the CePtSn and (Ce_0.9La_0.1)NiSn compounds in the range from 1.5 to 293 K. In CePtSn, the spectra observed above 8 K are well explained by an electric quadrupole interaction. The spectral shape changes below 8 K due to the presence of a magnetic hyperfine field produced by the ordering of the Ce magnetic moments. We have analyzed these spectra assuming an incommensurate magnetic structure. The temperature dependence of the magnetic hyperfine field matches with anS=1/2 mean field curve with a step at 5 K. In (Ce_0.9La_0.1)NiSn, no magnetic order exists down to 1.5 K.     

Optical investigations of Mn2+ ion in Cs2CdCl4 and CsCaCl3 single crystals

Summary Polarized absorption, emission and excitation spectra of Cs₂CdCl₄∶Mn²⁺ and emission as well as excitation spectra of CsCaCl₃∶Mn²⁺ single crystals at temperatures down to 77 K are reported. The general features of the spectra are fruitfully analysed within the framework of the strong field scheme of Tanabe and Sugano including Trees' correction. Some finer structure of the crystal field independent levels are observed which are rationalized in terms of vibrational mechanism. A detailed analysis of the spectra indicates octahedral site symmetry around the central metal ion. The authors of this paper have agreed to not receive the proofs for correction.     

Optical absorption spectra of some transition metal thiophosphates

Near-infrared and visible absorption spectra at room temperature of MnPS₃, CoPS₃, CoPS₃ are reported. These materials show weak structures below their fundamental absorption thresholds, due to the 3d-3d transitions occurring on the transition metal ion. By comparison with other transition metal compounds, such excitations are interpreted on the basis of the ligand field theory. The appearance of well developed crystal field spectra is a further confirmation that these materials are considerably ionic.     

Electromodulation spectroscopy of excitons: High field regime

The effects of electric field on excitons have been investigated experimentally by means of electroabsorption (EA). The behavior of excitons with ionization fields F_I of the same order of magnitude as or smaller than typical applied fields is reported. EA spectra associated with excitons in TlBr, PbI₂, BiI₃, trigonal Se, and α-monoclinic Se will illustrate this case. In this situation the EA signal arises principally from the effect on the exciton ground state, and no finer structure could be detected. The exciton ground state undergoes a shift to higher energies with the applied field. Characteristic dependences with field of the sizes, energy position of the peaks, and zero crossing points of the EA signals have been found. Estimates of exciton parameters can be readily obtained from the EA spectra. Unusual features of the exciton EA spectra PbI₂ are discussed. Qualitatively, at least, theoretical predictions are obeyed.     

Laser probes of intramolecular energy transfer between internal rotation and vibrations in large polyatomics

Laser excited S₁→S₀ fluorescence spectra are obtained from p-fluorotoluene in a supersonic jet in order to probe internal rotational-vibrational coupling. Resolved fluorescence spectra after selective excitation of S₁ levels with high quanta states of the CH₃ internal rotation contain evidence of extensive interactions with isoenergetic vibrational levels. Analogous spectra from states without excitation of the internal rotor show little or no interactions. The results are consistent with a recently developed theory of the intramolecular collisional transfer of rotor energy to the vibrational field.     

Mixed hyperfine interactions and defect structure in magnesiowüstite Fe−Mg−O

An analysis of the 4.2 K spectra of Fe_xO (x∼0.91) and (Fe_0.4Mg_0.6)_xO is presented in which it is considered that because of the large electric field gradient at Fe²⁺ defect sites, the spectra cannot be described by Lorentzian sextets. It is assumed that the magnetic hyperfine field vector is oriented at random in the coordinate system defined by the EFG main axis, and that the EFG coordinate system is also distributed randomly. The simplifying assumption of the asymmetry parameter η=0 allows an analytical formula to be used to describe the complex spectra. Distributions of both magnetic hyperfine field and quadrupole interaction were progressively refined resulting in reasonable fits to the spectra with the main features being well reproduced. The magnetic hyperfine field distribution is rather broad with several features present while distinct values were obtained in the distribution of quadrupole interactions. These latter values are considered to correspond to the defect configurations around the Fe²⁺ sites. The distribution of hyperfine fields is considered to reflect the varying strengths of superexchange due to the high defect concentration as well as the effects of magnetic relaxation.     

微带阵列天线的时域散射特性

本文用时域有限差分方法(FDTD)研究了微带阵列天线的时域散射场,分析了入射脉冲极化方向不同以及入射方向不同时的散射场的分布情况;讨论了时域散射场的时域波形以及频谱与微带阵列天线结构的关系;用散射场分离算法讨论了地板对于微带贴片阵列散射场的影响.研究发现,有限大地板的微带阵列天线的散射场主要是由地板的边沿电流产生的,同时微带贴片阵列的谐振频率与入射脉冲的极化方向有关,因此不同的极化方向对应于不同的散射频谱. 关键词： 时域散射 微带天线 FDTD     

The properties of the nonequilibrium LaB6 surface resulting from field evaporation

The nonequilibrium surface of single-crystal lanthanum hexaboride needles and its modifications are studied with a time-of-flight atomic probe. The surface is obtained by room-temperature field evaporation. The mass spectra of field evaporation shed light on the surface composition at the needle tip immediately after tip etching, corrosion in residual gases, intense cleaning by field evaporation, and the relaxation of the nonequilibrium surface by heating to 1250 K. Conditions for the breakdown of an oxide film on the tip surface and for obtaining the mass spectra of field evaporation for stoichiometric or lanthanum-enriched pure LaB₆ single crystals are discussed.     

Investigation of amorphous and crystalline Sc3Fe alloys

Amorphous Sc₃Fe alloy has been prepared by splat-cooling with levitation melting. The quadrupole splitting distributions for Sc₃Fe were determined from Mössbauer spectra: the zero-field distribution has a Gaussian form. The analysis of Mössbauer spectra taken in applied magnetic field show that both positive and negative signs of principal component (V_z2) of electrical field gradients (EFG) are present. The crystallization process has also been investigated. Heat treatment of the amorphous alloys causes crystallization first into a metastable, and then into the stable phase.     

Hyperfine interactions and site population in the spinel compounds Ca x Co1−x Fe2O4

Mössbauer spectra of the spinel series Ca _x Co_1–x Fe₂O₄, withx=0.0, 0.05 and 0.10, have been collected between 80 and 300 K and in an applied field of 6 T at 4.2 K. From the shape-independent hyperfine field distribution fits of the external field spectra, and from the binomial distribution fits of the temperature-dependent spectra, the hyperfine field and the center shift could be unambiguously assigned to octahedrally and tetrahedrally coordinated ferric ions. The importance of the application of an external field in conjunction with a reasonable physical model to obtain a correct assignment of hyperfine parameters to a specific site is demonstrated.     

Dispersion properties of cyclotron waves in periodic semiconductor-insulator structures

The band spectrum of cyclotron waves propagating in a periodic layered semiconductor-insulator structure at an angle to an external magnetic field that is applied perpendicularly to the layers is calculated for two relationships between the characteristic frequencies of the semiconductor: ω_H>ω_P and ω_H<ω_P. The wave field distributions across the layers and over the period of the structure are analyzed. In both spectra, transmission bands arise when the conditions for dimensional resonance across the semiconductor layer are fulfilled. The graphic solution of the dispersion relation demonstrates that the cyclotron wave spectrum can be subdivided into two spectra of normal waves according to the Bloch wavenumbers of the periodic structure. The cases where the band spectra complement each other or overlap are considered.     

Radio-frequency Mössbauer spectra of the “easy”-plane type magnetic system (FeBO3)

The theory of formation of the RF Mössbauer spectra for the “easy”-plane type magnetics (FeBO₃) and for various types of RF field polarization is presented. Experiments using both linearly and circularly polarized external RF fields were carried out at different temperatures. At room temperature the experimental spectra for both cases are well described by switching hyperfine (hf) field model. At temperatures close to the Neel temperature (335 K), the spectra in the oscillating and rotating RF field were obtained and their forms are described by models of switching and rotating hf field, respectively.     

X-ray absorption near edge structure (XANES) for KCl

The cluster calculations of K and L_2,3 edge XANES of K and Cl in KCl within the multiple scattering theory formalism using nonlocal HF potentials with abd without consideration of core hole field were performed. For K spectra the influence of the core hole potential is rather weak and the results are similar to those obtained with Xα potentials. For L_2,3 spectra, particularly for that of K⁺, core hole field leads to a radical redistribution of oscillator strength caused mainly by the spatial rearrangement of d like states. Calculated XANES curves show good over-all agreement with the experimental spectra (the L_2,3 absorption of K⁺ in KCl was measured using the synchrotron radiation of the USSR Academy of Sciences storage ring VEPP-2M in Novosibirsk).     

IR photoluminescence of Bi<Superscript>+</Superscript> impurity centers in the RbY<Subscript>2</Subscript>Cl<Subscript>7</Subscript> ternary chloride

Single-crystal samples of RbY₂Cl₇ ternary chloride containing an Bi⁺ isomorphic impurity are prepared for the first time. The optical absorption spectra in the visible region and photoluminescence spectra in the near-IR associated with the presence of Bi⁺ impurity center are studied. The kinetics of the photoluminescence decay is investigated. The influence of the symmetry of the crystal field on the arrangement of the energy levels and on the characteristics of the absorption and photoluminescence spectra of Bi⁺ is demonstrated.     

Studies of119Sb ions adsorbed on ferrimagnetic spinel oxide CoFe2O4 surfaces by means of emission Mössbauer spectroscopy

The chemical states of¹¹⁹Sb⁵⁺ ions hydrolytically adsorbed on spinel type ferrimagnetic oxide CoFe₂O₄ powders are studied by means of emission Mössbauer spectroscopy of the daughter nuclide¹¹⁹Sn. The spectra show a broadening which is attributed to the supertransferred hyperfine magnetic field coming from the magnetically ordered metal ions of the substrate. Distribution of the field is obtained from the spectra and its change with temperature is discussed.     

Optical investigation of the vertical diffusion of manganese in planar structures based on CdTe and Cd1 − x Mg x Te with ultrathin MnTe layers

The emission spectra of planar structures based on CdTe and Cd_{1 ? x} Mg _x Te containing periodically built-in MnTe layers with a nominal thickness of one monolayer have been investigated. The luminescence spectra and luminescence excitation spectra of manganese ions and excitons, as well as the dependences of the spectra on the temperature and magnetic field strength, are used to determine the actual distribution of manganese ions. The full width at half-maximum of the profile describing the change in the concentration of manganese in the growth direction of the structures is estimated to be 7–8 monolayers.     

Magnetic-field dependent optically detected ESR in the photoexcited triplet states of bridged Zr(IV) metallocenes

We report on the magnetic-field-dependent optically detected magnetic resonance (ODMR) spectra for polycrystalline samples of the bridged Zr(IV) metallocenes, Me₂Si<(Cp₂)ZrCl₂ ( (dimethylsilylbis(cyclopentadienyl)zirconium-dichloride) and Me₂C<(Cp₂)ZrCl₂ (iso-propylidenebis(cyclopentadienyl)zirconium-dichloride). ODMR spectra at zero magnetic field were recorded by frequency sweeping a microwave source from 0.1 to 10 GHz with the sample contained in a microwave helix. ODMR spectra at finite magnetic fields were recorded with the sample contained in either a helix or a slotted-tube resonator with a fixed microwave frequency and sweeping the magnetic field. For all experiments, the sample and microwave probes were contained in an immersion dewar cryostat, and the temperature was held at about 2 K. All three zero field ODMR transitions (2|E|, and |D| − |E| and |D|+|E|) were observed in the frequency-swept ODMR spectra recorded at zero and small magnetic fields. The zero-field frequency-swept spectra allowed the determination ofD andE values uniquely. For frequency-swept small-field ODMR spectra recorded at successively higher magnetic fields, each of the ODMR line intensities was observed to increase with increasing magnetic field. This intensity increase was observed for all three ODMR lines, reflecting an increase in the total intensity rather than simply a change in the polarization of the triplet sublevels. The latter would result in a change in the relative intensities of the ODMR lines but would not change simultaneously the intensities of all three lines. The ODMR line intensities increase in proportion toB ⁿ, wheren<1. This field dependence is weaker than the expected proportionalB ² dependence from the Zeeman effect, which likely originates from the magnetic field dependence of the spin relaxation rates between the triplet sublevels. Magnetic-field-swept ODMR spectra recorded at fixed microwave frequencies in the X-band frequency range (9.8 GHz) do not show all three expected classic Pake powder pattern line shape profiles, exhibited by the molecules with their magneticZ, Y, andX axes parallel to the external magnetic field. In particular, the intensity for molecular magneticY-axes parallel to the external magnetic field is completely suppressed. In addition, an external magnetic field dependence in field-swept ODMR spectra was observed, which results in a linear decrease of the ODMR intensity with increasing strength of the external magnetic field over and above that would be expected in a polycrystalline spectrum. The data are analyzed by simulation of the continuous-wave ESR spectrum with the eigenvalues and eigenvectors of the spin Hamiltonian matrix characterizing the triplet state exhibiting the ODMR spectrum, in conjunction with homotopy, as a function of the orientations of the magnetic axes of the various molecules in a polycrystalline sample. This approach is useful to interpret the experimentally observed ODMR transition frequencies andg-values but does not take the amplitudes in the ODMR spectrum. The corrections required to modify the continuous-wave ESR spectral amplitudes that reproduce the observed ODMR amplitudes are effects associated with the ODMR processes.     

Optical spectroscopy of Yb in the Cs2NaYF6 single crystal

Results of the optical spectroscopy investigation of the cubic paramagnetic center Yb³⁺ ion in the Cs₂NaYF₆ single crystal are presented. The Stark level energies of the Yb³⁺ multiplets are established from absorption, luminescence and excitation luminescence spectra and the crystal field parameters are calculated. Information about the phonon spectra of Cs₂NaYF₆ crystals is obtained from the electron-vibrational structure of the optical absorption and luminescence spectra.