共查询到20条相似文献,搜索用时 17 毫秒
1.
Eberhard Reimann Rainer Hertel Jürgen Krauss 《Monatshefte für Chemie / Chemical Monthly》2008,139(6):673-684
Alkylation of Reissert compounds derived from 3-methylisoquinolines with several 2-cyanobenzylbromides followed by hydrolytic cleavage provided the corresponding 1-benzyl-3-methylisoquinolines. Treatment of the latter with methylmagnesiumiodide caused cyclization to the title compounds rather than formation of 2-acetylbenzylisoquinolines. 相似文献
2.
Calorimetric measurements
have been performed in glassy Se90M10
(M=In, Te, Sb) alloys to study the effect
of In, Te and Sb additives on the kinetics of glass transition and crystallization
in glassy Se90M10 system. Kinetic
parameters of glass transition and crystallization such as the activation
energy of glass transition (E
g),
the activation energy of crystallization (M
c),
the order parameter (n), the rate constant
(K), etc. have been determined using different
non-isothermal methods. The composition dependence of the activation energies
of glass transition and crystallization processes is also discussed. 相似文献
3.
T. F. Ibragimov M. G. Levkovich V. A. Saprykina Kh. M. Shakhidoyatov 《Chemistry of Natural Compounds》2010,46(5):767-770
N-Chloroacetylcytisine was synthesized by acylation of (–)-cytisine. Stable Z- and E-conformers with respect to rotational isomerism around the N-12–CO bond were found in PMR spectra at room temperature. The
point at which PMR resonances of the Z- and E-conformers coalesced upon heating was measured. The transition barrier between the conformers was estimated. 相似文献
4.
By means of the ab initio DMol3 method Mo n Si m nanoparticles and fragments of Mo3Si and MoSi2 crystal lattices are theoretically modeled. For both crystals a few neutral Mo4Si6 and Mo6Si6 fragments of different shapes and symmetry are considered. In each case, after cluster separation its geometry is optimized, as a result of which the geometric structure noticeably changes and its stability increases. In order to theoretically search for the spatial configurations of Mo4Si6 and Mo6Si6 nanoparticle, two approaches are used: 1) in the most stable Fe4C6 and Fe6C6 isomers found previously, iron and carbon atoms are replaced by molybdenum and silicon respectively and then the geometry is optimized to obtain new equilibrium distances and angles; 2) the search for main Mo4Si6 and Mo6Si6 configurations is performed using the binominal scheme, starting from Mo2, MoSi, and Si2 dimers. The nanoparticle structures are found to contain metal atom chains and isolated pairs and triples of silicon atoms. In most cases, the nanoparticle stability proves to be higher than that of the crystal clusters. 相似文献
5.
P. K. Sazonov G. A. Artamkina I. P. Beletskaya 《Theoretical and Experimental Chemistry》2011,46(6):350-358
The mechanism of the reaction of carbonylate anions ([M(CO)
n
L]–) with highly activated vinyl halides (Hal = Cl, Br, I) was investigated by the method of “anion traps” – the effect of proton
donors on the composition of the reaction products. It was demonstrated that the reactions with PhCHal=C(Z)2 (Hal = Br, I;Z=CN, CO2Et) and PhCN=CClI take place through initial attack by the carbonylate at the halogen atom, the reactions with PhCCl=C(CO2Et)2 and PhCOCH=CHHal (Hal = Cl, I) take place through attack by the carbonylate at the π bond (AdNE mechanism), and in the case of E-and Z-PhCN=CHI the two mechanisms operate concurrently. The main laws determining the reaction
mechanisms are analyzed. 相似文献
6.
I. V. Polyakov M. G. Khrenova A. A. Moskovskii P. N. Telegin J.-P. Zhang A. V. Nemukhin 《Moscow University Chemistry Bulletin》2017,72(3):111-114
Excitation energies of the bacteriochlorophyll (BChl) chromophores embedded in the photosynthetic light-harvesting complex of the purple bacterium Thermochromatium tepidum are computed using the time-dependent density functional theory based upon the fragmental molecular orbital (FMO-TDDFT) method. The results are correlated with the empirically based estimates of the Q y absorption maximum, as well as with the observed large red shift induced by the binding of calcium. 相似文献
7.
V. K. Laurinavichyute S. E. Bakhtenkova O. A. Drozhzhin S. M. Kazakov E. V. Antipov 《Russian Journal of Electrochemistry》2016,52(11):1048-1056
Iron selenide (FexSey) thin films were electrodeposited on a glassy carbon electrode (GCE) surface under constant potential and pulse potential modes. The deposition mechanism was investigated using cyclic voltammetry. Electrochemical processes at room temperature are accompanied by adsorption of selenium on the electrode surface and complicated by chemical reactions in the solution bulk. Several approaches to control the film stoichiometry were applied: varying of electrodeposition potential; the use of elevated temperatures (60–80°C) to decrease the electrode passivation and electrodissolution of interfering elements under pulse mode. The composition of FexSey thin films was analyzed using an energy dispersive X-rays (EDX) analysis. 相似文献
8.
Michał Adamczyk Janusz Lasek Agnieszka Skawińska 《Applied biochemistry and biotechnology》2016,179(7):1248-1261
CO2 biofixation was investigated using tubular bioreactors (15 and 1.5 l) either in the presence of green algae Chlorella vulgaris or Nannochloropsis gaditana. The cultivation was carried out in the following conditions: temperature of 25 °C, inlet-CO2 of 4 and 8 vol%, and artificial light enhancing photosynthesis. Higher biofixation were observed in 8 vol% CO2 concentration for both microalgae cultures than in 4 vol%. Characteristic process parameters such as productivity, CO2 fixation, and kinetic rate coefficient were determined and discussed. Simplified and advanced methods for determination of CO2 fixation were compared. In a simplified method, it is assumed that 1 kg of produced biomass equals 1.88 kg recycled CO2. Advance method is based on empirical results of the present study (formula with carbon content in biomass). It was observed that application of the simplified method can generate large errors, especially if the biomass contains a relatively low amount of carbon. N. gaditana is the recommended species for CO2 removal due to a high biofixation rate—more than 1.7 g/l/day. On day 10 of cultivation, the cell concentration was more than 1.7?×?107 cells/ml. In the case of C. vulgaris, the maximal biofixation rate and cell concentration did not exceed 1.4 g/l/day and 1.3?×?107 cells/ml, respectively. 相似文献
9.
The polypropylene-graft-polyisoprene (PP-g-PIP) copolymers with different side chain length were synthesized by the combination of solid phase graft and anionic polymerization. The copolymers were characterized by nuclear magnetic resonance spectrum (1H-NMR), gel permeation chromatography (GPC) and differential scanning calorimetry (DSC). Five PP/PP-g-PIP blends with PP-g-PIP as a flexibilizer to toughen PP were prepared and characterized by scanning electron microscope (SEM), dynamic mechanical analysis (DMA), DSC, wide-angle X-ray diffraction (WAXD). Their morphologies, glass transition temperatures, crystallinity and mechanical properties were investigated. All the results pointed out that the covalent bonding of PP and PIP increased the compatibility and interfacial adhesion, which led to PIP well dispersed in the system and small size PIP particles in the binary blends. In addition, the toughness of PP was improved while its tensile strength slightly decreased. 相似文献
10.
Group-theoretical and quantum-chemical investigations of the spectrum of low-lying excited states have been performed by the ROHF and FCI-RAS (Full CI in Restricted Active Space) methods for 3d metal endofullerenes (MEFs) M@C60 (M =Mn, Cr, and Fe) in different charged states. The major purpose of this study is quantum-chemical verification of the anomalous (“non-Bethe’s”) character of splitting of the d N atomic states in an electrostatic field with icosahedral symmetry, predicted previously within the theory of integral invariants theory. The interrelation between the integral invariants theory and the quantumchemical methods applied in this work is considered in detail. Our calculations suggest that the d N atomic states in the icosahedral field generated by fullerene C60 (I h ) on a metal atom (ion) remain non-split for different charged states of the metal and C60. Reasons for this phenomenon and other possible approaches to verification of the prediction are discussed. It is demonstrated that the d N states of the encapsulated metal are split in icosahedral 3d MEFs only under very strong compression of these structures. 相似文献
11.
J. H. Sterba M. Blaauw G. Steinhauser M. Bichler F. Grass G. P. Westphal 《Journal of Radioanalytical and Nuclear Chemistry》2008,278(3):613-616
Combining the powers of a fast pneumatic transport system and the Automatic Activation Analyzer (AAA) of the Atominstitut
in Vienna with the newest version of the IAEA k
0-Software, the application of the k
0-method to the determination of short-lived radionuclides becomes easily possible. By calculating Asp-values with the IAEA
software, the often expensive and time-consuming measurement of Asp-values using certified reference materials is reduced
to quality control checks. Measurements clearly show that the two approaches are equivalent, especially since both take self-absorption
and neutron self-shielding into account. In this way it is possible to expand the library of the AAA with many hitherto unobtainable
Asp-values. At the same time, using highly accurate Asp-values already measured for many short-lived radionuclides, k
0-values for those can be produced with a simple procedure. 相似文献
12.
D. A. Köse G. Gökçe S. Gökçe İ. Uzun 《Journal of Thermal Analysis and Calorimetry》2009,95(1):247-251
Three novel mixed ligand complexes of Ni(II), Zn(II) and Cd(II) with p-chlorobenzote and N,N-diethylnicotinamide were synthesised and characterized on the basis of elemental analysis, FTIR spectroscopic
analysis, solid state UV-Vis spectrometric and magnetic susceptibility data. The thermal behavior of the complexes was studied
by simultaneous TG-DTA methods in static air atmosphere and the mass spectra data were recorded.
According to microanalytical results, formulas of complexes are C34H40N4O8ClNi, C34H40N4O8ClZn and C34H44N4O10ClCd. The complexes contain two moles of coordination waters, two moles p-chlorobenzoate and two mole N,N-diethylnicotinamide (dena) ligands per formula unit. In these complexes, the p-chlorobenzoate and N,N-diethylnicotinamide behave as monodentate ligand through acidic oxygen and nitrogen of pyridine ring.
The decomposition pathways and the stability of the complexes are interpreted in the terms of the structural data. The final
decomposition products were found to be as metal oxides. 相似文献
13.
A. V. Lezov G. E. Polushina A. A. Lezov P. S. Vlasov N. S. Domnina 《Polymer Science Series A》2011,53(2):93-101
The hydrodynamic and conformational properties of molecules of poly(N,N-diallyl-N,N-dimethylammonium chloride) and N,N-diallyl-N,N-dimethylammonium chloride-maleic acid copolymers of different compositions in solutions with various ionic-strength and pH
values, as well as of the polyelectrolyte complex based on the copolymer with dodecyl sulfate anions in chloroform, are studied.
For poly(N,N-diallyl-N,N-dimethylammonium chloride) molecules in a 1 M NaCl solution, the Kuhn segment length and the hydrodynamic diameter of the
chain are estimated as A = 3.9 nm and d = 0.48 nm, respectively. In acidic solutions with pH 3.5, the copolymers demonstrate behavior typical for polyelectrolytes.
In an alkaline solution with pH 13, when 1 M NaCl is added to the solution of the copolymer containing 29 mol % maleic acid
units, there is an antipolyelectrolyte effect that manifests itself as an increase in the intrinsic viscosity of the copolymer
and in the hydrodynamic radius of its molecules. It is found that an increase in the fraction of maleic acid units in the
copolymer from 12 to 42 mol % brings about a reduction in the equilibrium rigidity of its macromolecules from 4.1 to 2.2 nm.
The equilibrium rigidity of polyelectrolyte-complex molecules is higher than that of initial copolymer molecules owing to
steric interactions arising between the aliphatic chains of dodecyl sulfate anions. In an electric field, the molecules of
the complex are oriented owing to the induced dipole moment resulting from the displacement of dodecyl sulfate anions along
the chain contour. 相似文献
14.
15.
Hongli Liu Tomoko Yamashita Tadashi Kamiyama Masao Fujisawa Takayoshi Kimura 《Journal of Thermal Analysis and Calorimetry》2010,99(1):95-103
The excess molar enthalpies of 8 binary mixtures for the o-, m-, and p-isomers of fluoroiodobenzene, fluoromethoxybenzene, bromofluorobenzene, chlorofluoro-benzene, difluorobenzene, fluoromethylbenzene,
fluoronitrobenzene, and aminofluoro-benzene were measured at 298.15 K. The changes of the measured enthalpies were very small.
The experimental results revealed that the isomers containing two electron-acceptor groups showed the most positive excess
enthalpy change, while isomers containing both one electron donor and one electron acceptor group, such as aminofluorobenzene,
showed more stable and always the most negative results. 相似文献
16.
G. G. Fontanari G. R. Souza J. P. Batistuti V. A. Neves I. A. Pastre F. L. Fertonani 《Journal of Thermal Analysis and Calorimetry》2008,93(2):397-402
Glutelin, the major protein fraction from guava seed, was obtained by fractioning as described by Osborne. The total proteins
were extracted and the isolates obtained by isoelectric precipitation presented similar DSC curves, concordant with the results
obtained by gel filtration chromatography and electrophoresis in polyacrylamide gel (PAGE-SDS). However, the DSC curves showed
a higher enthalpy with regard to the denaturing protein isolate (PI) extracted at pH 10.0 when compared to a PI at pH 11.5.
Such results are in accordance with those obtained for PI extracted at pH 10.0 using chromatography, this one being present
in the form of molecular aggregates of greater molecular mass. The glutelin fraction, however, did not present a denaturation
peak in the DSC curve, showing that the process for obtaining the same significantly altered its conformation. 相似文献
17.
Density functional calculations are performed to study the structures and electronic properties of Al
n
Co
m
clusters with n = 1–7 and m = 1–2. Frequency analysis is also performed after structural optimization to make sure that the calculated ground states
are real minima. The corresponding total and binding energies, adiabatic electron affinities and ionization potentials are
presented and discussed to aid the identification of our calculations. The BSSE correction is also considered in our calculation.
Among Al
n
Co
m
, Al
n
Co
m
−, and Al
n
Co
m
= clusters (n = 1–7 and m = 1–2), Al4Co−, Al6Co−, Al2Co2, and Al6Co2 are predicted to be more stable. Our results are consistent with the available experimental data. 相似文献
18.
This paper reports the synthesis and characterization of polystyrene nanorods in hemicylindrical hemimicelles of a nonionic polyoxyethylene surfactant, C
12
E
5, on graphite. The surface structure is characterized by atomic force microscopy (AFM), Fourier transform infrared spectroscopy, and contact angle goniometry. Uniformly aligned polystyrene nanorods are captured by AFM. The nanorod dimensions are studied as a function of the reaction time and styrene monomer concentration. The template synthesis using self-assembled surfactant surface aggregates promises to create functional and stable nanostructures for optoelectronics and surface engineering. 相似文献
19.
Background
Adenylation of nicotinate mononucleotide to nicotinate adenine dinucleotide is the penultimate step in NAD+ synthesis. In Escherichia coli, the enzyme nicotinate mononucleotide adenylyltransferase is encoded by the nadD gene. We have earlier made an initial characterization in vivo of two mutant enzymes, NadD72 and NadD74. Strains with either mutation have decreased intracellular levels of NAD+, especially for one of the alleles, nadD72. 相似文献20.
E. F. Kustov V. I. Nefedov A. V. Kalinin M. S. Karelina 《Russian Journal of Inorganic Chemistry》2008,53(7):1088-1097
A method has been developed for the determination of the structure and number of atoms in the shells of nanoparticles as a function of the arrangement of atoms at the symmetry elements of a symmetry group. The formulas for calculation of the number of particles of symmetry D 3d have been reported. It has been shown that the number of atoms in trigonal shells is determined by three structurally invariant numbers and the quantum number of the group order n. All possible nanostructures of symmetry D 3d have been classified: Cθ + 6z , z = 0, 1, 2, ..., where the basic shells are Cθ = C6, C8, and C14. A sum rule has been obtained for the coordination numbers of the shell sites located on symmetry axes. Trigonal nanoparticles are parent ones for obtaining (3,0), (6,0), and (9,0) nanotubes of trigonal type. The general formulas of these nanotubes with icosahedral, dodecahedral, and cubic caps are N8 + 12p , N20 + 24p , and N60 + 36p (p = 1, 2, ...), respectively. The graphical constructions of all classes of trigonal nanoparticles and nanotubes are reported. 相似文献