发光及显示器件光电特性测试系统设计

为了提高发光及显示器件光电特性测量实验的智能化程度,减小人为误差,并考虑工作温度对其光电特性的影响,设计了一种能够自动、同步测量发光体亮度、温度、伏安特性和寿命的系统。系统主要由LS-110型亮度计、GPD-3303型电源、自制的温度测量模块及测量软件四部分组成。基于实验室虚拟仪器工程平台,利用亮度计对器件的亮度进行测量,利用单片机和温度传感器对器件的温度进行测量,通过上位机程序控制电源步进输出、读取实际输出电流值和电压值,并将采集到的数据发送到上位机,实时绘制出了亮度-电压、电流-电压、温度-电压、亮度-温度、电流-温度、亮度-电流特性曲线。系统目前可以同时对器件的亮度、温度和伏安特性进行自动测量和直观显示,并且具备自动保存数据和图像的功能,实现了发光及显示器件光电特性测量的智能化,具有综合性强、精确度及自动化程度高、操作简易等特点。     

高亮度掺杂红色有机电致发光器件的制备与光电性能研究

采用真空热蒸镀的方法,在高精度膜厚控制仪监控下,实现了有机薄膜功能材料的精确蒸镀,其中发光层采用主体材料与掺杂材料在一个真空腔体同时共同蒸发,制备了一种高亮度多层结构的红色有机电致发光(OLED)器件:ITO-CuPc(20 nm)--αNPD(60 nm)-Alq3(40 nm)∶Rubrene(10%)∶DCJTB(1%)-Alq3(20 nm)-LiF(10 nm)-Al(100 nm)。研究发现:驱动在电压为5~52 V变化时,其亮度基本满足线性增加关系,随之饱和;随着驱动电压的变化,其电致发光光谱有蓝移的现象,发射峰从638 nm变到632 nm,同时色坐标CIEx,y值也发生相应的变化;器件的流明效率在驱动电压较低时(V=5 V),达到最大值ηLmax=0.497 lm.W-1,随着驱动电压的增加,流明效率有降低的趋势。     

发展InGaN基半导体绿色发光器件的材料挑战

我从事光电领域的研究已经很久了，20世纪70年代早期我在斯坦福大学就开始该方向的研究，在那里研究将光能转化为电能的太阳能电池。我的第一份工作是在惠普公司的Hewlett—Packard实验室，该公司在20世纪70年代早期的一个产品是计算器。计算器首先要用到集成电路，它要求电路达到很高的集成度，能够非常快地完成计算。但随后的问题就是如何显示出计算结果。     

Luminescent Eu(III) and Tb(III) Complexes: Developing Lanthanide Luminescent-Based Devices

This mini review gives some highlights of the work recently carried out in our research group in Dublin on the developments of lanthanide luminescent devices, where the future goal is to produce devices that can operate as sensors. A few examples demonstrate our design principles for targeting both anion and cations that are of biological or pharmaceutical relevance, where the recognition occurs in aqueous competitive media. We also discuss the possibility of developing mixed f-d metal complexes and conjugates that can be employed as novel supramolecular architectures.     

Synthesis,Photoluminescence Behavior of Green Light Emitting Tb(III) Complexes and Mechanistic Investigation of Energy Transfer Process

A series of five new terbium(III) ion complexes with 4,4-difluoro-1-phenylbutane-1,3-dione (HDPBD) and anciliary ligands was synthesized. The composition and properties of complexes were analyzed by elemental analysis, IR, NMR, powder X-ray diffaraction, TG-DTG and photoluminescence spectroscopy. These complexes exhibited ligand sensitized green emission at 546 nm associated with ⁵D₄?→?⁷F₅ transitions of terbium ion in the emission spectra. The photoluminescence study manifested that the organic ligands act as antenna and facilitate the absorbed energy to emitting levels of Tb(III) ion efficiently. The enhanced luminescence intensity and decay time of ternary C2-C5 complexes observed due to synergistic effect of anciliary ligands. The CIE color coordinates of complexes came under the green region of chromaticity diagram. The mechanistic investigation of intramolecular energy transfer in the complexes was discussed in detail. These terbium(III) complexes can be thrivingly used as one of the green component in light emitting material and in display devices.

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Graphical Abstract Illustrate the sensitization process of the Tb ion and intramolecular energy transfer process in the Tb³⁺ complex.

     

多孔硅-导电聚酯材料复合发光器的光学特性研究

poly-4-dicyanomethylene-4H-cyclopenta[2,1-b:3,4-b]dithiophene monolayer(PCDM)是一种导电,低导带聚酯材料。如果在多孔硅纳米结构中附上一层以自组方式生成的PCDM单分子层,就可以制成能够产生稳定电致发光的器件。发光器的结构是金／PCDM／多孔硅／硅／铝,发光器的电致发光,在白天可用肉眼观察到。有很宽的发光波长,几乎覆盖了整个可见光区域且峰值位于650nm,发光器的面积为1cm^2,启动正向电压在14－30V,电流约300mA。经长时间测试,发光器的稳定性很好,在空气中放置3个月,在输入功率不变的情况下,发光强度也不发生变化,当施以反向电压时,样品仍可以发光而且稳定性较高,在250h内I－V未发生明显变化,扫描电镜图像显示PCDM覆盖的表面要比多孔硅表面平整,而PCDM分子有可能进入到多孔硅纳米孔径当中去,起到了提高发光器稳定性和延长其寿命的作用。     

New Insights into Optoelectronic Features of Eu(III) Complexes with Heterocyclic Ligand for Advanced Optical Applications

Our present technological society needs the assistance of lanthanide luminescence in almost every field to meet the global energy demands. In present research work we have synthesized five (one binary and four ternary) 5-(4-methylphenyl)-2- furoic acid based Eu(III) complexes with ancillary ligands, namely, aqua (H₂O), neocuproine (neo), 2, 2’-bipyridyl (bipy), bathophenanthroline (batho) and 1, 10-phenanthroline (phen). The spectroscopic analysis and photophysical features are characterized by the use of different investigative techniques. All the findings obtained from EDAX, elemental (CHN) analysis, FT-IR, NMR, UV–visible spectroscopy declared the coordination of ligand binding sites with the europium ion. These Eu(III) complexes possess good thermal stability and excellent optoelectronic features as predicted with the help of TGA and PL analysis. Diffuse reflectance spectral studies confirm their applications in the wide band gap semiconductors. The Judd–Ofelt analysis and monoexponential behavior of lifetime reveals the existence of asymmetric and single local environment around europium ion. All the complexes show sharp red emission validated by CIE color coordinates, color purity, asymmetric ratio and CCT values. SEM analysis tells that the bulk of these complexes comprised of spherical shaped particles with uniform distribution.

     

Synthesis and Characterization of 8-hydroxyquinoline Complexes of Tin(IV) and Their Application in Organic Light Emitting Diode

A series of 8-hydroxyquinoline complexes of tin, Q(2)SnCl(2) (Q?=?2-methyl-8-hydroxyquinoline, 8-hydroxyquinoline, 5,7-dibromo-8-hydroxyquinoline, 5-chloro-8-hydroxyquinoline, 5,7-dichloro-8-hydroxyquinoline and 5-nitro-8-hydroxyquinoline) were prepared by reacting stannous dichloride with 8-hydroxyquinoline and its derivatives. All complexes were characterized by elemental analysis, mass spectrometry and infrared, UV-vis and (1)H NMR spectroscopes. Furthermore, the molecular structure of a representative complex, dichlorido-bis(5-nitro-quinolin-8-olato-2N,O)tin(IV), was determined by single-crystal X-ray diffraction. The photoluminescence (PL) properties of all prepared compounds and electroluminescence (EL) property of a selected complex (Q?=?5-chloro-8-hydroxyquinoline) were investigated. The results showed that the emission wavelength can be tuned by electron donating or withdrawing group substituent on 8-hydroxyquinoline. Application of prepared complexes in fabrication of an OLED has been demonstrated.     

利用磷光敏化改善聚合物白光OLED性能

基于新型聚合物白光材料PF-DTFO制备了一种聚合物白光发光二极管(PWOLED),通过在聚合物发光层中掺杂蓝光磷光染料FIrpic,利用磷光敏化发光原理,改善器件电致发光性能。在敏化PWOLED中,掺杂的FIrpic染料作为给体将产生的三重态能量传递给白光聚合物的长波发射基团,进一步提高了长波基团的发光强度,改善了白光光谱,使基色更平衡并且光谱更稳定。驱动电压从8 V增加到16 V时,器件电致发光光谱基本不变,色坐标仅从(0.33,0.38)移动至(0.32,0.38)。敏化后的器件发光效率相对于未掺杂器件提高了38%。     

Exploration of Induced Blue Phases and Orthogonal Smectic Batonnets in Hydrogen-Bonded Ferroelectric Nanoliquid Crystalline Complexes for Optoelectronic Devices

A novel blue phase hydrogen-bonded ferroelectric liquid crystal (HBFLC) series has been synthesized from cholesteryl stearate (CHS) and p-n-alkyloxybenzoic acid (nOBA, where n?=?2 to12). Blue phase (BP) liquid crystalline complex is a high potent material for next-generation optoelectronic devices. The structural, optical, and thermal properties of present HBFLC complexes have been characterized by X-ray diffraction techniques (XRD), Fourier transform infrared spectroscopy (FT-IR), nuclear magnetic resonance spectroscopy (NMR), polarizing optical microscope (POM), and differential scanning calorimetry (DSC) techniques. The band gap energy of the present HBFLC complex (4.6 eV) is estimated by UV-Visible spectrometer. X-ray diffraction and scanning electron microscope (SEM) studies which confirm the monoclinic nature and morphology of the present complex. Phase diagram of the present CHS + nOBA is constructed from DSC data and the same is discussed. The lower homologous of CHS + nOBA HBFLC (n?=?2 to 6) complex shows BP_sm1, BP_sm2, BP_sm3 while higher homologous (n?=?7 to 12) exhibiting orthogonal smectic A* (SmA*) character with blue phases. A noteworthy observation is that the identification of extended thermal span of smectic blue phases and induced SmA* phase in the present HBFLCs. Another important observation is that the widest BP range is reported in the present hydrogen-bonded ferroelectric nanoliquid crystalline (HBFNLC) complex which is more suitable for photonic devices. In addition, LC parameters such as, phase width, thermal stability factor, phase transition temperature with enthalpy value, and the origination of orthogonal phases in CHS + nOBA HBFLC complex is also reported.     

Luminescent Properties of Zeolite Modified by Eu(III) and Tb(III) Complexes

The luminescence of the sorbates of the Eu(III) and Tb(III) complexes on the CaA-type zeolite with derivatives of aliphatic and aromatic carbonic acids has been studied. It is shown that the luminescent materials obtained can be used as light regulators and transformers which absorb energy in the UV spectral region and transform it into visible radiation.     

Structural Investigation and Photoluminescent Properties of Gadolinium(III), Europium(III) and Terbium(III) 3-Mercaptopropionate Complexes

This work reports on the synthesis, crystallographic determination and spectroscopic characterization of gadolinium(III), terbium(III) and europium(III) 3-mercaptopropionate complexes, aqua-tris(3-mercaptopropionate)lanthanide(III) - [Ln(mpa)₃(H₂O)]. The Judd-Ofelt intensity parameters were experimentally determined from emission spectrum of the [Eu(mpa)₃(H₂O)]complex and they were also calculated from crystallographic data. The complexes are coordination polymers, where the units of each complex are linked together by carboxylate groups leading to an unidimensional and parallel chains that by chemical interactions form a tridimensional framework. The emission spectrum profile of the [Eu(mpa)₃(H₂O)] complex is discussed based on point symmetry of the europium(III) ion, that explains the bands splitting observed in its emission spectrum. Photoluminescent analysis of the [Gd(mpa)₃(H₂O)] complex show no efficient ligand excitation but an intense charge transfer band. The excitation spectra of the [Eu(mpa)₃(H₂O)] and [Tb(mpa)₃(H₂O)] complexes do not show evidence of energy transfer from the ligand to the excited levels of these trivalent ions. Therefore the emission bands are originated only by direct f-f intraconfigurational excitation of the lantanide(III) ions.     

白光LED用红色荧光粉α-Gd2(MoO4)3:Eu的制备及其发光性能研究

以Gd2O3,MoO3,Eu2O3为原料,采用传统的高温固相反应方法制备了一种新的白光LED用红色荧光粉材料α相Gd2(MoO4)3:Eu.利用XRD,SEM,激发和发射光谱对其进行了研究.分析了助熔剂和激 .活剂对样品的晶体结构,表面形貌和发光性能的影响.结果表明这种荧光粉可以被近紫外光(395 nm)和蓝光(465 nm)有效激发,发射峰值位于613 nm(Eu3 离子的5D0→7F2跃迁)的红光,激发波长与目前广泛使用的蓝光和紫外光LED芯片相符合.因此,三价Eu离子激活的α相Gd2(MoO4)3是一种可能应用在白光LED上的红色荧光粉材料.     

电场变化对有机磷光器件中激子形成影响的研究

激子形成区域随电场变化的移动会使得有机电致发光器件(OLEDs)的效率和色度发生改变,从而影响器件的性能。文章首先制备了两种OLED器件,器件1为ITO/PEDOT∶PSS/PVK∶Ir(ppy)₃∶DCJTB (100∶2∶1 wt)/BCP(10 nm)/Alq₃(15 nm)/Al,器件2为ITO/PEDOT∶PSS/PVK∶Ir(ppy)₃(100∶2 wt)/BCP(10 nm)/Alq₃(15 nm)/Al,研究了电场强度对单层多掺杂结构器件激子形成的影响。实验发现在多掺杂发光层中,随着电压的增加,Ir(ppy)₃,PVK和DCJTB的发光均增强,PVK和DCJTB发光增强更快。对其发光机制进行分析,认为较高电场下,载流子获得较高能量,更容易形成高能量激子,产生宽禁带材料PVK的发光;另一方面,从能级结构分析DCJTB的带隙较窄, 俘获更多的载流子发光更强。同时,在器件的电致发光(EL)光谱发现在460 nm处一新的发射峰, 发光随着电压的增大相对减弱。为了研究460 nm发光的来源,制备了器件：ITO/PEDOT∶PSS/PVK∶BCP∶Ir(ppy)₃(x∶y∶2 wt)/Alq₃(15 nm)/Al, 改变x, y的比值研究发现,460 nm处的发光依然存在,推测此发光峰应与PVK及BCP之间有关。     

迁移率对单层有机发光器件中复合率分布的影响

以载流子运动的扩散-漂移理论为基础,利用数值方法研究了有机发光层中双极载流子注入时的电势、电场、载流子浓度和复合率分布.结果表明:当两种载流子的迁移率相同实现平衡注入,并且当空穴和电子的复合为Langevin型时,复合率的分布曲线相当理想,参与复合的空穴和电子总量远大于其他情况,由此器件的发光性能也得到更大的优化.     

用于动物细胞和组织培养的新型LED生物光源系列

采用透镜组扩大光束、透镜阵列聚焦和点阵光曲面聚集光能三种光路设计,通过选择各光源中的四个工作参数调节光源输出的辐射照度,本文研制出可用于动物细胞和组织培养使用的、不同强度的三种新型LED生物光源,并使用统计分析软件SPSS拟合得出它们的辐射照度经验计算公式.     

Photophysical and Analyte Sensing Properties of Cyclometalated Ir(III) Complexes

The synthesis of some heteroleptic, cyclometalated iridium(III) complexes is described. The utility of these [Ir(ppy)₂(N-N)]Cl (ppy = 2-phenylpyridine and N-N = substituted bipyridine, biquinoline, or phenanthroline) complexes as luminescence-based sensors is assessed. The emission intensity of an Ir(III) complex featuring the 3,3′-H_ndcbpy ligand (H_ndcbpy = dicarboxylic acid-2,2′-bipyridine; n = 0,1,2 to indicate deprotonated, mono- and diprotonated species, respectively) is seen to increase in the presence of Pb(II). Insight into the structure and analyte-sensing capability is achieved by X-ray crystallography in conjunction with computational modeling. Complexes incorporating carboxylic acid-functionalized bipyridine and biquinoline as the polypyridyl ligand show pH sensitivity while similar phenanthroline complexes do not.     

水溶性酞菁化合物对有机电致发光器件亮度和效率的影响

以水溶性酞菁铜(CuTcPc)为空穴注入层制备多层有机电致发光器件.ITO表面经过CuTcPc溶液修饰,能够提高空穴的注入能力,增加器件的电流密度和亮度.在有机电致发光器件中,空穴传输材料的空穴迁移率一般大于电子传输材料的电子迁移率,空穴是多数载流子;但是,CuTcPc修饰处理不仅提高了器件的电流密度和亮度,也提高了器...     

发光二极管光谱测量中的杂散光与带宽校正

光谱仪的杂散光和带宽是LED光谱测量中比较重要的两个误差影响因素,为了得到更精确的测量结果,必须对杂散光和带宽影响进行校正.用He-Ne激光测出光谱仪的线扩展函数,在假设光谱仪是线性波长不变系统的前提下,构建杂散光分布函数矩阵,转化为杂散光校正矩阵,从而对所测信号进行杂散光校正;在三个波段内分别由光谱仪带宽函数计算带宽校正系数,将被测波长点及其邻近带宽波长点上的测量结果进行加权平均,从而得到带宽校正结果.将两种校正方法应用在一台多通道快速光谱仪上,测量各种颜色的LED,实验结果表明能有效地校正杂散光和带宽影响,色品坐标最大校正了(-0.003,0.007).且该方法降低了应用成本,在保证精度的情况下简化了计算量,使得校正更易于实施.     

Luminescence Characteristics of the Sorbates of Eu(III) and Tb(III) Complexes with Diphenacylphosphinic Acid on Zeolite

The possibility of obtaining new luminescent materials based on the CaA zeolite modified by complex compounds of Eu(Tb) with diphenacylphosphinic acid has been shown. The optimal sorption conditions have been established and the luminescent characteristics of the sorbates have been determined.