Shear softening and thixotropic properties of wheat flour doughs in dynamic testing at high shear strain

Shear softening and thixotropic properties of wheat flour doughs are demonstrated in dynamic testing with a constant stress rheometer. This behaviour appears beyond the strictly linear domain (strain amplitude ₀ 0.2%),G,G and |^*| decreasing with ₀, the strain response to a sine stress wave yet retaining a sinusoidal shape. It is also shown thatG recovers progressively in function of rest time. In this domain, as well as in the strictly linear domain, the Cox-Merz rule did not apply but() and | ^*())| may be superimposed by using a shift factor, its value decreasing in the former domain when ₀ increases. Beyond a strain amplitude of about 10–20%, the strain response is progressively distorted and the shear softening effects become irreversible following rest.     

On shock layer method for the hypersonic flow problems

Chernyi’s series method[1] is not proper for the case that(γ-l)/(γ+l)<<2/(γ+1)×M²sin²β (γ=c_p/c_v-adiabatic index number, M-Much number, β-shock incidence). In this paper, we only suppose that in the neighbour of the shock, there exists a shock layer in which the density of the gas is very big, but we do not remove the case that (γ-1)/(γ+1)<<2/(γ+1)M²sin²β.     

Symmetry-Breaking Bifurcations of Charged Drops

It has been observed experimentally that an electrically charged spherical drop of a conducting fluid becomes nonspherical (in fact, a spheroid) when a dimensionless number X inversely proportional to the surface tension coefficient is larger than some critical value (i.e., when <_c). In this paper we prove that bifurcation branches of nonspherical shapes originate from each of a sequence of surface-tension coefficients ), where ₂=_c. We further prove that the spherical drop is stable for any >₂, that is, the solution to the system of fluid equations coupled with the equation for the electrostatic potential created by the charged drop converges to the spherical solution as t provided the initial drop is nearly spherical. We finally show that the part of the bifurcation branch at =₂ which gives rise to oblate spheroids is linearly stable, whereas the part of the branch corresponding to prolate spheroids is linearly unstable.     

Nonlinear rheological behavior of a concentrated spherical silica suspension

Linear and nonlinear viscoelastic properties were examined for a 50 wt% suspension of spherical silica particles (with radius of 40 nm) in a viscous medium, 2.27/1 (wt/wt) ethylene glycol/glycerol mixture. The effective volume fraction of the particles evaluated from zero-shear viscosities of the suspension and medium was 0.53. At a quiescent state the particles had a liquid-like, isotropic spatial distribution in the medium. Dynamic moduli G^* obtained for small oscillatory strain (in the linear viscoelastic regime) exhibited a relaxation process that reflected the equilibrium Brownian motion of those particles. In the stress relaxation experiments, the linear relaxation modulus G(t) was obtained for small step strain (0.2) while the nonlinear relaxation modulus G(t, ) characterizing strong stress damping behavior was obtained for large (>0.2). G(t, ) obeyed the time-strain separability at long time scales, and the damping function h() (–G(t, )/G(t)) was determined. Steady flow measurements revealed shear-thinning of the steady state viscosity () for small shear rates (< ^–1; = linear viscoelastic relaxation time) and shear-thickening for larger (>^–1). Corresponding changes were observed also for the viscosity growth and decay functions on start up and cessation of flow, + (t, ) and _– (t, ). In the shear-thinning regime, the and dependence of ₊(t,) and _–(t,) as well as the dependence of () were well described by a BKZ-type constitutive equation using the G(t) and h() data. On the other hand, this equation completely failed in describing the behavior in the shear-thickening regime. These applicabilities of the BKZ equation were utilized to discuss the shearthinning and shear-thickening mechanisms in relation to shear effects on the structure (spatial distribution) and motion of the suspended particles.Dedicated to the memory of Prof. Dale S. Parson     

Symmetries and Global Solvability of the Isothermal Gas Dynamics Equations

We study the Cauchy problem associated with the system of two conservation laws arising in isothermal gas dynamics, in which the pressure and the density are related by the -law equation p() with =1. Our results complete those obtained earlier for >1. We prove the global existence and compactness of entropy solutions generated by the vanishing viscosity method. The proof relies on compensated compactness arguments and symmetry group analysis. Interestingly, we make use here of the fact that the isothermal gas dynamics system is invariant modulo a linear scaling of the density. This property enables us to reduce our problem to that with a small initial density.One symmetry group associated with the linear hyperbolic equations describing all entropies of the Euler equations gives rise to a fundamental solution with initial data imposed on the line =1. This is in contrast to the common approach (when >1) which prescribes initial data on the vacuum line =0. The entropies we construct here are weak entropies, i.e., they vanish when the density vanishes.Another feature of our proof lies in the reduction theorem, which makes use of the family of weak entropies to show that a Young measure must reduce to a Dirac mass. This step is based on new convergence results for regularized products of measures and functions of bounded variation.Acknowledgement P.G.L. and V.S. were supported by a grant from INTAS (01-868). The support and hospitality of the Isaac Newton Institute for Mathematical Sciences, University of Cambridge, where part of this research was performed during the Semester Program Nonlinear Hyperbolic Waves in Phase Dynamics and Astrophysics (January to July 2003) is also gratefully acknowledged. P.G.L. was also supported by the Centre National de la Recherche Scientifique (CNRS).     

On the Ellipticity of the Middle Surface of a Shell and its Application to the Asymptotic Analysis of ‘Membrane’ Shells

We consider a surface S = (), where ² is a bounded, connected, open set with a smooth boundary and : ³ is a smooth map; let () denote the components of the two-dimensional linearized strain tensor of S and let 0 with length 0 > 0. We assume the the norm ,|| ()||0, in the space V0() = { H¹() × H¹() × L²(); = 0 on 0 } is equivalent to the usual product norm on this space. We then establish that this assumption implies that the surface S is uniformly elliptic and that we necessarily have 0 = .     

The dynamic performance of the Weissenberg rheogoniometer III. Large amplitude oscillatory shearing — harmonic analysis

The harmonic content of the nonlinear dynamic behaviour of 1% polyacrylamide in 50% glycerol/water was studied using a standard Model R 18 Weissenberg Rheogoniometer. The Fourier analysis of the Oscillation Input and Torsion Head motions was performed using a Digital Transfer Function Analyser.In the absence of fluid inertia effects and when the amplitude of the (fundamental) Oscillation Input motion _I is much greater than the amplitudes of the Fourier components of the Torsion Head motion _Tn empirical nonlinear dynamic rheological propertiesG _n (, ⁰),G _n (, ⁰) and/or _n (, ⁰), _n (, ⁰) may be evaluated without a-priori-knowledge of a rheological constitutive equation. A detailed derivation of the basic equations involved is presented.Cone and plate data for the third harmonic storage modulus (dynamic rigidity)G ₃ (, ⁰), loss modulusG ₃ (, ⁰) and loss angle ₃ (, ⁰) are presented for the frequency range 3.14 × 10^–2 1.25 × 10² rad/s at two strain amplitudes, _CP ⁰ = 2.27 and 4.03. Composite cone and plate and parallel plates data for both the third and fifth harmonic dynamic viscosities ₃ (, ⁰), _S (, ⁰) and dynamic rigiditiesG ₃ (, ⁰),G ₅ (, ⁰) are presented for strain amplitudes in the ranges 1.10 _CP ⁰ 4.03 and 1.80 _PP ⁰ 36 for a single frequency, = 3.14 × 10^–1 rad/s. Good agreement was obtained between the results from both geometries and the absence of significant fluid inertia effects was confirmed by the superposition of the data for different gap widths.     

New calculations on the Faraday effect in wave guides

Summary The propagation of electromagnetic waves is investigated theoretically for a round wave guide, containing a gyroelectrie-gyromagnetic medium with gyroaxis parallel to the guide in the form of a cylindrical shell of thickness, adjacent to the wall of the guide. An equation is set up, permitting to compute the change in the propagation constant due to the presence of the shell, including terms proportional to ². Assuming only the presence of gyromagnetism, the change ₁ of first order in for TE-waves is determined and is found to be the same fpr right- and left-circular polarization. The second order difference ₂ ⁺ — ₂ ^- for the two senses of polarization, however, appears to have a non-vanishing value which, just like ₁ can be expressed in terms of the radius of the guide, the frequency, the dielectric constant and the elements of the gyromagnetic permeability tensor which characterize the medium of the shell.     

On the effects of a periodic, spanwise variation of suction upon asymptotic suction flow

Summary The effects of superposing streamwise vorticity, periodic in the lateral direction, upon two-dimensional asymptotic suction flow are analyzed. Such vorticity, generated by prescribing a spanwise variation in the suction velocity, is known to play an important role in unstable and turbulent boundary layers. The flow induced by the variation has been obtained for a freestream velocity which (i) is steady, (ii) oscillates periodically in time, (iii) changes impulsively from rest. For the oscillatory case it is shown that a frequency can exist which maximizes the induced, unsteady wall shear stress for a given spanwise period. For steady flow the heat transfer to, or from a wall at constant temperature has also been computed.Nomenclature (x, y, z) spatial coordinates - (u, v, w) corresponding components of velocity - (, , ) corresponding components of vorticity - t time - stream function for v and w - v _w mean wall suction velocity - nondimensional amplitude of variation in wall suction velocity - characteristic wavenumber for variation in direction of z - T temperature - P pressure - density - coefficient of kinematic viscosity - coefficient of thermal diffusivity - (/v _w)² - frequency of oscillation of freestream velocity - nondimensional amplitude of freestream oscillation - /v _w ² - z z - y –v _w y/ - v _w ² t/4 - /v _w - U ₀ characteristic freestream velocity - u/U ₀ - coefficient of viscosity - _w wall shear stress - Prandtl number (/) - q heat transfer to wall - T _w wall temperature - T (T _w–T)/(T _w–)     

The value of the critical exponent for reaction-diffusion equations in cones

Let D R ^N be a cone with vertex at the origin i.e., D = (0, )x where S ^N–1 and x D if and only if x = (r, ) with r=¦x¦, . We consider the initial boundary value problem: u _t = u+u ^p in D×(0, T), u=0 on Dx(0, T) with u(x, 0)=u ₀(x) 0. Let ₁ denote the smallest Dirichlet eigenvalue for the Laplace-Beltrami operator on and let ₊ denote the positive root of (+N–2) = ₁. Let p ^* = 1 + 2/(N + ₊). If 1 < p < p ^*, no positive global solution exists. If p>p ^*, positive global solutions do exist. Extensions are given to the same problem for u _t=+¦x¦ u ^p .This research was supported in part by the Air Force Office of Scientific Research under Grant # AFOSR 88-0031 and in part by NSF Grant DMS-8 822 788. The United States Government is authorized to reproduce and distribute reprints for governmental purposes not withstanding any copyright notation therein.     

Deformation to breaking of deep water gravity waves

The results of laboratory observations of the deformation of deep water gravity waves leading to wave breaking are reported. The specially developed visualization technique which was used is described. A preliminary analysis of the results has led to similar conclusions than recently developed theories. As a main fact, the observed wave breaking appears as the result of, first, a modulational instability which causes the local wave steepness to approach a maximum and, second, a rapidly growing instability leading directly to the breaking.List of symbols L total wave length - H total wave height - crest elevation above still water level - trough depression below still water level - wave steepness =H/L - crest steepness =/L - trough steepness =/L - F ₁ forward horizontal length from zero-upcross point (A) to wave crest - F ₂ backward horizontal length from wave crest to zero-downcross point (B) - crest front steepness =/F ₁ - crest rear steepness =/F ₂ - vertical asymmetry factor=F ₂/F ₁ (describing the wave asymmetry with respect to a vertical axis through the wave crest) - µ horizontal asymmetry factor=/H (describing the wave asymmetry with respect to a horizontal axis: SWL) - T ₀ wavemaker period - L ₀ theoretical wave length of a small amplitude sinusoïdal wave generated at T _inf0 ^sup–1 frequency - ₀ average wave height     

Relation between viscoelasticity and shear-thinning behaviour in liquids

Summary The shear-thinning behaviour of a liquid is represented in terms of a relaxation time, defined by the ratio ₀/G₀ of initial viscous and elastic constants. The relationship provides a very simple basis for the evaluation of andG ₀ from viscosity/shear data. Results are compared with relaxation times and moduli from primary normal-stress measurement, from stress relaxation and from direct measurement of recoverable shear strain. Good agreement is found but there is experimental evidence the recoverable shear strain _e is related to normal stressN ₁ and shear stress by _e = N₁/3, which does not agree with the theoretical prediction of eitherWeissenberg orLodge.

---

Zusammenfassung Das Scherentzähungsverhalten einer Flüssigkeit wird mittels einer Relaxationszeit beschrieben, die durch das Verhältnis der Anfangswerte von Viskosität und Elastizitätsmodul ₀/G₀ definiert ist. Diese Beziehung eröffnet eine einfache Methode zur Bestimmung von undG ₀ aus Scherviskositätsmessungen. Die damit erhaltenen Ergebnisse werden mit Relaxationszeiten und Moduln verglichen, die durch Messung der ersten Normalspannungsdifferenz, der Spannungsrelaxation und der Scherdehnungsrückstellung (recoverable shear strain) gewonnen worden sind. Es wird eine gute Übereinstimmung gefunden, zugleich aber wird der experimentelle Nachweis geführt, daß die Scherdehnungsrückstellung _e mit der ersten NormalspannungsdifferenzN ₁ und der Schubspannung durch die Beziehung _e = N₁/3 verknüpft ist, was sowohl zu der theoretischen Voraussage vonWeissenberg als auch zu derjenigen vonLodge im Widerspruch steht.

---

---

With 10 figures and 1 table     

Diffusion in anisotropic porous media

An experimental system was constructed in order to measure the two distinct components of the effective diffusivity tensor in transversely isotropic, unconsolidated porous media. Measurements were made for porous media consisting of glass spheres, mica particles, and disks made from mylar sheets. Both the particle geometry and the void fraction of the porous media were determined experimentally, and theoretical calculations for the two components of the effective diffusivity tensor were carried out. The comparison between theory and experiment clearly indicates that the void fraction and particle geometry are insufficient to characterize the process of diffusion in anisotropic porous media. Roman Letters A interfacial area between - and -phases for the macroscopic system, m² - A _e area of entrances and exits of the -phase for the macroscopic system, m² - A interfacial area contained within the averaging volume, m² - a characteristic length of a particle, m - b average thickness of a particle, m - c _A concentration of species A, moles/m³ - c _o reference concentration of species A, moles/m³ - c _A intrinsic phase average concentration of species A, moles/m³ - c _a c _A–c _A, spatial deviation concentration of species A, moles/m³ - C c _A/c ₀, dimensionless concentration of species A - binary molecular diffusion coefficient, m²/s - D _eff effective diffusivity tensor, m²/s - D _xx component of the effective diffusivity tensor associated with diffusion parallel to the bedding plane, m²/s - D _yy component of the effective diffusivity tensor associated with diffusion perpendicular to the bedding plane, m²/s - D _eff effective diffusivity for isotropic systems, m₂/s - f vector field that maps c _A on to c _a , m - h depth of the mixing chamber, m     

Hydrodynamic instability of the contact zone between accelerated gases

An experimental apparatus for investigating Rayleigh-Taylor instability in the transition layer between two gases at accelerations g 10⁵g₀ (g₀ is the acceleration of gravity) is described. The constantly acting acceleration is communicated to the contact zone by the compression wave formed ahead of a flame front. The linear stage of development is investigated together with the effect of the thickness of the contact zone. It is shown that on the interval 0.3 < <- ( is the wavelength of the disturbance at the edge of the contact zone) the rate of growth of the perturbation amplitude 0.5₀, where ₀ is the amplitude growth rate for media separated by an interface with a discontinuous change of density.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 15–21, November–December, 1991.     

Construction of exact numerical solutions of the stationary traveling wave type for viscous thin films

An effective numerical procedure, based on the Galerkin method, for finding solutions of the stationary traveling wave type in the complete formulation is proposed for the case of viscous liquid films. Examples of a viscous film flowing freely down a vertical surface have been calculated. The calculations have been made for various values of the dimensionless surface tension , including =0. The method makes it possible to predict a number of bifurcations that occur as decreases. The existence of numerous families of stationary traveling waves when 1 was demonstrated in [6]. The present study shows that as 1 all but one of these families of wave solutions disappear. The shape of the periodic and solitary waves and the pressure distribution in the film are found for various . When =0 and the wave number is fairly small, the periodic solution has a singularity, as predicted in [14]: at the crest of the wave a corner point appears; the angle between the tangents at this point =140–150. The method proposed can be used to calculate other wavy film flows.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 3, pp. 94–100, May–June, 1990.     

The mirror relations and nonlinear viscoelasticity of polymer melts

An attempt is made to incorporate into a quasilinear viscoelastic constitutive equation of the Boltzmann superposition type the two mirror relations of Gleissle, as well as his relation between the steady-state first normal-stress difference and the shear viscosity curve. It is shown that the three relations can hold separately within this constitutive model, but not simultaneously, because they require a different nonlinear strain measure, namelyS ₁₂ () = – a ( – 1) (a = 0 for 1,a = 1 for 1) for the mirroring of the viscosities,S ₁₂ () = – a (–k ²/) (a = 0 for k, a = 1 for k) for the mirroring of the first normal-stress coefficients, and for the third relation. Here denotes the shear strain and erf the error function. Experimental data on melts of a low-density polyethylene, a high-density polyethylene and a polypropylene show that the mirror relations are passable approximations, but that the third relation meets reality surprisingly close if the right value ofk is used.     

One-dimensional problem of a shock in a gas

The self-similar problem of the motion of a cold gas subjected to an instantaneous impulse is considered. A solution is constructed in the neighborhood of the known exact solution for a gas with a specific heat ratio =1.4 [1–4]. An analytic expression is obtained in this neighborhood for the dependence of the index of self-similarity n on the parameter h, which is related to the adiabatic index by h=(+1)/(–1). The results of a numerical calculation of n versus h are compared with the analytic expression.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 6, pp. 74–78, November–December, 1973.     

Optical co-ordinates in general relativity 2 — the problem of distance

Summary Let denote the congruence of null geodesics associated with a given optical observer inV ₄. We prove that determines a unique collection of vector fieldsM₍₎ ( =1, 2, 3) and ₍₀₎ overV ₄, satisfying a weak version of Killing's conditions.This allows a natural interpretation of these fields as the infinitesimal generators of spatial rotations and temporal translation relative to the given observer. We prove also that the definition of the fieldsM₍₎ and ₍₀₎ is mathematically equivalent to the choice of a distinguished affine parameter f along the curves of, playing the role of a retarded distance from the observer.The relation between f and other possible definitions of distance is discussed.

---

Sommario Sia la congruenza di geodetiche nulle associata ad un osservatore ottico assegnato nello spazio-tempoV ₄. Dimostriamo che determina un'unica collezione di campi vettorialiM₍₎ ( =1, 2, 3) e ₍₀₎ inV ₄ che soddisfano una versione in forma debole delle equazioni di Killing. Ciò suggerisce una naturale interpretazione di questi campi come generatori infinitesimi di rotazioni spaziali e traslazioni temporali relative all'osservatore assegnato. Dimostriamo anche che la definizione dei campiM₍₎, ₍₀₎ è matematicamente equivalente alla scelta di un parametro affine privilegiato f lungo le curve di, che gioca il ruolo di distanza ritardata dall'osservatore. Successivamente si esaminano i legami tra f ed altre possibili definizioni di distanza in grande.

---

---

Work performed in the sphere of activity of: Gruppo Nazionale per la Fisica Matematica del CNR.     

Natural convection from a horizontal permeable surface in a porous medium - numerical and asymptotic solutions

The equations which govern the similarity solution for free convection boundary-layer flow above a permeable, horizontal surface in a fluid-saturated porous medium are considered. These are seen to depend on the dimensionless parameters and m measuring mass transport rate and the wall temperature variation, respectively. Numerical solutions are presented for a wide range of values of and m. Asymptotic solutions are obtained for ¦¦ large (for both fluid injection, > 0, and fluid withdrawal, < 0) and for m large. These are compared with the numerical solutions.     

An example of a quasiconvex function that is not polyconvex in two dimensions

We study the different notions of convexity for the function f () = ||² (||² – 2 det ) where ^2×2, introduced by Dacorogna & Marcellini. We show that f is convex, polyconvex, quasiconvex, rank-one convex, if and only if ¦¦ 2/3 2, 1, 1+ (for some >0), 2/3, respectively.