Synthesis and characterization of C3N4 hard films

C₃N₄ films have been synthesized on both Si and Ft substrates by microwave plasma chemical vapor deposition (MPCVD) method. X-ray spectra were calculated for single phase α-C₃N₄ and β-C₃N₄ respectively. The experimental X-ray spectra of films deposited on both Si and Pt substrates showed all the strong peaks of α-C₃N₄ and β-C₃N₄ so the films are mixtures of α-C₃N₄ and β-C₃N₄. The N/C atomic ratio is in the range of 1.0–2.0. X-ray photoelectron spectroscopy (XPS) analysis indicated that the binding energy of Is and N ls are 286.2 eV and 399.5 eV respectively, corresponding to polarized C-N bond. Fourier transform infrared absorption (FT-IR) and Raman spectra support the existence of C-N covalent bond in the films. Nano-indentation hardness tests showed that the bulk modulus of a film deposited on Pt is up to 349 GPa     

Synthesis and characterization of C3N4 crystal (I)

A successful experimental synthesis of pure crystalline β- and α-C₃N₄ films on Si(100) substrate was carried out by bias-assisted hot filament chemical vapor deposition (bias-HFCVD). It is found that a mixed-phase C₃-_I-Si_xN_y buffer layer was formed between the Si substrate and the C-N film. A “lattice match selection” was proposed to study the growth mechanism of C₃N₄ clusters composed of many crystal columns with hexagonal facets. Project supported by the National Natural Science Foundation of China and the Chinese Academy of Sciences.     

Growth morphology and structural characteristic of C70 single crystals

Large size C₇₀ single crystals with the dimension of more than 5 mm are grown from the vapor phase by controlling nucleation. X-ray diffraction and electron diffraction confirm that in the C₇₀ single crystal a phase of the hexagonal close-packed (hcp) structure coexists with a minor face-center-cubic (fcc) phase at room temperature. The morphologies and their formation mechanism of the C₇₀ single crystals are investigated by means of scanning electron micrascopy and optical microscopy. The influence of growth conditions on the morphologies of C₇₀ single crystals is discussed. Project supported by the National Natural Science Foundation of China (Grant No. 59772026).     

Synchrotron radiation photoemission spectrum study on K3C60 film

K₃C₆₀, single crystal film was prepared on the cleaved (111) surface of C₆₀, single crystal. Synchrotron radiation angle-resolved photoemission spectra were measured at normal emission with sample temperature at × 150K. Up to four subpeaks of LUMO-derived band were observed. These sub-peaks exhibit distinct energy dispersions which resemble in general the theoretical ones calculated for K₃C₆₀ at low temperature with the so-called one-dimensional disordered structure. But there is large deviation of experimental sub-band intervals from the theoretical values. This result is meaningful for the studies of the physical properties of alkali-doped C₆₀ solids, e.g. the mechanism for superconductivity.     

Relative Projective and Injective Dimensions

We study the concepts of the 𝒫_C-projective and the ?_C-injective dimensions of a module in the noncommutative case, weakening the condition of C being semidualizing. We give the relations between these dimensions and the C-relative Gorenstein dimensions (G_C-projective and G_C-injective dimensions) of the module. Finally, we compare, in some circumstances, the global 𝒫_C-projective dimension of a ring and the global dimension of the endomorphisms ring of C.     

A Variation of an Extremal Theorem Due to Woodall

We consider a variation of an extremal theorem due to Woodall [12, or 1, Chapter 3] as follows: Determine the smallest even integer (₃C₁,n), such that every n-term graphic sequence = (d₁, d₂,..., d_n) with term sum () = d₁ + d₂ + ... + d_n (₃C₁,n) has a realization G containing a cycle of length r for each r = 3,4,...,l. In this paper, the values of (₃C_l,n) are determined for l = 2m – 1,n 3m – 4 and for l = 2m,n 5m – 7, where m 4.AMS Mathematics subject classification (1991) 05C35Project supported by the National Natural Science Foundation of China (Grant No. 19971086) and the Doctoral Program Foundation of National Education Department of China     

Formation of nanocrystalline Fe73.5Cu1Nb3Si13.5B9 alloy under high pressure

The formation of nanocrystalline Fe_73.5 Cu₁Nb₃Si_13.5 B₉ alloy by annealing an amorphous Fe_73.5Cu₁Nb₃Si_13.5B₉ alloy at a temperature of 823 K under pressures in the range of 1–5 GPa is investigated by using X-ray diffraction, electron diffraction, and transmission electron microscopy. The high pressure experiments are carried out in belt-type pressure apparatus. Experimental results show that the initial crystalline phase in these annealed alloys is a-Fe solid solution (named a-Fe phase below), and high pressure has a great influence on the crystallization process of the a-Fe phase. The grain size of the a-Fe phase decreases with the increase of pressure (P). The volume fraction of the a-Fe phase increases with increasing the pressure as the pressure is below 2 GPa, and then decreases (Pδ2 GPa). The mechanism for the effects of the high pressure on the crystallization process of amorphous Fe_73.5Cu₁Nb₃Si_13.5B₉ alloy is discussed Project supported by the National Natural Science Foundation of China (Grant No. 19674070) and the Natural Science Foundation of Hebei Province.     

The Flag-Transitive C 3-Geometries of Finite Order

It is shown that a flag-transitive C ₃-geometry of finite order (x, y) with x2 is either a finite building of type C ₃ (and hence the classical polar space for a 6-dimensional symplectic space, a 6-dimensional orthogonal space of plus type, a 6- or 7-dimensional hermitian space, a 7-dimensional orthogonal space, or an 8-dimensional orthogonal space of minus type) or the sporadic A ₇-geometry with 7 points.     

Phase transition in layered perovskite-like manganate Ca3Mn2O7 under high pressure

In situ high pressure energy dispersive X-ray diffraction measurements on the layered perovskite-like manganate Ca₃Mn₂O₇ powder under pressures were performed by using the diamond anvil cell with synchrotron radiation. The results show that the structure of layered perovskite-like manganate Ca₃Mn₂O₇ is unstable under pressure due to the easy compression of NaCl-type blocks. The structure of Ca₃Mn₂O₇ underwent two phase transitions under pressures in the range of 0–35 GPa. One was at about 1.3 GPa with the crystal structure changing from tetragonal to orthorhombic. The other was at about 9.5 GPa with the crystal structure changing from orthorhombic back to another tetragonal.     

Diamond nucleation on surface of C60 thin layers

Diamond nucleation on the surface of C₆₀ thin layers and intermediate layer of Si substrates are studied by scanning electron microscopy (SEM). The cross-section SEM images of diamond films show that diamond grains really nucleate on the surface of C₆₀ thin layers. The SEM images of diamond nucleating sites show the nucleating aggregation of diamond on C₆₀ surfaces. The preferential oriented diamond films are observed. The plasma pretreatment of C₆₀ sublimating layers is a key factor for diamond nucleation.     

Synthesis and characterization of C3N4 crystal (II)

Single C₃N₄ crystals with 1–3 μ in length and 300 nm in cross area was obtained on nickel substrate. The results rule out the uncertainty of the experimental lattice parameters caused by C-Si-N phase when the growth was on silicon. The X-ray diffraction and transmission electron microscopy with selective-area electron diffraction give the lattice constantsa = 0.624 nm andc = 0.236 nm for β-C₃N₄, and α=0. 638 nm andc = 0.464 8 nm for α-C₃N₄, which are respectively 2.5% and 1.3% lower than those of the latest first-principle calculations. An N:C ratio of 1.30–1.40 was determined by energy dispersive X-ray. Based on the experimental lattice constants, the bulk modulus of the obtained β-C₃N₄ are in the region of 425–445 GPa.     

退化C_0-半群族的指数稳定性

首先,应用泛函分析和算子理论在Hilbert空间中得到了关于退化C_0-半群指数稳定的充分必要条件.然后,讨论了退化C_0-半群族的指数稳定性问题,应用退化C_0-半群理论给出了充分必要条件.     

A variant smoothing Newton method for P0-NCP based on a new smoothing function

In this paper, we present a new one-step smoothing Newton method proposed for solving the non-linear complementarity problem with _P0$P_0$-function based on a new smoothing NCP$NCP$-function. We adopt a variant merit function. Our algorithm needs only to solve one linear system of equations and perform one line search per iteration. It shows that any accumulation point of the iteration sequence generated by our algorithm is a solution of _P0-NCP$P_0\text{-}NCP$. Furthermore, under the assumption that the solution set is non-empty and bounded, we can guarantee at least one accumulation point of the generated sequence. Numerical experiments show the feasibility and efficiency of the algorithm.     

On C2.L-Geometries

A C₂.L-geometry is a geometry of rank 3 with elements called points, lines and quads, where residues of points are linear spaces, residues of lines are generalized digons and residues of quads are generalized quadrangles. Some sufficient conditions can be found in the literature for a C₂.L-geometry to be a quotient of a truncated C_n-building. We shall weaken those conditions in this paper.     

Atomic scale epitaxial growth of BaTiO3 thin films by laser molecular beam epitaxy

By using laser molecular beam epitaxy (L-MBE), atomic scale epitaxid growth of BaTiO₃(BTO) thin films on SrTiO₃ (STO) substrates is achieved. Measurements of reflection high energy electron diffraction (RHEED), X-ray diffraction (XRD), scanning electron microscopy, and transmission electron microscopy reveal that the BTO films arec-axis oriented single crystals with smooth surface. The multi-layer ferroelectric/superconducting heterostructures are also prepared and the ferroelectric properties of BTO films are studied. The results show that by using L-MBE technique, high quality BTO films and improved device performance can be obtained. Project supported by the National Natural Science Foundation of China, the National Department of Finance, and the National Center for R and D on Superconductivity of China.     

Absolute summability of infinite series

It is shown in [4] that if a normal matrix,A satisfies some conditions then |C,1| _k summability implies |A| _k summability wherek≥1. In the present paper, we consider the converse implication.     

一类二阶哈密尔顿系统的周期解

在(CPS)_C及(PS)_C条件下,利用Ambrosetti-Rabinowitz对称形式的山路引理,研究了一类二阶哈密尔顿保守系统在给定能量面上的无穷多个周期解的存在性问题.     

Weak barrelledness for C(X) spaces

Buchwalter and Schmets reconciled C_c(X) and C_p(X) spaces with most of the weak barrelledness conditions of 1973, but could not determine if -barrelled ⇔ ?^∞-barrelled for C_c(X). The areas grew apart. Full reconciliation with the fourteen conditions adopted by Saxon and Sánchez Ruiz needs their 1997 characterization of Ruess' property (L), which allows us to reduce the C_c(X) problem to its 1973 status and solve it by carefully translating the topology of Kunen (1980) and van Mill (1982) to find the example that eluded Buchwalter and Schmets. The more tractable C_p(X) readily partitions the conditions into just two equivalence classes, the same as for metrizable locally convex spaces, instead of the five required for C_c(X) spaces. Our paper elicits others, soon to appear, that analytically characterize when the Tychonov space X is pseudocompact, or Warner bounded, or when C_c(X) is a df-space (Jarchow's 1981 question).     

The N-Isometric Isomorphisms in Linear N-Normed C^＊-Algebras

We prove the Hyers-Ulam stability of linear N-isometries in linear N-normed Banach mod- ules over a unital C^＊-algebra. The main purpose of this paper is to investigate N-isometric C^＊-algebra isomorphisms between linear N-normed C^＊-algebras, N-isometric Poisson C^＊-algebra isomorphisms between linear N-normed Poisson C^＊-algebras, N-isometric Lie C^＊-algebra isomorphisms between linear N-normed Lie C^＊-algebras, N-isometric Poisson JC^＊-algebra isomorphisms between linear N-normed Poisson JC^＊-algebras, and N-isometric Lie JC^＊-algebra isomorphisms between linear N-normed Lie JC^＊-algebras. Moreover, we prove the Hyers- Ulam stability of t：heir N-isometric homomorphisms.     

Busy period analysis of queue: Lattice path approach

In this paper, we find the busy period density of queues in explicit computational form, through lattice path (LP) approach. Both the arrival and service time distributions are approximated by 2-phase Cox distribution C₂, which has a Markovian property enabling us to use LP combinatorics. Since any distribution with rational Laplace–Stieltjes transform (LST) and square coefficient of variation (CV²) lying in [1/2,∞) can be approximated by a C₂([M. Agarwal, K. Sen, B. Borkakaty, Busy period density of queueing system C₃/M/1, Journal of Combinatorics, Information and Systems Sciences 31 (1–4) (2006) 127–161]), the results obtained would be applicable to a very wide class of distributions occurring in real life.