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The syntheses of ∝ - sulfinated compounds are described. Their reactions with HF are investigated. A Cl/F-exchange reaction with a spontaneous rearrangement into a β-fluorinated thioethercarbonylfluoride was observed. Factors influencing the reaction and the mechanism are discussed. 相似文献
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A Main‐Group Analogue of Housene: The Subtle Influence of the Inert‐Pair Effect in Group 15 Clusters
Cheryl Fish Michael Green John C. Jeffery Richard J. Kilby Jason M. Lynam John E. McGrady Dimitrios A. Pantazis Christopher A. Russell Charlotte E. Willans 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2006,118(40):6837-6841
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