共查询到20条相似文献,搜索用时 15 毫秒
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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(6):1675-1679
Solar light harvesting by photocatalytic H2 evolution from water could solve the problem of greenhouse gas emission from fossil fuels with alternative clean energy. However, the development of more efficient and robust catalytic systems remains a great challenge for the technological use on a large scale. Here we report the synthesis of a sol–gel prepared mesoporous graphitic carbon nitride (sg‐CN) combined with nickel phosphide (Ni2P) which acts as a superior co‐catalyst for efficient photocatalytic H2 evolution by visible light. This integrated system shows a much higher catalytic activity than the physical mixture of Ni2P and sg‐CN or metallic nickel on sg‐CN under similar conditions. Time‐resolved photoluminescence and electron paramagnetic resonance (EPR) spectroscopic studies revealed that the enhanced carrier transfer at the Ni2P–sg‐CN heterojunction is the prime source for improved activity. 相似文献
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Wenlong Yang Lei Zhang Yong Hu Yijun Zhong Hao Bin Wu Xiong Wen Lou 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2012,124(46):11807-11807
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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(24):6968-6972
Transition metals have been successfully applied to catalyze non‐natural chemical transformations within living cells, with the highly efficient labeling of subcellular components and the activation of prodrugs. In vivo applications, however, have been scarce, with a need for the specific cellular targeting of the active transition metals. Here, we show the design and application of cancer‐targeting palladium catalysts, with their specific uptake in brain cancer (glioblastoma) cells, while maintaining their catalytic activity. In these cells, for the first time, two different anticancer agents were synthesized simultaneously intracellularly, by two totally different mechanisms (in situ synthesis and decaging), enhancing the therapeutic effect of the drugs. Tumor specificity of the catalysts together with their ability to perform simultaneous multiple bioorthogonal transformations will empower the application of in vivo transition metals for drug activation strategies. 相似文献
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Mohd Izham binSaiman Gemma L. Brett Ramchandra Tiruvalam Michael M. Forde Kate Sharples Adam Thetford Robert L. Jenkins Nikolaos Dimitratos Jose A. Lopez‐Sanchez Damien M. Murphy Donald Bethell David J. Willock Stuart H. Taylor David W. Knight Christopher J. Kiely Graham J. Hutchings 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2012,124(24):6083-6087
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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(17):4817-4821
Ta3N5 is a very promising photocatalyst for solar water splitting because of its wide spectrum solar energy utilization up to 600 nm and suitable energy band position straddling the water splitting redox reactions. However, its development has long been impeded by poor compatibility with electrolytes. Herein, we demonstrate a simple sputtering‐nitridation process to fabricate high‐performance Ta3N5 film photoanodes owing to successful synthesis of the vital TaOδ precursors. An effective GaN coating strategy is developed to remarkably stabilize Ta3N5 by forming a crystalline nitride‐on‐nitride structure with an improved nitride/electrolyte interface. A stable, high photocurrent density of 8 mA cm−2 was obtained with a CoPi/GaN/Ta3N5 photoanode at 1.2 VRHE under simulated sunlight, with O2 and H2 generated at a Faraday efficiency of unity over 12 h. Our vapor‐phase deposition method can be used to fabricate high‐performance (oxy)nitrides for practical photoelectrochemical applications. 相似文献
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