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《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2017,129(26):7782-7786
Methylammonium‐mediated phase‐evolution behavior of FA1−xMAxPbI3 mixed‐organic‐cation perovskite (MOCP) is studied. It is found that by simply enriching the MOCP precursor solutions with excess methylammonium cations, the MOCPs form via a dynamic composition‐tuning process that is key to obtaining MOCP thin films with superior properties. This simple chemical approach addresses several key challenges, such as control over phase purity, uniformity, grain size, composition, etc., associated with the solution‐growth of MOCP thin films with targeted compositions. 相似文献
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Zhipeng Shao Zaiwei Wang Zhipeng Li Yingping Fan Hongguang Meng Ranran Liu Yan Wang Anders Hagfeldt Guanglei Cui Shuping Pang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(17):5643-5647
An easy and scalable methylamine (MA) gas healing method was realized for inorganic cesium‐based perovskite (CsPbX3) layers by incorporating a certain amount of MAX (X=I or Br) initiators into the raw film. It was found that the excess MAX accelerated the absorption of the MA gas into the CsPbX3 film and quickly turned it into a liquid intermediate phase. Through the healing process, a highly uniform and highly crystalline CsPbX3 film with enhanced photovoltaic performance was obtained. Moreover, the chemical interactions between a series of halides and MA gas molecules were studied, and the results could offer guidance in further optimizations of the healing strategy. 相似文献
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Fengzhu Li Chaoshen Zhang Jin‐Hua Huang Haochen Fan Huijia Wang Pengcheng Wang Chuanlang Zhan Cai‐Ming Liu Xiangjun Li Lian‐Ming Yang Yanlin Song Ke‐Jian Jiang 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2019,131(20):6760-6764
Tin‐based halide perovskite materials have been successfully employed in lead‐free perovskite solar cells, but the overall power conversion efficiencies (PCEs) have been limited by the high carrier concentration from the facile oxidation of Sn2+ to Sn4+. Now a chemical route is developed for fabrication of high‐quality methylammonium tin iodide perovskite (MASnI3) films: hydrazinium tin iodide (HASnI3) perovskite film is first solution‐deposited using presursors hydrazinium iodide (HAI) and tin iodide (SnI2), and then transformed into MASnI3 via a cation displacement approach. With the two‐step process, a dense and uniform MASnI3 film is obtained with large grain sizes and high crystallization. Detrimental oxidation is suppressed by the hydrazine released from the film during the transformation. With the MASnI3 as light harvester, mesoporous perovskite solar cells were prepared, and a maximum power conversion efficiency (PCE) of 7.13 % is delivered with good reproducibility. 相似文献