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大学有机化学实验课程中的思政案例设计 总被引:1,自引:0,他引:1
为充分挖掘有机化学实验课程中的思政元素,发挥专业课程在立德树人方面的重要作用,我们对部分有机化学教学实验的教学理念和教学内容进行了改革和探索。构建了以有机化学实验知识为主体,以中华传统文化、有机化学中的励志故事、日常生活中的有机化学等人文素材为主导的有机化学实验课程的思政教学体系,本文主要对课程思政的设计理念和具体案例进行了介绍。 相似文献
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课程思政是高校落实立德树人根本任务的重要举措,是完善“三全育人”的重要抓手。化学是我国科学研究的重要基础,对提升原始创新能力具有重要意义。化学专业教学中融入思想政治教育的前提是建设好一门课程。针对当前专业课教学中存在的课程思政体系不完善、思政元素与专业课程融合程度低、教师思政教学水平有待提高等问题,以华中科技大学化学与化工学院专业概论课为试点,完善课程设计与教学方法,探索化学专业教学中的课程思政建设。通过剖析化学课程思政的意义与难点,构建专业概论课实施方案,形成一套行之有效的化学课程思政建设体系。 相似文献
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为适应西部地区对化学类高素质人才的迫切需求,提高教学质量,以满足新时代教育的不断发展,实现课程专业育人与思政育人的同向同行、互融互促,广西师范大学在有机化学教学中不断深化教育教学改革,在提升课程教学水平的同时深化对思政教育的探索与实践。课程教学以“育人为本、德育为先”为理念,通过构建思政资源库、现代信息技术与思政教学深度融合、开展专题活动等多种形式将思政教育与有机化学教学相融合,在教授课程专业知识的全过程中渗透思想品德教育,帮助学生树立正确的人生观、价值观,培养学生的爱国情怀、社会责任感、创新精神、实践能力等。 相似文献
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Charles H. Langley Diwakar M. Pawar Eric A. Noe 《Journal of Molecular Structure》2005,732(1-3):99-111
The optimized geometries, relative free energies and related thermodynamic properties, harmonic frequencies, and dipole moments have been calculated at the HF and MP2 levels for ethynyl formate (1a), ethynyl acetate (1b), cyano formate, HCO2CN (1c), cyano acetate (1d), S-ethynyl thioformate (2a), S-ethynyl thioacetate (2b), S-cyano thioformate (2c), S-cyano thioacetate (2d), N-ethynylformamide (3a), N-ethynylacetamide (3b), N-cyanoformamide (3c), and N-cyanoacetamide (3d) with the gaussian 98 program. For ethynyl formate, the calculation for 25 °C at the MP2/6-311++G(df,pd) level predicts that the Z isomer is more stable by 1.23 kcal/mol. For S-ethynyl thioformate, calculations at the MP2/6-311++G(2d,2p) level predict that the E isomer is favored by 0.71 kcal/mol at 25 °C. The E isomers of N-ethynylformamide and N-ethynylacetamide were found at all levels to be more stable than the Z isomers at 25 °C. For cyano formate and cyano acetate, calculations at the MP2/6-311++G(df,pd) level predict that the Z isomers are more stable at 25 °C by 1.50 and 2.72 kcal/mol, respectively. At this level and temperature, the Z isomers of 2c, 2d, 3c, and 3d are predicted to have free energies of 0.46, −0.07, 1.22, and 2.28 kcal/mol, respectively, relative to the E conformations. Z to E free-energy barriers at 25 °C of 8.63, 10.64, 17.63, 7.39, and 14.03 kcal/mol were calculated for 1a, 2a, 3a, 1c, and 3c at the HF/6-311G(d,p) level, and at the HF/6-311+G(d,p) level, the free-energy barrier for 2c was 7.08 kcal/mol. 相似文献
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Several kinds of tea, camomile and herbal tea were analysed to determine natural and artificial radioactivity. The radionuclides were determined by alpha (210Po) and gamma (228Ac, 214Pb, 214Bi, 210Pb, 40K and 137Cs) spectrometry. 228Ac ranged between 0.6 and 9.0 Bq kg−1dry; 210Po between 1.90 and 36.1 Bq kg−1dry; 214Pb and 214Bi between 0.7 and 4.9 Bq kg−1dry; 210Pb between < 10.0 and 58.9 Bq kg−1dry; 40K between 463 and 936 Bq kg−1dry; 137Cs between < 0.3 and 2.6 Bq kg−1dry. The percentage of 210Po extraction in infusion was also determined; the arithmetical mean value of percentage of 210Po extraction resulted 20.7 ± 7.50. 相似文献
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黎志明 《广东微量元素科学》2010,17(7):49-70
从心脑血管疾病的流行率、心脑血管疾病的元素病因、心脑血管疾病的元素诊断和心脑血管疾病的元素治疗等4个方面讨论了元素医学防治心脑血管疾病的临床意义。 相似文献
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Gas chromatography-mass spectrometry (GC-MS) and liquid chromatography with fluorescence detection (LC-FL) methods have been proposed for the determination of low level nitrite and nitrate in biological, food and environmental samples. The methods include derivatization of aqueous nitrite with 2,3-diaminonaphthalene (DAN), enzymatic reduction of nitrate to nitrite, extraction with toluene and chromatographic analyses of highly fluorescent 2,3-naphthotriazole (NAT) derivative of nitrite by using GC-MS in selected-ion-monitoring (SIM) mode and LC-FL. Nitrite and nitrate ions in solid samples were extracted with 0.5 M aqueous NaOH by sonication. The recoveries of nitrite and nitrate ions based on GC-MS and LC-FL results were 98.40% and 98.10% and the precision of these methods, as indicated by the relative standard deviations (RSDs) were 1.00% for nitrite and 1.20% for nitrate, respectively. The limits of detection of the GC-MS in SIM mode and LC-FL methods based on S/N = 3 were 0.02 and 0.29 pg/ml for nitrite and 0.03 and 0.30 pg/ml for nitrate, respectively. 相似文献
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阐述了SHAB规则,分类,酸碱软硬度的定量标度和理论解释。根据SHAB规则把体内微量元素分为Lewis硬酸,软酸与交界酸和硬碱,软碱与交界碱,体内不同体液和器官含有丰富的软硬配体,与各类软硬酸(金属离子)结合成不同稳定性的配合物,发挥其生物活性作用。 相似文献
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Iwona A. Rutkowska Anna Wadas Ewelina Szaniawska Anna Chmielnicka Agnieszka Zlotorowicz Pawel J. Kulesza 《Current Opinion in Electrochemistry》2020
Copper- and copper oxide–based materials are, in principle, promising components (supports, reactive sites, and visible light–absorbing semiconductors) of electrocatalysts and photocathodes for reduction of carbon dioxide. Electrochemical and photoelectrochemical approaches are generally suitable for the low-temperature CO2-conversion to carbon-based simple organic fuels or utility chemicals.Different concepts of utilization, including nanostructuring, doping, admixing, preconditioning, modification, or functionalization of various copper- and copper oxide–based systems for catalytic electroreduction and photoelectrochemical reduction of CO2 are elucidated, as well as important strategies to enhance the systems' overall activity and stability are discussed. 相似文献
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M. Gaber S. S. Al-Shihry A. A. El-Bindary 《Journal of Thermal Analysis and Calorimetry》2005,82(1):63-68
Summary Proton-ligand dissociation constant of 2-mercapto-5-(2-hydroxynaphthylideamino)-1,3,4-thiadiazole (MHT) and the stepwise stability
constants of its metal complexes were determined potentiometrically in 40 mass/mass% ethanol-water mixture containing 0.1
M KCl. The stabilities of the complexes follow the order: Cu2+>Ni2+>Co2+>Mn2+. The dissociation constant (pKH) of MHT and the stability constants (logK) of its metal complexes were determined at different temperatures and the corresponding thermodynamic parameters were calculated
and discussed. The proton dissociation process is non-spontaneous, endothermic and entropically unfavoured. The formation
of the metal complexes was found to be spontaneous, endothermic and entropically favoured. 相似文献
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M. G. Voronkov O. M. Trofimova Yu. I. Bolgova L. V. Klyba L. I. Larina A. I. Albanov V. A. Pestunovich N. F. Chernov K. B. Petrushenko 《Chemistry of Heterocyclic Compounds》2003,39(12):1639-1644
We have synthesized 1- and 2-(trimethylsilylmethyl)- and 1- and 2-(trimethoxysilylmethyl)benzotriazoles by reaction of 1,2,3-benzotriazolylsodium with trimethyl- or trimethoxy(chloromethyl)silane. We obtained 1- and 2-(silatranylmethyl)benzotriazoles by transesterification of the latter with triethanolamine. 相似文献
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The high-resolution (1)H, (13)C, (1)H-(1)H COSY and (1)H-(13)C COSY NMR spectra have been recorded in CDCl(3) for arylacetonitriles 1-12 and analyzed. The arylacetonitriles 3-7 exist in two isomeric forms E (methyl group is anti to cyano group) and Z (the methyl group is syn to cyano group) in solution. Normal chair conformation with equatorial orientations of phenyl rings at C-2 and C-6 for monocyclic nitriles 1 and 2, epimeric chair structure EC (axial configuration of methyl group at C-3) for both the E and Z isomers of arylacetonitrile derivatives (3-7) and a distorted boat form, B(3), for the N-acylacetonitrile derivatives (8-10) have been proposed based on NMR data. The bicyclic nitriles 11 and 12 exist in twin chair conformations in solution. DFT calculations and chemical shifts also support these conformations. Geometry optimizations for 1-12 were carried out according to density functional theory using B3LYP/6-31G(d,p) basis set and for 1 and 8 the theoretical geometrical parameters have been compared with those of single crystal measurements. 相似文献
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C. K. Kim M. Aguilar-vega D. R. Paul 《Journal of Polymer Science.Polymer Physics》1992,30(10):1131-1142
Dynamic mechanical and gas transport properties for homogeneous homopolymer blends and random copolymers of bisphenol-A and tetramethyl bisphenol-A polycarbonates (PC-TMPC) were determined. The gas transport measurements were performed at 35°C for the gases He, H2, O2, Ar, N2, CH4, and CO2. The results show that the copolymers have lower permeability, apparent diffusion, and solubility coefficients than the blends. Permeability coefficients for blends follow a semilogarithmic ideal mixing rule while copolymers exhibit negative deviations from this. Specific volume measurements show that the free volume available for gas transport is slightly larger in copolymers than in blends of the same composition. These apparently contradictory results may relate to the differences in local mode chain motions observed for the copolymer and blend series. The γ relaxation processes in PC and TMPC seem to operate independently in the blends (no intermolecular coupling) while there is clear evidence for intramolecular coupling in the copolymers. © 1992 John Wiley & Sons, Inc. 相似文献