Derivation of the classical theory of correlations in fluids by means of functional differentiation

The k-particle, infinite-volume distribution functions $\text{n}\text{?}{}_{\mathrm{k}}\text{(}\text{r}{}_1\text{, …,}\text{r}{}_{\mathrm{k?1}}\text{, γ)}$ and modified Ursell correlation functions $\text{U}\text{?}{}_{\mathrm{k}}\text{(}\text{r}{}_1\text{, …,}\text{r}{}_{\mathrm{k?1}}\text{, γ)}$ of a classical system of particles with the two-body potential $\text{q(}\text{r}\text{) + γ}{}^{\mathrm{\nu }}\text{K(γ}\text{r}\text{)}$ are considered. The limiting values of the functions $\text{n}\text{?}{}_{\mathrm{k}}\text{(}\text{r}{}_1\text{, …,}\text{r}{}_{\mathrm{k?1}}\text{, γ),}\text{n}\text{?}{}_{\mathrm{k}}\text{(}\text{S}{}_1\text{/γ, …,}\text{S}{}_{\mathrm{k?1}}\text{/γ, γ)}$ and $\text{γ(}{}^{\mathrm{1?k}}\text{)ν}\text{U}\text{?}{}_{\mathrm{k}}\text{(}\text{S}{}_1\text{/γ, …,}\text{S}{}_{\mathrm{k?1}}\text{/γ, γ)}$ in the limit γ → 0 are calculated, under fairly weak conditions on q and K, by a method involving functional differentiation. These limiting functions are used to describe the molecular structure of the various states of the system both in the range of the potential q(r) and in the rage of the potential γ^νK(γr). The direct correlation function c? (r, γ) is also considered and it is shown that for $\text{S}\text{≠ 0}$, $\text{lim}{}_{\mathrm{\gamma \to 0}}\text{γ}{}^{\mathrm{?\nu }}\text{c}\text{?}\text{(}\text{S}\text{γ}\text{, γ) = ?βK (}\text{S}\text{)}$, for all one-phase states, where β is the reciprocal temperature. Special cases of our results confirm those of other authors, including the well-known results of Ornstein and Zernike.     

Extending the QCD leading logs up to reggeon field theory

The deep inelastic structure function D(ω, q²) is calculated in the leading log approximation for $\text{(}\text{Nβ}{}_2\text{π}{}^2\text{)α}{}^2{}_{\mathrm{<mtext>S</mtext>}}\text{(q}{}_0{}^2\text{) 1}\text{n}\text{ω < 0.84 1}\text{n}\text{(}\text{1}\text{α}{}_{\mathrm{<mtext>S</mtext>}}\text{(q}{}^2\text{))}$. For larger ω up to ( the influence of reggeon cuts proves to slow down the growth of the structure function. A reggeon diagram technique is developed, and D is calculated up to a pre-exponent O(1), leading to D(ω, q²) ∝ q² for $\text{(}\text{Nβ}{}_2\text{π}{}^2\text{)α}{}^2{}_{\mathrm{<mtext>S</mtext>}}\text{(q}{}^2{}_0\text{) 1}\text{n}\text{ω ? 0.42}\text{α}{}^2{}_{\mathrm{<mtext>S</mtext>}}\text{(q}{}_0{}^2\text{)}\text{α}{}_{\mathrm{<mtext>S</mtext>}}{}^2\text{(q}{}^2\text{)}$. By assuming the reggeon diagrams when ω is still greater, one can expect to obtain a strong coupling behaviour: D(ω, q²) ∝ q²(ln ω)^η (η <2).     

Reflection of long waves by interfaces

We derive comparison identities for waves satisfying the equation d²Ψ/dz²+q²(z)Ψ=0. One of these identities is used to show that to second order in the product (wavenumber component normal to interface) × (interface thickness), the reflection amplitude is given by $\text{r=(1?2q}{}_1\text{q}{}_2\text{l}{}^2\text{)}\text{(q}{}_1\text{?q}{}_2\text{)}\text{(q}{}_1\text{+q}{}_2\text{)}$, where l is a legnth determined by the deviation of the interface profile from a step, and q₁, q₂ are the normal components of the wave numbers in media 1 and 2 on either side of the interface. For the continuous interfaces discussed, l is about two-fifths of the 10–90 interface thickness. The corresponding formula for the transmission amplitude is $\text{t=(1+}\text{1}\text{2}\text{(q}{}_1\text{?q}{}_2\text{)}{}^2\text{l}{}^2\text{)}\text{2q}{}_1\text{(q}{}_1\text{+q}{}_2\text{)}$.     

Matthiessen's rule and its variation for cyclotron resonance width in two and three dimensions

Based on the proper connected diagram expansion, we calculated cyclotron resonance widths Γ_n associated with neighboring Landau states (n, n +1) for free electrons in interaction with more than one kind of impurities. In 3D usual Matthiessen's rule Γ_n=Γ⁽¹⁾_n+Γ⁽²⁾_n+…where Γ⁽ⁱ⁾_n represent widths calculated separately for each kind, is obtained. In 2D a new rule: is obtained.     

Nonorthogonality corrections in the method of correlated basis functions

A set of normalized linearly independent basis functions φ₁, φ₂, …, φ_j, … generates matrix representatives $\text{H}$ and $\text{N}$ of the Hamiltonian operator and the identity. An orthonormal basis $\text{φ}{}_1$, $\text{φ}{}_2$, …, $\text{φ}{}_{\mathrm{j}}$, … generated by a Löwdin transformation is characterized by the distance in Hilbert space between $\text{φ}{}_{\mathrm{j}}$ and φ_j. The choice of positive definite $\text{N}$${}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ minimizes these distances and maximizes the diagonal elements of $\text{N}$${}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$. Again for positive definite $\text{N}$${}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and a finite basis, 1 ? j ? p, the analysis yields a general theorem on Trace $\text{N}$${}^{\mathrm{<mtext>?n</mtext><mtext>2</mtext>}}$ (? p for all positive and negative integral values of n except n = ?1 and ? p for n = ?1).Sufficient conditions are determined which permit the application of the binomial theorem to the evaluation of the transform of $\text{H}$. Approximate formulas for the energy eigenvalues through third order in nondiagonal matrix elements are presented in a compact form containing characteristic nonorthogonality corrections depending on the exterior or interior location of the matrix element in the perturbation formulas.     

Activation energy of field emission flicker noise power due to adsorbed potassium on tungsten

The temperature dependence of the field emission flicker noise spectral density functions has been investigated for potassium adsorbed on tungsten (112) planes by a probe hole technique. By integration of the spectral density functions $\text{W(?) = B}{}_{\mathrm{i}}\text{?}{}^{\mathrm{?ge}}\text{i}$ the noise power $\text{(δn}{}^2{}_{\mathrm{\Delta ?}}$ for different frequency intervals Δ? is obtained. From the exponential temperature dependence of $\text{(δn}{}^2{}_{\mathrm{\Delta ?}}$ noise power “activation energies” q_Δ? are determined. Plots of these energies versus coverage show a similar “oscillating” behaviour as recently found for $\text{W(?}{}_{\mathrm{j}}\text{)}$ or which indicates phase transitions of the adsorbed potassium submonolayers. The noise activation energies are discussed in terms of existing models and a comparison is made between the experimental q values and surface diffusion energies E_d as determined by conventional methods.     

Morphogenesis of sliced N-soliton solutions

Consider an instantaneous severing interaction which at t = t_s transforms is given N-soliton solution q⁰ into two new solutions, q^L and q^R, with discontinuous anitial conditions at t = t_s such that q^L(q^R) is equal to q⁰ to the left (right) of the severing point x_s and vanishes to the right (left) of x_s. The soliton content of q^L and q^R is studied in the context of the cubic Schrödinger equation and the sine-Gordon equation by solving the direct scattering problem. It is shown that the motion constants C_n, n = 1, 2 …, are related by , Furthermore, if q⁰ contains N solitons and no contribution from the continuous spectrum, then q^L(q^R) contains N^L(N^R) solitons with 0 ? N^L, N^R ? N and N^L + N^R = N. The slicing puts a soliton into q^L or q^R, respectively as the slicing point x_s is taken to the right or left of the soliton's “center” at t = t_s.     

An inequality for the trace of matrix products

In this paper we consider a product of n complex m×m matrices A_k (k=1,…,n) with singular values ∝^(k)_i ordered in decreasing magnitude. Using the spectral resolution for the operators $\text{A}{}^{\mathrm{dagger;}}{}_{\mathrm{k}}\text{A}{}_{\mathrm{k}}$, it is shown that $\text{|}\text{Tr}\text{A}{}_1\text{…A}{}_{\mathrm{n}}\text{|≤}\text{∑}\text{i=1}\text{m}\text{Φ}\text{i=1}\text{n}\text{α}{}^{\mathrm{(k)}}{}_{\mathrm{i}}\text{.}$This inequality is an extension of an inequality of von Neumann in the simple case that n=2. The necessary and sufficient condition for the equality sign to hold is established. Application of Hölder's inequality leads to further inequalities which can be useful in statistical mechanics.     

The uniform and the strong topology on realizations of the algebra of polynomials

It is shown that under quite general assumptions on the operators A₁,…,A_n (unbounded, symmetric) and on the domain $\text{D}$ on the realization $\text{P}\text{(A}{}_1\text{,…,A}{}_{\mathrm{n}}\text{)}$ of the algebra of polynomials $\text{P}\text{(x}{}_1\text{,…,x}{}_{\mathrm{n}}\text{)}$, the strongest locally convex topology τ_st coincides with the uniform topology τ_$\text{D}$ as well as with the strong operator topology τ_s. In the case n = 2 some conditions are given, under which these general assumptions are fulfilled.     

Stress-optical dispersion in rubidium chloride and rubidium bromide crystals

The stress-optical coefficients $\text{C = (}\text{n}{}^3\text{2}\text{) (q}{}_{11}\text{?q}{}_{12}\text{)}$ and $\text{C′ = (}\text{n}{}^3\text{2}\text{)q}{}_{44}$ of RbCl and RbBr crystals have been measured at room temperature (26°C) over the wave length range 5750-2500 Å.     

A simplified Fokker-Planck operator for unlike-particle collisions

The linearized Fokker-Planck operator reads $\text{C}{}^1{}_{\mathrm{jk}}\text{= C(f}{}_{\mathrm{1j}}\text{, f}{}_{\mathrm{0k}}\text{)}$. The first term is rather simple, but the second one is very complicated. A much simpler - though exact - form of C(f_0j, f_1k) is proposed, for a special class of f_1k occuring in diffusion theory.     

Self-adjointness of the minimal Schrödinger operator with potential belonging to L1, loc

Let $\text{0 ?q(x) ∈L}{}_{\mathrm{1,loc}}\text{(}\text{R}{}^{\mathrm{m}}\text{)}$,m? 1.Consider the operatorT₀ = ?Δ+q with domain consisting of all bounded measurable functions $\text{u(x), x ∈}\text{R}{}^{\mathrm{m}}$, having bounded support, for which the distribution ?Δu+qu belongs to $\text{L}{}_2\text{(}\text{R}{}^{\mathrm{m}}\text{)}$. The main result of the paper is essential self-adjointness of $\text{T}{}_0\text{in L}{}_2\text{(}\text{R}{}^{\mathrm{m}}\text{)}$. The proof is independent of a method due to Kato who recently established the self-adjointness of a maximal Schrödinger operator corresponding to such potential.     

On the mobility of very pure semiconductors at very low temperatures

The mobility μ of a very pure semiconductor at very low temperatures is investigated in terms of a model where electrons are scattered by charged impurities distributed uniformly in space, and the electron-electron interaction is taken into account by the Debye-Hueckel screening in the interaction potential. The equation for the current relaxation rate Γ, derived previously by the proper connected diagram expansion, incorporates the quasi-particle effect in a self-consistent manner. The solution of this equation at high carrier concentrations n yields the so-called Brooks-Herring formula. At lower concentrations, the solution deviates significantly from the latter. The solution is in general smaller than the standard expression for the rate based on the Boltzmann equation; and this is consistent with the existing conductivity data available. At the very low concentrations e.g. n = n₃ = 10¹³cm^?3 or lower for Ge, the mobility calculated is inversely proportional to the square-root of the impurity concentration n_s, and has a $\text{T}{}^{\mathrm{<mtext>1</mtext><mtext>4</mtext>}}$-dependence (T: temperature).

$\text{μ = 0.3597\&z.xl;h}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{k(k}{}_{\mathrm{B}}\text{T)}{}^{\mathrm{<mtext>1</mtext><mtext>4</mtext>}}\text{(ze)}{}^{\mathrm{?1}}\text{n}{}_{\mathrm{s}}{}^{\mathrm{<mtext>?1</mtext><mtext>2</mtext>}}\text{m}{}^1{}^{\mathrm{<mtext>?3</mtext><mtext>4</mtext>}}$

, where k is the dielectric constant. The conductivity data directly comparable with this formula are not available at present. However, the quasi-particle effect which led to this peculiar concentration-dependence should also show itself in the cyclotron resonance width; there, experiment and theory both show the ${}_{\mathrm{n}}{}_{\mathrm{s}}$-dependence for very pure semiconductors.     

Anomalous mass dependence of glueball exclusive decay rates

Exclusive decays such as G → ππ are studied in the framework ofperturbative QCD. We discuss the possibility of the constituent gluons' virtualness scaling as the glueball mass M_G, which is a picture equivalent to a glueball containing a few slow-moving, heavy gluons. In this case, the decay rate exhibits a pinch singularity which enhances it by a factor of order (M_G²/m_q²)² over the dimensional scaling expectation. This singularity is partially suppressed by Sudakov effects which reduce the enhancement factor to $\text{(M}{}_{\mathrm{<mtext>G</mtext>}}{}^2\text{/m}{}_{\mathrm{<mtext>q</mtext>}}{}^2\text{)}{}^{\mathrm{2n}}\text{,}\text{where}\text{n ? 0.4}$.     

Complexified Pöschl–Teller II potential model

With the help of complexifying a five-parameter exponential-type potential model, we obtain a general complex version of the Pöschl–Teller II potential, , where q_c=q₀e^2iαε, real V₁>0, q₀>0 and $\text{0<λε<}\text{π}\text{2}$. It has been shown that this complex potential is P-pseudo-Hermitian and PT-symmetric, where the parity operator P acts on the position operator as $\text{PxP}{}^{\mathrm{-1}}\text{=}\text{ln}\text{q}{}_0\text{λ}\text{−x}$. The discrete energy eigenvalues are shown to be real when $\text{V}{}_2\text{⩾−}\text{q}{}_0\text{λ}{}^2\text{4}$ while they are complex conjugate pairs if $\text{V}{}_2\text{<−}\text{q}{}_0\text{λ}{}^2\text{4}$.     

Classical integrable finite-dimensional systems related to Lie algebras

During the last few years many dynamical systems have been identified, that are completely integrable or even such to allow an explicit solution of the equations of motion. Some of these systems have the form of classical one-dimensional many-body problems with pair interactions; others are more general. All of them are related to Lie algebras, and in all known cases the property of integrability results from the presence of higher (hidden) symmetries. This review presents from a general and universal viewpoint the results obtained in this field during the last few years. Besides it contains some new results both of physical and mathematical interest.The main focus is on the one-dimensional models of n particles interacting pairwise via potentials V(q) = g²ν(q) of the following 5 types: $\text{ν}{}_{\mathrm{<mtext>I</mtext>}}\text{(q)=q}{}^{\mathrm{?2}}\text{, ν}{}_{\mathrm{<mtext>II</mtext>}}\text{(q)=a}{}^{\mathrm{?2}}\text{sinh}{}^2\text{(aq), ν}{}_{\mathrm{<mtext>III</mtext>}}\text{(q)=a}{}^2\text{/}\text{sin}\text{2(aq), ν}{}_{\mathrm{<mtext>IV</mtext>}}\text{=a}{}^2\text{P}\text{(aq), , ν}{}_{\mathrm{<mtext>V</mtext>}}\text{(q)=q}{}^{\mathrm{?2}}\text{+ω}{}^2\text{q}{}^2$. Here $\text{P}$(q) is the Weierstrass function, so that the first 3 cases are merely subcases of the fourth. The system characterized by the Toda nearest-neighbor potential, g_j²exp[-a(q_j?q_j+1)], is moreover considered. Various generalizations of these models, naturally suggested by their association with Lie algebras, are also treated.     

Scaling function for two-point correlations with long-range interactions to order 1/η

The two-point correlation function ? (q, ξ) is calculated in the critical region of momentum space q in terms of a suitable correlation lenght ξ, by means of perturbation expansion to order 1/n, for an n-vector system with long-range interactions decaying as $\text{|}\text{R}\text{/a|}{}^{\mathrm{?(d\; +\; \sigma )}}$, for $\text{|}\text{R}\text{/a|}\text{a}\text{?}\text{1}$, where a is the spacing on a d-dimensional lattice, σ < d < 2σ and 0 < σ ? 2 ? η_SR. The calculations are done in zero field for T ? T_c. Explicit expansions for long-range propagators are developed for $\text{σ « 1}$ and for the neighborhood of σ ? 2 ? η_SR, in terms of which a universal, cut-off independent scaling function is obtained over the whole range of $\text{x = |}\text{q}\text{| ξ}$, and it is shown that the amplitude of the correlation-length dependence of the susceptibility becomes a universal parameter. Both the exponents and the coefficients of the expansion for fixed q as $\text{(T ? T}{}_{\mathrm{<mtext>c</mtext>}}\text{)}\text{T}{}_{\mathrm{<mtext>c</mtext>}}\text{→0}$ are calculated explicitly. The former are shown to require the validity of the operator-product expansion and explicit logarithmic correction terms are obtained for $\text{d = d}{}^1\text{= 3σ/2}$. For these and other dimensionalities, the coefficients are shown to be finite functions of d and σ. The correction to the Ornstein-Zernike form is given explicitly, with non-integer powers of x that have finite coefficients.     

On the super symmetry charges in the theory of scalar and spinor free fields

It is shown that for spinorial charges Q^(L))_α (α = 1, 2, L = 1, …, S) satisfying the commutation relations

$\text{{Q}{}^{\mathrm{(L)}}{}_{\mathrm{\alpha }}\text{, Q}{}^{\mathrm{(M)}}{}_{\mathrm{\beta }}\text{} = ε}{}_{\mathrm{\alpha }}\text{βa}{}^{\mathrm{LM}}\text{Q,}$

$\text{{Q}{}^{\mathrm{(L)}}{}_{\mathrm{\alpha }}\text{, Q}{}^{\mathrm{(M)+}}{}_{\mathrm{\beta }}\text{} = cσ}{}^{\mathrm{\mu }}{}_{\mathrm{\alpha \beta }}\text{P}{}_{\mathrm{\mu }}\text{δ}{}^{\mathrm{LM}}\text{,}$

$\text{[Q}{}^{\mathrm{(L)}}\text{)}{}_{\mathrm{\alpha }}\text{, P}{}^{\mathrm{\mu }}\text{] = 0,}$

where Q is a scalar charge commuting with the spinor charges as well aswith the energy- momentum vector Pμ, there can exist several different multiplets for free massive scalar and spinor fields.     

Excited vibrational state microwave spectra,structure, and force-field of trifluorosilane

The J = 2?1 microwave spectrum of six isotopic species of HSiF₃ has been observed and assigned in excited states of five of the six fundamental vibrations. The assignment is based on relative intensities, double resonance experiments, and trial anharmonic force constant calculations. Analysis of the spectra leads to experimental values for five of the $\text{α}{}_{\mathrm{r}}{}^{\mathrm{B}}$ constants, all three l-doubling constants q_t, one Fermi resonance constant φ₂₃₃, and one zeta constant $\text{ζ}{}_{\mathrm{6,\; 6}}{}^{\mathrm{(z)}}$.The harmonic force field has been refined to all the available data on vibration wavenumbers, centrifugal distortion constants, and zeta constants. The cubic anharmonic force field has been refined to the data on $\text{α}{}_{\mathrm{r}}{}^{\mathrm{B}}$ and q_t constants, using two models: a valence force model with two cubic force constants for SiH and SiF stretching, and a more sophisticated model. With the help of these calculations, the following equilibrium structure has been determined: $\text{r}{}_{\mathrm{e}}\text{(}\text{SiH}\text{) = 1.4468(±5)}\text{A}\text{?}$, $\text{r}{}_{\mathrm{e}}\text{(}\text{SiF}\text{) = 1.5624(±1)}\text{A}\text{?}$, ∠HSiF = 110.64(±3)°,