Measurement of the surface concentration (liquid) of an evaporating multicomponent droplet using pendant droplet method

The surface concentration on the liquid side of the interface of an evaporating multicomponent droplet could be different from the bulk concentration. In this work, surface tension is used as a means to measure surface concentration of an evaporating multicomponent droplet. Surface tension is measured using pendant droplet method that relies on the best fit between theoretical and experimental drop profiles. Surface tension is a surface property, and it exhibits a dependence on concentration. Hence, it is an ideal candidate to track the variation of surface concentration during the evaporation of a multicomponent droplet. This method is used to study the evaporation of ethanol–water and methanol–water droplets. The correctness and applicability of this technique are critically assessed, and important observations are made for single droplet evaporation for these binary mixtures.     

Modeling of droplet collisions using Smoothed Particle Hydrodynamics

We present an approach to model collisions of different droplets using Smoothed Particle Hydrodynamics (SPH). We consider bouncing and coalescence of two droplets. We only discretize the droplets neglecting the gaseous phase and consider a free surface at the boundaries. We use a modified continuum surface force model for the surface tension at a free surface. The transition between bouncing and coalescence is modeled using a critical Weber number and calculating the loss of kinetic energy during the collision to determine the point of coalescence. We demonstrate numerical convergence and analyze the error of the method for the transition of bouncing and coalescence. We show that the proposed approach is applicable to weakly-compressible SPH and incompressible SPH and compare binary collisions of Newtonian droplets with experimental results from the literature. Finally we apply the model to non-Newtonian droplets that show shear-thinning and shear-thickening behavior and discuss the differences to Newtonian droplets.     

Explosive boiling of a liquid droplet

A mathematical model describing growth of an internal vapor bubble produced by homogeneous nucleation within a liquid droplet during explosive boiling is presented. Existing experimental results for explosive boiling of superheated droplets confirm the predictions of the model. The difference between the present model and the classical theories of bubble growth is discussed.     

Hydrodynamics of a liquid with deformable and interacting particles

Interest in the hydrodynamics of a liquid with particle rotations and microdeformations has recently intensified [1–9] in connection with the technical applications of different artificially synthesized structured media. A model of a liquid with deformable microstructure was first proposed in [4] and was thermodynamically analyzed in [6], in which a model of a liquid was constructed by means of methods from the thermodynamics of irreversible processes. A model of a macro- and microincompressible liquid with particle rotations and deformations has been proposed [7, 8] based on constitutive equations from [6]. Below we will solve the sphere rotation problem in an infinite liquid given different boundary conditions on the rates of particle rotation and microdeformation within the context of the system of equations presented in [7]. The solution of an analogous problem for a micropolar liquid simulating a suspension with solid particles has been obtained [9] and the solution for a viscous liquid was found by Stokes in [10].Translated from Zhurnal Prikladnoi Mekhaniki i Tekhnieheskoi Fiziki, No. 1, pp. 79–87, January–February, 1976.     

Thermocapillary drift of a droplet of viscous liquid

The article discusses the thermocapillary drift of a drop of a viscous liquid, filling the whole space, in another liquid, with a constant temperature gradient at infinity, in the absence of the force of gravity. The distribution of the velocities, temperatures, and pressures in the liquid are obtained in the Ozeenov approximation, and the rate of drift of a drop and its form are found.     

Motion of a liquid droplet in a vibrating fluid

The motion of a liquid droplet in a liquid with density different from that of the liquid composing the droplet and subjected to harmonic excitations is investigated. Nonlinear equations are obtained that describe the translational motion of the droplet and its oscillations. It is shown by numerical means that, under the essential resonance conditions, the droplet ascends by a cascade method if the value of the load coefficient is small.S. P. Timoshenko Institute of Mechanics, National Academy of Sciences of Ukraine, Kiev. Translated from Prikladnaya Mekhanika, Vol. 31, No. 7, pp. 78–83, July, 1995.     

Hydrodynamics of contact of a falling drop with a liquid free surface

A fine structure of the flows developing during primary contact of freely falling drops with a deep quiescent fluid is studied using the macrophotography and high-speed video filming methods. Water drops falling in water, alcohol, and oil, as well as drops of oil, petroleum, and aqueous solutions of salt or alcohol falling in water are investigated. The work is focused on the visualization of the finespray scattering from the primary contact area. The collisions of small droplets with the surface of the submerging drop are first recorded. The direction of the spray and streamer scattering is determined by the surface tension coefficients of the coalescing liquids. The conditions under which the spray droplets collide with the drop surface are determined.     

Measurement of liquid droplet disintegration mechanisms

An experimental study is made of deformation mechanisms and break-up duration of liquid droplets due to an air stream. A relationship between flow conditions and the type of droplet deformation mechanisms has been obtained as well as some data concerning duration of disintegration. The investigations have been carried out for several liquids of various viscosity.     

Axisymmetric wetting of a liquid droplet on a stretched elastic membrane

Wetting of a liquid droplet on another liquid substrate is governed by the well-known Neumann equations. The present work aims to develop an explicit modified version of the Neumann equations for axisymmetric wetting of a liquid droplet on a highly stretched elastic membrane of non-zero bending rigidity. An explicit modified form of the Neumann equations is derived to determine the two contact angles, which is reduced to Young’s equation for a liquid droplet on a rigid membrane or to the Neumann...     

Kinetic theory analysis of explosive boiling of a liquid droplet

The process of rapid phase transition from highly superheated liquid to vapor is frequently so fast and violent that it is called explosive boiling. The paper uses the kinetic theory of evaporation to study growth of an internal vapor bubble produced by homogeneous nucleation within a highly superheated liquid droplet boiling explosively in a hot medium. Evaporation/condensation coefficient is estimated by comparing the predictions of the theory with available experimental data. We show that the value of the evaporation coefficient can be very low for high reduced temperatures (0.06 for butane at 378 K), in agreement with recent molecular dynamic simulations.     

Modeling of vacuum desorption of multicomponent moisture in freeze drying

A mathematical model of multicomponent vacuum desorption, which occurs in the vacuum freeze drying process has been developed. Drying with conductive heating and constant contact surface temperature was considered. Pressure drop in the layer of the material to be dried was taken into account in the model formulation and process simulation. Equilibrium moisture content for pure water, toluene, and m-xylene and their two- and three-component mixtures on zeolite DAY 20F were described by means of the multitemperature extended Langmuir isotherm equation. Model equations were solved by the numerical method of lines. Moisture content and temperature distributions within the drying material were predicted from the model as a function of drying time.     

An experimental study of a water droplet impinging on a liquid surface

An experimental study is presented for water droplet impingement on a liquid surface. The impaction process was recorded using a high-speed digital camera at 1,000 frames/s. The initial droplet diameter was fixed at 3.1 mm ± 0.1 mm, and all experiments were performed in atmospheric air. The impact velocity was varied from 0.36 m/s to 2.2 m/s thus varying the impact Weber number from 5.5 to 206. The impacted liquid surface consisted of two fluids, namely water and methoxy-nonafluorobutane, C₄F₉OCH₃ (HFE7100). The depth of the water and HFE7100 pool was varied from 2 mm to 25 mm. The collision dynamics of water in the HFE7100 pool was observed to be drastically different from that observed for the water droplet impingement on a water pool. The critical impact Weber number for jet breakup was found to be independent of liquid depth. Water–HFE7100 impact resulted in no jet breakup over the range of velocities studied. Therefore, no critical impact Weber number can be defined for water–HFE7100 impact. Received: 27 June 2001/Accepted: 29 November 2001     

Transition from droplet flow to stream flow in a liquid

The transition from droplet flow to stream flow is examined theoretically for flow of liquid from a vertical capillary and runoff from the edge of an inclined plane under the influence of the force of gravity, and also for spraying of a liquid from a rotating perforated drum and a smooth disk. The formulas proposed agree satisfactorily with experiment.     

Application of a droplet cluster to visualize microscale gas and liquid flows

The possibility of using microdroplets, which form a dissipative droplet-cluster structure, as tracers localized in the boundary layer of a gas adjoining a liquid-gas interface is experimentally demonstrated. Examples of the visualization of boundary layer flow fields generated by both processes in the gaseous phase and liquid convection are considered.     

Capillary and gravitational convection in a droplet immersed in a nonuniformly heated liquid

Under the conditions of the Plato technique, the problem of convection in a droplet immersed in a nonuniformly heated liquid is solved analytically. The influence of gravitational convection on the thermocapillary flow is studied. In the linear approximation with respect to the Marangoni and Grashof numbers and their product, the shape of the droplet and the displacement of its center of the mass are obtained.Perm. Translated from Izvestiya Rossiiskoi Akademii Nauk, Mekhanika Zhidkosti i Gaza, No. 4, pp. 43–51, July–August, 1996.     

Comparison of multicomponent fuel droplet vaporization experiments in forced convection with the Sirignano model

The vaporization of multicomponent fuel droplets was studied experimentally in a heated flow and the results were compared to the model proposed by Abramzon and Sirignano. The droplet was suspended on a permanent holder which was set up in a thermal wind-tunnel. This wind-tunnel was fitted with a video recording system and an infra-red camera. The period during which the droplet was suspended on the holder before the opening of the hot air flow damper was recorded. This first sequence corresponds to the droplet vaporization in natural convection, whose initial experiment conditions, especially diameter, temperature, composition of the droplet, are well known. Then the damper was turn on, and the sequence of forced convection begun. The initial diameter of the droplet was recorded by the video system. The other initial conditions of this second sequence cannot be determined experimentally. The distribution of temperature in the droplet and the surface temperature, the mass fraction distribution in the droplet and the surface mass fraction were unknown. These unknown parameters were determined by coupling our experiment with a model using “the film concept” in natural convection. Experimental results were compared with the calculations and found satisfactory, in natural convection as well as in forced convection initiated by this method. The method was tested in the case of a fuel mixture droplets (heptane–decane) for different initial concentrations and variable durations of the sequence in natural convection.