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1.
C_(60)硫衍生物──C_(60)S~+的气相合成刘子阳,郝国仑,郭兴华,刘淑莹(中国科学院长春应用化学研究所,长春,130022)关键词C_(60),CS_2,离子-分子反应自实现C(60)的宏观量合成以来[1],通过将C(60)进行化学衍生进而改变?..  相似文献   

2.
TiCl_4/SiO_2-MgCl_2载体催化剂下的乙烯/己烯-1共聚反应陈辉,张学全,黄葆同王展望,杨永然(中国科学院长春应用化学研究所长春130022)(辽阳化纤公司化工三厂辽阳)关键词乙烯,己烯,共聚,Ziegler-Natta催化剂乙烯/α-烯?..  相似文献   

3.
乙基苯基二氯化锡与2-羟基萘醛缩对甲氧基苯胺Schiff碱1∶1配合物的合成和晶体结构刘宝殿,包明,孙振刚,贺庆林,邢彦,贾恒庆,林永华(东北师范大学化学系,长春,130024)(中国科学院长春应用化学研究所,长春)关键词乙基苯基二氯化锡,Schif...  相似文献   

4.
丙烯酸丁酯-苯乙烯-丙烯腈共聚物的结构与力学性能张会轩,韩业,张会良,冯之榴(吉林工学院化工系长春130012)(中国科学院长春应用化学研究所长春)关键词ASA,乳液聚合,粒子,力学性能丙烯酸丁酯-苯乙烯-丙烯腈共聚物(ASA)是两相结构,聚丙烯酸丁...  相似文献   

5.
水溶性壳聚糖的制备与应用   总被引:22,自引:1,他引:22  
水溶性壳聚糖的制备与应用赵文伟,于黎,钟晓光,张月芳,孙家珍(中国科学院长春应用化学研究所,长春130022)壳聚糖(chitosan,(1,4)-2-胺基-2-脱氧-β-D-葡聚糖)是由甲壳素(chitin,(1,4)-2-乙酰胺基-2-2脱氧-β...  相似文献   

6.
杂多阴离子柱撑水滑石层柱相互作用(Ⅰ)李兴林*佘益民郭军蒋大振(中国科学院长春应用化学研究所长春130022)(吉林大学化学系长春)关键词杂多阴离子,柱撑水滑石,XPS,IR,XRD1996-06-18收稿,1996-10-12修回国家自然科学基金资...  相似文献   

7.
掺钕钙铝磷酸盐玻璃的光谱参数于亚勤,张思远,王庆元,盛桂云(中国科学院长春应用化学研究所长春130022)(长春冶金专科学校长春)关键词掺钕钙铝磷酸盐玻璃,光谱参数,Judd-Ofelt理论1960年第一台红宝石激光器问世后,1961年便出现了掺钕钡...  相似文献   

8.
4-(2-氨基噻唑)-间苯二酚为柱前衍化剂液相色谱/电化学检测Fe、Co、Ni格日勒,李惠梅,李南强,汪尔康(中国科学院长春应用化学研究所电分析化学开放实验室,北京大学化学系,长春,130022)关键词液相色谱,Fe,Co,Ni,4-(2-氨基噻唑)...  相似文献   

9.
二(2,6-二叔丁基-4-甲基苯氧基)钐配合物催化甲基丙烯酸甲酯聚合扈晶余,齐贵中(中国科学院长春应用化学研究所稀土化学与物理开放实验室长春130022)沈琪(苏州大学化学系苏州)关键词钐配合物,甲基丙烯酸甲酯,聚合二价稀土有机化合物具有很强的还原性...  相似文献   

10.
复合卤化物中钐价态的异常变化及其稳定性孙淑清,石春山(中国科学院长春应用化学研究所稀土化学与物理开放实验室长春130022)关键词钐,价态,复合卤化物,光谱Sm2+离子在红区和红外区可以产生4f6组态内的f-f跃迁锐线发射和4f55d组态的d-f跃迁...  相似文献   

11.
用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%.  相似文献   

12.
Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields.  相似文献   

13.
In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments.  相似文献   

14.
The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula.  相似文献   

15.
The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines.  相似文献   

16.
KMnO4-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields.  相似文献   

17.
The review contains a concise historical account and information on the most significant researches undertaken by the staff at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry of Heterocyclic Compounds. Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008.  相似文献   

18.
A general synthesis of previously unknown semicarbazone-based α-amidoalkylating reagents, 4-(tosylmethyl)semicarbazones, has been developed. The synthesis involved three-component condensation of semicarbazones of aliphatic or aromatic aldehydes with the same or other aldehydes and p-toluenesulfinic acid. The scope and limitations of this reaction were investigated. The compounds obtained were demonstrated to be an efficient α-(4-semicarbazono)alkylating agents. They were reacted with H- (sodium borohydride), O- (sodium methylate), S- (sodium phenylthiolate), N- (pyrrolidine, sodium succinimide), P- (trialkyl phosphites), and C-nucleophiles (sodium diethyl malonate) to give the corresponding products of the tosyl group substitution, 4-substituted semicarbazones, including analogues of nitrofurazone. Among the prepared compounds tested in vitro for antibacterial and antifungal activity, three nitrofuryl-containing semicarbazones exhibited high biological activities with minimum inhibitory concentration (MIC) values of 8–32 μg/mL.  相似文献   

19.
Zhanhui Yang  Shiyi Yang  Jiaxi Xu 《Tetrahedron》2017,73(23):3240-3248
Regiospecific and direct imidation of the methyl C(sp3)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products.  相似文献   

20.
A small library of new chiral bidentate hydroxyalkyl-imidazolium salts 1 is conveniently synthesized on multi-gram scale from inexpensive and commercially available chiral pool amino acids. The corresponding carbenes, generated by deprotonation of imidazolium salts 1, in combination with palladium(II) chloride were tested in the Mizoroki–Heck coupling reaction. The most significant results in terms of yields and reactivities were achieved with low catalyst loading. The catalytic activities of these imidazolium salts were also investigated in the asymmetric addition of diethylzinc to benzaldehyde. The use of MgO nanoparticles as an additive in conjunction with these ligands played a crucial role in increasing the efficiency of these reactions.  相似文献   

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