共查询到20条相似文献,搜索用时 15 毫秒
1.
Kabatc J Ośmiałowski B Paczkowski J 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2006,63(3):524-531
The ground state (mu(g)) and excited state (mu(e)) dipole moments of 15 hemicyanine dyes were studied at room temperature. They were estimated from solvatochromic shifts of the absorption and the fluorescence spectra as function of the solvent dielectric constant (varepsilon) and refractive index (n). In this paper we applied the Stokes shift phenomena not only for the determination of the difference in the dipole moment of excited state and ground state, but to determine the value of polarizability alpha as well. The obtained results show that excited state dipole moments of hemicyanine dyes are in the range from 5 to 15 Debye, and the difference between the excited and ground state dipole moments vary from 1 to 7 Debye. The excited and ground state dipole moments difference (mu(e)-mu(g)) obtained for selected dyes are positive. It means that the excited states of the dyes under the study are more polar than the ground state ones. Additionally, the value of both polarizability (alpha) and the Onsager radius (a) of each investigated hemicyanine dye molecule are determined, and the ratio of alpha/a(3) for each dye were calculated, which oscillate from 0.29 to 5.21. The increase in dipole moment has been explained in terms of the nature of excited state and its resonance structure. 相似文献
2.
Poisson L Roubin P Coussan S Soep B Mestdagh JM 《Journal of the American Chemical Society》2008,130(10):2974-2983
The dynamics of the enolic form of acetylacetone (E-AcAc) was investigated using a femtosecond pump-probe experiment. The pump at 266 nm excited E-AcAc in the first bright state, S2(pi pi*). The resulting dynamics was probed by multiphoton ionization at 800 nm. It was investigated for 80 ps on the S2(pi pi*) and S1(n pi*) potential energy surfaces. An important step is the transfer from S2 to S1 that occurs with a time constant of 1.4 +/- 0.2 ps. Before, the system had left the excitation region in 70 +/- 10 fs. An intermediate step was identified when E-AcAc traveled on the S2 surface. Likely, it corresponds to an accidental resonance in the detection scheme that is met along this path. More importantly, some clues are given that an intramolecular vibrational energy relaxation is observed, which transfers excess vibrational energy from the enolic group O-H to the other modes of the molecule. The present multistep evolution of excited E-AcAc probably also describes, at least qualitatively, the dynamics of other electronically excited beta-diketones. 相似文献
3.
Masternak A Wenska G Milecki J Skalski B Franzen S 《The journal of physical chemistry. A》2005,109(5):759-766
A novel solvatochromic betaine dye has been synthesized from xanthosine and characterized spectroscopically by UV-vis in a broad range of solvents. The dye 9-(2',3',5'-tri-O-acetyl-beta-d-ribofuranosyl)-2-(pyridinium-1-yl)-9H-purin-6-olate, 1a, exhibits solvent-induced spectral band shifts that are (2)/(3) as large as that of the betaine known as Reichardt's dye, which forms the basis of the E(T)(30) solvent polarity scale. Moreover, the dye 1a is a ribonucleoside and hence has the potential application as a polarity probe for application in RNA oligonucleotides. The isomeric dye 6-(pyridinium-1)-yl-9H-purin-2-olate, 2a, has also been synthesized and exhibits slightly smaller solvatochromic band shifts. The new betaine dyes have also been studied by comparing the experimental and calculated solvatochromic shifts based on the calculation of the UV/vis absorption spectra, using a combination of methods with density functional theory (DFT). The COSMO continuum dielectric method, an applied electric field term in the Hamiltonian, and time-dependent density functional theory (TD-DFT) methods were used to obtain absorption energies, ground-state dipole moments, and the difference dipole moment between the ground and excited states. The calculations predict a lower energy absorption band of charge-transfer character that is highly solvatochromic, and a higher energy absorption band that has pi-pi character which is not solvatochromic, in agreement with the experimental data. For Reichardt's dye the difference dipole moment between the ground and excited state (Deltamu = mu(e) - mu(g)) was also calculated and compared to experiment: Deltamu(calcd) = -6 D and Deltamu(exptl) = -9 +/- 1 D.(1) The ground-state dipole moment was found to be mu(g)(calcd) = 18 D and mu(g)(exptl) = 14.8 +/- 1.2 D.(1). 相似文献
4.
Guzow K Milewska M Wiczk W 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,61(6):1133-1140
The photophysical properties of 3-[2-(4-diphenylaminophenyl)benzoxazol-5-yl]alanine methyl ester (1b) and its Boc derivative (1a) were studied in a series of solvents. Its UV-Vis absorption spectra are less sensitive to the solvent polarity than the corresponding fluorescence spectra which show pronounced solvatochromic effect leading to large Stokes shifts. Using an efficient solvatochromic method, based on the molecular-microscopic empirical solvent polarity parameter E(T)(N), a large change of the dipole moment on excitation has been found. From an analysis of the solvatochromic behaviour of the UV-Vis absorption and fluorescence spectra in terms of bulk solvent polarity functions, f(epsilon(r),n) and g(n), a large excited-state dipole moment (mu(e) = 11D), almost perpendicular to the smaller ground-state dipole moment, was observed. This demonstrates the formation of an intramolecular charge-transfer excited state. Large changes of the fluorescence quantum yields as well as the fluorescence lifetimes with an increase of a solvent polarity cause that the new non-proteinogenic amino acid, 3-[2-(4-diphenylaminophenyl)benzoxazol-5-yl]-alanine methyl ester, is a new useful fluorescence probe for biophysical studies of peptides and proteins. 相似文献
5.
Azobenzene E<==>Z photoisomerization, following excitation to the bright S(pi pi*) state, is investigated by means of ab initio CASSCF optimizations and perturbative CASPT2 corrections. Specifically, by elucidating the S(pi pi*) deactivation paths, we explain the mechanism responsible for azobenzene photoisomerization, the lower isomerization quantum yields observed for the S(pi pi*) excitation than for the S1(n pi*) excitation in the isolated molecule, and the recovery of the Kasha rule observed in sterically hindered azobenzenes. We find that a doubly excited state is a photoreaction intermediate that plays a very important role in the decay of the bright S(pi pi*). We show that this doubly excited state, which is immediately populated by molecules excited to S(pi pi*), drives the photoisomerization along the torsion path and also induces a fast internal conversion to the S1(n pi*) at a variety of geometries, thus shaping (all the most important features of) the S(pi pi*) decay pathway and photoreactivity. We reach this conclusion by determining the critical structures, the minimum energy paths originating on the bright S(pi pi*) state and on other relevant excited states including S1(n pi*), and by characterizing the conical intersection seams that are important in deciding the photochemical outcome. The model is consistent with the most recent time-resolved spectroscopic and photochemical data. 相似文献
6.
Measurements of the Stark effect on the rotationally resolved S(1)<--S(0) fluorescence excitation spectrum of aniline are reported, providing quantitative information about the degree of charge transfer in the electronic transition. We find that mu(a)(S(1)) = 2.801 +/- 0.007 D, a value that is approximately 150% larger than the ground state, mu(a)(S(0)) = 1.129 +/- 0.005 D. The enhanced value of the dipole moment in the S(1) state is attributed to more efficient electron donation by the quasi-planar amino group to the aromatic ring. 相似文献
7.
Dhanya R Kishore VC Sudha Kartha C Sreekumar K Joseph R 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,71(4):1355-1359
The ground state and excited state dipole moment of a series of alkyl substituted para-nitroaniline derivatives is reported. Ground state dipole moment was determined by the Debye-Guggenheim method and the excited state dipole moment was estimated using the solvatochromic method. For all molecules under investigation, the excited state dipole moment was found to be higher than the ground state dipole moment. The molecules exhibited positive solvatochromism. 相似文献
8.
Rauf MA Graham JP Bukallah SB Al-Saedi MA 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2009,72(1):133-137
The absorption and fluorescence spectra of Rose Bengal dye were studied in various solvents. It was found that solvent effects on the absorption wavelength are consistent with the solvatochromic model of Kamlet, Abboud and Taft. The solvent polarizability value pi* was found to have a linear relationship with the absorption wavelength of the dye in various solvents. Additionally, the normalized transition energy value (E(T)(N)) showed some scattering when plotted versus Deltanu(af). Density functional calculations were used to assign the absorption in the region 540-570 nm to a pi-pi* transition between the HOMO and LUMO of the anion. Experimental ground state and excited state dipole moments were calculated by using the solvatochromatic shifts of absorption and fluorescence spectra as a function of the dielectric constant (epsilon) and refractive index (n). The dipole moment for Rose Bengal was found to be 1.72 Debye in the ground state, whereas this value was 2.33 Debye in the excited state. 相似文献
9.
Yang J Wagner M Okuyama K Morris K Arp Z Choo J Meinander N Kwon O Laane J 《The Journal of chemical physics》2006,125(3):34308
The fluorescence excitation (jet cooled), single vibrational level fluorescence, and the ultraviolet absorption spectra of coumaran associated with its S1(pi,pi*) electronic excited state have been recorded and analyzed. The assignment of more than 70 transitions has allowed a detailed energy map of both the S0 and S1 states of the ring-puckering (nu45) vibration to be determined in the excited states of nine other vibrations, including the ring-flapping (nu43) and ring-twisting (nu44) vibrations. Despite some interaction with nu43 and nu44, a one-dimensional potential energy function for the ring puckering very nicely predicts the experimentally determined energy level spacings. In the S1(pi,pi*) state coumaran is quasiplanar with a barrier to planarity of 34 cm(-1) and with energy minima at puckering angles of +/-14 degrees. The corresponding ground state (S0) values are 154 cm(-1) and +/-25 degrees . As is the case with the related molecules indan, phthalan, and 1,3-benzodioxole, the angle strain in the five-membered ring increases upon the pi-->pi* transition within the benzene ring and this increases the rigidity of the attached ring. Theoretical calculations predict the expected increases of the carbon-carbon bond lengths of the benzene ring in S1, and they predict a barrier of 21 cm(-1) for this state. The bond length increases at the bridgehead carbon-carbon bond upon electron excitation to the S1(pi,pi*) state give rise to angle changes which result in greater angle strain and a nearly planar molecule. 相似文献
10.
The excited-state properties and related photophysical processes of the acidic and basic forms of pterin have been investigated by the density functional theory and ab initio methodologies. The solvent effects on the low-lying states have been estimated by the polarized continuum model and combined QM/MM calculations. Calculations reveal that the observed two strong absorptions arise from the strong pi --> pi* transitions to 1(pipi*L(a)) and 1(pipi*L(b)) in the acidic and basic forms of pterin. The first 1(pipi*L(a)) excited state is exclusively responsible for the experimental emission band. The vertical 1(n(N)pi*) state with a small oscillator strength, slightly higher in energy than the 1(pipi*L(a)) state, is less accessible by the direct electronic transition. The 1(n(N)pi*) state may be involved in the photophysical process of the excited pterin via the 1(pipi*L(a)/n(N)pi*) conical intersection. The radiationless decay of the excited PT to the ground state experiences a barrier of 13.8 kcal/mol for the acidic form to reach the (S(1)/S(0)) conical intersection. Such internal conversion can be enhanced with the increase in excitation energy, which will reduce the fluorescence intensity as observed experimentally. 相似文献
11.
《Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy》1987,43(11):1317-1322
The dipole moments of fluorinated anilines in the first excited singlet state (1Lb) have been determined from the solvent shifts of absorption and fluorescence spectra. It is concluded that in the monofluoro isomers as well as in aniline itself this dipole moment must be of the order of 5 debye, whereas the gas phase dipole moment is estimated to be some 2 debye only from Stark effect measurements. Ortho-substituted difluoro- and trifluoroanilines show anomalous Stokes shifts of the absorption and fluorescence spectra which are indicative of substantial reorganization of their nuclear framework in the excited state; in these cases no excited state dipole moment could be determined. 相似文献
12.
Reported here are measurements of the magnitude and orientation of the induced dipole moment that is produced when an indole molecule in its ground S(0) and electronically excited S(1) states is polarized by the attachment of a hydrogen bonded water molecule in the gas phase complex indole-H(2)O. For the complex, we find the permanent dipole moment values mu(IW)(S(0)) = 4.4 D and mu(IW)(S(1)) = 4.0 D, values that are substantially different from calculated values based on vector sums of the dipole moments of the component parts. From this result, we derive the induced dipole moment values mu(I) (*)(S(0)) = 0.7 D and mu(I) (*)(S(1)) = 0.5 D. The orientation of the induced moment also is significantly different in the two electronic states. These results are quantitatively reproduced by a purely electrostatic calculation based on ab initio values of multipole moments. 相似文献
13.
Invisible energy levels of the T1(pi, pi*) state of p-methoxybenzaldehyde (anisaldehyde) and p-cyanobenzaldehyde vapors have been estimated through the temperature dependence of the T2(n, pi*) --> S0 phosphorescence and the S1(n, pi*) --> S0 delayed fluorescence spectra. It is shown that the T1(pi, pi*) levels are located at 900 +/- 100 and 300 +/- 100 cm(-1) below the T2(n, pi*) levels, respectively, for p-methoxybenzaldehyde and p-cyanobenzaldehyde vapors. The estimated T1 energy levels are in good agreement with the phosphorescence origins in rigid glass at 77 K. 相似文献
14.
The triplet state dipole moments mu(T) of a series of 4-amino- and 3-aminobenzonitriles in cyclohexane, benzene, and 1,4-dioxane are recalculated from previously published [J. Phys. Chem. 1992, 96, 10809] time-resolved microwave conductivity data, on the basis of newly measured intersystem crossing yields. For 4-(dimethylamino)benzonitrile (DMABN), the following values are now determined for mu(T): 8.3 D (cyclohexane), 8.9 D (benzene), and 9.7 D (1,4-dioxane), as compared with the previously reported dipole moment of 12 D for the first and the last solvent. With the other aminobenzonitriles, similar mu(T) data are obtained, between 6.9 D for 4-aminobenzonitrile (ABN) in n-hexane and 10.0 D for 4-(di-n-decylamino)benzonitrile (DDABN) in 1,4-dioxane. The increase of mu(T) observed for all aminobenzonitriles when going from cyclohexane via benzene to 1,4-dioxane may indicate that their triplet dipole moments become larger with increasing solvent polarity. The present mu(T) of DMABN, between 8.3 and 9.7 D, although larger than the ground state dipole moment mu(0) of 6.6 D, is somewhat smaller than that of the locally excited (LE) state (9.9 D) but considerably smaller than the dipole moment of the intramolecular charge transfer (ICT) state (17 D). By comparing these mu(X) data with the frequency (CN) of the cyano vibration in each state, it appears that at least for DMABN in the triplet state (CN) is not a reliable indication of the extent of charge transfer as compared with the other states S0, LE, and ICT. 相似文献
15.
Samoylova E Lippert H Ullrich S Hertel IV Radloff W Schultz T 《Journal of the American Chemical Society》2005,127(6):1782-1786
The excited-state dynamics of adenine and thymine dimers and the adenine-thymine base pair were investigated by femtosecond pump-probe ionization spectroscopy with excitation wavelengths of 250-272 nm. The base pairs showed a characteristic ultrafast decay of the initially excited pi pi* state to an n pi* state (lifetime tau(pi pi*) approximately 100 fs) followed by a slower decay of the latter with tau(n pi*) approximately 0.9 ps for (adenine)2, tau(n pi*) = 6-9 ps for (thymine)2, and tau(n pi*) approximately 2.4 ps for the adenine-thymine base pair. In the adenine dimer, a competing decay of the pi pi* state via the pi sigma* state greatly suppressed the n pi* state signals. Similarities of the excited-state decay parameters in the isolated bases and the base pairs suggest an intramonomer relaxation mechanism in the base pairs. 相似文献
16.
17.
4-(Dimethylamino)-4'-cyano-1,4-diphenylbutadiene (DCB) and 4-(dimethylamino)-2,6-dimethyl-4'-cyano-1,4-diphenylbutadiene (DMDCB) have been characterized spectroscopically. Quantum chemical calculations were performed for comparison. Solvatochromic shifts of the fluorescence were strong and showed a linear dependence on the solvent polarity parameters, whereas shifts in the absorption spectra are very weak only correlate better with the polarizability of the solvents. Excited state dipole moments derived from fluorescence using the Onsager model are very large and similar for both compounds. It is concluded that a strongly allowed and highly dipolar pi, pi* state is the lowest excited state in polar solvents. The strong difference in absorption and fluorescence solvatochromic slopes suggests that the simple Onsager model with a point dipole approximation is not sufficient here. 相似文献
18.
Chang JL 《The Journal of chemical physics》2005,122(19):194321
The equilibrium geometries and harmonic vibrational frequencies of three low-lying triplet excited states of vinyl chloride have been calculated using the state-averaged complete active space self-consistent field (CASSCF) method with the 6-311++G(d,p) basis set and an active space of four electrons distributed in 13 orbitals. Both adiabatic and vertical excitation energies have been obtained using the state-averaged CASSCF and the multireference configuration-interaction methods. The potential-energy surfaces of six low-lying singlet states have also been calculated. While the 3(pi, pi*) state has a nonplanar equilibrium structure, the 3(pi, 3s) and 3(pi, sigma*) states are planar. The calculated vertical excitation energy of the 3(pi, pi*) state is in agreement with the experiment. The singlet excited states are found to be multiconfigurational, in particular, the first excited state is of (pi, 3s) character at the planar equilibrium structure, of (pi, sigma*) as the C-Cl bond elongates, and of (pi, pi*) for highly twisted geometries. Avoided crossings are observed between the potential-energy surfaces of the first three singlet excited states. The absorption spectra of vinyl chloride at 5.5-6.5 eV can be unambiguously assigned to the transitions from the ground state to the first singlet excited state. The dissociation of Cl atoms following 193-nm excitation is concluded to take place via two pathways: one is through (pi, sigma*) at planar or nearly planar structures leading to fast Cl atoms and the other through (pi, pi*) at twisted geometries from which internal conversion to the ground state and subsequent dissociation produces slow Cl atoms. 相似文献
19.
Wiosetek-Reske AM Wysocki S Bak GW 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2005,62(4-5):1172-1178
The absorption and fluorescence spectra of N-nonyl acridine orange are determined at room temperature (298 K) in cyclohexane, benzene, carbon tetrachloride, chloroform, chlorobenzene and dichloromethane. The ground state of dipole moment was obtained by impedance measurements using Guggenheim-Debeye's method. The experimental excited state dipole moment of N-nonyl acridine orange was determined using Bakhshiev's and Kawski-Chamma-Viallet's formulae and solvent polarity parameter proposed by Reichardt. These experimental results were completed with theoretical results using quantum chemical methods. The experimental (muexp=10.76 D) and theoretical (mucal=9.9 D) dipole moments in the ground and excited state (muexp*=14.56 D) were compared. 相似文献
20.
Sasirekha V Umadevi M Ramakrishnan V 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,69(1):148-155
Preferential solvation of a solvatochromic probe has been studied in binary mixtures comprising of a non-protic and a protic solvent. The non-protic solvents employed are carbon tetrachloride (CCl(4)), acetonitrile (AcN) and N,N-dimethyl formamide (DMF) and the protic solvents are methanol (MeOH) and ethanol (EtOH). The probe molecule exhibits different spectroscopic characteristics depending upon the properties of the solubilizing media. The observed spectral features provide an indication of the microenvironment immediately surrounding the probe. Solvatochromic shifts of the ground and excited states of the probe were analysed by monitoring the charge transfer absorption band and the fluorescence emission spectra in terms of the solute-solvent and solvent-solvent interactions. Fluorescence emission spectra show the dual emission due to excited state proton transfer nature of the probe molecule. The effect of solvent and the excitation energy on dual emission are also studied. The observed magnitude of the Stokes shift in the above solvents has been used to deduce experimentally the dipole moment ratio of the probe molecule for the excited state to the ground state. The dipole moment of excited state is higher than the ground state. 相似文献