Quantitative NMR spin-lattice-relaxation imaging of brine in sandstone reservoir cores

Two- and three-dimensional quantitative, saturation-recovery, NMR imaging has been applied to two sandstone reservoir cores. M₀ and T₁ images of high quality have been obtained with reasonable data-acquisition and data-processing times. The T₁ and T₂ processes have been shown to be correlated; the variations of the parameters within the images and the differences between the bulk and image relaxation values are discussed. The results of a quantitative T₁ imaging experiment of a phantom are also presented in order to demonstrate the advantages of quantitative NMR imaging over standard bulk measurements.     

Slow dynamics of embedded fluid in mesoscopic confining systems as probed by NMR relaxometry

Mesoscopic media such as porous materials or colloidal dispersions strongly influence the dynamics of the embedded fluid. In the strong-adsorption regime, it was recently proposed that the effective surface diffusion on flat surface is anomalous and exhibits long-time pathology, enlarging the time domain of the embedded-fluid dynamics towards the low-frequency regime. An interesting way to probe such a slow interfacial process is to use the field-cycling NMR relaxometry. This technique is used here to probe the fluid dynamics in two types of interfacial systems: i) a colloidal glass made of thin and flat particles; ii) a fully saturated porous media, the Vycor glass. Experimental results are critically compared to either a simple theoretical model of NMR dispersion involving elementary steps of the fluid dynamics near an interface (loops, trains, tails) or Brownian-dynamics simulations performed inside 3D reconstructions of these confined systems.Received: 1 January 2003, Published online: 14 October 2003PACS: 76.60.Es Relaxation effects - 61.43.Gt Powders, porous materials - 82.70.Dd Colloids     

NMR imaging in solids

The use of NMR imaging for the study of solids is demonstrated. A modified version of the convolution algorithm is used to construct the images. The modification removes the NMR linebroadening as the image is formed. Examples are presented using the mixed ionic conductor (Na_1?x, K_x) β-alumina.     

Temporal and spatial assessment of normal cerebrospinal fluid dynamics with MR imaging

The purpose of this study was to measure normal cerebrospinal fluid (CSF) pulsations within the intracranial and upper cervical subarachnoid spaces and the ventricular system. Phase contrast cine MR sequences were performed in sagittal and axial planes on 13 volunteers with flow encoding in the craniocaudal direction. CSF pulsations displayed considerable variations in healthy subjects, depending both on measurements localization and subjects, with CSF peak velocities ranging from 0 to 7 cm/s. In the subarachnoid spaces, the highest velocities occurred in the anterior location and increased from the cerebellar pontine angle cisterns towards the lower cervical spaces. In the ventricular system, the highest velocities occurred through the aqueduct of Sylvius. CSF flow within the third ventricle seemed to reflect a circular motion. There was a caudal net CSF flow in the aqueduct whereas in the upper cervical spaces net CSF flow was caudal anteriorly and cranial laterally. Velocity profiles of CSF pulsations demonstrated arterial morphology. After the R wave, caudal systolic motion was first observed in the posterior subarachnoid spaces, soon after in the anterior subarachnoid spaces and later in the ventricular system. Considering the morphology of CSF pathways, three successively initiated phenomena may explain the temporal course of CSF motion: the systolic expansion of the main arteries at the base of the brain, the systolic expansion of the cerebrospinal axis and, finally, the systolic expansion of the choroid plexuses.     

NMR properties of petroleum reservoir fluids

NMR well logging of petroleum reservoir require the measurement of the NMR response of water, oil, and gas in the pore space of rocks at elevated temperatures and pressures. The viscosity of the oil may range from less than 1 cp to greater than 10,000 cp. Also, the oil and gas are not a single component but rather a broad distribution of components. The log mean T1 and T2 relaxation time of dead (gas free) crude oils are correlated with viscosity/temperature and Larmor frequency. The relaxation time of live oils deviate from the correlation for dead crude oils. This deviation can be correlated with the methane content of the oil. Natural gas in the reservoir has components other than methane. Mixing rules are developed to accommodate components such as ethane, propane, carbon dioxide, and nitrogen. Interpretation of NMR logs uses both relaxation and diffusion to distinguish the different fluids present in the formation. Crude oils have a broad spectrum of components but the relaxation time distribution and diffusion coefficient distribution are correlated. This correlation is used to distinguish crude oil from the response of water in the pores of the rock. This correlation can also be used to estimate viscosity of the crude oil.     

NMR dynamics in disordered magnets

The excitation dynamics of site diluted magnets can be described at low energies (long length scales) by magnons, and above a crossover frequency, ω_c, (short length scales) by fractons. The density of fracton states is given by , where is the fracton dimensionality. Dilution gives rise to a characteristic length ξ∝(p−p _c)^ν, wherep _c is the critical concentration for (magnetic) percolation. The crossover frequency ω_c is proportional to ξ^-1[1+(θ/2)], where θ is the rate at which the diffusion constant decays with distance for diffusion on an equivalent network. A fractal dimensionD describes the density of magnetic sites on the infinite network, and . For percolating networks, for all dimensions ≥2. Neutron scattering structure factor measurements by Uemura and Birgeneau compare well with calculations using fracton concepts. Magnons are extended at low energies, while the fracton states are geometrically localized, with a wave function envelope proportional to exp . Here, is the fracton length scale at frequency ω. The exponentd _ϕ lies between 1 andd _min, the chemical length index (of the order of 1.6 in three dimensions). The localization of the magnetic excitations causes a spread in the NMR relaxation rates. A given nuclear moment will experience only a limited set of fracton excitations, resulting in an overall non-exponential decay of the NMR relaxation signal. When strong cross-relaxation is present, the relaxation will be exponential, but the temperature dependence will be strongly altered from the concentrated result.     

Contrast manipulation in NMR imaging

The past few years have shown rapid growth of NMR imaging in both image quality and diagnostic usefulness. It has become apparent, as the images have been published, that both inter- and intra-group imaging of the same underlying pathology produces images which can have vastly differing appearance. This effect is mainly due to imaging techniques which use different pulse sequence types and timings thus varying the relative contribution of the protpn density, T1, and T2 properties of the tissues. In this paper we investigate the contrast manipulation effects and methods for SNR optimization for the saturation recovery, inversion recovery, spin echo, and inversion recovery spin echo pulse sequences when applied to three clinically relevant imaging tasks.     

Cryogenic fluid dynamics

Ultrahigh Reynolds (Re) and Rayleigh (Ra) number flow can be produced and studied under controlled laboratory conditions using cryogenic liquid and gaseous He. Recent results on Rayleigh–Benard convection, pipe flow and towed grid turbulence are discussed together with some aspects of the future development.     

Nuclear fluid dynamics

For energies where the mean free nucleon path is comparable to the nuclear size, there is no fast local relaxation in nuclear collective motion. Therefore, in a fluid-dynamical approach, the intrinsic energy-density functional must take the distortion of the local Fermi surface into account. This can be achieved by a dynamical Thomas Fermi method which leads to additional restoring forces for the collective modes, except for the casesL=0 andL=1 where usual hydrodynamics is sufficient.     

Vorticity in nuclear fluid dynamics

We consider a model for gloun jet fragmentation based on QCD in which the fast hadrons in the jet are produced by the sequential reaction gluon $\text{→}\text{q}\text{q}\text{?}\text{q}\text{→}$ hadrons. The resulting jet shows an oblate transverse momentum structure, with a major axis preferential oriented normally to the direction of linear polarization of the gluon. We discuss jet-jet oblateness angular correlations in decays of heavy QQ? pseudoscalar and vector systems.     

Nongaussian processes in fluid dynamics

Computer experiments are performed to establish the relevance of nongaussian effects for the velocity v in dense fluids. Both nongaussianicity and long time features are interpreted assuming that v is driven by a nonlinear Fokker-Planck equation, yet compatible with canonical equilibrium.