Analyzing power measurements for n-p scattering between 13.5 and 16.9 MeV

The analyzing power A_γ(θ) for neutron-proton scattering has been measured for θ = 90°(c.m.) from 13.5 to 16.9 MeV and from θ = 50° to 145°(c.m.) at 16.9 MeV. Extensive Monte Carlo calculations have been made to correct for multiple scattering effects. Overall uncertainties are about ± 0.002. All the A_γ(θ) data, but primarily those at 16.9 MeV, disagree with predictons based on the phase-shift sets which have been derived previously by way of global analyses of nucleon-nucleon scattering data. Data for the product σ(θ)A_γ(θ) have been fitted with an expansion of the form (sin θ)($\text{a}{}_0\text{+ a}{}_1\text{cos}\text{θ + a}{}_2\text{cos}{}^2\text{θ)}$. For the first time the need for a non-zero a₂ has been illustrated for energies below 20 MeV. This parameter is shown to be related to the nucleon-nucleon F-state spin-orbit phase parameter. In addition, the P, D, and F spin-orbit phase parameter values derived from the present data differ significantly from the ones based on the Yale-IV and Liver-more-X global analyses. The derived D and F spin-orbit phase parameters also differ from those obtained in the recent analysis of nucleon-nucleon scattering data by Arndt et al.     

“Forbidden” rotational spectra of symmetric-top molecules: PH3 and PD3

A millimeter-wave spectrometer having a sensitivity of 4 × 10^?10 cm^?1 in the 2-mm region has been constructed for observation of extremely weak millimeter-wave spectra of gases. It has been used to measure J → J, K = 0 ← 3 transitions in PH₃ and J → J, K = 0 ← 3 as well as K = ±1 ← ±4 transitions in PD₃. The B₀ and C₀ spectral constants (in MHz) are: for PH₃, B₀ = 133 480.15 ± 0.12 and C₀ = 117 488.85 ± 0.16; for PD₃, B₀ = 69 471.10 ± 0.03 and C₀ = 58 974.37 ± 0.05. The effective ground-state values obtained for the bond angle and bond length are: for PH₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.420}{}_0$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.34}{}_5$; for PD₃, $\text{r}{}_0\text{(}\text{A}\text{?}\text{) = 1.417}{}_6$ and $\text{α}{}_0\text{(}{}^{\mathrm{o}}\text{) = 93.35}{}_9$. The corresponding zero-point-average values were calculated to be: for PH₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4269}{}_9\text{± 0.0002}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.228}{}_7$; for PD₃, $\text{r}{}_{\mathrm{z}}\text{(}\text{A}\text{?}\text{) = 1.4226}{}_5\text{± 0.0001}$ and $\text{α}{}_{\mathrm{z}}\text{(}{}^{\mathrm{o}}\text{) = 93.256}{}_7\text{± 0.004}$. For both species, the equilibrium values are $\text{r}{}_{\mathrm{e}}\text{(}\text{A}\text{?}\text{) = 1.4115}{}_9\text{± 0.0006}$ and $\text{α}{}_{\mathrm{e}}\text{(}{}^{\mathrm{o}}\text{) = 93.32}{}_8\text{± 0.02}$.     

Lorentz contracted geometrical model

The model assumes that when two high energy particles collide each behaves as a geometrical object which has a Gaussian density and is spherically symmetric except for the Lorentz-contraction in the incident direction. Folding the two spatial distribution together we obtain the slope (b) of the elastic diffraction peak in terms of the c.m. velocities (β_i and β_j) and the sizes (A_i and A_j) of the two incident particles. These sizes are assumed to have the experimental s-dependence of σ_tot ∝ πA² for each reaction. The combined s-dependence of the σ_tot's and the β's gives the s-dependence of the elastic slope $\text{b}{}_{\mathrm{ij}}\text{(s) =}\text{1}\text{2}\text{(A}{}_{\mathrm{i}}{}^2\text{β}{}_{\mathrm{i}}{}^2\text{+ A}{}_{\mathrm{j}}{}^2\text{β}{}_{\mathrm{j}}{}^2\text{)}\text{σ}{}^{\mathrm{ij}}{}_{\mathrm{<mtext>tot</mtext>}}\text{(s)}\text{σ}{}^{\mathrm{ij}}{}_{\mathrm{<mtext>tot</mtext>}}\text{(∞)}$. This formula agrees with the experimental slope for p-p, $\text{p}$-p, K⁺-p, K^?-p and π^±-p elastic scattering from 3 to 1500 GeV/c, with only 3 parameters: A_π² = 6.1, A_K² = 3.3 and A_p² = 10.5 (GeV/c)^?2.     

Diode laser spectroscopy of the CCl radical

Vibration-rotation transitions of the fundamental band have been observed for both C³⁵Cl and C³⁷Cl in the ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and ${}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ states by using an infrared diode laser spectrometer with Zeeman modulation. A few lines of the “hot” band (v = 2 ← 1) have also been recorded for C³⁵Cl. From an analysis of the observed spectra improved values were obtained for the vibrational harmonic frequency and anharmonicity constant, rotational constants, and Λ-doubling parameters. It was found necessary to take into account centrifugal distortion effects on the spin-orbit coupling constant A in the analysis, which gave $\text{(}\text{dA}\text{dr}\text{)}{}_{\mathrm{<mtext>e</mtext>}}\text{r}{}_{\mathrm{<mtext>e</mtext>}}$ to be ?176 ± 38 or ?125 ± 38 cm^?1, depending upon whether ²Σ^? or ²Σ⁺ states contribute more to the Λ-type doubling. The equilibrium internuclear distance r_e was calculated from the derived rotational constants to be 1.64506 ± 0.00016 Å.     

Electronic-excitation transfer collisions in flames-III: Cross sections for quenching and doublet mixing of Rb(52P32, 12) doublet by N2, O2, H2 and H2O

Weighted average quenching cross sections for the Rb(5²P) doublet by N₂ and H₂O were determined in flames with temperatures ranging from 1500 to 2500 K by measuring the fluorescence efficiency. The values found are $\text{(σ}{}_{\mathrm{qu}}\text{)}{}_{\mathrm{<mtext>N</mtext><mtext>2</mtext>}}\text{= (19±2)}\text{A}\text{?}{}^2$ and over the entire temperature range. At a temperature of 1720 K, mixing cross sections were obtained for the same doublet with N₂, H₂, O₂ and H₂O molecules. The cross sections found are: $\text{σ}{}_{21}\text{(}{}^2\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{→}{}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)}{}_{\mathrm{<mtext>N</mtext><mtext>2</mtext>}}\text{= (60±12)}\text{A}\text{?}{}^2$, $\text{σ}{}_{12}\text{(}{}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{→}{}^2\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{)}{}_{\mathrm{<mtext>N</mtext><mtext>2</mtext>}}\text{= 99±20)}\text{A}\text{?}{}^2$; , $\text{(σ}{}_{21}\text{)}{}_{\mathrm{<mtext>H</mtext><mtext>2</mtext>}}\text{> 30}\text{A}\text{?}{}_2$, $\text{(σ}{}_{12}\text{)}{}_{\mathrm{<mtext>H</mtext><mtext>2</mtext>}}\text{> 50}\text{A}\text{?}{}^2\text{;}$, . The ratios σ₁₂/σ₂₁ were measured independently and were found to agree with the detailed- balance condition within 3 per cent. A critical comparison of the flame values with previous literature data on N₂-cross sections shows that both mixing and quenching cross sections are temperature dependent in the range from 300 to 2500 K.     

Optical absorption by neutral bound excitons

In this note we determine the oscillator strengths for the dipole absorption of neutral bound excitons in direct gap semiconductors, using our previously obtained 35-term Page and Fraser type wave function, and taking into account the detailed electronic structure as well as the electron-hole exchange interaction.The envelope part of the oscillator strengths varies considerably with the electron-hole mass ratio $\text{σ =}\text{m}{}^1{}_{\mathrm{e}}\text{m}{}^1{}_{\mathrm{h}}$, and is maximum for the (D⁰, X)- complex when σ = 0.4. For typical σ-values (σ? 0.1–0.2), . But when σ approaches zero, the overlapping of the electron and the hole envelope wave functions of the (A⁰,X)-complex decreases progressively so that the oscillator strength also decreases and tends to zero.In the case of zinc-blende materials (T_d) and positive spin-orbit coupling at $\text{k}\text{= 0}$, we confirm that the line strength for transitions to or from $\text{J =}\text{1}\text{2}\text{(Γ}{}_6\text{)}$ or $\text{J =}\text{5}\text{2}\text{(Γ}{}_7\text{+ Γ}{}_8\text{)}$ level of the (A⁰, X)-complex is equal to one quarter of the line strength to or from the $\text{J =}\text{3}\text{2}\text{(Γ}{}_8\text{)}$ level.In the case of CdS, where our computed values are only in qualitative agreement with the experimental values, we discuss the use of the phenomenological result of Rashba.     

Molecular structure of phosgene as studied by gas electron diffraction and microwave spectroscopy: The rz structure and isotope effect

The r_z structure of phosgene has been determined by a joint analysis of the electron diffraction intensity and the rotational constants as follows: $\text{r}{}_{\mathrm{z}}\text{(}\text{CO}\text{) = 1.1785 ± 0.0026}\text{A}\text{?}$, $\text{r}{}_{\mathrm{z}}\text{(}\text{CCl}\text{) = 1.7424 ± 0.0013}\text{A}\text{?}$, ∠_z;ClCCl = 111.83 ± 0.11°, where uncertainties represent estimated limits of experimental error. The effective constants representing bond-stretching anharmonicity have been obtained from an analysis of the isotopic differences in the r_z structure: $\text{a}{}_3\text{(}\text{CO}\text{) = 2.9 ± 0.9}\text{A}\text{?}{}^{\mathrm{?1}}$, $\text{a}{}_3\text{(}\text{CCl}\text{) = 1.6 ± 0.4}\text{A}\text{?}{}^{\mathrm{?1}}$. The equilibrium bond distances have been estimated from the r_z structure for the normal species and from the anharmonic constants to be $\text{r}{}_{\mathrm{e}}\text{(}\text{CO}\text{) = 1.1756 ± 0.0032}\text{A}\text{?}$, $\text{r}{}_{\mathrm{e}}\text{(}\text{CCl}\text{) = 1.7381 ± 0.0019}\text{A}\text{?}$.     

Neutron-proton radius differences and isovector deformations from π+ and π− inelastic scattering from 18O

π⁺ and π^? elastic and inelastic scattering from ¹⁸O have been measured at T(π)=164 MeV. Consistent with the results at 230 MeV, it is found that the ratio $\text{σ(π}{}^{\mathrm{?}}\text{)}\text{σ(π}{}^{\mathrm{+}}\text{)}$ for the 2₁⁺ state is 1.86(16), while for the 3₁^? state it is 0.89(6). These results are interpreted as indicating differences in neutron and proton deformations characterizing the 2₁⁺ transition and partial neutron blocking for the 3₁^? transition. Optical model analysis of elastic scattering leads to the conclusion that $\text{〈r}{}_{\mathrm{<mtext>n</mtext>}}{}^2\text{〉}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{?〈r}{}_{\mathrm{<mtext>p</mtext>}}{}^2\text{〉}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{=0.03(3)}\text{fm}$.     

Scaling violation,the Callan Gross relation,and color excitation in electroproduction

The Callan-Gross relation is shown to be consistent with MIT-SLAC data for $\text{σ}{}_{\mathrm{<mtext>L</mtext>}}\text{(Q}{}^2\text{)}\text{σ}{}_{\mathrm{<mtext>T</mtext>}}\text{(Q}{}^2\text{)}$ for x ? 0.33 in deep inelastic eN scattering, despite the fact that these data are taken in the large Q² region where F₁ and F₂ individually exhibit scaling violation. Comparison is made with asymptotic freedom predictions, and color excitation is proposed to explain large values of $\text{σ}{}_{\mathrm{<mtext>L</mtext>}}\text{σ}{}_{\mathrm{<mtext>T</mtext>}}$ at small x.     

Some effects of spin-orbit interaction on rotational levels and rotational line intensities in vibrationally unexcited 2A, 2E, and 2F electronic states of open-shell XY4 molecules

Rotational energy levels in vibronic ground states of ²A, ²E, and ²F electronic states of open-shell XY₄ molecules, as well as rotational line intensities for allowed transitions between such states, are discussed, including the effects of spin-orbit interaction and tetrahedral splittings. Jahn-Teller effects are assumed to be small, and are only taken into account implicitly, through their contributions to various parameters in the effective Hamiltonian. Qualitative information is obtained by considering several limiting-case coupling schemes among the electron spin angular momentum S, the electron orbital angular momentum L, and the pure rotational angular momentum R. These limiting cases are similar in spirit to Hund's coupling cases in diatomic molecules, but differ sufficiently from the latter to make detailed correspondences unhelpful. Quantitative information on rotational energy levels and line intensities is obtained numerically by diagonalizing a Hamiltonian matrix set up in a basis set characterized by uncoupled moleculefixed projections of S, L, and the total angular momentum J, and symmetrized so that all basis set functions belong to a definite species in the subgroup D_2d of the true point group T_d. Hamiltonian matrix elements are determined by ladder operator techniques. Three sample calculated spectra, corresponding to $\text{p(}{}^2\text{F}{}_2\text{)-s(}{}^2\text{A}{}_1\text{)}$, $\text{d(}{}^2\text{E)-p(}{}^2\text{F}{}_2\text{)}$, and $\text{d(}{}^2\text{F}{}_2\text{)-p(}{}^2\text{F}{}_2\text{)}$ are presented. As one might expect, when the spin-orbit constant A is set equal to zero, then both qualitative and quantitative aspects of the rotational-electronic problem in open-shell XY₄ molecules can be mapped easily onto discussions of the rotation-vibration problem from the CH₄ literature.     

α(Q2) corrections to particle multiplicity ratios in gluon and quark jets

The order $\text{α(Q}{}^2\text{)}$ correction to the particle multiplicity ratio in gluon and quark jets is calculated in QCD. We find

$\text{r=}\text{9}\text{4}\text{1?}\text{αC}{}_{\mathrm{<mtext>A</mtext>}}\text{2π}\text{1}\text{3}\text{+}\text{N}{}_{\mathrm{?}}\text{3C}{}_{\mathrm{<mtext>A</mtext>}}\text{?}\text{2N}{}_{\mathrm{?}}\text{C}{}_{\mathrm{<mtext>F</mtext>}}\text{3C}{}^2{}_{\mathrm{<mtext>A</mtext>}}$

with r=〈n〉_{gluon jet}/〈n〉_{quark jet}. The method used is systematic and could be used for an order α(Q²) calculation.     

Temperature variation of the magnetic cluster structures in an iron-nickel invar alloy

Small-angle scattering of long wavelength neutrons $\text{(λ = 6.42}\text{A}\text{?}\text{)}$ from an Fe₆₅Ni₃₅ single crystal has been measured with the applied magnetic field (6.2 kG) parallel and perpendicular to the scattering vector $\text{K}$ of the elastic scattering over the temperature range from 25 to 422°C (T_c = 227°C). The scattering cross sections due to the longitudinal spin fluctuation have been analyzed by means of Guinier's approximation $\text{(dσ/dω)}{}_0\text{exp}\text{(?κ}{}^2\text{R}{}_{\mathrm{<mtext>g</mtext>}}{}^2\text{3}\text{)}$, where the forward cross section (dσ/dω)₀ is proportional to n, which is the number of atoms in a paramagnetic cluster, and R_g is the radius of gyration of the cluster. The empirical relation between n and R_g is = 0.298 × R_g^2.34 to be compared with that calculated for a simple spherical cluster model n = 1.274 R_g³.     

Excited vibrational state microwave spectra,structure, and force-field of trifluorosilane

The J = 2?1 microwave spectrum of six isotopic species of HSiF₃ has been observed and assigned in excited states of five of the six fundamental vibrations. The assignment is based on relative intensities, double resonance experiments, and trial anharmonic force constant calculations. Analysis of the spectra leads to experimental values for five of the $\text{α}{}_{\mathrm{r}}{}^{\mathrm{B}}$ constants, all three l-doubling constants q_t, one Fermi resonance constant φ₂₃₃, and one zeta constant $\text{ζ}{}_{\mathrm{6,\; 6}}{}^{\mathrm{(z)}}$.The harmonic force field has been refined to all the available data on vibration wavenumbers, centrifugal distortion constants, and zeta constants. The cubic anharmonic force field has been refined to the data on $\text{α}{}_{\mathrm{r}}{}^{\mathrm{B}}$ and q_t constants, using two models: a valence force model with two cubic force constants for SiH and SiF stretching, and a more sophisticated model. With the help of these calculations, the following equilibrium structure has been determined: $\text{r}{}_{\mathrm{e}}\text{(}\text{SiH}\text{) = 1.4468(±5)}\text{A}\text{?}$, $\text{r}{}_{\mathrm{e}}\text{(}\text{SiF}\text{) = 1.5624(±1)}\text{A}\text{?}$, ∠HSiF = 110.64(±3)°,     

A note on the momentum distribution function for an electron gas

The one-electron momentum distribution function $\text{〈a}{}_{\mathrm{k\sigma }}{}^2\text{a}{}_{\mathrm{k\sigma }}\text{〉}$ for an electron gas is investigated by a diagrammatic analysis of perturbation theory. It is shown that $\text{〈a}{}_{\mathrm{k\sigma }}{}^2\text{a}{}_{\mathrm{k\sigma }}\text{〉}$ has the following exact asymptotic form for large k (k ? p_F; p_F, the Fermi momentum): $\text{〈a}{}_{\mathrm{k\sigma }}{}^2\text{a}{}_{\mathrm{k\sigma }}\text{〉 =}\text{4}\text{9}\text{(}\text{αr}{}_{\mathrm{s}}\text{π}\text{)}{}^2\text{×(}\text{p}{}_{\mathrm{<mtext>F</mtext>}}{}^8\text{k}{}^8\text{) g?(0) + ?}$, where g?(0) is the zero-distance value of the spin-up-spin-down pair correlation function. The physical implications of the above asymptotic form are discussed.     

The A-dependence of J/ψ-particle inclusive distributions

The differential cross sections $\text{d}\text{σ}\text{d}\text{x}$ and $\text{d}\text{σ}\text{d}\text{p}{}_{\mathrm{t}}{}^2$ of inclusive J/ψ production by 43 GeV/c π^? off Be, Cu and W nuclei have been measured. Fitting $\text{d}\text{σ}\text{d}\text{p}{}_{\mathrm{t}}{}^2\text{～ A}{}^{\mathrm{\alpha }}\text{(p}{}_{\mathrm{t}}{}^2\text{)}$ we observed the increase of α with p_t².     

Coupling constants for several light nuclei from a dispersion analysis of nucleon and deuteron scattering amplitudes

A forward dispersion relation cannot be applied to charged particle scattering amplitudes unless the influence of the Coulomb interaction is explicitly considered. Earlier studies have shown how Coulomb effects can be taken into account when direct (s-channel or bound-state) poles are investigated. In this paper we extend the Coulomb modification to include I = 0 exchange (u-channel) processes as well. We then apply a forward dispersion relation to empirical d + α, p + d and n + d elastic scattering amplitudes which contain both direct and exchange poles with and without Coulomb effects. We obtain detailed and model-independent information on the following vertices: ⁶Li-α-d (S- and D-state) ⁴He-d-d, ³He-d-p, ³H-d-n and d-p-n. From the coupling constants we calculate the asymptotic normalization (spectroscopic factors) C²₁ of the corresponding cluster wave functions, which become: $\text{C}{}^2{}_0\text{(}{}^6\text{Li}\text{, α}\text{d}\text{) = 4.62 ± 0.23}$, $\text{C}{}^2{}_2\text{(}{}^6\text{Li}\text{, α}\text{d}\text{) = (1 ± 6) × 10}{}^{\mathrm{?4}}$, C²₀(α, dd) < 2, $\text{C}{}^2{}_0\text{(}{}^3\text{He, dp}\text{) = 3.5 ± 0.4}$, $\text{C}{}^2{}_0\text{(}{}^3\text{H, dn}\text{) = 2.6 ± 0.3}\text{and}\text{C}{}^2{}_0\text{(}\text{d, np}\text{) = 1.66 ± 0.1}$.     

Inclusive pion distributions in e+e− annihilation from sum rules and duality

The threshold behaviour of pion production presented in our earlier work is successfully compared with the new SPEAR data. By using duality and sum rules we derive F_T^(π+)(x) ≈ F_L^(π+)(x) ≈ F_T^(π0)(x) ? F_L^(π0)(x) for x near 1. An accompanying results is $\text{σ}{}_{\mathrm{<mtext>\pi </mtext><mtext>A</mtext>}}{}_2\text{(s) ≈ 2σ}{}_{\mathrm{\pi \omega }}\text{(s) ≈ 4σ}{}_{\mathrm{\pi \pi }}\text{(s) ≈ 9(m}{}_{\mathrm{?}}{}^2\text{/s)}{}^3\text{σ}{}_{\mathrm{<mtext>\mu </mtext><mtext>\mu </mtext>}}$ for large s.     

Three-nucleon results for separable potentials modelled on the Reid soft-core potential

Using a solution to the inverse scattering problem we have generated phase-equivalent separable potentials in the ${}^1\text{S}{}_0$ and ${}^3\text{S}{}_1\text{?}{}^3\text{D}{}_1$ states, which have nearly the same singlet UPA form factors and deuteron parameters (E_D, P_D, Q_D, A_S and $\text{A}{}_{\mathrm{D}}\text{A}{}_{\mathrm{S}}$) as the Reid soft-core potential. We compare our results for the binding energy of the triton and the neutron-deuteron doublet scattering length with the corresponding values for the Reid soft-core potential.     

The ã3A2 ← X̃1A1 absorption spectrum of thioformaldehyde: A vibrational and rotational analysis

The results of a vibrational and rotational analysis of the banded $\text{a}\text{?}{}^3\text{A}{}_2\text{←}\text{X}\text{?}{}^1\text{A}{}_1$ transition in $\text{CH}{}_2\text{S}\text{CD}{}_2\text{S}$ are presented. Only three of the six vibrational modes are active in the spectrum with $\text{ν′}{}_2\text{=}\text{1320}\text{1012}$, $\text{ν′}{}_3\text{=}\text{859}\text{798}$, and $\text{2ν′}{}_4\text{=}\text{711}\text{516}\text{cm}{}^{\mathrm{?1}}$. The spin forbidden transition gains intensity primarily by a mixing of the ${}^1\text{A}{}_1\text{(π}{}^1\text{,π)}$ and ${}^3\text{A}{}_2\text{(π}{}^1\text{,n)}$ states. This is confirmed by a rotational analysis of the 0₀⁰ band of both isotopes. The rotational analysis shows that the coupling in the $\text{a}\text{?}{}^3\text{A}{}_2$ state is near Hund's case b and that the spin constants are nearly 10 times greater than those observed for CH₂O. A $\text{CNDO}\text{2}$ calculation shows that this difference is due to the greater spin orbit coupling of S in CH₂S and to the smaller energy differences between the $\text{B}\text{?}{}^1\text{A}{}_1\text{(π}{}^1\text{,π)}$, $\text{b}\text{?}{}^3\text{A}{}_1\text{(π}{}^1\text{,π)}$, $\text{X}\text{?}{}^1\text{A}{}_1$, and the $\text{a}\text{?}{}^3\text{A}{}_2\text{(π}{}^1\text{,n)}$ states. The r₀ structure calculated from the rotational constants is $\text{r}{}_{\mathrm{<mtext>CS</mtext>}}\text{= 1.683}\text{A}\text{?}$, $\text{r}{}_{\mathrm{<mtext>CH</mtext>}}\text{= 1.082}\text{A}\text{?}$, β_HCH = 119.6°, and α (out of plane) = 16.0°. A simultaneous fit of the vibrational levels in ν′₄ of CH₂S and CD₂S to a double minimum potential function yielded a barrier to molecular inversion of 13 cm^?1 and an equilibrium out-of-plane angle of 15°.     

Electronic conductivity of AgI using D.C. polarization and charge transfer techniques

A Study of electronic conductivity using the d.c. polarization technique has been carried out in α and β-AgI which shows the former is a hole and the latter an electron conductor. Activation energies of undoped and Cu-doped single crystals and polycrystalline β-AgI were found to be 0.46 eV, 0.34 eV and 0.44 eV respectively and can be related to electron trap depths. The electron transference number ($\text{σ}{}_{\mathrm{\theta }}\text{σ}{}_{\mathrm{t}}$) for polycrystalline β-AgI was found to be 0.008 at 306 K. The activation energy for hole conduction in α-AgI was determined to be 0.97 eV in agreement with previous XPS studies.Transient measurements have also been conducted using the charge transfer technique in double cells of polycrystalline β-AgI. The carrier concentration C_θ and electron mobility μ_θ, have thus been estimated to be 1.8 × $\text{10}{}^{15}\text{cm}{}^3$ and 5.14 × 10^?5$\text{cm}{}^2\text{V}$?sec. respectively at 306 K, while the double layer capacitance was 0.496 $\text{μF}\text{cm}{}^2$.