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通过测试光延迟研究了聚酰亚胺LB膜的光学各向异性,分析了在LB膜成膜过程中成膜分子的流动取向特性,并研究了液晶的表面锚定能,分析了LB膜上液晶的取向机制.聚酰亚胺LB膜的链段的取向程度较强摩擦情形的聚酰亚胺表面的链段取向要差.强摩擦的聚酰亚胺会比聚酰亚胺LB膜具有更好的排列液晶分子的能力.LB膜的流动取向模式使得聚酰亚胺成膜分子沿拉伸方向形成一定的有序排列,并诱导液晶分子定向排列,液晶和聚合物分子相互作用是液晶表面排列的主要动力
关键词: 相似文献
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本文以LB膜技术研究了向列相液晶的取向机理。选择了四种不同金属的可溶性酞菁化合物MPc-R4作为取向材料,拉制成LB膜,诱导向列相正性液晶E-7。通过对菁酞LB膜的表征和液晶取向及电光性能的研究,认为液晶的取向是由分子间的相互作用力决定的。 相似文献
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制备了不同单体浓度的聚合物稳定铁电液晶器件,测试了震动实验和热稳定实验前后样品的排列织构、电光特性和对比度.用原子力显微镜研究了各样品的聚合物形貌,表明在器件内部形成了沿摩擦方向延伸的聚合物网络,并且随着单体含量的增加聚合物网络更加致密.由于聚合物网络体锚定的引入,使得铁电液晶分子在外力和温度场下的运动受到限制,聚合物体锚定的增强使聚合物稳定铁电液晶的稳定性也逐渐提高.实验结果表明,单体含量为4%时,聚合物稳定铁电液晶的抗震性和热稳定性良好,电光曲线为无阈值“V”字型,对比度达150∶1. 相似文献
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本文通过偏振红外吸收光谱研究了铁电与反铁电液晶分子TFMHxPOCBC-D 相似文献
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聚酰亚胺LB膜的研究:Ⅰ聚酰胺酸N,N—二甲基十八胺前聚物的LB膜 总被引:1,自引:0,他引:1
聚酰胺酸N,N-二甲基十八胺是制备本身不具备两亲性的聚酰亚胺LB膜的前聚物。合成制备了均苯四酸二酐-4,4’-二胺基二苯酸N,N-二甲基十八胺,研究了它单分子膜的各异性,比较了伯胺和叔胺膜的不同,并用低角X射线衍射研究这前聚物LB膜分子的详细排列。 相似文献
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本文通过偏振红外吸收光谱研究了铁电与反铁电液晶分子TFMHxPOCBC-D2(4-(trifluoromethylhexy-3-d2 carbonyl)phenyl 4′-octyloxybiphenyl caboxylate)在垂直排列取向液晶盒中CD2基团绕手征性烷基链转动的受阻行为.实验结果显示CD2的偏振红外吸收在Sm-C相不同于Sm-CA相.建立了一个CD2转动受阻模型,在这一模型的基础上,对CD2的偏振红外吸收进行了模拟计算,较好地解释了CD2红外吸收在铁电和反铁电液晶相下的行为差异,得到了CD2基团绕手征性烷基链转动受阻的结论.
关键词:
反铁电液晶
红外光谱
受阻转动 相似文献
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采用分层蒸镀法,在玻璃基片上依次蒸镀二氨基二苯醚(ODA)和均苯四甲酸二酐(PMDA)两种单体,然后在空气环境中对样品进行不同温度和时间的热亚胺化处理,使二者在交界面上反应生成聚酰亚胺。经加热150 ℃ 1 h然后经350 ℃ 2 h处理的样品,在脱膜后能制备出直径1.8 cm,厚度为100 nm的聚酰亚胺自支撑薄膜。用FTIR测量了自支撑薄膜的红外光谱,特征吸收峰的分析表明薄膜已基本上完全亚胺化。用原子力显微镜分析了浮法玻璃衬底上聚酰亚胺薄膜的表面形貌,结果表明以ODA作为内层制备的膜层表面更光滑平整。 相似文献
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Guided-Wave Two-Dimensional Acousto-Optic Scanner Using Proton-Exchanged Lithium Niobate Waveguide 总被引:1,自引:0,他引:1
Two-dimensional scanning of a 0.6328 mum guided-light beam has been realized using noncolinear acousto-optic (AO) coplanar Bragg diffraction together with colinear AO guided-mode to substrate radiation-mode conversion in a Z-cut Xpropagation LiNbO3 proton-exchanged (PE) waveguide. The two surface acoustic (SAW) waves utilized are at the center frequencies of 500 and 200 MHz, propagating in the Y and X axes, respectively. Two-dimensional scanning of approximately 720 resolvable light beam spots, namely, 18 40 (horizontal vertical) scanning, has been demonstrated using a light beam of 1.0 mm aperture. The total number of resolvable beam spots can be greatly increased from 720 by simply utilizing SAW transducers of larger bandwidth and a light beam of greater aperture. It should also be possible to significantly increase the diffraction efficiency from 3 % by optimizing the parameters of the PE waveguide and the SAWs. 相似文献
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A review of schemes for multiple access in fiber optic networks shows that a hybrid of wavelength and code division multiple access (WCDMA) combines the best features of both. In particular, the hybrid scheme retains the large information carrying capacity of wavelength division multiple access (WDMA) and flexibility of code division multiple access (CDMA). In this paper WDMA, optical CDMA (OCDMA), and WCDMA networks are discussed. In OCDMA networks, concept of incoherent and coherent coding including inverse decoding and matched filter is introduced. The delay performance of both WDMA and WCDMA networks, under the simple suboptimum access protocols based on cyclic search, is computed. It has been shown quantitatively that tuning delay significantly affects the delay performance of both WDMA and WCDMA networks. Futhermore, delay performance of WCDMA networks is always better than the WDMA networks for the same tuning delay, load, and number of users. 相似文献
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S. G. Nedel’ko M. A. Krysyuk A. L. Apanasenko L. N. Lymarenko Z. T. Moroz 《Journal of Applied Spectroscopy》1997,64(1):55-61
Results of a study of the effect of γ-radiation on the spectral luminescence properties of cadmium tungstate crystals doped
with silver, bismuth, and molybdenum cations are presented. Spectral characteristics of the nondnnnoped crystals are briefly
described. Absorption and photo and X-ray luminescence spectra of the crystals taken before and after exposure to γ-radiation
(5.5·104 Gy) are compared. It is found that the spectral characteristics of the crystals doped with silver, bismuth, and molybdenum
cations do not change markedly after the exposure. The relation between the type of impurity-induced defects, individual characteristics
of the impurity cations, and the character of the effect of γ-radiation on the spectral luminescence properties of impure
crystals is analyzed (preliminarily).
Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 64, No. 1, pp. 55–60, January–February, 1997. 相似文献
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A simple technique of pulse compression, based on the linear chirp compensation of self-phase modulation (SPM) spectra in dispersion shifted fibers, is demonstrated. The optimization procedure is carried out, for a short span of a single-mode fiber, using a parabolic law, which describes the behavior of the squared output pulse width versus the pump peak power in the case of Gaussian pulses. The experimental results give a minimum pulse duration of 233 fs, which is in good agreement with the model. Shorter and coherent pulses, down to 90 fs, have been obtained by inserting an interference filter at the optical output. 相似文献
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The Shanghai Synchrotron Radiation Facility(SSRF)booster ring,a full energy injector for the storage ring,is deigned to accelerate the electron beam energy from 150MeV to 3.5GeV that demands high extraction efficiency at the extraction energy with low beam loss rate when electrons are ramping.Closed orbit distortion(COD)caused by bending magnet field uniformity errors which affects the machine performance harmfully could be effectively reduced by bending magnet location sorting.Considering the affections of random errors in measurement,both ideal sorting and realistic sorting are studied based on measured bending magnet field uniformity errors and one reasonable combination of bending magnets which can reduce the horizontal COD by a factor of 5is given as the final installation sequence of the booster bending magnets in this paper. 相似文献
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We measure the waveform and phase curves of short optical pulses before and after transmission over different lengths of fibers by use of the pulse analyzer with the frequency-resolved optical gating (FROG),and numerically simulate pulse evolution under the experimental conditions.The nonlinear coefficient of the fiber is given by comparing the experimental results with the numerical ones.Difference between the experiment and numerical simulation is analyzed. 相似文献
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Resonance scattering of elastic spherical shell and cylindrical shell while the surrounding fluid medium has absorption is studied. The normal mode solution derived using exact elastic theory and the separation of variables is still applicable. However, the scattering form function has to be modified for the absorbing medium, otherwise the unreasonable result would be obtained. The backscattering form function in the absorbing medium is redefined, and the form function of elastic spherical and cylindrical shell with vacuum or solid matter filled is calculated in various absorption conditions. The results show that the absorption of surrounding fluid leads to notable attenuation of the coincidence resonances in the mid-frequency, but it has a little influence on the low-frequency resonance scattering induced by the filler inside the shell. 相似文献
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A versatile and low-cost single-beam self-referenced phase-sensitive surface plasmon resonance(SPR)sensing system with ultra-high resolution performance is presented.The system exhibits a root-mean-square phase fluctuation of ±0.0028.over a period of 45 min.i.e.a resolution of±5.2×10-9 refractive index units.The enhanced performance has been achieved through the incorporation of three design elements:a true single-beam configuration enabling complete self-referencing so that only the phase change associated with SPR gets detected,a differential measurement scheme to eliminate spurious signals not related to the sensor response,and the elimination of retardation drifts by incorporating temperature stabilization in the liquid crystal phase modulato .Our design should bring the detection sensitivity of non-labeling SPR biosensing closer to that achievable by conventional fluorescence-based techniques. 相似文献
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Ta2O5 films are prepared on BK7 substrates with conventional electron beam evaporation deposition.The effects of SiO2 protective layers and annealing on the laser-induced damage threshold (LIDT) of the films are investigated.The results show that SiO2 protective layers exert little influence on the electric field intensity(EFI)distribution,microstructure and microdefect density but increase the absorption slightly.Annealing iS effective on decreasing the microdefect density and the absorption of the films.Both SiO2 protective layers and annealing are beneficial to the damage resistance of the films and the latter is more effective to improve the LIDT.Moreover,the maximal LIDT of Ta2O5 films is achieved by the combination of SiO2 protective layers and annealing. 相似文献