共查询到20条相似文献,搜索用时 62 毫秒
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便携式钨丝电热原子吸收光谱仪测定水样中铜、铬、铅和镉 总被引:6,自引:1,他引:6
以钨丝原子化器和小型化CCD检测器为主要部件,组装了便携式钨丝电热原子吸收光谱分析仪,优化了载气(Ar/H2) 流速、空心阴极灯位置、原子化器高度、灰化和原子化电流等主要仪器条件.最佳载气(Ar/H2)流速(mL/min)为600 /300(Cd),800/200(Cu, Pb, Cr);灰化电流为2.9~3.2 A;原子化电流为8.5 A;CCD的积分时间为50 ms.并在优化的仪器条件下准确测定了环境水样中的铜(Cu)、铬(Cr)、铅(Pb)和镉(Cd),进样10 μL时,其检出限分别为2、5、9和0.5 μg/L.此便携式原子吸收光谱仪在环境水样痕量元素分析中可望有良好的应用前景. 相似文献
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用标准的150 W幻灯灯泡的钨丝作原子化加热材料,设计制作了一种新颖的、结构简单的钨丝电热原子化器,同时还设计了该原子化器的电源电路和信号的数据采集电路.该原子化器能的最高原子化温度可达3100 K左右;编写了硬件的控制软件和信号处理的应用软件.用该原子化器将实验室一台火焰原子吸收光谱仪改装成钨丝原子吸收光谱仪,并以铜元素标准溶液和PerkinElmer公司多元素标准溶液对仪器性能作了研究.仪器对铜的检出限为0.0133 μg/mL,线性范围为0.10~4.0 μg/mL;对1.0 μg/mL的铜标准溶液测试的相对标准偏差为RSD=4.1%(测试次数n=10),每次分析所需样品量20 μL. 相似文献
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电热原子吸收光谱法快速测定白酒中痕量铅 总被引:3,自引:0,他引:3
向立人 《理化检验(化学分册)》1998,34(3):119-120
利用石墨炉原子化器灵敏度高,程序升温的特点,研究了铅吸收线特征,干燥、灰化和原子化温度时间的影响,拟定了不经分离富集及消化前处理快速测定样品中铅的方法,Ph(Ⅱ)在0~1.0μg·ml~(-1)范围内符合比耳定律,特征量C.M.=3.1×10~(-11)g。升温周期52s,分析周期102s。方法用于多种中国名酒中痕量铅的分析,标准加入量的回收率在93.0%~105.5%之间。 相似文献
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Direct Determination of Some Trace Elements in Milk by Electrothermal Atomic Absorption Spectrometry
《Analytical letters》2012,45(12):1519-1531
Abstract A method for the determination of trace and ultra-trace elements (Fe, Cu, Mn, Co, Cr, Mo and Ni) in milk by electrothermal atomic absorption spectrometry is described. Milk samples are injected directly into the graphite tube. Optimal operating conditions have been established. The method appears to be accurate and reproducible. The relative standard deviation was, on average, 9%. 相似文献
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J. L. Kacprzak 《International journal of environmental analytical chemistry》2013,93(4):561-564
Abstract Graphite-furnace atomic absorption spectrometry for tributyltin in oysters is described. Tributyltin is extracted by n-hexane after digestion with hydrochloric acid. The 3[sgrave] detection limit for tributyltin is better than 0.01 mg Sn/kg. Typical absorbance values are about 0.10 for tributyltin contents as low as 0.03 mg Sn/kg. Tributyltin contents of 29 oyster samples are given. 相似文献
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李志明 《分析测试技术与仪器》2003,9(2):91-94
探讨了痕量铕的富集、解吸条件及测定时的干扰情况.实验表明适量Fe2+的存在才能满足分析要求.利用浸钽液热解镀层石墨管和光温控制技术以保证方法的灵敏度和重现性.方法操作简便、结果准确,适合大批岩石、矿物中Eu2O3大于1×10-5%的测定. 相似文献
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Irina Karadjova Sonja Arpadjan Julijana Cvetković Trajcče Stafilov 《Mikrochimica acta》2004,147(1-2):39-43
An accurate, simple and precise method for total mercury determination in wines is described. Liquid/liquid extraction of inorganic and organic mercury species directly from untreated wine samples is recommended as a preconcentration procedure prior to determination by electrothermal atomic absorption spectrometry (ETAAS). Ammonium pyrrolidinedithiocarbamate was used as complexation agent. The optimal instrumental parameters for ETAAS measurement of mercury species extracted are proposed. The detection limit for total mercury determination is 0.2µgL–1. The relative standard deviation is 15–22% for mercury in wine in the range of 0.2–5µgL–1. The proposed procedure has been successfully applied to the determination of mercury in bottled wines in Bulgaria and Macedonia. 相似文献
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研究了用湿法消解啤酒样品、石墨炉原子吸收光谱(GFAAS)及火焰原子吸收光谱(FAAS)法分别测定啤酒中的痕量Pb2+和Zn2+。对仪器的工作参数进行了优化,探讨了混合酸消解体系、消解液用量,消解温度等因素的影响。结果表明,在200℃温度下,HNO3+HClO4(16+4)混酸能完全消解样品。Pb2+、Zn2+分别在0~80μg/L、0~1.50μg/mL范围内线性关系良好(线性相关系数r分别为0.9995和0.9997),其检出限分别为0.2μg/L、8.0μg/L。测定Pb2+、Zn2+的相对标准偏差(RSD)分别为1.8%和0.92%,加标回收率分别为96.5%和99.8%。该方法检出限低,精密度和准确度高,适用于啤酒样品中痕量铅、锌含量的测定。检测的9种啤酒样品中铅、锌含量范围分别为11.34~47.15μg/L、277~422μg/L,低于食品中的限量值。 相似文献
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《Analytical letters》2012,45(5):1341-1354
Abstract Twelve procedures of sample pretreatment for manganese determination in blood serum were tested in comparable instrumental conditions. the best results were obtained by dilution of serum with diluted nitric acid, which leads to formation of an internal matrix modifier composed of calcium and phosphoric acid. Other procedures may also give satisfactory results, but then as standards aqueous albumin solutions should be used. 相似文献
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The slurry sample introduction approach is a convenient method of solid sampling that allows the rapid and accurate determination of trace metals in foodstuffs by ETAAS. Since complex dissolution of the samples is avoided,sample handling is minimal and possible sources of contamination are reduced. Among which, preparation of suspension and optimization of the graphite furnace heating program are important. First, the samples are pulverized using homogenizer at speed lOOOOr/min. Ninety percent of the particles are less than 30um in diameter after a pulverizing period of 6min for vegetable, fruit and liver; 25min for beef and pork; 8min for cereals, which allow the preparation of stable slurries up to at least 10%. Second, suspensions are prepared in medium containing 0.15% agar as stabilizing agent, which stabilizing time is up to two days. 相似文献
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