Depth profiles of long lived radionuclides in Chernobyl soils sampled around 10 years after the accident

Depth profiles of the long-lived radionuclides, ¹³⁷Cs, ⁹⁰Sr, Pu isotopes and ²⁴¹Am were examined in undisturbed sandy, peaty and Podsol soils in the Chernobyl 30 km exclusion zone sampled around 10 years after the accident. Two Podsol soils, which have different radioactive deposition characteristics, have also been examined. Activity ratios of ^239,240Pu/¹³⁷Cs, ⁹⁰Sr/¹³⁷Cs, and ²⁴¹Am/¹³⁷Cs in the 0-1 cm layer of the two Podsol soils differed very much. Speciation of the radionuclides by sequential selective extraction was examined in the soils. Depth profiles of the soils have been analyzed according to the speciation results and soil characteristics.     

Distribution of radionuclides in the environment in northern Italy after the Chernobyl accident.

Soon after the Chernobyl nuclear accident, the air-pumping stations in Pavia (northern Italy) were alerted. In a few days, a rapid increase in radionuclide concentration in air particulates was observed. Consequently, an environmental radioactivity monitoring programme was started in which several matrices such as soil, grass, vegetables and cows' milk were subjected to direct gamma-ray spectrometry. The radioactivity distribution and its variation with time is presented, discussed and compared with other available data. Detection limits, precision and accuracy are also reported, and depth profiles in soils for 137Cs are presented and correlated with soil quality parameters. A survey of environmental radioactivity in soil, in a search for residual Chernobyl fallout, was carried out and a map of the 137Cs distribution over a large area in northern Italy is presented and discussed.     

Migration of Chernobyl plutonium in soils

Various geochemically linked landscapes were studied for the distribution of Chernobyl plutonium in soils.     

Radioactive contamination of soils in lower Saxony, Germany, after the Chernobyl accident.

The horizontal and spatial distribution of artificial and natural radionuclides in soils, and the vertical migration velocity of 0.8-2.0 cm per annum for caesium were examined in order to determine whether caesium is still in the root zone of major plants and, therefore, part of the food-chain. The vertical distribution patterns of caesium are dependent on the different physico-chemical soil properties. The soil samples were analysed with a pure Ge detector. In south-eastern Lower Saxony, the maximum gamma-activity for 137Cs of 33.3 kBq m-2 was found in a depth range of 0-20 cm (January 1, 1989). This was correlated with areas that had received heavy rainfall on May 4, 1986. On January 1, 1989 approximately 60% of the Chernobyl caesium was still in the top 0-2 cm of the topsoil.     

Determination of strontium-90 in various kinds of water after Chernobyl accident in Austria

As a consequence of the reactor-accident of Chernobyl on Tuesday 29 April 1986 the environmental radioactivity in Austria increased for above the level recorded before. Depending on the amount of precipitation the deposition of radioactive fallout showed great differences. Many water samples /rain water, lake water, swimming pool water, drinking water, underground water/ collected /during period of April 29 to May 30/ from Vienna, Lower Austria and Steiermark were analyzed for⁹⁰Sr. The following concentrations in /nCi 1^–1/ of⁹⁰Sr was found: 8.69±2.3 for rain water, 0.09±0.12 for lake water, 0.08–0.18 for swimming pool, 0.04–0.13 for drinking water, 0.07–0.2 for underground water. The⁹⁰Sr concentration was not higher than the maximal permissible /0.004–0.4 nCi 1^–1/ except for rain water.     

Comparison of radionuclides levels from the Chernobyl reactor accident and from global fallout

Studies on radioactive fallout from atmospheric nuclear weapons tests have been carried out at this laboratory since the mid-fifties. The data thus generated on the levels and composition of radioactive fallout in India has been published periodically. Consequent to the Chernobyl reactor accident in the USSR in April 1986, similar studies were carried out. A number of fairly active samples were collected from commercial aircraft which had flown over the USSR soon after the accident. Even though the levels of fallout from the Chernobyl reactor accident observed in India were not significant from a health hazard view point, the studies provided detailed information on differences in the composition of fallout from the accident and long term radiation exposures likely to accrue from the Chernobyl fallout as opposed to global fallout from atmospheric nuclear weapons tests. This paper presents the results and their interpretation on the above aspects.     

Radiocesium concentration in milk after the Chernobyl accident in Japan

Radiocesium concentrations in cow's milk from two producing districts in Japan were measured monthly for three years following the Chernobyl accident. The Chernobyl contribution in¹³⁷Cs concentration was evaluated from the¹³⁴Cs concentration and the¹³⁷Cs/¹³⁴Cs ratio. The highest¹³⁷Cs concentration of 0.6 Bq l^–1 was observed in May 1986 and the Chernobyl contribution has decreased during three years to levels corresponding to the contribution from past nuclear weapons fallout. Annual values of child internal dose through milk consumption were estimated at 0.6, 0.3 and 0.1 Sv for the first, the second and the third year following the accident, respectively.     

Cesium-137 in air late after the Chernobyl reactor accident

Summary Cesium-137 in air as high as 88.1 μBq ^. m^-3 was recorded in Thessaloniki, Northern Greece (40°38’N, 22°58’E) on June 3, 1998 very late after the Chernobyl reactor accident following a radiological incident occurred in a steel factory at Acerinox, Spain.     

Radioactive iodine-131 over Taiwan after the Chernobyl accident

Two weeks after the Chernobyl Nuclear Power Plant accident, a substantial increase in radioactivity above normal background levels was observed in various samples taken in Taiwan, R. O. C., which is 7600 km from Chernobyl. The¹³¹I concentrations in grass, rainwater, and milk were monitored continuously in succeeding weeks and correlations with weather conditions are discussed. Levels of radiation fallout over Taiwan due to the Chernobyl accident are much lower than the response levels recommended by local authorities and pose no danger to the public.     

Radioactivity of cattle fodder and milk after the Chernobyl accident

The radioactivities of⁹⁰Sr,¹³⁷Cs and¹³⁴Cs have been measured in soil, fodder and milk from the south-western region of Slovenia, Yugoslavia after the Chernobyl accident. Maximal concentrations of Sr-isotopes in samples and the rate of their decrease in a period up to two years after the accident are given. The transfer of radionuclides from soil to grass and from fodder to milk is discussed.     

Isotopic composition of plutonium immissions in Austria after the Chernobyl accident

Alpha-spectrometric Pu determinations in aerosol samples collected after the Chernobyl accident in Austria show a²³⁸Pu/²³⁹ (240)Pu ratio in the range of 0.33–0.76 with a most reliable value of 0.47. From²⁴¹Am measurements in old Pu preparations and air filter analyses also²⁴¹Pu activities have been calculated. The ratio²⁴¹Pu/^{239 (240)}Pu during the main contamination period is 74.6±5.7, when maximum²⁴¹Pu concentrations in air achieved 4.5–6.0 mBq/m³.     

Some aspects of radioactive contamination after Chernobyl accident in Romania

After the Chernobyl disaster, the radioactive cloud passage over Romania beginning with the April 30th, 1986 caused fall-out of different intensities in different regions.. The principal contributors to the radioactive exposure during the month of May and rest of 1986 were the short and medium half-live radionuclides: ¹³²Te+¹³²I, ¹³¹I, ¹⁴⁰Ba+¹⁴⁰La, ¹⁰³Ru+¹⁰³Rh, ¹⁰⁶Ru+¹⁰⁶Rh, ⁹⁵Zr+⁹⁵Nb, ¹³⁶Cs, ¹³⁴Cs, ¹⁴¹Ce, ¹⁴⁴Ce and ¹²⁵Sb. After four-five years only ¹³⁷Cs and ⁹⁰Sr remained significant radioactive contaminants. During May 1986 the grass was the mostly affected component of the environment and it contaminated rapidly the majority of foods. Measurements made on the daily gathered pollen samples and eggs during May 1986 clearly indicated that these samples can be used as bioindicators of radioactive contamination of the atmospheric air and, respectively, for soil and grass. Regarding soil contamination, the higher ^134+137Cs deposits in Romania following the northeast-southwest direction were measured, some of these being above 80 kBq/m². This direction is the same with the cloud passage over Romania during the first week of May 1986 and it was confirmed by measurements in the former Yugoslavia, Albania, Greece, and south of Italy.     

Behaviour of long-lived Chernobyl radionuclides in a soil-water system.

Field and laboratory experiments have been used to study the behaviour of long-lived radionuclides in the zone affected by the Chernobyl accident. Speciation of 90Sr and 137Cs in soils and bottom sediments was determined. The principal distinction of the Chernobyl fallout was that it contained a relatively small proportion of exchangeable forms because a considerable fraction of the radionuclides was incorporated as part of the insoluble fuel particles. Disintegration of fuel particles in soils and bottom sediments results in transition of non-exchangeable forms into exchangeable forms. Radionuclide species have different pathways and rates of migration in soils and bottom sediments. Migration of each chemical form was described by a convective-dispersive equation taking into account transformation processes of radionuclide species in soils or bottom sediments. Adsorption of 90Sr and 137Cs in the environment is controlled by the cation-exchange capacity and the selectivity of the solid phase (i.e., soil, bottom sediments and suspended matter) and the cationic composition of the liquid phase (i.e., soil solution, surface run-off and river or lake water). The corresponding parameters for the processes were obtained.     

Radioactive pollution of Turkish biotas one year after the Chernobyl accident

Long-lived fission radionuclides spread out after the Chernobyl accident have been measured in samples collected from the Black Sea and at the Aegean coasts of Turkey between June 15 and September 15, 1987. Nondestructive analysis was performed using high resolution -spectroscopy. The activity remaining 16 months after the event was found to be enhanced in coniferous needles as well as in lichens, while foodstuff did not show any appreciable contamination. The relatively high¹⁰⁶Ru/¹³⁴Cs and¹⁴⁴Ce/¹³⁴Cs ratios compared to those found in analogous samples from Southern Europe, might result from a fractionation between refractory and volatile elements.     

Concept of seasonality in the light of the Chernobyl accident.

Seasonality could have a strong influence on the radiological impact of environmental radioactive contamination. Short-lived radionuclides (e.g., 131l) and those that mainly enter the food chain by direct contamination (e.g., 137Cs) are especially important in this context. In particular, the contamination of cereals is influenced by seasonality. For temperate latitudes it is generally true that radioactive contamination during winter, when the fields lie fallow and the domestic animals are stabled, will result in a significantly lower radiological impact than if a similar contamination were to take place in the summer shortly before harvesting. The impact of the Chernobyl accident on the radioactive contamination of human diet was strongly influenced by seasonality.     

Migration of radionuclides in the enviroment

The mechanisms of transport and retaidation processes, chemistry and migration behaviour of radionuclides of fission products and actinides in engineered barriers, especially bentonites, have been summarised. A “critical group of radionuclides” is proposed for thorough investigation of their retardation properties in natural sorbents. The evaluation of accessible data of retardation and transport parameters relevant for the conditions of underground deep repository to be projected is carried out from point of view their possible inclusion into a data-bank. The effect of solubilities and dissolution reactions, diffusion and sorption/desorption, complexation and variations in the aqueous phase composition, pH-value and oxidation-reduction properties and other phenomena on Kd values is discussed. Attention is devoted to thermodynamic modelling and its validation for evaluation of various phenomena in the buffer/backfill-ground water systems.     

Isotopic composition of the radioactive fallout in Eastern Poland after the Chernobyl accident

After the Chernobyl accident the radioactivity of air, soil, dust and grass samples, originating from Eastern Poland was investigated by gamma-ray techniques. The isotopic composition of the radioactive fission products in these samples was determined. By combining the obtained results with those from other groups the evolution of the activity ratio in air for some isotopes was gathered. It is suggested that this evolution may be related to the differences in the deposition velocities of various elements. The distributions of the activity ratio in the measured samples indicate different transport and deposition properties for the volatile and nonvolatile fission products. It is concluded that the main part of the released nonvolatile products was deposited in the form of hot particles.     

Photochemical aspects of the behavior of the atmospheric radioiodine after the Chernobyl accident

A hybrid stable iodine/radioiodine (¹³¹I) atmospheric photochemistry box model, including 27 reactions, has been developed and solved using algorithmic programme with the application of the Runge-Kutta method of the order 4(5). This modelling offers a clearer view of relationship among aerosol-associated (inorganic iodine compounds, mostly I₂O₂), gaseous inorganic (mostly IONO₂, HOI) and organic (CH₃I) iodine compounds in ambient atmosphere. Summing up the data of the Chernobyl accident, the problem of the standardised method for atmospheric aerosol-associated and gaseous (inorganic and organic) radioiodine activity measurements in the case of the nuclear power plant accident is discussed.     

Determination of239Pu in soil samples from Austria after the Chernobyl accident

As a consequence of the reactor accident at Chernobyl on Tuesday 29 April 1986 the environmental radioactivity in Austria increased for above the level recorded before. Depending on the amount of precipitation the deposition of radioactive fallout showed great differences. Many soil samples collected /during the period from June 15 to September 15/ from Lower-Austria, Styria and Burgenland were analyzed for²³⁹Pu. The concentration found for²³⁹Pu ranged between 2.9 and 9.2 fCi g^–1. The highest concentration was detected in the soil of south-eastern part of Austria /Radkersburg/.²³⁹Pu concentration increased with depth from which soil samples were taken.     

Chemical fraction of radiactive cesium in atmospheric aerosol in Prague after the Chernobyl accident

Aerosol filters exposed during the period of direct contamination after the NPP accident at Chernobyl have been analyzed with the aim to determine the physicochemical forms of¹³⁷Cs. A modified sequential analysis of solubility according to Tessier was used. It was shown that the content of water-soluble radiocesium fraction (about 45%) was substantially lower when compared with the analysis results of aerosols collected in the U.K. Another marked difference was found in the case of undissolved residue, where, on the contrary, the¹³⁷Cs content was higher. No significant differences were found in the composition of samples collected during the time period of, May 1–May 6, 1986. In a sample collected in a later period a lower percentage of water soluble¹³⁷Cs fraction and a higher percentage of¹³⁷Cs in the undissolved residue was found.