共查询到20条相似文献,搜索用时 31 毫秒
1.
E.J. Wolfson E.N. Caspi H. Ettedgui H. Shaked M. Avdeev 《Journal of magnetism and magnetic materials》2008
Tb0.75Y0.25Co3B2 was studied as a function of temperature by neutron powder diffraction, ac susceptibility and SQUID magnetization measurements. The solid solution, which is of hexagonal symmetry and is paramagnetic at 300 K, undergoes a magnetic Co–Co ordering transition at ∼150 K, and a second magnetic Tb–Tb ordering transition at ∼17 K. The latter induces a spin-reorientation transition, in which the magnetic axis rotates from the c-axis toward the basal plane. The component of the magnetic axis, which is perpendicular to c, leads to a crystal symmetry reduction from hexagonal to monoclinic. The observed magnitude of the magnetic moment of the Tb ion is 1.5 μB, unusually small relative to the free ion and parent compound (TbCo3B2) values. These magnetic and crystal properties are discussed and compared with what was previously published for the parent compound. 相似文献
2.
Two-dimensional crystal curved lines consisting of the nonlinear optical SmxBi1−xBO3 phase are fabricated at the surface of 8Sm2O3·37Bi2O3·55B2O3 glass by continuous wave Nd:YAG laser (wavelength: 1064 nm) irradiation (samarium atom heat processing) with a power of ∼0.9 W and a laser scanning speed of 5 μm/s. The curved lines with bending angles of 0-90° or with sine-shapes are written by just changing the laser scanning direction. The polarized micro-Raman scattering spectra for the line after bending are the same as those for the line before bending, indicating that the crystal plane of SmxBi1−xBO3 crystals to the crystal growth direction might be maintained even after the change in the laser scanning direction. It is found from laser scanning microscope observations that the crystal lines at the surface are swelled out smoothly, giving a height of about 10 μm. 相似文献
3.
The orthorhombic Sm5Ge4-type Tb2Ti3Ge4 shows square modulated non-collinear magnetic ordering with wave vector K=[±1/3, 1/2, 1/2] at 2 K. The terbium magnetic moments lie in the bc plane and magnetic moment value of 7.5(2) μB/Tb is obtained at 2 K. 相似文献
4.
New germanosilicate glasses giving the crystallization of yttrium iron garnet Y3Fe5O12 (YIG) and Bi-doped YIG, 23Na2O-xBi2O3-(12−x)Y2O3-25Fe2O3-20SiO2-20GeO2 (mol%), are developed, and the laser-induced crystallization technique is applied to the glasses to pattern YIG and Bi-doped YIG crystals on the glass surface. It is clarified from the Mössbauer effect measurements that iron ions in the glasses are present mainly as Fe3+. It is suggested from the X-ray diffraction analyses and magnetization measurements that Si4+ ions are incorporated into YIG crystals formed in the crystallization of glasses. The irradiations (laser power: 32-60 mW and laser scanning speed: 7 μm/s) of continuous wave Yb:YVO4 fiber laser (wavelength: 1080 nm) are found to induce YIG and Bi-doped YIG crystals, indicating that Fe3+ ions in the glasses act as suitable transition metal ions for the laser-induced crystallization. It is suggested that YIG and Bi-doped YIG crystals in the laser irradiated part might orient. The present study will be a first step for the patterning of magnetic crystals containing iron ions in glasses. 相似文献
5.
K. Sadhana 《Journal of magnetism and magnetic materials》2010,322(23):3729-3736
The nanocrystalline Ni0.53Cu0.12Zn0.35Fe1.88O4 and BaTiO3 powders were prepared using Microwave-Hydrothermal (M-H) method at 160 °C/45 min. The as synthesized powders were characterized using the X-ray diffraction (XRD) and Transmission Electron Microscope (TEM). The size of the powders that were synthesized using M-H system was found to be ∼30 and ∼50 nm for ferrite phase and ferroelectric phases, respectively. The powders were densified using microwave sintering method at 900 °C/30 min. The ferrite and ferroelectric phases were observed from XRD and morphology of the composites was observed with the Scanning Electron Microscope (SEM).The magnetic hysteresis loops were recorded using the Vibrating Sample Magnetometer (VSM).The frequency dependence of real (μ′) and imaginary (μ″) parts of permeability was measured in the range of 1 MHz-1.8 GHz. The permeability decreases with an increase of BaTiO3 content at 1 MHz. The transition temperature (TC) of ferrite was found to be 245 °C. The TC of composite materials decreases with an increase in BaTiO3 content. 相似文献
6.
M.I. KobetsK.G. Dergachev E.N. Khatsko S.L. GnatchenkoL.N. Bezmaternykh V.L. Temerov 《Physica B: Condensed Matter》2011,406(18):3430-3435
The AFMR spectra of the NdFe3(BO3)4 crystal are measured in a wide range of frequencies and temperatures. It is found that by the type of its magnetic anisotropy the compound is an “easy-plane” antiferromagnet with a weak anisotropy in the basal plane. The effective magnetic parameters are determined: anisotropy fields Ha1=1.14 kOe and Ha2=60 kOe and magnetic excitation gaps Δν1=101.9 GHz and Δν2=23.8 GHz. It is shown that commensurate-incommensurate phase transition causes a shift in resonance field and a considerable change in absorption line width.At temperatures below 4.2 K nonlinear regimes of AFMR excitation at low microwave power levels are observed. 相似文献
7.
Passively Q-switched c-cut Nd:Gd0.63Y0.37VO4 laser performance at 1.06 μm was demonstrated with Cr4+:YAG as saturable absorbers for the first time to our knowledge. This c-cut mixed crystal was found to have large energy storage capacity. The shortest pulse width, largest pulse energy, and highest peak power were obtained to be 6.6 ns, 201.7 μJ, and 30.6 kW, respectively. 相似文献
8.
M. Uehara T. Yamazaki T. Kashida K. Ohishi 《Journal of Physics and Chemistry of Solids》2007,68(11):2178-2182
The magnetic phase diagram for Mg1−xZnxCyNi3 has been tentatively constructed based on magnetization and muon spin relaxation (μSR) measurements. The superconducting phase was observed to fade as x (y) increases (decreases). The low y samples show early stages of long-range ferromagnetism, or complete long-range ferromagnetism. In the phase diagram, the ferromagnetic phase exists in addition to the superconducting phase, suggesting that there is some correlation between superconductivity and ferromagnetism, even though the coexistence of ferromagnetism and superconductivity is not observed from the μSR measurements down to 20 mK for the superconducting sample (Tc=2.5 K, (x, y)=(0, 0.9)). 相似文献
9.
Ytterbium tri-fluoromethanesulfonate (YbTFMS) single crystals are prepared from the slow evaporation of the aqueous solution of YbTFMS and the principal magnetic susceptibility perpendicular to the c-axis of the hexagonal crystal (χ⊥) is measured from 300 K down to 13 K. Principal magnetic anisotropy Δχ(=χ∥−χ⊥) is measured from 300 K down to 80 K which provides principal magnetic susceptibility parallel to the c-axis (χ∥) down to 80 K. Very good theoretical simulation of the observed magnetic properties of YbTFMS has been obtained using one electron crystal field (CF) analysis having C3h site symmetry. No signature of ordering effect in the observed magnetic data is noticed down to the lowest temperature (13 K) attained, indicating the inter-ionic interaction to be of predominantly dipolar type. The calculated g-values are found to be g∥=2.67 and g⊥=2.51, respectively. CF analysis provides the electronic specific heat which gives two Schottky anomalies in its thermal variation down to ∼13 K. The temperature dependences of quadrupole splitting and hyperfine heat capacity are studied from the necessary information obtained from the CF analysis. 相似文献
10.
R. Ortega-Zempoalteca R. Valenzuela 《Journal of magnetism and magnetic materials》2009,321(19):3159-3163
The thermomagnetic behaviour (within the temperature range 553-300 K) for the bulk composite Nd60Fe30Al10 alloy is described in terms of a transition from paramagnetic to superferromagnetic state at T=553 K, followed by a ferromagnetic ordering for T<473 K. For the superferromagnetic regime, the alloy thermomagnetic response was associated to a homogeneous distribution of magnetic clusters with mean magnetic moment and size of 1072 μB and 2.5 nm, respectively. For T<473 K, a pinning model of domain walls described properly the alloy coercivity dependence with temperature, from which the domain wall width and the magnetic anisotropy constant were estimated as being of ≈8 nm and ≈105 J/m3, typical values of hard magnetic phases. Results are supported by microstructural and magnetic domain observations. 相似文献
11.
I.M. Siouris R.K. KremerM. Hoelzel 《Journal of magnetism and magnetic materials》2011,323(22):2903-2911
The magnetic properties of the intermetallic compound Dy2CuIn3 have been investigated. Ac and dc-susceptibility measurements indicate an onset of antiferromagnetic ordering at TN=19.5 K and an additional frequency dependent transition at Tds∼9 K. Neutron diffraction studies confirm the ordered transition at 19.5±1 K. The magnetic unit cell can be described by the propagation vector k=(0.25,0.25,0) with the magnetic moment μ=2.63(4)μB/Dy3+ parallel to the c-axis. Nevertheless, neutron diffraction reveals no additional magnetic phase transition around or below 9 K, which suggests that, at lower temperatures, a spin glass state may be formed in coexistence with the antiferromagnetic mode as a result of frustration and the antagonism between ferromagnetic and antiferromagnetic exchange interactions. 相似文献
12.
The Sm2Co17-based intermetallic films with additives of Fe, Cu, and Zr have been deposited on Si(1 0 0) substrates by dc magnetron sputtering process. Subsequent thermal treatment and the film thickness are found to have significant contribution to the crystal structure and grain structure, which determines the magnetization reversal process and intrinsic coercivity (HC) of these films. The conventional thermal annealing (CTA) treatment almost failed to crystallize the as-deposited films, leading to a very low HC. Continuous and homogeneous domain walls cannot form in this deteriorated microstructure, so that the pinning mechanism can be excluded. Contrarily, the films with thickness exceeding 0.8 μm treated by rapid recurrent thermal annealing (RRTA) show an improved HC, which is attributed to the observed completed crystallization and compact microstructure. It is suggested that this film structure is responsible for providing continuous and homogeneous domain walls, leading to a magnetization reversal process controlled by domain wall pinning model. In special, the HC of the RRTA-treated film with thickness of 1.8 μm shows a good temperature dependence from 25 to 300 °C, with intrinsic coercivity temperature coefficient β of −0.23%/°C. 相似文献
13.
Electronic and magnetic properties of the bulk Co2Ti1−xFexGa Heusler alloys and Co2Ti0.5Fe0.5Ga (0 0 1) surfaces are studied within the framework of density functional theory using the augmented plane wave plus local orbital (APW+lo) approach. It will be shown that all alloys have the spin polarization of the ideal 100% value except the Co2FeGa alloy with spin polarization about 98%. Co2Ti0.5Fe0.5Ga is an example that is stable against the effects destroying the half-metallicity due to the position of the Fermi energy (EF) in the middle of the minority band gap. The phase diagram obtained by ab-initio atomistic thermodynamics shows that in the higher limit of μGa three surfaces of FeGa, TiGa and TiFeGa are accessible in the Co2Ti0.5Fe0.5Ga alloy but on decreasing μGa, the accessible region gradually moves towards FeGa termination. It is discussed that, at the ideal surfaces, half-metallicity of the alloy is lost, although the TiGa surface keeps high spin polarization (about 95%). 相似文献
14.
Bai-yang Zhou De-hui LeiSi-he Chen Han-bin Luo 《Journal of magnetism and magnetic materials》2011,323(17):2243-2247
Giant magnetostrictive SmFe2/Fe exchange-coupled multilayers were fabricated by ion beam sputtering deposition on glass substrates. The effects of SmFe2/Fe exchange coupling action and vacuum annealing on soft-magnetic property and static-dynamic magnetostrictive characteristics of SmFe2/Fe multilayers were investigated. The results showed that the soft-magnetic, static-dynamic magnetostrictive characteristics were greatly improved by SmFe2/Fe exchange coupling action and proper vacuum annealing treatment temperature. Compared with that of SmFe2 single film, the coercivity in the direction of easy magnetization axis for SmFe2/Fe exchange-coupled multilayers exhibited a greater decrease. Better soft-magnetic properties were achieved (Hc=2.54 kA/m, Ms=120.38 emu/g, and Mr/Ms=0.21) after vacuum annealing at certain temperature. The magnetostrictive coefficient for SmFe2/Fe exchange-coupled multilayers was about 135 ppm at 16 kA/m magnetic field. At first order resonant frequency (99.2 Hz), the amplitude peak-peak value for the as-deposited SmFe2/Fe exchange-coupled multilayers was 46 μm. After the vacuum annealing treatment at 250 °C, the amplitude peak-peak value increased to 650 μm. 相似文献
15.
The Gd60Co26Al6Ge8 alloy has been prepared by the copper-mold suck-casting and its phase component has been investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy-dispersive spectroscopy (EDS). It is shown that this alloy consists of primary crystalline Gd5Ge3 phase and amorphous matrix. The glass transition temperature (Tg) and crystallization temperatures (Tx) occur at 292 and 320 °C, respectively. The maximal magnetic entropy change (ΔSM) under 0-5 T field is about 7.6 J (kg−1 K−1) at 155 K and the refrigeration capacity (RC) is about 768 J kg−1, which makes Gd60Co26Al6Ge8 bulk metallic glass matrix composite a promising candidate for magnetic refrigerant. 相似文献
16.
The hydrothermal synthesis and magnetic entropy change for the perovskite manganite La0.5Ca0.3Sr0.2MnO3 have been studied. The La0.5Ca0.3Sr0.2MnO3 can be produced as phase-pure, crystalline powders in one step from solutions of metal salts in aqueous potassium hydroxide solution at a temperature of 513 K in 72 h. Scanning electron microscopy shows that the materials are made up of cuboid-shaped particles in typical dimension of 4.0×2.5×1.6 μm. Heat treatment can improve the magnetocaloric effect for the hydrothermal sample. The maximum magnetic entropy change ΔSM for the as-prepared sample is 0.88 J kg−1 K−1 at 315 K for a magnetic field change of 2.0 T. It increases to 1.52 J kg−1 K−1, near its Curie temperature (317 K) by annealing the sample at 1473 K for 6 h. The hydrothermal synthesis method is a feasible route to prepare high-quality perovskite material for magnetic refrigeration application. 相似文献
17.
A new series Nd:Lu3ScxGa5 − xO12 (x = 0.5, 0.8, 1, 1.2 and 1.5) laser crystals have been successfully grown by the optical floating zone method. Their absorption and luminescence spectra were measured at room temperature and spectral parameters were systemically calculated using Judd-Ofelt (JO) theory. The fluorescence τf lifetimes were experimentally measured and compared with the theoretical results. Diode-pumped continuous-wave (CW) laser performance at 1.06 μm with mixed crystals was demonstrated. The influence of different x values on laser performance and spectral parameters was also discussed. All the results show that Nd:Lu3ScxGa5 − xO12 series crystals should be suitable for laser application. 相似文献
18.
Ying-Fei Zhang Zhi-Hui Kang Yun Jiang Yury M. Andreev Konstantin A. Kokh Anna V. Shaiduko 《Optics Communications》2011,284(6):1677-1681
We report a systematic study of AgGaS2- and Al-doped GaSe crystals in comparison with pure GaSe and S-doped GaSe crystals. AgGaS2-doped GaSe (GaSe:AgGaS2) crystal was grown by Bridgman technique from the melt of GaSe:AgGaS2 (10.6 wt.%). Its real composition was identified as GaSe:S (2 wt.%). Al-doped GaSe (GaSe:Al) crystals were grown from the melt of GaSe and 0.01, 0.05, 0.1, 0.5, 1, 2 mass % of aluminium. Al content in the grown crystals is too small to be measured. The hardness of GaSe:S (2 wt.%) crystal grown from the melt of GaSe:AgGaS2 is 25% higher than that of GaSe:S (2 wt.%) crystal grown by a conventional S-doping technique and 1.5- to 1.9-times higher than that of pure GaSe. GaSe:Al crystals are characterized by 2.5- to 3-times higher hardness than that of pure GaSe and by extremely low conductivity of ≤ 10− 7 Om− 1 cm− 1. A comparative experiment on SHG in AgGaS2-, Al-, S-doped GaSe and pure GaSe is carried out under the pumps of 2.12-2.9 μm fs OPA and 9.2−10.8 μm ns CO2 laser. It was found that GaSe:S crystals possess the best physical properties for mid-IR applications among these doped GaSe crystals. GaSe:Al crystals have relatively low conductivity which have strong potential for THz application. 相似文献
19.
From crystalline V2O5 to nanostructured vanadium oxides using aromatic amines as templates 总被引:1,自引:0,他引:1
Nanoneedles, nanorods of B-VO2, and vanadium oxide nanotubes with high crystallinity were synthesized via a one-step hydrothermal treatment using crystalline V2O5 as a precursor and aromatic amines (C6H5-(CH2)n-NH2 with n=0, 1, 3) as structure-directing templates. Samples were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray powder diffraction (XRD), thermal analysis, nitrogen adsorption/desorption isotherms and infrared spectroscopy. Nanoneedles, 0.5-5 μm in length and about 50 nm in average diameter and VO2(B) nanorods about 20-100 nm wide and up to 2.5 μm long, have been obtained. The inner and the outer diameters of the vanadium oxide nanotubes vary, respectively, between 15-25 and 70-100 nm with a length up to 4 μm. 相似文献
20.
Xing Li Changtai Xia Guangqing Pei Xiaoli He 《Journal of Physics and Chemistry of Solids》2007,68(10):1836-1840
Observation of room-temperature ferromagnetism in Fe- and Ni-co-doped In2O3 samples (In0.9Fe0.1−xNix)2O3 (0?x?0.1) prepared by citric acid sol-gel auto-igniting method is reported. All of the samples with intermediate x values are ferromagnetic at room-temperature. The highest saturation magnetization (0.453 μB/Fe+Ni ions) moment is reached in the sample with x=0.04. The highest solubility of Fe and Ni ions in the In2O3 lattice is around 10 and 4 at%, respectively. The 10 at% Fe-doped sample is found to be weakly ferromagnetic, while the 10 at% Ni-doped sample is paramagnetic. Extensive structure including Extended X-ray absorption fine structure (EXAFS), magnetic and magneto-transport including Hall effects studies on the samples indicate the observed ferromagnetism is intrinsic rather than from the secondary impurity phases. 相似文献