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1.
Comparison of Properties of Carbon Particles Formed by Pyrolysis of C3O2 and C2H2 behind Shock Waves
Various carbon particles formed by the pyrolysis of C3O2 and C2H2 behind shock waves in the temperature range 1200–3800 K are studied. The formation of the condensed carbon particles is observed directly by the multichannel detection of the time profiles of the extinction of the medium in the UV, visible, and near-IR spectral regions. The samples of carbon material deposited on the walls of a shock tube after an experiment are analyzed using transmission electron microscopy with different resolutions and electron microdiffraction. Particles formed from C3O2 and C2H2 at 1500–2000 K are 10–30 nm in size and look like usual soot. The absence of molecular hydrogen in C3O2 only results in faster formation and graphitization. At 2100–2600 K, the formation of particles is retarded, and the yield of the carbon particles decreases for both substances. After experiments on pyrolysis of C3O2 at these temperatures, giant spherical particles up to 700 nm in size are found on the walls of the shock tube. Carbon particles formed at the highest temperatures (2700–3200 K) in C3O2 pyrolysis have the high degree of crystallinity of particles. 相似文献
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碳前驱体CH3ArCH2NH2的热解性能及动力学研究 总被引:2,自引:1,他引:2
通过密闭压力容器法、常压DSC、高压DSC及紫外分光光度定量分析法等实验手段,对液相沉积法制碳/碳复合材料用碳前驱体CH3ArCH2NH2的热裂解行为进行了研究,获得不同温度、不同压力下该碳前驱体的热分解温度和残碳率,用等温动力学和非等温动力学方法获得了热裂解反应的表观活化能,实验结果表明,常压热裂解温度大约为530.15-556.55K,1-3MPa的高压范围内的热裂解温度大约在618.34-675.49K,密闭压力容器中的残碳率为56.23%,常压下的残碳率为28.96%-36.47%,而高压下残碳率可达59.11%,根据基辛格等方法获得了等温条件下和非等温条件下热裂解反应的表观活化能Ea分别为206.78kJ/mol和183.93kJ/mol, 反应级数N~1. 相似文献
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The kinetics of the synthesis of YBa2Cu3O7-y (YBCO) was studied in situ on an X-ray diffractometer using the time vs temperature dependences of the concentration of the phase. The highest rate of YBCO synthesis was observed at 750-780°C. The effective activation energy was minimal at 700°C, E
a = 20-30 kJ/mole. The structural nonhomogeneity parameters and the dimensions of coherent scattering regions were determined for the YBCO product. 相似文献
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碳前驱体CH3ArCH2NH2热解反应的热力学和动力学DFT研究 总被引:1,自引:0,他引:1
在实验研究基础上 ,通过量子化学理论计算对碳前驱体 CH3 Ar CH2 NH2 的热裂解机理作了进一步的研究 .利用 Gaussian98程序包中 AM1方法及 DFT UB3 LYP/3 -2 1 G*方法 ,对化合物 5种可能热裂解路径的热力学和动力学计算结果表明 ,CH3 Ar CH2 NH2 热裂解的主反应路径为生成自由基 CH3 Ar CH2 ·和 NH2 · ,其主反应路径 AM1计算的活化能 Ea=2 3 0 .78k J/mol,DFT计算的活化能 Ea=3 2 1 .1 8k J/mol;比较键焓计算的数据与相应的实验数据 ,发现 DFT计算结果与实验结果吻合得较好 ;通过分析优化的反应物及产物自由基的部分结构参数 ,了解了理论支持主反应的原因 ;计算的产物自由基的空间构型表明主反应路径生成的产物自由基相互间若进行稠环缩合反应 ,将获得分子平面取向性很好的稠环芳烃产物 相似文献
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L. Pandolfo G. Paiaro . Somogyi S. Catinella P. Traldi 《Journal of mass spectrometry : JMS》1994,29(10):540-546
The gas-phase, ion molecule reaction between C3O2+. and C3O2 has been studied by both double-focusing and ion trap mass spectrometry, rationalized by the formation of a dimeric, odd electron cation [C6O4]+. which decomposes extensively through sequential CO losses giving rise to [C5O3]+. and [C4O2]+. ions. The thermodynamics of this process have been investigated by means of ab initio calculation performed on the above species using different basis sets (STO-3G, 3-21G and 6-31G*). 相似文献
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Carbon suboxide, C3O2, is crystallized from the melt. According to the X‐ray structure determination the crystal contains two non‐crystallographically equivalent molecules in the asymmetric unit: a = 986.9(2), b = 1206.0(2), c = 516.0(1) pm, space group Pnma. Both molecules are linear. A close inspection of the vibrational amplitudes indicates some systematic deviations from linearity. 相似文献
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Thethermolysisofpyruvicacid2Ieadstotheeliminationofcarbondioxideandacetaldehydeisformedasanotherproduct.Hong'hasstudiedthemechanismofthereactionintheMINDO/3molecularorbitaltheory.Al-AwadiandEL-Dusouqui'havestudiedthepyrolysisofthe3-hydroxy-3-methyl-2-butanoneinordertoexaminetheinfluenceofthehydrogenatominvolvedintheTransitionStateoftheeliminationprocessandtoassessitscontributiontotherate-controllingstep.TheygaveoutthethermalrateconstantsandhypothesizedthatthereactionmightproceedthroughafO… 相似文献
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对较小碳原子簇负离子C-n结构的研究是从直链向单环乃至双环构型发展的.氢原子在碳原子簇中起着电子给予体的作用[1,2].但以往的研究未发现碳原子数的奇偶性和氢原子数目对簇离子构型的影响.我们以激光溅射氘代蒽样品,产生了丰富的碳/氢团簇负离子CnD-m... 相似文献
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Conclusions Various fluorosulfatozirconates and fluorozirconates were crystallized, some for the first time, from solutions of the ZrO2-SO3-H2O system upon the introduction of KF.Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 967–972, May, 1982. 相似文献
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The formation of carbon filaments with different crystallographic and morphological characteristics in the course of 1,3-butadiene decomposition on Fe/Al2O3 catalysts at low (500–600°C) and high (700–800°C) temperatures was considered in terms of a carbide cycle mechanism. The conditions of formation and decomposition of an iron carbide phase in the course of formation of graphite nanotubes in the low-temperature region were studied. 相似文献
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E. Ingier-Stocka 《Journal of Thermal Analysis and Calorimetry》1997,50(4):603-616
The thermal decomposition of [Co(NH3)6]2(C2O4)3·4H2O was studied under isothermal conditions in flowing air and argon. Dissociation of the above complex occurs in three stages. The kinetics of the particular stages thermal decomposition have been evaluated. The RN and/or AM models were selected as those best fitting the experimental TG curves. The activation energies,E, and lnA were calculated with a conventional procedure and by a new method suggested by Kogaet al. [10, 11]. Comparison of the results have showed that the Arrhenius parameters values estimated by the use of both methods are very close. The calculated activation energies were in air: 96 kJ mol–1 (R1.575, stage I); 101 kJ mol–1 (Ain1.725 stage II); 185 kJ mol–1 (A
2.9, stage III) and in argon: 66 kJ mol–1 (A
1.25, stage I); 87 kJ mol–1 (A
1.825, stage II); 133 kJ mol–1 (A
2.525, stage III). 相似文献
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Zvereva I. A. Popova V. F. Missyul' A. V. Toikka A. M. Gusarov V. V. 《Russian Journal of General Chemistry》2003,73(5):684-688
Studies on phase formation in the system Gd2O3-SrO-Al2O3 in the range 900-1530°C showed that the synthesis of Gd2SrAl2O7 occur by a mechanism differing from the mechanism of Ln2SrAl2O7 formation (Ln = La, Nd, Sm), and the limiting stage is reaction between Gd2O3 and SrAl2O4. 相似文献
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通过密闭压力容器法、常压DSC、高压DSC及紫外分光光度定量分析法等实验手段,对液相沉积法制碳/碳复合材料用碳前驱体CH 相似文献
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I. A. Zvereva V. F. Popova N. S. Pylkina V. V. Gusarov 《Russian Journal of General Chemistry》2003,73(1):43-47
Phase formation in the Ln2O3-SrO-Al2O3 system (Ln = Nd, Sm) was studied in the range 900-1530°C. Comparative examination of the kinetics of the synthesis of Ln2SrAl2O7 oxides (Ln = La, Nd, Sm) showed that this reaction proceeds by a common mechanism and is substantially faster for neodymium and samarium complex aluminates than for lanthanum aluminate. 相似文献